CN106867278A - A kind of production method of polymolecularity titanium dioxide - Google Patents
A kind of production method of polymolecularity titanium dioxide Download PDFInfo
- Publication number
- CN106867278A CN106867278A CN201710151277.8A CN201710151277A CN106867278A CN 106867278 A CN106867278 A CN 106867278A CN 201710151277 A CN201710151277 A CN 201710151277A CN 106867278 A CN106867278 A CN 106867278A
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- CN
- China
- Prior art keywords
- titanium dioxide
- polymolecularity
- production method
- roll mill
- grinding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3615—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C1/3623—Grinding
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C3/041—Grinding
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The present invention relates to a kind of production method of titanium dioxide, in particular it relates to the grinding technics of polymolecularity titanium dioxide.Grinding steps are the increase roll-in mill apparatus under kiln, and thing is introduced into roll mill and is ground under kiln, and thing enters back into wet milk grinding under the kiln for grinding.The method that a kind of production method of polymolecularity titanium dioxide of the present invention is used, improves 20 ° of gloss of product, and the aqueous height for reducing product is stirred, and improves the dispersiveness of product.
Description
Technical field
The present invention relates to a kind of production method of titanium dioxide, in particular it relates to the life of polymolecularity titanium dioxide
Product method.
Background technology
Titanium dioxide is a kind of Chinese white, is widely used in coating, chemical fibre, rubber, enamel, ceramics, plastics, papermaking, print
The industry such as brush ink, electronic ceramics, glass, welding rod, cosmetics.Pigment is a kind of fine particle, particle diameter it is minimum less than 1 μ
M, is compared with particle inside due to the molecular number of these particle surfaces and occupies sizable ratio, the exposed molecule in particle surface
Among uneven in the field of force, there is energy very high in pigment particles surface, and itself plays pendulum, and this causes it
There are more performances than general solid, dispersion process of the pigment in color spreading agent is affected.
This ultra-fine state of pigment particles renders it susceptible to be distributed in its insoluble medium, and has and medium between
Certain active force and constitute a system, but due to a variety of properties of itself, it is difficult to stable dispersion, between particle
There is aggregation to be inclined to.The primary particle surface free energy of pigment is very high, has aggregation tendency to reduce surface area between particle, reduces certainly
By energy.Primary particle is bonded together to form offspring, more has some primary particles and offspring to jointly form again
Bigger aggregation, the diameter of this like-particles is just expanded a lot.So, pigment in coating application, in order to reach coating institute
The fineness for needing, it is necessary to smash these aggregations.Using roll mill, smaller particless fineness is reached, meet industrial application needs.
The content of the invention
The present invention is directed to the deficiencies in the prior art, and an object of the present invention is solution above-mentioned in the prior art
One or more problems for existing.
An object of the present invention is to provide a kind of production method of polymolecularity titanium dioxide.
To achieve these goals, the technical solution adopted by the present invention is:A kind of production method of polymolecularity titanium dioxide,
Increase roll-in mill apparatus under kiln, thing is introduced into roll mill and is ground under kiln, thing enters back into wet milk grinding under the kiln for grinding.
Preferably, the material that the roll-in mill apparatus are used is stainless steel.
Preferably, the roll-in mill apparatus roll mill pressure is 10-15MPa.
Preferably, the roll-in mill apparatus roll mill pressure is 13MPa.
Preferably, the Ginding process is specially:Powder is carried out to material after calcining using roll mill, wet-milling, serial sand
The poly- treatment of size degradation, reusing cyclone carries out classification treatment, and suitable material to the rear operation of preferable particle size is produced.
The method that a kind of production method of polymolecularity titanium dioxide of the present invention is used, improves 20 ° of gloss of product, drops
The aqueous height of low product is stirred, and improves the dispersiveness of product.
Specific embodiment
Above-mentioned example embodiment for a better understanding of the present invention, is carried out further with reference to specific example to it
Explanation.It should be appreciated that specific embodiment described herein is only used to explain the present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of production method of polymolecularity titanium dioxide, increases roll-in mill apparatus under kiln, and thing is introduced into roll mill under kiln
It is ground, thing enters back into wet milk grinding under the kiln for grinding.Roll-in mill apparatus roll mill pressure is 13MPa.
