CN106863976A - It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass - Google Patents
It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass Download PDFInfo
- Publication number
- CN106863976A CN106863976A CN201710024100.1A CN201710024100A CN106863976A CN 106863976 A CN106863976 A CN 106863976A CN 201710024100 A CN201710024100 A CN 201710024100A CN 106863976 A CN106863976 A CN 106863976A
- Authority
- CN
- China
- Prior art keywords
- parts
- layer
- effectively
- eyeglass
- sunshade panel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J3/00—Antiglare equipment associated with windows or windscreens; Sun visors for vehicles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/536—Hardness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/003—Interior finishings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/08—Cars
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
Present invention offer is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, including PMMA resin beds, and the PMMA resin beds front is provided with stiffening layer；The stiffening layer front is provided with antiglare layer；The antiglare layer front is provided with UV-resistant layer；The UV-resistant layer front is provided with scratch resistant layer；The stiffening layer is organosilicon membrane, and the antiglare layer is nanometer cobalt oxide reticulated film, and the UV-resistant layer is uvioresistant film layer, and the scratch resistant layer is PET resin film layer；The a kind of of present invention offer effectively prevents dazzling automotive sunshade panel eyeglass, and it has high-permeability, can effectively prevent dazzling, makes the soft of high light change, provides clear comfortable driving vision, the visual fatigue of alleviation human pilot to human pilot；Meanwhile, a kind of of present invention offer effectively prevents dazzling automotive sunshade panel eyeglass, and also with UV resistance, scratch resistant function, vdiverse in function, cost performance is high.
Description
Technical field
The present invention relates to automotive sunshade panel eyeglass field, and in particular to a kind of effectively to prevent dazzling automotive sunshade panel mirror
Piece.
Background technology
With the fast development of social economy, the continuous improvement of national life level, the vehicles make rapid progress, and automobile is made
It is one of main vehicles of modern society, has come into huge numbers of families.
Meanwhile, with the popularization of automobile, people run into increasing problem and highlight, thus, present people
It is a simple walking-replacing tool to be no longer regarded as automobile, and how safe driving is related to personal life security problem.
Either travelled on daytime and still travelled at night, the eyeglass on automotive sunshade panel can be big to sunshine or automobile
The high light of lamp has certain weakening effect, is improved in safety coefficient for human pilot.
But, existing automotive sunshade panel eyeglass, function is relatively simple, does not possess good anti-dazzle, UV resistance, scratch resistant etc.
Function, while existing automotive sunshade panel eyeglass can not often ensure good degree of getting a clear view, human pilot when in use
Visual fatigue etc. is also easily produced in driving procedure.
Therefore, based on above the problems such as, this invention address that a automotive sunshade panel eyeglass vdiverse in function of research.
The content of the invention
To solve above-mentioned problem, dazzling automotive sunshade panel is effectively prevented it is an object of the invention to provide a kind of
Eyeglass, it has high-permeability, can effectively prevent dazzling, makes the soft of high light change, is provided to human pilot and clearly comfortably driven
The visual field is sailed, alleviates the visual fatigue of human pilot；Meanwhile, also with UV resistance, scratch resistant function, vdiverse in function, cost performance is high.
To reach above-mentioned purpose, the technical solution adopted by the present invention is：
It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, including PMMA resin beds（Polymethyl methacrylate）, it is described
PMMA resin beds front is provided with stiffening layer；The stiffening layer front is provided with antiglare layer；The antiglare layer front is provided with UV-resistant layer；
The UV-resistant layer front is provided with scratch resistant layer.The PMMA resin beds include following weight proportion raw material：
Polymethyl methacrylate：60~70 parts, allyl diglycol acid esters：10~20 parts, styrene block copolymer：5~
10 parts, peroxidized t-butyl perbenzoate：2~3 parts, OIT：3~5 parts, methacryloxypropyl silane：It is 2~3 parts, adjacent
Dioctyl phthalate：5~10 parts, silica：3~5 parts, stabilizer：1~2 part, nucleator：0.1~1 part, initiator：
0.1~1 part, antioxidant：0.1~0.5 part.
It is of the invention effectively to prevent dazzling sunshading board eyeglass with PMMA resin beds as basic unit, increased the transparent of eyeglass
Degree, allyl diglycol acid esters can make the PMMA resin bed quality of synthesis lighter in the raw material of PMMA, and shock resistance more preferably, is prevented
It is quick-fried, non-breakable, by the eyeglass of above Material synthesis, can make eyeglass that there is more preferable definition.
Further, the stiffening layer is organosilicon membrane, and the thickness of the stiffening layer is 1~2 μm, and one is plated by eyeglass
Layer organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, eyeglass is more difficult when shock is subjected to
It is broken, at the same time can also increase by 2% light transmittance and for the follow-up institute's film plating layer of eyeglass improves more preferable adhesive force.
