CN106867608A - A kind of methane-desulfurizing device - Google Patents

A kind of methane-desulfurizing device Download PDF

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Publication number
CN106867608A
CN106867608A CN201710231633.7A CN201710231633A CN106867608A CN 106867608 A CN106867608 A CN 106867608A CN 201710231633 A CN201710231633 A CN 201710231633A CN 106867608 A CN106867608 A CN 106867608A
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China
Prior art keywords
nutrient solution
zoneofoxidation
gas
oxidation
spray equipment
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CN201710231633.7A
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Chinese (zh)
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万玉山
庄伟�
温馨
沈梦
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Changzhou University
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Changzhou University
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/95Specific microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)

Abstract

A kind of methane-desulfurizing device, gas scrubbing zoneofoxidation, biological oxidation uptake zone is followed successively by from bottom of device, except fog-zone, charcoal absorption area and exhaust fan upwards;Gas scrubbing zoneofoxidation is provided with washing oxidation solution spray equipment, and the bottom for washing oxidation solution spray equipment is provided with air inlet pipe, gas distribution pipe, water collection sheet and air deflector;The bottom of air deflector is provided with air aeration disk;The side wall of gas scrubbing zoneofoxidation is provided with air outlet;The lower outside of air outlet is provided with washing oxidation solution precipitate and separate groove;The tapered structure of gas scrubbing zoneofoxidation bottom design, drain valve is provided with pyramidal structure bottom;Biological oxidation uptake zone is provided with nutrient solution spray equipment, filler, nutrient solution and stores groove and nutrient solution circulating pump, and the cross section that nutrient solution stores groove is circle, and nutrient solution stores groove top and is provided with spray liquid aggregation apparatus;Except the demister that fog-zone is provided with is deflection plate demister or overflowing board demister.

