CN106867482A - A kind of special defoamer in oil field - Google Patents

A kind of special defoamer in oil field Download PDF

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Publication number
CN106867482A
CN106867482A CN201611226085.0A CN201611226085A CN106867482A CN 106867482 A CN106867482 A CN 106867482A CN 201611226085 A CN201611226085 A CN 201611226085A CN 106867482 A CN106867482 A CN 106867482A
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CN
China
Prior art keywords
nonionic surfactant
present
oil
oil field
suds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611226085.0A
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Chinese (zh)
Inventor
王梅玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Federal Fine Chemical Co Ltd
Original Assignee
Guangdong Federal Fine Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Federal Fine Chemical Co Ltd filed Critical Guangdong Federal Fine Chemical Co Ltd
Priority to CN201611226085.0A priority Critical patent/CN106867482A/en
Publication of CN106867482A publication Critical patent/CN106867482A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02Well-drilling compositions
    • C09K8/03Specific additives for general use in well-drilling compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/02Foam dispersion or prevention
    • B01D19/04Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/02Foam dispersion or prevention
    • B01D19/04Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • B01D19/0409Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

The present invention discloses a kind of special defoamer in oil field, by weight percentage, including:Polysiloxanes 20 50%;Nonionic surfactant 4 6%;Polyoxyethylene polyoxypropylene polymeric acid 40 60%;Mutual solvent 3 8%;Catalyst 0.1 0.2%;Dispersant 0.6 0.8%.30 60 minutes prepared special defoamers in oil field are stirred after above-mentioned substance is added.Wherein polysiloxane molecule amount is 1,000 5000, and nonionic surfactant is nitrogenous class, and mutual solvent is diethylene glycol butyric acid.Described nonionic surfactant is cetyl trimethylammonium bromide.Present invention specifically addresses froth breaking problem in oil exploitation or processing.The present invention is made up of nonionic surfactant with hydroxy compounds, and with outstanding dispersiveness and the suds that disappear, froth breaking is fast, suds are long.There is good suds effect for various mink cell focuses, light oil.Good stability of the present invention, and the compatibility of solvent is good.

Description

A kind of special defoamer in oil field
Technical field
The present invention relates to defoamer field, more particularly to a kind of special defoamer in oil field.
Background technology
In crude oil stabilization technology, gas mixture enters separator, and some stabilizations will be formed on the interface of oil and gas Foam, when Oil-gas Separation, bubble burst has the loss of some liquid crude oils in the gas flow, in order to overcome these problems, it is necessary to Defoamer is added in crude oil, and general defoamer is all pure silicon oil type defoamer, viscosity is big, is difficult to disperse in crude oil, And dosage is big, defoaming effect is also not ideal enough.It is an object of the invention to provide a kind of improved crude oil antigassing additive, to solve The foam that certainly crude oil is produced in Oil-gas Separation or crude oil stabilization process.Less developer low cost is reached, defoaming effect is preferable Purpose.So as to improve the efficiency of oil gas separation equipment, oil and gas loss is reduced, improve yield;
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of special defoamer in oil field, it is intended to solve Certainly when oil gas product is processed, the defoaming effect that exists is undesirable, it is low to there is oil and gas loss, efficiency for the defoamer of prior art Problem.
A kind of special defoamer in oil field, wherein:By weight percentage, including:
Polysiloxanes 20-50%;
Nonionic surfactant 4-6%;
Polyoxyethylene polyoxypropylene polymeric acid 40-60%;
Mutual solvent 3-8%;
Catalyst 0.1-0.2%;
Dispersant 0.6-0.8%.
The polysiloxane molecule amount is 1000-5000, and nonionic surfactant is nitrogenous class non-ionic surface active Agent, mutual solvent is diethylene glycol butyric acid.
Described nonionic surfactant is cetyl trimethylammonium bromide.
Present invention specifically addresses froth breaking problem in oil exploitation or processing.The present invention matches somebody with somebody hydroxyl by nonionic surfactant Compound group is into outstanding dispersiveness and the suds that disappear, froth breaking is fast, suds are long.Have very for various mink cell focuses, light oil Good suds effect.Good stability of the present invention, and the compatibility of solvent is good.It is a kind of heavy duty detergent defoamer.
Specific embodiment
The present invention provides a kind of special defoamer in oil field, for make the purpose of the present invention, technical scheme and effect it is clearer, Clearly, the present invention is described in more detail below.It should be appreciated that specific embodiment described herein is only used to explain this Invention, is not intended to limit the present invention.
Embodiment 1:
A kind of special defoamer in oil field, wherein:By weight percentage, including:
Polysiloxanes 45%;
Nonionic surfactant 5%;
Polyoxyethylene polyoxypropylene polymeric acid 45%;
Mutual solvent 4.1%;
Catalyst 0.1%;
Dispersant 0.8%.
After above-mentioned each raw material is added into container, 45 minutes prepared special defoamers in oil field are stirred.
Wherein polysiloxane molecule amount is 2000, and nonionic surfactant is nitrogenous class, and mutual solvent is diethylene glycol fourth Acid;Nonionic surfactant is cetyl trimethylammonium bromide.
Embodiment 2:
A kind of special defoamer in oil field, wherein:By weight percentage, including:
Polysiloxanes 35%;
Nonionic surfactant 4.5%;
Polyoxyethylene polyoxypropylene polymeric acid 55%;
Mutual solvent 4.6%;
Catalyst 0.1%;
Dispersant 0.8%.
After above-mentioned each raw material is added into container, 40 minutes prepared special defoamers in oil field are stirred.
Wherein polysiloxane molecule amount is 2500, and nonionic surfactant is nitrogenous class, and mutual solvent is diethylene glycol fourth Acid;Nonionic surfactant is cetyl trimethylammonium bromide.
Present invention specifically addresses froth breaking problem in oil exploitation or processing.The present invention matches somebody with somebody hydroxyl by nonionic surfactant Compound group is into outstanding dispersiveness and the suds that disappear, froth breaking is fast, suds are long.Have very for various mink cell focuses, light oil Good suds effect.Good stability of the present invention, and the compatibility of solvent is good.It is a kind of heavy duty detergent defoamer.
It should be appreciated that application of the invention is not limited to above-mentioned citing, and for those of ordinary skills, can To be improved according to the above description or converted, all these modifications and variations should all belong to the guarantor of appended claims of the present invention Shield scope.