Further, the antiglare layer is nanometer cobalt oxide reticulated film, and the antiglare layer thickness is 0.1~0.5 μm, institute
Stating antiglare layer includes following weight proportion raw material:
Nanometer cobalt oxide：20~30 parts, makrolon：10~20 parts, titanium oxide：5~10 parts, cerium oxide：3~5 parts, bromination
Silver：1~2 part, pigmented powder：1~2 part, light diffusing agent：0.1~1 part, light stabilizer：0.1~0.5 part, antioxidant：0.1~
0.5 part, lubricant：0.1~1 part.
Antiglare layer of the present invention is nanometer cobalt oxide reticulated film, can be entered according to sunshine and car light and various high lights
Row filtering, adds lustre to and hinders the light pollution that shelves are harmful to eyeball, so as to reach different anti-dazzle degree, solves and " filters and do not keep off
The anti-dazzle problem of light "；Meanwhile, road surface " snow blindness " phenomenon is effectively eliminated, dim eyesight, mitigation kopiopia are prevented, especially can be at night
During meeting the dazzling high beam of other side is down to soft, comfortable degree, the safety driven under effective guarantee high light.
Further, the UV-resistant layer is uvioresistant film layer, and the thickness of the UV-resistant layer is 0.2~0.3 μm, described
Uvioresistant film layer includes following weight proportion raw material：
Acrylic resin：40~50 parts, nano titanium oxide：10~15 parts, nano zine oxide：5~10 parts, magnesia：3~5
Part, propane diols：5~10 parts, pentaerythrite：8~12 parts, N- cyclohexylthiophthalimides：1~2 part, divinyl
Benzene：0.1~1 part, methyl oleate：0.1~1 part, pigmented powder：0.1~0.5 part.
Uvioresistant layer of the present invention is uvioresistant film layer, and the uvioresistant film layer synthesized by above dispensing can be effective
Filters ultra violet line, so as to effectively prevent injury of the ultraviolet to eyes.
Further, the scratch resistant layer is PET resin film layer, and the thickness of the scratch resistant layer is 0.2~0.4 μm, described scratch resistant
Layer includes following weight proportion raw material：
PET resin：50~60 parts, dimethyl diethylsilane：10~20 parts, nano-silver powder：3~5 parts, nano silicon：4
~8 parts, mica powder：2~3 parts, isocyanates：6~12 parts, polyvinylpyrrolidone：1~2 part, ethyl acetate：10~20 parts,
Divinylbenzene：0.1~0.5 part, methyl oleate：0.2~0.4 part.
Scratch resistant layer of the present invention is PET resin film layer, and the PET resin film layer synthesized by above dispensing can be carried effectively
The Wear-resistant scratch-resistant performance of eyeglass high, improves the service life of eyeglass.So that whole lens function is more complete, cost performance is more
It is high.
Preferably, in the PMMA resin beds raw material, the stabilizer is organic tin stabilizer, it is easy to resin forming,
With good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented
Only resin material is decomposed and old saying；The nucleator is double（To tert-butyl benzene epoxide）Sodium phosphate, by using double（To the tert-butyl group
Phenoxy group）Sodium phosphate improves the tensile strength and impact strength of PMMA resin beds as nucleator, improves PMMA resins
The finish of layer surface, contributes to lifting PMMA resin beds rigidity, crystallization rate, the transparency.
Preferably, in the PMMA resin beds raw material, the initiator is peroxidized t-butyl perbenzoate, peroxidating two
The reaction efficiency of the whole reaction of the one kind in diisopropyl carbonate, TBHP, effectively lifting, shortens the reaction time；
The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can effectively drop
The oxidized performance of low PMMA resin beds, extends the service life of eyeglass.
Preferably, in the antiglare layer synthesis material, the light diffusing agent is styrene and TMS cage type
The random copolymer of polysilsesquioxane, can be effectively increased the scattering and transmission of light, cover the same of light emitting source and dazzling light source
When, whole material can be made to send softer again, light attractive in appearance, graceful reaches the opaque comfortable effect of printing opacity；Light stabilizer
It is N, double (4- amino -2,2,6,6- the tetramethyl-piperidyls) -1,3- benzenedicarboxamides of N'- or hindered amine as light stabilizer 3- (2,2,
6,6- tetramethyl piperidine 4- amino) the third dodecyl gallate, can effectively extend the service life of material.
Preferably, in the antiglare layer synthesis material, the lubricant is ethylene bis-fatty acid amides series lubricant agent, is had
Effect improves the adhering state between a raw material, lifts reaction efficiency.
The beneficial effects of the present invention are：
（1）Present invention offer is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, with PMMA resin beds as basic unit, increased mirror
The transparency of piece, allyl diglycol acid esters can make the PMMA resin bed quality of synthesis lighter in the raw material of PMMA, impact resistance
Can be more preferably explosion-proof, non-breakable, by the eyeglass of above Material synthesis, can make eyeglass that there is more preferable definition.
（2）Present invention offer is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, and the antiglare layer is nanometer cobalt oxide
Reticulated film, can be filtered according to sunshine and car light and various high lights, add lustre to and hinder the light dirt that shelves are harmful to eyeball
Dye, so as to reach different anti-dazzle degree, solves the anti-dazzle problem of " filter and be not in the light "；Meanwhile, effectively eliminate road surface " snow
It is blind " phenomenon, dim eyesight, mitigation kopiopia are prevented, the dazzling high beam of other side can be especially down to when meeting at night soft, easypro
Suitable degree, the safety driven under effective guarantee high light.