Description

A kind of methane-desulfurizing device
Technical field
The present invention relates to technical field of atmospheric pollution control, especially a kind of methane-desulfurizing device.
Background technology
Biogas is a kind of high-grade clean energy resource, is widely used and is conducive to improving the quality of living.The composition of biogas into It is methane, carbon dioxide to divide, and other also contain a small amount of hydrogen sulfide, carbon monoxide, ammonia, hydrogen etc..Hydrogen sulfide master in biogas Come from the degradation process of protein and other sulfur-containing compounds, the difference that content is originated with anaerobic fermentation product and become Change.Hydrogen sulfide in biogas not only can serious harm health, corrode the cement and steel construction of biogas plant, can also damage transmission Pipeline, shortens the service life of cogeneration unit motor, and triggers the rotten so as to the infringement of acceleration motor of lubricating oil.Natural pond Gas forms acid rain by after burning, hydrogen sulfide can be converted into oxysulfide, be emitted into air, pollutes environment.Therefore, biogas Before being used as clean energy resource, it is necessary to remove hydrogen sulfide therein.
At present, common biogas desulfurization method includes dry desulfurization, wet desulphurization and biological desulphurization.Dry desulfurization is adapted to place Reason H2The low biogas of S contents, is by H therein by the physics chemical action of solid absorbent2S is removed, and its shortcoming has desulfurization to imitate Rate is unstable, and the easy saturation of desulfurizing agent, sulfur capacity is low, needs periodic replacement, and operating cost is high and easily causes secondary pollution.Wet desulphurization It is adapted to treatment H2The biogas that S contents are high or flow is big, is by H therein by liquid-absorbant2S is removed, and engineer applied is wider, Its shortcoming is big liquid-absorbant consumption, H2S removal efficiency is low compared with dry method, and operating difficulties.Biological desulphurization is using work Sulfur-oxidizing bacteria in property desulfurization sludge is by the H in biogas2S gets rid of by biological oxidation process, while being microorganism itself Growth metabolism provide needed for energy, product is usually elemental sulfur or sulfate radical.Compared to dry and wet desulfurization, advantage is bright It is aobvious, mainly there is technological process to be simple and convenient to operate, process is easy to control, the low advantage of cost of investment.
Large-scale promotion of the rare biological desulfurizing technology of current China in engineering, main cause one is by desulfurization microorganism The limitation of efficient amplification research, two is that the research and development of efficiency high, economical and practical biological desulfurizing technology and equipment are less.
The content of the invention
The technical problem to be solved in the present invention is:Overcome prior art device complex structure, cumbersome, processing cost compared with Problem high, there is provided a kind of methane-desulfurizing device, simple structure is easy to operate.
The technical solution adopted for the present invention to solve the technical problems is:A kind of methane-desulfurizing device, from bottom of device to On be followed successively by gas scrubbing zoneofoxidation, biological oxidation uptake zone, except fog-zone, charcoal absorption area and exhaust fan.
Described gas scrubbing zoneofoxidation is located at the foot of whole device;Described gas scrubbing zoneofoxidation is provided with washing Oxidation solution spray equipment, described washing oxidation solution spray equipment is helical form spray equipment;The liquid for ejecting is presented vaporific, And mixing together between water smoke, dead angle is not stayed, be conducive to the contact area of enlargement gas and solution, improve absorptivity and absorb and imitate Really;The bottom for washing oxidation solution spray equipment is provided with air inlet pipe and gas distribution pipe;The bottom of gas distribution pipe is provided with water collection sheet, water collection sheet It is the air deflector that circular vertical section is rhombus that bottom is provided with cross section;The bottom of air deflector is provided with air aeration disk, air aeration Disk is the pore type aeration plate for being evenly arranged with micropore, and described air aeration disk is connected with gas scrubbing zoneofoxidation by pipeline Outer air-blaster;The side wall of gas scrubbing zoneofoxidation is provided with air outlet;The lower outside of air outlet is provided with Washing oxidation solution precipitate and separate groove;Described washing oxidation solution spray equipment is connected with outside gas scrubbing zoneofoxidation by pipeline Washing oxidation solution circulating pump, described washing oxidation solution circulating pump is connected with washing oxidation solution adding set and washing by pipeline Oxidation solution precipitate and separate groove;The tapered structure of gas scrubbing zoneofoxidation bottom design, drain valve is provided with pyramidal structure bottom.
Described biological oxidation uptake zone is provided with gas oxidation absorbent assembly, and described gas oxidation absorbent assembly includes battalion Nutrient solution spray equipment, dry load, nutrient solution store groove and the nutrient solution that stores nutrient solution in groove pumps into nutrient solution spray dress The nutrient solution circulating pump put.Described nutrient solution spray equipment is helical form spray equipment;The liquid for ejecting is presented vaporific, and Mixing together between water smoke, does not stay dead angle, is conducive to the contact area of enlargement gas and solution, improves absorptivity and absorbs and imitates Really.The cross section that described nutrient solution stores groove is circle, and nutrient solution stores groove top and is provided with spray liquid aggregation apparatus, described The lower end diameter of spray liquid aggregation apparatus stores the diameter of groove topmost less than nutrient solution.Spray liquid aggregation apparatus can make spray liquid Aggregation is back to nutrient solution and stores groove.Described gas oxidation absorbent assembly is also equipped with nutrient solution addition and tapping equipment, described Nutrient solution addition and tapping equipment include nutrient tank and agitating device, nutrient solution addition and tapping equipment pass through pipeline and valve Door connection nutrient solution circulating pump.The dry load is inorganic inert filler, and there is inorganic inert filler unit volume filler to give birth to The advantages of thing amount is big, operating mode is easy to control, energy consumption is low, metabolite can be flushed away with circulated sprinkling, the dry load is using more Face hollow ball or other are polyhedron-shaped.
