CN106863943A - A kind of molybdenum trioxide/nano-carbon material modified fiber cloth reinforced resin based composites and preparation method thereof - Google Patents
A kind of molybdenum trioxide/nano-carbon material modified fiber cloth reinforced resin based composites and preparation method thereof Download PDFInfo
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- CN106863943A CN106863943A CN201710089304.3A CN201710089304A CN106863943A CN 106863943 A CN106863943 A CN 106863943A CN 201710089304 A CN201710089304 A CN 201710089304A CN 106863943 A CN106863943 A CN 106863943A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/08—Impregnating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
- B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
- B32B2262/0269—Aromatic polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
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- Chemical & Material Sciences (AREA)
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Abstract
The invention discloses a kind of molybdenum trioxide/nano-carbon material modified fiber cloth reinforced resin based composites and preparation method thereof, it is prepared from by vacuum assistant resin injection by following raw material：0.1~5 part of molybdenum trioxide/nano-carbon material, 30~70 parts of epoxy resin, 10~50 parts of curing agent, 2~30 parts of fabric, antifriction particle is dispersed in resin matrix relative to traditional, fiber reinforced resin based composites prepared by mould technology are then shifted by vacuum resin, a kind of molybdenum trioxide/nano-carbon material modified fiber cloth reinforced epoxy composite prepared using the present invention has intensity high, wearability is good, the advantage for easily preparing.
Description
Technical field
The present invention relates to a kind of molybdenum trioxide/nano-carbon material modified fiber cloth reinforced resin based composites and its system
Preparation Method, belongs to field of compound material.
Background technology
Fiber reinforced resin based composites are because its proportion is small, specific strength is high, mechanical property is good, corrosion-resistant, insulation
The advantages of property good, heat-resist and light weight and be widely used in the every field of national product.For example：It is building trade, chemicalization
The field such as industrial and commercial bank's industry, automobile and railway traffic carrier, electrical equipment industry and Communication Engineering.
High-abrasive material is widely used in industrial every field, and with science and technology and the height of modern industry
Speed development, the caused economic loss such as the energy caused because material weares and teares and material consumption increase is quite surprising.In recent years
Come, to material abrasion and the research of high-abrasive material, increasingly cause the extensive attention of domestic and international people.The conventional fiber for preparing is knitted
The method of thing reinforced resin base wearing composite material is that abrasion-proof particle is dispersed in resin matrix, then shifts mould by resin
Technology prepares fiber reinforced resin base wearing composite material.Fiber reinforced resin base prepared by this method is wear-resisting
Abrasion-proof particle content is few in composite, and the crocking resistance of composite is poor.How increased fiber reinforced resin base
The content of abrasion-proof particle in composite, the anti-wear performance for improving composite is the problem that researcher faces.If will be resistance to
Abrasive particle is made lamelliform, is then shifted mould technology and is prepared by vacuum resin and contains the compound of film wearing layer in material surface
Material, then be remarkably improved the anti-wear performance of composite.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of molybdenum trioxide/nano-carbon material modified fiber cloth enhancing
Polymer matrix composites, to improve the anti-wear performance of fiber reinforced resin based composites.
In order to realize the above object a kind of molybdenum trioxide of the invention/nano-carbon material modified fiber cloth reinforced resin base
The technical scheme that composite is used is：A kind of molybdenum trioxide/nano-carbon material modified fiber cloth reinforced epoxy is answered
Condensation material, is prepared from by vacuum assistant resin injection by following raw material：0.1~5 part of molybdenum trioxide/nano-carbon material, ring
30~70 parts of oxygen tree fat, 10~50 parts of curing agent, 2~30 parts of fabric.
Further, the molybdenum trioxide/nano-carbon material can be molybdenum trioxide/oxide/carbon nanometer tube composite materials or three
Molybdenum oxide/graphene oxide composite material.
Further, the molybdenum trioxide/nano-carbon material is prepared into film shape.
Further, the thickness of the molybdenum trioxide/nano-carbon material can be 0.01mm~2.0mm.
According to another aspect of the present invention, there is provided above-mentioned molybdenum trioxide/nano-carbon material modified fiber cloth enhancing
The preparation method of polymer matrix composites, the resin matrix for being used can be epoxy resin or vinylite.
A kind of molybdenum trioxide of the invention/nano-carbon material modified fiber cloth reinforced resin based composites and its preparation
Method, the resin curing agent that the resin curing agent for being used is prepared in the market known method, without particular/special requirement.
A kind of molybdenum trioxide of the invention/nano-carbon material modified fiber cloth reinforced resin based composites and its preparation
Method, the fabric for being used can be glass fabric, carbon fibre fabric or aramid fabric.
A kind of molybdenum trioxide of the invention/nano-carbon material modified fiber cloth reinforced resin based composites and its preparation
Method, the fabric for being used needs first to be cut into square piece shape when in use.
A kind of molybdenum trioxide of the invention/nano-carbon material modified fiber cloth reinforced resin based composites and its preparation
Method, the glass fabric for being used can be fiberglass needled mat, glass fibre continuous strand felt, glass chopped original
Silk felt, fiberglass surfacing mat, glass fibre loop bonding chopped mat, woven glass roving fabric weaving mat etc..
A kind of molybdenum trioxide of the invention/nano-carbon material modified fiber cloth reinforced resin based composites and its preparation
Method, the carbon fibre fabric for being used can be woven carbon fiber cloth, knitting carbon cloth, weaving carbon fiber cloth, carbon-fibre nonwoven
Cloth etc..