（3）Present invention offer is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, except it has high-permeability, can have
Effect prevents dazzling, makes the soft of high light change, provides clear comfortable driving vision to human pilot, alleviates the vision of human pilot
The advantage accident of fatigue；Meanwhile, it is vdiverse in function, the characteristics of cost performance is high also with UV resistance, scratch resistant function.
Brief description of the drawings
A kind of schematic diagram for effectively preventing dazzling automotive sunshade panel eyeglass that Fig. 1 is provided for the present invention；
Wherein, 1 is PMMA resin beds, and 2 is stiffening layer, and 3 is antiglare layer, and 4 is UV-resistant layer, and 5 is scratch resistant layer.
Specific embodiment
Clear, complete description will be carried out to the technical scheme in the embodiment of the present invention below, it is clear that described implementation
Example is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common
The every other embodiment that technical staff is obtained on the premise of creative work is not made, belongs to present invention protection
Scope.
Embodiment one
It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, including PMMA resin beds 1 referring to Fig. 1（Poly-methyl methacrylate
Ester）, the front of PMMA resin beds 1 is provided with stiffening layer 2；The front of the stiffening layer 2 is provided with antiglare layer 3；The front of the antiglare layer 3
It is provided with UV-resistant layer 4；The front of the UV-resistant layer 4 is provided with scratch resistant layer 5.The PMMA resin beds 1 include that following weight proportion is former
Material：
Polymethyl methacrylate：65 parts, allyl diglycol acid esters：10 parts, styrene block copolymer：7.5 parts, peroxidating
T-butyl perbenzoate：2 parts, OIT：5 parts, methacryloxypropyl silane：2.52 parts, dioctyl phthalate：5
Part, silica：5 parts, stabilizer：1.2 parts, nucleator：1 part, initiator：0.55 part, antioxidant：0.25 part.
It is of the invention effectively to prevent dazzling sunshading board eyeglass with PMMA resin beds 1 as basic unit, increased the transparent of eyeglass
Degree, allyl diglycol acid esters can make the mass of PMMA resin beds 1 of synthesis lighter in the raw material of PMMA, and shock resistance is more preferable,
It is explosion-proof, non-breakable, by the eyeglass of above Material synthesis, can make eyeglass that there is more preferable definition.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 1 μm, and one layer is plated by eyeglass
Organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, also makes eyeglass more not fragile when shock is subjected to
It is broken, at the same time can also increase by 2% light transmittance and for the follow-up institute's film plating layer of eyeglass improves more preferable adhesive force.
Further, the antiglare layer 3 is nanometer cobalt oxide reticulated film, and the thickness of the antiglare layer 3 is 0.5 μm, described anti-
Dizzy layer 3 includes following weight proportion raw material:
Nanometer cobalt oxide：20 parts, makrolon：16 parts, titanium oxide：10 parts, cerium oxide：3 parts, silver bromide：1.53 parts, pigment
Powder：2 parts, light diffusing agent：0.1 part, light stabilizer：0.5 part, antioxidant：0.24 part, lubricant：0.52 part.
Antiglare layer of the present invention 3 is nanometer cobalt oxide reticulated film, can be according to sunshine and car light and various high lights
Filtered, added lustre to and hindered the light pollution that shelves are harmful to eyeball, so as to reach different anti-dazzle degree, solved and " filter not
Be in the light " anti-dazzle problem；Meanwhile, road surface " snow blindness " phenomenon is effectively eliminated, dim eyesight, mitigation kopiopia are prevented, especially can be at night
Between meeting when the dazzling high beam of other side is down to soft, comfortable degree, the safety driven under effective guarantee high light.
Further, the UV-resistant layer 4 is uvioresistant film layer, and the thickness of the UV-resistant layer 4 is 0.3 μm, the anti-purple
Theca externa includes following weight proportion raw material：
Acrylic resin：45 parts, nano titanium oxide：15 parts, nano zine oxide：5 parts, magnesia：4 parts, propane diols：7.6 parts,
Pentaerythrite：10 parts, N- cyclohexylthiophthalimides：1.58 parts, divinylbenzene：0.1 part, methyl oleate：1
Part, pigmented powder：0.5 part.
Uvioresistant layer 4 of the present invention is uvioresistant film layer, and the uvioresistant film layer synthesized by above dispensing can be effective
Filters ultra violet line, so as to effectively prevent injury of the ultraviolet to eyes.
Further, the scratch resistant layer 5 is PET resin film layer, and the thickness of the scratch resistant layer 5 is 0.3 μm, the scratch resistant layer 5
Including following weight proportion raw material：
PET resin：55 parts, dimethyl diethylsilane：20 parts, nano-silver powder：5 parts, nano silicon：4 parts, mica powder：
2.5 parts, isocyanates：9.5 parts, polyvinylpyrrolidone：2 parts, ethyl acetate：10 parts, divinylbenzene：0.3 part, oleic acid first
Ester：0.4 part.