Described biological adsorption area top is provided with except fog-zone, and except fog-zone is provided with demister, demister is will be big in gas Drop is collected, and is allowed to return, and reduces the moisture in gas, and its operation principle is that gas enters demister, is by one Row bend, from top discharge, and water droplet is due to the effect of its quality and kinetic energy, and when by racetrack portion, straight line falls, and collides The surface of demister, and rebounded under to Action of Gravity Field.Described demister is deflection plate demister or overflowing board demister.
It is described that activated carbon is set in described charcoal absorption area except fog-zone top is provided with charcoal absorption area, activity Charcoal requirement have the advantages that hole prosperity, specific surface area is big, adsorption rate is fast, friction resistant, resistance to flushing, as by the long period Operation, it is found that activated carbon becomes sticky, and just needs to change activated carbon in time during gas velocity reduction.
For cylinder, upper and lower ends are conical tank body in the middle of described methane-desulfurizing device, offered on the tank body Observation port and maintenance replacement port, tank body volume size can according to pending gas flow number depending on, using vertical vertical placement.
For ease of the clean gas discharge for having processed, installed at the conical tank body of described methane-desulfurizing device topmost There is exhaust fan.
The beneficial effects of the invention are as follows biogas is initially entered in gas scrubbing zoneofoxidation, and washing oxidation solution is washed from uniform The ejection of oxidation solution spray equipment is washed, countless fine mists are formed, is sufficiently mixed with gas after contacting, the H in biogas2S is absorbed In oxidation solution is washed;Air aeration disk is aerated, and the activated sludge rich in sulfur oxidizing bacterium in gas scrubbing zoneofoxidation will Sulfide-oxidation is sulphur simple substance or sulfate, and oxidation product is emitted by drain valve;Washing oxidation solution is by washing oxygen Change liquid precipitate separating tank and washing oxidation solution circulating pump enters washing oxidation solution spray equipment, recycle;Gas is ascended into Biological oxidation uptake zone, the microorganism on dry load is using the nutriment and a small amount of H in nutrient solution2It is numerous that S carries out itself Grow, nutrient solution inflow bottom nutrient solution is stored in groove, nutrient solution enters nutrient solution and sprays dress by pipeline and nutrient solution circulating pump Put, recycle;Gas continues rising and is contacted with the nutrient solution of nutrient solution spray equipment ejection, H2S is further absorbed simultaneously Biological oxidation uptake zone is returned to nutrient solution;Subsequently into except fog-zone, the drop in gas is blocked gas herein;Connect Gas into charcoal absorption area, the material being mingled with gas and drop are intercepted absorb herein, so far gas It is processed into the biogas of cleaning.
Brief description of the drawings
The present invention is further described with reference to the accompanying drawings and examples.
Fig. 1 is the structural representation of embodiments of the invention;
In figure:1. gas scrubbing zoneofoxidation, 1-1. washing oxidation solution spray equipments, 1-2. air inlet pipe, 1-3. gas distribution pipes, 1- 4. water collection sheet, 1-5. air deflectors, 1-6. air aeration disks, 1-7. air-blasters, 1-8. air outlets, 1-9. washing oxidations Liquid precipitate separating tank, 1-10. washing oxidation solution circulating pumps, 1-11. washing oxidation solution adding sets, 1-12. drain valves are 2. biological Oxidative absorption area, 2-1. nutrient solution spray equipments, 2-2. dry loads, 2-3. nutrient solutions store groove, 2-4. nutrient solution circulating pumps, 2-5. spray liquid aggregation apparatus, the addition of 2-6. nutrient solutions and tapping equipment, 3. remove fog-zone, 4. charcoal absorption area, 5. exhaust fan.
Specific embodiment
In conjunction with the accompanying drawings, the present invention is further explained in detail.These accompanying drawings are simplified schematic diagram, only with Illustration illustrates basic structure of the invention, therefore it only shows the composition relevant with the present invention.
Embodiment
Of the invention a kind of methane-desulfurizing device as shown in Figure 1, gas scrubbing oxidation is followed successively by from bottom of device upwards Area 1, biological oxidation uptake zone 2, except fog-zone 3, charcoal absorption area 4 and exhaust fan 5.
