CN106867469A - A kind of low coking fire-resistant L QB300 organic heat carrier compositions of environment-friendly synthesis type - Google Patents
A kind of low coking fire-resistant L QB300 organic heat carrier compositions of environment-friendly synthesis type Download PDFInfo
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- CN106867469A CN106867469A CN201710093359.1A CN201710093359A CN106867469A CN 106867469 A CN106867469 A CN 106867469A CN 201710093359 A CN201710093359 A CN 201710093359A CN 106867469 A CN106867469 A CN 106867469A
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
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Abstract
The invention discloses a kind of environment-friendly low coking fire-resistant L QB300 organic heat carrier compositions of synthesis type, the triaryl phosphine acid esters of its polyalphaolefin for using 50% (m) and 50% (m) it is compound based on oil, coordinate various compound additives.It includes：Antioxidant preservative, high-temperature antioxidant, antioxidant, matal deactivator, metal deactivator, anti-coking agent, antirust agent, base number retention agent, anti-foaming agent, reinforcing agent, activity increase agent.The advantage is that：Heat endurance is good, 60~400 DEG C of series of products temperature in use scope, and long service life is renewable, biodegradable.
Description
Technical field
The present invention relates to a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type.
Background technology
Synthesis type organic heat carrier is produced with chemical synthesis process, with certain chemical constitution and the chemical name for determining
The product of title.According to maximum permissible service temperature, synthesis type organic heat carrier can be divided into common synthesis type and with special stabilization
The class of synthesis type two of property.It is characterized in that heat endurance is good, -60~400 DEG C of series of products temperature in use scope, long service life,
It is renewable, it is biodegradable.It is applicable enclosed and open type heat transfer system
Usual heat carrier heat transfer has two kinds of basic modes, and one kind is in initial boiling point or the following liquid phase heat transfer of boiling temperature, separately
A kind of is the gaseous heat transfer more than boiling temperature.Most heat carrier is liquid phase heat transfer medium, maximum operation (service) temperature difference
It is 320 DEG C and 350 DEG C.Fraction heat carrier is gas-liquid phase heat transfer agent, and maximum operation (service) temperature is up to 400 DEG C.Liquid phase heat transfer gas
Force down, security it is good, using more extensive；And gaseous heat transfer performance meets temperature and temperature-controlled precision requirement higher, but can not
Completely liquid phase systems substitution.
The content of the invention
The invention provides a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type, it is special
Levy and be：Using oil based on the composite foundation oil of the triaryl phosphine acid esters of the poly alpha olefin and 50% (m) of 50% (m), match somebody with somebody
Close various compound additives, its each mass percent into being grouped into：
The low coking fire-resistant L-QB300 organic heat carrier compositions of described a kind of environment-friendly synthesis type, it is characterised in that
Using oil based on the composite foundation oil of the triaryl phosphine acid esters of the poly alpha olefin and 50% (m) of 50% (m)；
The low coking fire-resistant L-QB300 organic heat carrier compositions of described a kind of environment-friendly synthesis type, it is characterised in that
Antioxidant preservative is dialkyl dithio amino formate；
The low coking fire-resistant L-QB300 organic heat carrier compositions of described a kind of environment-friendly synthesis type, it is characterised in that
High-temperature antioxidant is relative molecular mass phenolic ester type (KT5135) high；Antioxidant is amine and relative molecular mass phenol mixture high
(IrganoxL150)；
The low coking fire-resistant L-QB300 organic heat carrier compositions of described a kind of environment-friendly synthesis type, it is characterised in that
Matal deactivator is the methyl formyl triazole derivative of 50% (m) and the sulfenyl benzimidazole of 50% (m)；
The low coking fire-resistant L-QB300 organic heat carrier compositions of described a kind of environment-friendly synthesis type, it is characterised in that
Metal deactivator is the thiadiazoles derivative (T561) of the benzotriazole derivative (T551) with 50% (m) of 50% (m)；
The low coking fire-resistant L-QB300 organic heat carrier compositions of described a kind of environment-friendly synthesis type, it is characterised in that
Anti-coking agent is the polybutene succinimide of the boronation polyisobutylene-bis-succinimide (T154B) with 50% (m) of 50% (m)
(T161)；Antirust agent is the alkenyl succinic acid half ester (T747) of the oil barium carbonate (T701) with 50% (m) of 50% (m)；
The low coking fire-resistant L-QB300 organic heat carrier compositions of described a kind of environment-friendly synthesis type, it is characterised in that
Base number retention agent is magnesium naphthenate (T111)；Anti-foaming agent is methyl-silicone oil (T901)；
The low coking fire-resistant L-QB300 organic heat carrier compositions of described a kind of environment-friendly synthesis type, it is characterised in that
Reinforcing agent is dialkyl diphenylamine (T534)；Activity increase agent is diene base succimide (T152).
A kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type of the invention, heat endurance
Good, -60~400 DEG C of series of products temperature in use scope, long service life is renewable, biodegradable.
Specific embodiment
Embodiment 1：
Following masses percentage is reconciled and is formed：
Above component summation is 100%.
Embodiment 2：
Following masses percentage is reconciled and is formed：
Above component summation is 100%.
Embodiment 3：
Following masses percentage is reconciled and is formed：
Above component summation is 100%.
The main physical and chemical index of the product of embodiment 1,2,3：
A kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type of the invention, heat endurance
Good, -60~400 DEG C of series of products temperature in use scope, long service life is renewable, biodegradable.