Scratch resistant layer of the present invention 5 is PET resin film layer, and the PET resin film layer synthesized by above dispensing can be effective
The Wear-resistant scratch-resistant performance of eyeglass is improved, the service life of eyeglass is improved.So that whole lens function is more complete, cost performance is more
It is high.
Preferably, in the raw material of PMMA resin beds 1, the stabilizer is organic tin stabilizer, it is easy to resin forming,
With good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented
Only resin material is decomposed and old saying；The nucleator is double（To tert-butyl benzene epoxide）Sodium phosphate, by using double（To the tert-butyl group
Phenoxy group）Sodium phosphate improves the tensile strength and impact strength of PMMA resin beds as nucleator, improves PMMA resins
The finish of layer surface, contributes to lifting PMMA resin beds rigidity, crystallization rate, the transparency.
Preferably, in the raw material of PMMA resin beds 1, the initiator is peroxidized t-butyl perbenzoate, peroxidating
The reaction efficiency of the whole reaction of the one kind in two diisopropyl carbonates, TBHP, effectively lifting, when shortening reaction
Between；The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can have
Effect reduces the oxidized performance of PMMA resin beds 1, extends the service life of eyeglass.
Preferably, in the synthesis material of the antiglare layer 3, the light diffusing agent is styrene and TMS cage type
The random copolymer of polysilsesquioxane, can be effectively increased the scattering and transmission of light, cover the same of light emitting source and dazzling light source
When, whole material can be made to send softer again, light attractive in appearance, graceful reaches the opaque comfortable effect of printing opacity；Light stabilizer
It is N, double (4- amino -2,2,6,6- the tetramethyl-piperidyls) -1,3- benzenedicarboxamides of N'- or hindered amine as light stabilizer 3- (2,2,
6,6- tetramethyl piperidine 4- amino) the third dodecyl gallate, can effectively extend the service life of material.
Preferably, in the synthesis material of the antiglare layer 3, the lubricant is ethylene bis-fatty acid amides series lubricant agent,
The adhering state between a raw material is effectively improved, reaction efficiency is lifted.
Embodiment two
It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, including PMMA resin beds 1 referring to Fig. 1（Poly-methyl methacrylate
Ester）, the front of PMMA resin beds 1 is provided with stiffening layer 2；The front of the stiffening layer 2 is provided with antiglare layer 3；The front of the antiglare layer 3
It is provided with UV-resistant layer 4；The front of the UV-resistant layer 4 is provided with scratch resistant layer 5.The PMMA resin beds 1 include that following weight proportion is former
Material：
Polymethyl methacrylate：60 parts, allyl diglycol acid esters：20 parts, styrene block copolymer：5 parts, benzoyl peroxide
T-butyl formate：2.52 parts, OIT：3 parts, methacryloxypropyl silane：2 parts, dioctyl phthalate：10
Part, silica：3 parts, stabilizer：2 parts, nucleator：0.5 part, initiator：0.12 part, antioxidant：0.5 part.
It is of the invention effectively to prevent dazzling sunshading board eyeglass with PMMA resin beds 1 as basic unit, increased the transparent of eyeglass
Degree, allyl diglycol acid esters can make the mass of PMMA resin beds 1 of synthesis lighter in the raw material of PMMA, and shock resistance is more preferable,
It is explosion-proof, non-breakable, by the eyeglass of above Material synthesis, can make eyeglass that there is more preferable definition.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 1.5 μm, and one is plated by eyeglass
Layer organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, eyeglass is more difficult when shock is subjected to
It is broken, at the same time can also increase by 2% light transmittance and for the follow-up institute's film plating layer of eyeglass improves more preferable adhesive force.
Further, the antiglare layer 3 is nanometer cobalt oxide reticulated film, and the thickness of the antiglare layer 3 is 0.3 μm, described anti-
Dizzy layer 3 includes following weight proportion raw material:
Nanometer cobalt oxide：25 parts, makrolon：10 parts, titanium oxide：7.8 parts, cerium oxide：5 parts, silver bromide：1 part, pigmented powder：
1.6 parts, light diffusing agent：0.58 part, light stabilizer：0.13 part, antioxidant：0.1 part, lubricant：0.98 part.
Antiglare layer of the present invention 3 is nanometer cobalt oxide reticulated film, can be according to sunshine and car light and various high lights
Filtered, added lustre to and hindered the light pollution that shelves are harmful to eyeball, so as to reach different anti-dazzle degree, solved and " filter not
Be in the light " anti-dazzle problem；Meanwhile, road surface " snow blindness " phenomenon is effectively eliminated, dim eyesight, mitigation kopiopia are prevented, especially can be at night
Between meeting when the dazzling high beam of other side is down to soft, comfortable degree, the safety driven under effective guarantee high light.