Described gas scrubbing zoneofoxidation 1 is located at the foot of whole device;Described gas scrubbing zoneofoxidation is provided with washes Oxidation solution spray equipment 1-1 is washed, described washing oxidation solution spray equipment is helical form spray equipment;The liquid for ejecting is presented It is vaporific, and mixing together between water smoke, do not stay dead angle, be conducive to the contact area of enlargement gas and solution, improve absorptivity and Assimilation effect;The bottom for washing oxidation solution spray equipment is provided with air inlet pipe 1-2 and gas distribution pipe 1-3;The bottom of gas distribution pipe 1-3 is provided with Water collection sheet 1-4, it is the air deflector 1-5 that circular vertical section is rhombus that the bottom of water collection sheet is provided with cross section;The bottom of air deflector 1-5 Air aeration disk 1-6 is provided with, air aeration disk 1-6 is the pore type aeration plate for being evenly arranged with micropore, described air aeration Disk 1-6 is connected with the air-blaster 1-7 outside gas scrubbing zoneofoxidation by pipeline;The side wall of gas scrubbing zoneofoxidation is provided with Air outlet 1-8;The lower outside of air outlet is provided with washing oxidation solution precipitate and separate groove 1-9;Described washing oxidation Liquid spray equipment 1-1 is connected with the washing oxidation solution circulating pump 1-10 outside gas scrubbing zoneofoxidation, described washing by pipeline Oxidation solution circulating pump 1-10 is connected with washing oxidation solution adding set 1-11 and washing oxidation solution precipitate and separate groove 1- by pipeline 9;The tapered structure of gas scrubbing zoneofoxidation bottom design, drain valve 1-12 is provided with pyramidal structure bottom.
Described biological oxidation uptake zone 2 is provided with gas oxidation absorbent assembly, and described gas oxidation absorbent assembly includes Nutrient solution spray equipment 2-1, dry load 2-2, nutrient solution store groove 2-3 and the nutrient solution that stores nutrient solution in groove pumps into battalion The nutrient solution circulating pump 2-4 of nutrient solution spray equipment.Described nutrient solution spray equipment 2-1 is helical form spray equipment;Eject Liquid vaporific, and mixing together between water smoke is presented, do not stay dead angle, be conducive to the contact area of enlargement gas and solution, carry High-absorbility and assimilation effect.The cross section that described nutrient solution stores groove 2-3 is circle, and nutrient solution stores groove top and is provided with spray Liquid aggregation apparatus 2-5 is drenched, the lower end diameter of described spray liquid aggregation apparatus stores the diameter of groove topmost less than nutrient solution, sprayed Drench liquid aggregation apparatus and can assemble spray liquid and be back to nutrient solution and store groove.Described gas oxidation absorbent assembly is also equipped with nutrition Liquid is added and tapping equipment 2-6, described nutrient solution addition and tapping equipment 2-6 include nutrient tank and agitating device, nutrition Liquid addition connects nutrient solution circulating pump 2-4 with valve with tapping equipment 2-6 by pipeline.The dry load 2-2 is inorganic lazy Property filler, inorganic inert filler has that unit volume filler biological amount is big, operating mode is easy to control, energy consumption is low, metabolite can be with following Ring spray is drenched the advantages of be flushed away, and the dry load 2-2 is using polyhedron empty ball or other are polyhedron-shaped.
Described biological adsorption area top is provided with except fog-zone 3, and except fog-zone 3 is provided with demister, demister is by gas Big drop is collected, and is allowed to return, and reduces the moisture in gas, and its operation principle is that gas enters demister, by one Serial bend, from top discharge, and water droplet is due to the effect of its quality and kinetic energy, and when by racetrack portion, straight line falls, punching The surface of demister is hit, and is rebounded under to Action of Gravity Field.Described demister is deflection plate demister or overflowing board demister.
It is described to be provided with activated carbon in described charcoal absorption area 4 except fog-zone top is provided with charcoal absorption area 4, Activated carbon requirement have the advantages that hole prosperity, specific surface area is big, adsorption rate is fast, friction resistant, resistance to flushing, such as by it is more long when Between operation, find activated carbon become sticky, gas velocity reduction when just need to change activated carbon in time.
For cylinder, upper and lower ends are conical tank body in the middle of described methane-desulfurizing device, offered on the tank body Observation port and maintenance replacement port, tank body volume size can according to pending gas flow number depending on, using vertical vertical placement.
For ease of the clean gas discharge for having processed, installed at the conical tank body of described methane-desulfurizing device topmost There is exhaust fan 5.
Specifically, biogas is initially entered in gas scrubbing zoneofoxidation 1, washing oxidation solution is sprayed from uniform washing oxidation solution Device 1-1 sprays, and forms countless fine mists, is sufficiently mixed with gas after contacting, the H in biogas2S is absorbed in washing oxidation In liquid;Air aeration disk 1-6 is aerated, and sulfide is oxidized to sulphur simple substance or sulfate, and oxidation product passes through drain valve Emit;Washing oxidation solution enters washing by washing oxidation solution precipitate and separate groove 1-9 and washing oxidation solution circulating pump 1-10 Oxidation solution spray equipment 1-1, recycles;Gas ascends into biological oxidation uptake zone 2, the microorganism on dry load 2-2 Using the nutriment in nutrient solution and a small amount of H2S carries out self-reproduction, and nutrient solution flows into bottom nutrient solution and stores groove 2-3 In, gas continues rising and is contacted with the nutrient solution of nutrient solution spray equipment 2-1 ejections, H2S is further absorbed and with nutrition Liquid returns to biological oxidation uptake zone, and nutrient solution enters nutrient solution spray equipment 2-1, follows by pipeline and nutrient solution circulating pump 2-4 Ring is used;Subsequently into except fog-zone 3, the drop in gas is blocked gas herein;Then gas is inhaled into activated carbon Attached area 4, the material being mingled with gas and drop are intercepted absorb herein, and so far gas is processed into the natural pond of cleaning Gas.
With above-mentioned according to desirable embodiment of the invention as enlightenment, by above-mentioned description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.