Claims (3)

1. the special defoamer in a kind of oil field, it is characterised in that:By weight percentage, including:
Polysiloxanes 20-50%;
Nonionic surfactant 4-6%;
Polyoxyethylene polyoxypropylene polymeric acid 40-60%;
Mutual solvent 3-8%;
Catalyst 0.1-0.2%;
Dispersant 0.6-0.8%.
2. the special defoamer in a kind of oil field according to claim 1, it is characterised in that:The polysiloxane molecule amount is 1000-5000, nonionic surfactant is nitrogenous class nonionic surfactant, and mutual solvent is diethylene glycol butyric acid.
3. the special defoamer in a kind of oil field according to claim 2, it is characterised in that:Described nonionic surfactant It is cetyl trimethylammonium bromide.
CN201611226085.0A 2016-12-27 2016-12-27 A kind of special defoamer in oil field Pending CN106867482A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611226085.0A CN106867482A (en) 2016-12-27 2016-12-27 A kind of special defoamer in oil field

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611226085.0A CN106867482A (en) 2016-12-27 2016-12-27 A kind of special defoamer in oil field

Publications (1)

Publication Number Publication Date
CN106867482A true CN106867482A (en) 2017-06-20

Family

ID=59165086

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611226085.0A Pending CN106867482A (en) 2016-12-27 2016-12-27 A kind of special defoamer in oil field

Country Status (1)

Country Link
CN (1) CN106867482A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220203268A1 (en) * 2019-05-03 2022-06-30 Sasol Chemicals Gmbh Non-Aqueous Defoamer Compositions and Their Use to Control Foaming of Non-Aqueous Foams

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86106653A (en) * 1986-10-08 1988-04-20 大庆石油管理局油田建设设计研究院 Crude defoamer and preparation method thereof
CN102949867A (en) * 2012-09-19 2013-03-06 天津科创医药中间体技术生产力促进有限公司 High-efficiency antifoaming agent
CN103041623A (en) * 2012-12-28 2013-04-17 河南省科学院高新技术研究中心 High-efficiency organic silicon defoaming agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86106653A (en) * 1986-10-08 1988-04-20 大庆石油管理局油田建设设计研究院 Crude defoamer and preparation method thereof
CN102949867A (en) * 2012-09-19 2013-03-06 天津科创医药中间体技术生产力促进有限公司 High-efficiency antifoaming agent
CN103041623A (en) * 2012-12-28 2013-04-17 河南省科学院高新技术研究中心 High-efficiency organic silicon defoaming agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220203268A1 (en) * 2019-05-03 2022-06-30 Sasol Chemicals Gmbh Non-Aqueous Defoamer Compositions and Their Use to Control Foaming of Non-Aqueous Foams

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Application publication date: 20170620