Further, the UV-resistant layer 4 is uvioresistant film layer, and the thickness of the UV-resistant layer 4 is 0.25 μm, described anti-
Ultraviolet film layer includes following weight proportion raw material：
Acrylic resin：50 parts, nano titanium oxide：12.5 parts, nano zine oxide：10 parts, magnesia：3 parts, propane diols：5
Part, pentaerythrite：12 parts, N- cyclohexylthiophthalimides：1 part, divinylbenzene：0.5 part, methyl oleate：0.5
Part, pigmented powder：0.3 part.
Uvioresistant layer 4 of the present invention is uvioresistant film layer, and the uvioresistant film layer synthesized by above dispensing can be effective
Filters ultra violet line, so as to effectively prevent injury of the ultraviolet to eyes.
Further, the scratch resistant layer 5 is PET resin film layer, and the thickness of the scratch resistant layer 5 is 0.2 μm, the scratch resistant layer 5
Including following weight proportion raw material：
PET resin：60 parts, dimethyl diethylsilane：16 parts, nano-silver powder：3 parts, nano silicon：8 parts, mica powder：2
Part, isocyanates：12 parts, polyvinylpyrrolidone：1.2 parts, ethyl acetate：15 parts, divinylbenzene：0.5 part, oleic acid first
Ester：0.2 part.
Scratch resistant layer of the present invention 5 is PET resin film layer, and the PET resin film layer synthesized by above dispensing can be effective
The Wear-resistant scratch-resistant performance of eyeglass is improved, the service life of eyeglass is improved.So that whole lens function is more complete, cost performance is more
It is high.
Preferably, in the raw material of PMMA resin beds 1, the stabilizer is organic tin stabilizer, it is easy to resin forming,
With good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented
Only resin material is decomposed and old saying；The nucleator is double（To tert-butyl benzene epoxide）Sodium phosphate, by using double（To the tert-butyl group
Phenoxy group）Sodium phosphate improves the tensile strength and impact strength of PMMA resin beds as nucleator, improves PMMA resins
The finish on 1 surface of layer, contributes to lifting PMMA resin beds rigidity, crystallization rate, the transparency.
Preferably, in the raw material of PMMA resin beds 1, the initiator is peroxidized t-butyl perbenzoate, peroxidating
The reaction efficiency of the whole reaction of the one kind in two diisopropyl carbonates, TBHP, effectively lifting, when shortening reaction
Between；The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can have
Effect reduces the oxidized performance of PMMA resin beds 1, extends the service life of eyeglass.
Preferably, in the synthesis material of the antiglare layer 3, the light diffusing agent is styrene and TMS cage type
The random copolymer of polysilsesquioxane, can be effectively increased the scattering and transmission of light, cover the same of light emitting source and dazzling light source
When, whole material can be made to send softer again, light attractive in appearance, graceful reaches the opaque comfortable effect of printing opacity；Light stabilizer
It is N, double (4- amino -2,2,6,6- the tetramethyl-piperidyls) -1,3- benzenedicarboxamides of N'- or hindered amine as light stabilizer 3- (2,2,
6,6- tetramethyl piperidine 4- amino) the third dodecyl gallate, can effectively extend the service life of material.
Preferably, in the synthesis material of the antiglare layer 3, the lubricant is ethylene bis-fatty acid amides series lubricant agent,
The adhering state between a raw material is effectively improved, reaction efficiency is lifted.
Embodiment three
It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, including PMMA resin beds 1 referring to Fig. 1（Poly-methyl methacrylate
Ester）, the front of PMMA resin beds 1 is provided with stiffening layer 2；The front of the stiffening layer 2 is provided with antiglare layer 3；The front of the antiglare layer 3
It is provided with UV-resistant layer 4；The front of the UV-resistant layer 4 is provided with scratch resistant layer 5.The PMMA resin beds 1 include that following weight proportion is former
Material：
Polymethyl methacrylate：70 parts, allyl diglycol acid esters：16 parts, styrene block copolymer：10 parts, peroxidating
T-butyl perbenzoate：3 parts, OIT：4 parts, methacryloxypropyl silane：3 parts, dioctyl phthalate：7 parts,
Silica：4 parts, stabilizer：1.6 parts, nucleator：0.1 part, initiator：0.98 part, antioxidant：0.12 part.
It is of the invention effectively to prevent dazzling sunshading board eyeglass with PMMA resin beds 1 as basic unit, increased the transparent of eyeglass
Degree, allyl diglycol acid esters can make the mass of PMMA resin beds 1 of synthesis lighter in the raw material of PMMA, and shock resistance is more preferable,
It is explosion-proof, non-breakable, by the eyeglass of above Material synthesis, can make eyeglass that there is more preferable definition.
Further, the stiffening layer 2 is organosilicon membrane, and the thickness of the stiffening layer 2 is 2 μm, and one layer is plated by eyeglass
Organosilicon membrane, effectively increases the hardness and scratch resistance capability of eyeglass, also makes eyeglass more not fragile when shock is subjected to
It is broken, at the same time can also increase by 2% light transmittance and for the follow-up institute's film plating layer of eyeglass improves more preferable adhesive force.