Claims (1)

1. a kind of methane-desulfurizing device, it is characterised in that:It is followed successively by gas scrubbing zoneofoxidation (1), biology upwards from bottom of device Oxidative absorption area (2), except fog-zone (3), charcoal absorption area (4) and exhaust fan (5);
Foot of the described gas scrubbing zoneofoxidation (1) positioned at whole device;Described gas scrubbing zoneofoxidation is provided with washing Oxidation solution spray equipment (1-1), described washing oxidation solution spray equipment is helical form spray equipment, and the liquid for ejecting is presented It is vaporific, and mixing together between water smoke;The bottom for washing oxidation solution spray equipment is provided with air inlet pipe (1-2) and gas distribution pipe (1-3); The bottom of gas distribution pipe (1-3) is provided with water collection sheet (1-4), and it is circular vertical section leading for rhombus that the bottom of water collection sheet is provided with cross section Stream device (1-5);The bottom of air deflector (1-5) is provided with air aeration disk (1-6), air aeration disk (1-6) be evenly arranged with it is micro- The pore type aeration plate in hole, the air that described air aeration disk (1-6) is connected with outside gas scrubbing zoneofoxidation by pipeline is roused Blower fan (1-7);The side wall of gas scrubbing zoneofoxidation is provided with air outlet (1-8);The lower outside of air outlet is provided with Washing oxidation solution precipitate and separate groove (1-9);Described washing oxidation solution spray equipment (1-1) is connected with gas scrubbing by pipeline Washing oxidation solution circulating pump (1-10) outside zoneofoxidation, described washing oxidation solution circulating pump (1-10) is connected with by pipeline to be washed Wash oxidation solution adding set (1-11) and washing oxidation solution precipitate and separate groove (1-9);Gas scrubbing zoneofoxidation bottom design is into cone Shape structure, drain valve (1-12) is provided with pyramidal structure bottom;
Described biological oxidation uptake zone (2) is provided with gas oxidation absorbent assembly, and described gas oxidation absorbent assembly includes battalion Nutrient solution spray equipment (2-1), dry load (2-2), nutrient solution store groove (2-3) and nutrient solution are stored the nutrition liquid pump in groove Enter the nutrient solution circulating pump (2-4) of nutrient solution spray equipment;Described nutrient solution spray equipment (2-1) is that helical form sprays dress Put;The liquid for ejecting is presented vaporific, and mixing together between water smoke;The cross section that described nutrient solution stores groove (2-3) is Circle, nutrient solution stores groove top and is provided with spray liquid aggregation apparatus (2-5), and the lower end diameter of described spray liquid aggregation apparatus is small The diameter of groove topmost is stored in nutrient solution, spray liquid aggregation apparatus can be assembled spray liquid to be back to nutrient solution and store groove;Institute The gas oxidation absorbent assembly stated is also equipped with nutrient solution addition and tapping equipment (2-6), described nutrient solution addition and discharge dress Putting (2-6) includes nutrient tank and agitating device, and nutrient solution addition connects nutrition by pipeline with tapping equipment (2-6) with valve Liquid circulating pump (2-4);The dry load (2-2) is inorganic inert filler, and the dry load (2-2) uses polyhedron empty ball Or other are polyhedron-shaped;
Described biological adsorption area top is provided with except fog-zone (3), except fog-zone (3) are provided with demister;
It is described except fog-zone top is provided with charcoal absorption area (4), be provided with activated carbon in described charcoal absorption area (4);
For cylinder, upper and lower ends are conical tank body in the middle of described methane-desulfurizing device, observation is offered on the tank body Mouth and maintenance replacement port, tank body use vertical vertical placement;
Exhaust fan (5) is installed at the conical tank body of described methane-desulfurizing device topmost.
CN201710231633.7A 2017-04-11 2017-04-11 A kind of methane-desulfurizing device Pending CN106867608A (en)