Embodiment 2
A kind of production method of polymolecularity titanium dioxide, increases roll-in mill apparatus under kiln, and thing is introduced into roll mill under kiln
It is ground, thing enters back into wet milk grinding under the kiln for grinding, and then enters back into sand milling.Roll-in mill apparatus roll mill pressure is
13MPa。
Comparing embodiment 1
A kind of production method of polymolecularity titanium dioxide, thing grinds into wet milk under kiln.
The application method of table 1 obtains titanium dioxide and comparative example method obtains the performance test data of titanium dioxide
By above table it can be seen that, the product that the method for the present invention is obtained has great in 20 ° of gloss this parameters
Breakthrough, improve 22.1% than original glossiness, greatly improved the quality of titanium dioxide.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (5)
1. a kind of production method of polymolecularity titanium dioxide, it is characterised in that:Including grinding, the grinding steps are to increase under kiln
Plus roll-in mill apparatus, thing is introduced into roll mill and is ground under kiln, and thing enters back into wet milk grinding under the kiln for grinding.
2. the production method of a kind of polymolecularity titanium dioxide according to claim 1, it is characterised in that:The roll mill dress
Used material is put for stainless steel.
3. the production method of a kind of polymolecularity titanium dioxide according to claim 1, it is characterised in that:The roll mill dress
Roll mill pressure is put for 10-15MPa.
4. the production method of a kind of polymolecularity titanium dioxide according to claim 1, it is characterised in that:The roll mill dress
Roll mill pressure is put for 13MPa.
5. the production method of a kind of polymolecularity titanium dioxide according to claim 1, it is characterised in that:The grinding steps
Specially:Material after calcining is carried out to crush depolymerization treatment using roll mill, wet-milling, serial sand, reusing cyclone is carried out
Classification is processed, and suitable material to the rear operation of preferable particle size is produced.
Priority Applications (1)
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CN201710151277.8A CN106867278A (en) | 2017-03-14 | 2017-03-14 | A kind of production method of polymolecularity titanium dioxide |
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CN201710151277.8A CN106867278A (en) | 2017-03-14 | 2017-03-14 | A kind of production method of polymolecularity titanium dioxide |
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CN106867278A true CN106867278A (en) | 2017-06-20 |
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CN201710151277.8A Pending CN106867278A (en) | 2017-03-14 | 2017-03-14 | A kind of production method of polymolecularity titanium dioxide |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111175479A (en) * | 2020-03-31 | 2020-05-19 | 龙佰四川钛业有限公司 | Method for testing grinding performance of titanium white kiln product |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201543485U (en) * | 2009-10-21 | 2010-08-11 | 攀枝花东方钛业有限公司 | Device used for crushing material below kiln of titanium white device in sulfuric acid method of titanium white |
CN102649095A (en) * | 2011-02-24 | 2012-08-29 | 苏州纳方工程材料有限公司 | Grinding method of titanium dioxide |
CN105921212A (en) * | 2016-06-23 | 2016-09-07 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for reducing viscosity of titanium dioxide slurry |
-
2017
- 2017-03-14 CN CN201710151277.8A patent/CN106867278A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201543485U (en) * | 2009-10-21 | 2010-08-11 | 攀枝花东方钛业有限公司 | Device used for crushing material below kiln of titanium white device in sulfuric acid method of titanium white |
CN102649095A (en) * | 2011-02-24 | 2012-08-29 | 苏州纳方工程材料有限公司 | Grinding method of titanium dioxide |
CN105921212A (en) * | 2016-06-23 | 2016-09-07 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for reducing viscosity of titanium dioxide slurry |
Non-Patent Citations (2)
Title |
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邓婕 吴立峰: "《钛白粉应用手册(修订版)》", 1 January 2005 * |
金斌: "分散剂及不同设备组合在硫酸法金红石型钛白生产中的应用研究", 《上海涂料》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111175479A (en) * | 2020-03-31 | 2020-05-19 | 龙佰四川钛业有限公司 | Method for testing grinding performance of titanium white kiln product |
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Application publication date: 20170620 |
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