Further, the antiglare layer 3 is nanometer cobalt oxide reticulated film, and the antiglare layer thickness is 0.1 μm, described anti-
Dizzy layer 3 includes following weight proportion raw material:
Nanometer cobalt oxide：30 parts, makrolon：20 parts, titanium oxide：5 parts, cerium oxide：4 parts, silver bromide：2 parts, pigmented powder：1
Part, light diffusing agent：0.9 part, light stabilizer：0.3 part, antioxidant：0.5 part, lubricant：0.1 part.
Antiglare layer of the present invention 3 is nanometer cobalt oxide reticulated film, can be according to sunshine and car light and various high lights
Filtered, added lustre to and hindered the light pollution that shelves are harmful to eyeball, so as to reach different anti-dazzle degree, solved and " filter not
Be in the light " anti-dazzle problem；Meanwhile, road surface " snow blindness " phenomenon is effectively eliminated, dim eyesight, mitigation kopiopia are prevented, especially can be at night
Between meeting when the dazzling high beam of other side is down to soft, comfortable degree, the safety driven under effective guarantee high light.
Further, the UV-resistant layer 4 is uvioresistant film layer, and the thickness of the UV-resistant layer 4 is 0.2 μm, the anti-purple
Theca externa includes following weight proportion raw material：
Acrylic resin：40 parts, nano titanium oxide：10 parts, nano zine oxide：8 parts, magnesia：5 parts, propane diols：10 parts,
Pentaerythrite：8 parts, N- cyclohexylthiophthalimides：2 parts, divinylbenzene：1 part, methyl oleate：0.1 part, color
Plain powder：0.1 part.
Uvioresistant layer 4 of the present invention is uvioresistant film layer, and the uvioresistant film layer synthesized by above dispensing can be effective
Filters ultra violet line, so as to effectively prevent injury of the ultraviolet to eyes.
Further, the scratch resistant layer 5 is PET resin film layer, and the thickness of the scratch resistant layer 5 is 0.4 μm, the scratch resistant layer 5
Including following weight proportion raw material：
PET resin：50 parts, dimethyl diethylsilane：10 parts, nano-silver powder：4 parts, nano silicon：6.5 parts, mica
Powder：3 parts, isocyanates：6 parts, polyvinylpyrrolidone：1.6 parts, ethyl acetate：20 parts, divinylbenzene：0.1 part, oleic acid
Methyl esters：0.3 part.
Scratch resistant layer of the present invention 5 is PET resin film layer, and the PET resin film layer synthesized by above dispensing can be effective
The Wear-resistant scratch-resistant performance of eyeglass is improved, the service life of eyeglass is improved.So that whole lens function is more complete, cost performance is more
It is high.
Preferably, in the raw material of PMMA resin beds 1, the stabilizer is organic tin stabilizer, it is easy to resin forming,
With good heat endurance and the transparency, the UV resistance of synthetic resin can be increased by using organic tin stabilizer, prevented
Only resin material is decomposed and old saying；The nucleator is double（To tert-butyl benzene epoxide）Sodium phosphate, by using double（To the tert-butyl group
Phenoxy group）Sodium phosphate improves the tensile strength and impact strength of PMMA resin beds as nucleator, improves PMMA resins
The finish on 1 surface of layer, contributes to lifting PMMA resin beds rigidity, crystallization rate, the transparency.
Preferably, in the raw material of PMMA resin beds 1, the initiator is peroxidized t-butyl perbenzoate, peroxidating
The reaction efficiency of the whole reaction of the one kind in two diisopropyl carbonates, TBHP, effectively lifting, when shortening reaction
Between；The antioxidant is dibutyl hydroxy toluene or tetraethyl resorcinol, and with low volatilization, the performance of hydrolysis can have
Effect reduces the oxidized performance of PMMA resin beds 1, extends the service life of eyeglass.
Preferably, in the synthesis material of the antiglare layer 3, the light diffusing agent is styrene and TMS cage type
The random copolymer of polysilsesquioxane, can be effectively increased the scattering and transmission of light, cover the same of light emitting source and dazzling light source
When, whole material can be made to send softer again, light attractive in appearance, graceful reaches the opaque comfortable effect of printing opacity；Light stabilizer
It is N, double (4- amino -2,2,6,6- the tetramethyl-piperidyls) -1,3- benzenedicarboxamides of N'- or hindered amine as light stabilizer 3- (2,2,
6,6- tetramethyl piperidine 4- amino) the third dodecyl gallate, can effectively extend the service life of material.
Preferably, in the synthesis material of the antiglare layer 3, the lubricant is ethylene bis-fatty acid amides series lubricant agent,
The adhering state between a raw material is effectively improved, reaction efficiency is lifted.