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CN107991152A (en) * 2017-11-23 2018-05-04 四川速荣科技有限公司 A kind of gas and oil separating plant for moisture content static measurement instrument
CN108043218A (en) * 2017-12-12 2018-05-18 常州大学 A kind of oxidation of formaldehyde absorber
CN108607350A (en) * 2018-05-17 2018-10-02 芜湖撼江智能科技有限公司 A kind of chemical industry foul smell Environmental-protecting treater
CN109316937A (en) * 2018-11-15 2019-02-12 临沂齐泽医药技术有限公司 A kind of wet boiler fume desulfurizing and dedusting device
CN109355122A (en) * 2018-12-24 2019-02-19 瑞昊新能源科技集团有限公司 Methane microbial-desulfurization method
CN109401806A (en) * 2018-12-24 2019-03-01 瑞昊新能源科技集团有限公司 Methane microbial-desulfurization device
CN109609228A (en) * 2019-01-07 2019-04-12 中广核生物燃气河北有限公司 Biogas environmental protection purifying plant

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CN103031172A (en) * 2013-01-06 2013-04-10 浙江大学 Layered biological-chemical combined biogas desulfurizing device
CN104923067A (en) * 2015-06-06 2015-09-23 常州大学 Integrated CS2 exhaust air treatment device

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Publication number Priority date Publication date Assignee Title
CN103031172A (en) * 2013-01-06 2013-04-10 浙江大学 Layered biological-chemical combined biogas desulfurizing device
CN104923067A (en) * 2015-06-06 2015-09-23 常州大学 Integrated CS2 exhaust air treatment device

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107991152A (en) * 2017-11-23 2018-05-04 四川速荣科技有限公司 A kind of gas and oil separating plant for moisture content static measurement instrument
CN108043218A (en) * 2017-12-12 2018-05-18 常州大学 A kind of oxidation of formaldehyde absorber
CN108607350A (en) * 2018-05-17 2018-10-02 芜湖撼江智能科技有限公司 A kind of chemical industry foul smell Environmental-protecting treater
CN109316937A (en) * 2018-11-15 2019-02-12 临沂齐泽医药技术有限公司 A kind of wet boiler fume desulfurizing and dedusting device
CN109355122A (en) * 2018-12-24 2019-02-19 瑞昊新能源科技集团有限公司 Methane microbial-desulfurization method
CN109401806A (en) * 2018-12-24 2019-03-01 瑞昊新能源科技集团有限公司 Methane microbial-desulfurization device
CN109609228A (en) * 2019-01-07 2019-04-12 中广核生物燃气河北有限公司 Biogas environmental protection purifying plant

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Application publication date: 20170620