Claims (10)
1. low coking fire-resistant L-QB300 organic heat carrier compositions of a kind of environment-friendly synthesis type, it is characterised in that：With quality hundred
Fraction meter, into being grouped into：
2. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type according to claim 1,
It is characterized in that using oil based on the composite foundation oil of the triaryl phosphine acid esters of the poly alpha olefin and 50% (m) of 50% (m).
3. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carriers combination of synthesis type according to claim 1 and 2
Thing, it is characterised in that antioxidant preservative is dialkyl dithio amino formate.
4. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type according to claim 1,
It is characterized in that high-temperature antioxidant is relative molecular mass phenolic ester type (KT5135) high；Antioxidant is amine and average molecular matter high
Amount phenol mixture (IrganoxL150).
5. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type according to claim 1,
It is characterized in that matal deactivator is the methyl formyl triazole derivative of 50% (m) and the sulfenyl benzimidazole of 50% (m).
6. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type according to claim 1,
It is characterized in that metal deactivator is the thiadiazoles derivative of the benzotriazole derivative (T551) with 50% (m) of 50% (m)
(T561)。
7. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type according to claim 1,
It is characterized in that anti-coking agent is the polybutene fourth of the boronation polyisobutylene-bis-succinimide (T154B) with 50% (m) of 50% (m)
Imidodicarbonic diamide (T161)；Antirust agent is the alkenyl succinic acid half ester of the oil barium carbonate (T701) with 50% (m) of 50% (m)
(T747)。
8. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type according to claim 1,
It is characterized in that base number retention agent is magnesium naphthenate (T111)；Anti-foaming agent is methyl-silicone oil (T901).
9. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier compositions of synthesis type according to claim 1,
It is characterized in that reinforcing agent is dialkyl diphenylamine (T534)；Activity increase agent is diene base succimide (T152).
10. a kind of environment-friendly low coking fire-resistant L-QB300 organic heat carrier groups of synthesis type according to claim 1 and 2
Compound, it is characterised in that high-temperature antioxidant is relative molecular mass phenolic ester type (KT5135) high；Antioxidant is that amine and height are relative
Molecular mass phenol mixture (IrganoxL150)；Matal deactivator is the methyl formyl triazole derivative and 50% of 50% (m)
The sulfenyl benzimidazole of (m)；Metal deactivator is that the benzotriazole derivative (T551) of 50% (m) spreads out with the thiadiazoles of 50% (m)
Biological (T561)；Anti-coking agent is the polybutene of the boronation polyisobutylene-bis-succinimide (T154B) with 50% (m) of 50% (m)
Succimide (T161)；Antirust agent is the alkenyl succinic acid half ester of the oil barium carbonate (T701) with 50% (m) of 50% (m)
(T747)；Base number retention agent is magnesium naphthenate (T111)；Anti-foaming agent is methyl-silicone oil (T901)；Reinforcing agent is dialkyl diphenylamine
(T534)；Activity increase agent is diene base succimide (T152).
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| CN201710093359.1A CN106867469A (en) | 2017-02-21 | 2017-02-21 | A kind of low coking fire-resistant L QB300 organic heat carrier compositions of environment-friendly synthesis type |
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Citations (7)
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| CN1955271A (en) * | 2001-01-04 | 2007-05-02 | 国际壳牌研究有限公司 | Lubricating oil composition |
| CN102925256A (en) * | 2011-08-10 | 2013-02-13 | 中国石油化工股份有限公司 | Heat-conductive oil composition having high temperature oxidation resistance |
| CN103232837A (en) * | 2013-04-12 | 2013-08-07 | 广西大学 | Environment friendly energy-efficient heat conduction oil |
| CN104893683A (en) * | 2015-06-29 | 2015-09-09 | 成都迈斯拓新能源润滑材料有限公司 | Anti-coking alkylbenzene synthesis heat conduction oil and preparation method thereof |
| WO2016044975A1 (en) * | 2014-09-22 | 2016-03-31 | Dow Global Technologies Llc | Thermal grease based on hyperbranched olefinic fluid |
| CN106010464A (en) * | 2016-06-14 | 2016-10-12 | 山东沾化莱斯特石油化工有限公司 | Environment-friendly conduction oil and preparation method thereof |
| CN106133109A (en) * | 2014-03-18 | 2016-11-16 | 旭硝子株式会社 | Heat circulating system compositions and heat circulating system |
-
2017
- 2017-02-21 CN CN201710093359.1A patent/CN106867469A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1955271A (en) * | 2001-01-04 | 2007-05-02 | 国际壳牌研究有限公司 | Lubricating oil composition |
| CN102925256A (en) * | 2011-08-10 | 2013-02-13 | 中国石油化工股份有限公司 | Heat-conductive oil composition having high temperature oxidation resistance |
| CN103232837A (en) * | 2013-04-12 | 2013-08-07 | 广西大学 | Environment friendly energy-efficient heat conduction oil |
| CN106133109A (en) * | 2014-03-18 | 2016-11-16 | 旭硝子株式会社 | Heat circulating system compositions and heat circulating system |
| WO2016044975A1 (en) * | 2014-09-22 | 2016-03-31 | Dow Global Technologies Llc | Thermal grease based on hyperbranched olefinic fluid |
| CN104893683A (en) * | 2015-06-29 | 2015-09-09 | 成都迈斯拓新能源润滑材料有限公司 | Anti-coking alkylbenzene synthesis heat conduction oil and preparation method thereof |
| CN106010464A (en) * | 2016-06-14 | 2016-10-12 | 山东沾化莱斯特石油化工有限公司 | Environment-friendly conduction oil and preparation method thereof |
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Application publication date: 20170620 |