The a kind of of present invention offer effectively prevents dazzling automotive sunshade panel eyeglass, with PMMA resin beds as basic unit, increases
The transparency of eyeglass, allyl diglycol acid esters can make the PMMA resin bed quality of synthesis lighter in the raw material of PMMA, anti-impact
Hit performance more preferably, it is non-breakable, by the eyeglass of above Material synthesis, can make eyeglass that there is more preferable definition.Furthermore, this hair
The a kind of of bright offer effectively prevents dazzling automotive sunshade panel eyeglass, and the antiglare layer is nanometer cobalt oxide reticulated film, can root
Filtered according to sunshine and car light and various high lights, added lustre to and hindered the light pollution that shelves are harmful to eyeball, so as to reach not
Same anti-dazzle degree, solves the anti-dazzle problem of " filter and be not in the light "；Meanwhile, road surface " snow blindness " phenomenon is effectively eliminated, prevent eye
Flower, mitigation kopiopia, especially can be down to soft, comfortable degree, effectively when meeting at night by the dazzling high beam of other side
The safety driven under high light is ensured.Additionally, present invention offer is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, except it
With high-permeability, can effectively prevent dazzling, make the soft of high light change, provide clear comfortable driving vision to human pilot,
Alleviate the advantage accident of the visual fatigue of human pilot；Meanwhile, also with UV resistance, scratch resistant function, vdiverse in function, cost performance is high
The characteristics of.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
Good embodiment has been described in detail to the present invention, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should cover in power of the invention
In sharp claimed range.
Claims (9)
1. it is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that including PMMA resin beds, the PMMA resins
Layer front is provided with stiffening layer；
The stiffening layer front is provided with antiglare layer；
The antiglare layer front is provided with UV-resistant layer；
The UV-resistant layer front is provided with scratch resistant layer；
The PMMA resin beds include following weight proportion raw material：
Polymethyl methacrylate：60~70 parts, allyl diglycol acid esters：10~20 parts, styrene block copolymer：5~
10 parts, peroxidized t-butyl perbenzoate：2~3 parts, OIT：3~5 parts, methacryloxypropyl silane：It is 2~3 parts, adjacent
Dioctyl phthalate：5~10 parts, silica：3~5 parts, stabilizer：1~2 part, nucleator：0.1~1 part, initiator：
0.1~1 part, antioxidant：0.1~0.5 part.
2. it is according to claim 1 a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that the stiffened
Layer is organosilicon membrane, and the thickness of the stiffening layer is 1~2 μm.
3. it is according to claim 1 a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that described anti-dazzle
Layer is nanometer cobalt oxide reticulated film, and the antiglare layer thickness is 0.1~0.5 μm, and the antiglare layer includes following weight proportion
Raw material:
Nanometer cobalt oxide：20~30 parts, makrolon：10~20 parts, titanium oxide：5~10 parts, cerium oxide：3~5 parts, bromination
Silver：1~2 part, pigmented powder：1~2 part, light diffusing agent：0.1~1 part, light stabilizer：0.1~0.5 part, antioxidant：0.1~
0.5 part, lubricant：0.1~1 part.
4. it is according to claim 1 a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that described anti-
Ultraviolet layer is uvioresistant film layer, and the thickness of the UV-resistant layer is 0.2~0.3 μm, and the uvioresistant film layer includes following weight
Proportioning raw material：
Acrylic resin：40~50 parts, nano titanium oxide：10~15 parts, nano zine oxide：5~10 parts, magnesia：3~5
Part, propane diols：5~10 parts, pentaerythrite：8~12 parts, N- cyclohexylthiophthalimides：1~2 part, divinyl
Benzene：0.1~1 part, methyl oleate：0.1~1 part, pigmented powder：0.1~0.5 part.
5. it is according to claim 1 a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that described scratch resistant
Layer is PET resin film layer, and the thickness of the scratch resistant layer is 0.2~0.4 μm, and the scratch resistant layer includes following weight proportion raw material：
PET resin：50~60 parts, dimethyl diethylsilane：10~20 parts, nano-silver powder：3~5 parts, nano silicon：4
~8 parts, mica powder：2~3 parts, isocyanates：6~12 parts, polyvinylpyrrolidone：1~2 part, ethyl acetate：10~20 parts,
Divinylbenzene：0.1~0.5 part, methyl oleate：0.2~0.4 part.
6. it is according to claim 1 a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that the stabilization
Agent is organic tin stabilizer, and the nucleator is double（To tert-butyl benzene epoxide）Sodium phosphate.
7. it is according to claim 1 a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that the initiation
Agent is the one kind in peroxidized t-butyl perbenzoate, di-isopropyl peroxydicarbonate, TBHP, described anti-oxidant
Agent is dibutyl hydroxy toluene or tetraethyl resorcinol.
8. it is according to claim 3 a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that the light expands
Powder is the random copolymer of styrene and TMS cage type polysilsesquioxane, and light stabilizer is N, double (the 4- ammonia of N'-
Base -2,2,6,6- tetramethyl-piperidyls) -1,3- benzenedicarboxamides or hindered amine as light stabilizer 3- (2,2,6,6- tetramethyl piperidines
4- amino) the third dodecyl gallate.
9. it is according to claim 3 a kind of effectively to prevent dazzling automotive sunshade panel eyeglass, it is characterised in that the lubrication
Agent is ethylene bis-fatty acid amides series lubricant agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710024100.1A CN106863976A (en) | 2017-01-13 | 2017-01-13 | It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710024100.1A CN106863976A (en) | 2017-01-13 | 2017-01-13 | It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106863976A true CN106863976A (en) | 2017-06-20 |
Family
ID=59157360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710024100.1A Pending CN106863976A (en) | 2017-01-13 | 2017-01-13 | It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106863976A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987695A (en) * | 2017-12-23 | 2018-05-04 | 苏州佳亿达电器有限公司 | Energy-conserving road lamp light-transmitting plate |
| CN112477301A (en) * | 2019-09-12 | 2021-03-12 | 颖华科技股份有限公司 | Light-permeable plastic plate structure with curved surface and manufacturing method thereof |
| CN112596270A (en) * | 2020-12-02 | 2021-04-02 | 明月镜片股份有限公司 | Novel infrared-proof lens |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1551830A (en) * | 2001-09-06 | 2004-12-01 | ����̩˹���������ι�˾ | Polycarbonate automotive window panels with coating system blocking UV and IR radiation and providing abrasion resistant surface |
| CN101588923A (en) * | 2006-12-28 | 2009-11-25 | 埃克阿泰克有限责任公司 | Polycarbonate glazing system and method for making the same |
| CN101678580A (en) * | 2007-05-01 | 2010-03-24 | 埃克阿泰克有限责任公司 | Poly (methyl methacrylate) plate and manufacture method thereof with UV curable printed patterns |
| CN205522833U (en) * | 2016-04-07 | 2016-08-31 | 广州跃美塑料工业有限公司 | Prevent scraping colored polycarbonate board |
-
2017
- 2017-01-13 CN CN201710024100.1A patent/CN106863976A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1551830A (en) * | 2001-09-06 | 2004-12-01 | ����̩˹���������ι�˾ | Polycarbonate automotive window panels with coating system blocking UV and IR radiation and providing abrasion resistant surface |
| CN101588923A (en) * | 2006-12-28 | 2009-11-25 | 埃克阿泰克有限责任公司 | Polycarbonate glazing system and method for making the same |
| CN101678580A (en) * | 2007-05-01 | 2010-03-24 | 埃克阿泰克有限责任公司 | Poly (methyl methacrylate) plate and manufacture method thereof with UV curable printed patterns |
| CN205522833U (en) * | 2016-04-07 | 2016-08-31 | 广州跃美塑料工业有限公司 | Prevent scraping colored polycarbonate board |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987695A (en) * | 2017-12-23 | 2018-05-04 | 苏州佳亿达电器有限公司 | Energy-conserving road lamp light-transmitting plate |
| CN112477301A (en) * | 2019-09-12 | 2021-03-12 | 颖华科技股份有限公司 | Light-permeable plastic plate structure with curved surface and manufacturing method thereof |
| CN112596270A (en) * | 2020-12-02 | 2021-04-02 | 明月镜片股份有限公司 | Novel infrared-proof lens |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106863976A (en) | It is a kind of effectively to prevent dazzling automotive sunshade panel eyeglass | |
| CN1295171C (en) | Neodymium oxide doped vehicle windshield, safety glazing material and window glass | |
| CN206456051U (en) | A kind of anti-glare automotive sunshade panel eyeglass | |
| CN106626658A (en) | Automobile sunvisor lens capable of effectively weakening high light | |
| CN204964919U (en) | Polarisation double -purpose lens discolours | |
| US20110233958A1 (en) | See thru sun visor | |
| WO2020169119A1 (en) | Infrared reflective film-type optical filter panel, use thereof against brake light glare, and optical filter | |
| CN114103800A (en) | Light emitting assembly of vehicle window light-transmitting piece and vehicle | |
| CN2862060Y (en) | Resin color change lens with anti-dazzle night vision | |
| CN106827699A (en) | A kind of antibacterial wear-resisting automotive sunshade panel eyeglass and eyeglass moulding process | |
| CN206456049U (en) | A kind of automotive sunshade panel eyeglass of the strong light of softening | |
| CN106863967A (en) | A kind of automotive sunshade panel eyeglass of efficient prevention snow blindness | |
| CN201901648U (en) | Anti-reflection automobile glass | |
| CN207274550U (en) | A kind of anti-dazzle reflection-proof rearview mirror | |
| CN203902214U (en) | Vehicle and front car window with sun shading film | |
| CN205942188U (en) | Car sun visor is LCD screen and car sun visor board for board | |
| CN201107488Y (en) | Glasses lens special for driver | |
| CN207081903U (en) | A kind of sunglass lens for improving drive safety | |
| CN206456050U (en) | A kind of automotive sunshade panel eyeglass of efficient antiultraviolet | |
| CN106827755A (en) | The automotive sunshade panel eyeglass and eyeglass moulding process of a kind of efficient antiultraviolet | |
| CN205589109U (en) | Anti -glare rearview mirror | |
| CN106626663A (en) | Multifunctional automobile sun shield lens and lens forming process | |
| CN201035166Y (en) | Complex structure for nights drive glasses lens | |
| CN107329193A (en) | A kind of lightweight anti-blue light uvioresistant antistatic automatically cleaning automotive sunshade panel eyeglass | |
| CN206456054U (en) | A kind of multifunctional automobile sun-shading plate eyeglass |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170620 |