A kind of molybdenum trioxide of the invention/nano-carbon material modified fiber cloth reinforced resin based composites and its preparation
Method, the aramid fabric for being used can be aramid fiber woven roving, aramid fiber non-woven fabrics, aramid fiber twisting spun yarn
Cloth etc..
Heretofore described oxide/carbon nanometer tube can be prepared using commercially available product or use chemical oxidization method, below be carried
Particular content for chemical oxidization method is easy to the understanding of the present invention：A certain amount of CNT is added to and is filled volume ratio and is
3:In 1 concentrated sulfuric acid and concentrated nitric acid mixed liquor, at 110 DEG C react 1 hour, product through filtering and washing to neutrality, then 80
DEG C vacuum drying oven in dry 12 hours after obtain oxide/carbon nanometer tube.
Heretofore described graphene oxide can use commercially available product or the Hummers methods preparation using routine,
The particular content of hummers methods presented below is easy to the understanding of the present invention：The concentrated sulfuric acid, graphite and nitric acid are added in beaker
Sodium, is cooled to 0 DEG C~4 DEG C in ice bath, and potassium permanganate is slowly added under stirring condition, and reacting liquid temperature is made 20 during being somebody's turn to do
Below DEG C；Then by beaker as in 35 DEG C of waters bath with thermostatic control, 0.5~1h is stirred in continuation；Water is slowly added under agitation, is made
Reacting liquid temperature reaches 98 DEG C~100 DEG C, continues to stir 15min~60min；Added after finally reaction solution is diluted with water excessive
Oxidation aqueous solution of hydrogen, graphene oxide is obtained after washing, filtering.
Molybdenum trioxide/nano-carbon material of the present invention can be prepared using using hydrothermal oxidization method, hydro-thermal presented below
The particular content of oxidizing process is easy to the understanding of the present invention：Nano-carbon material, molybdate and peroxide are added in hydrothermal reaction kettle
Change hydrogen, then the hydrothermal reaction kettle after sealing is put into 150~240 DEG C of baking oven and is reacted 12~48 hours, finally by liquid
Suction filtration is carried out, the composite of molybdenum trioxide/nano-carbon material has just been obtained.
Molybdenum trioxide/nano-carbon material of the present invention can be prepared using hydrothermal oxidization method, wherein nano-carbon material, molybdenum
The weight ratio of hydrochlorate and hydrogen peroxide can be 1:0.1~20:1~5.
Molybdenum trioxide/nano-carbon material of the present invention is prepared into film shape.Preparation method is as follows：Will be using hydro-thermal
Molybdenum trioxide/nano-carbon material solution prepared by method carries out suction filtration, by molybdenum trioxide/nano-carbon material and seperation film one after suction filtration
Rise to be put into frozen drying case and carry out freeze-drying, after drying by into the molybdenum trioxide/nano-carbon material of film-form from point
Peeled off on film.
A kind of vacuum of molybdenum trioxide of the invention/nano-carbon material modified fiber cloth reinforced epoxy composite
Assistant formation method, concrete technology method includes：
(1) 2~30 parts of fabric is laid in template；
(2) the superiors in fabric spread molybdenum trioxide/nano-sized carbon that thickness is the thick film-forms of 0.01~2.0mm
Material；
(3) molybdenum trioxide/nano-carbon material modified fiber cloth reinforced resin is prepared using vacuum resin transfer mould technology
Based composites.
Antifriction particle is dispersed in resin matrix relative to traditional, then shifting mould technology by vacuum resin prepares
Fiber reinforced resin based composites, using the present invention prepare a kind of molybdenum trioxide/nano-carbon material modified fibre
Fabric reinforced epoxy composite has intensity high, and wearability is good, the advantage for easily preparing
Brief description of the drawings
Constitute the part of this specification, show of the invention being preferable to carry out for further understanding accompanying drawing of the invention
Example, and be used for illustrating principle of the invention together with specification.
Fig. 1 be vacuum assistant resin injection prepare molybdenum trioxide/nano-carbon material modified fiber cloth reinforced epoxy answer
Condensation material schematic flow sheet.
Specific embodiment
Embodiments of the invention are described in detail below in conjunction with accompanying drawing, but the present invention can be defined by the claims
Multitude of different ways with covering is implemented.
A kind of molybdenum trioxide of the present embodiment/nano-carbon material modified fiber cloth reinforced epoxy composite, be
Mould technology is shifted by the primary raw material of following weight portion by vacuum resin to be prepared from：Molybdenum trioxide/oxide/carbon nanometer tube 3
Part, 60 parts of epoxy resin, 20 parts of curing agent, 20 parts of woven carbon fiber cloth.
(1) it is 1 by weight ratio:10:2 oxide/carbon nanometer tube, ammonium molybdate and hydrogen peroxide be put into hydrothermal reaction kettle in
200 DEG C react 24 hours, molybdenum trioxide/oxide/carbon nanometer tube composite materials are made using the method for suction filtration then it is membranaceous, it is low
To be peeled off from seperation film into the molybdenum trioxide/oxide/carbon nanometer tube of film-form after warm freeze drying box；
(2) it is 3 parts, three oxygen of the film-form that thickness is 1mm that the superiors in 20 parts of woven carbon fiber cloth spread weight portion
Change molybdenum/oxide/carbon nanometer tube composite materials；
(3) 60 parts of epoxy resin and 20 parts of curing agent are well mixed, vacuum defoamation；
(4) preparing molybdenum trioxide/oxide/carbon nanometer tube modified carbon fiber fabric using vacuum resin transfer mould technology strengthens
Epoxy resin-base composite material.
Embodiment 2
A kind of molybdenum trioxide of the present embodiment/nano-carbon material modified fiber cloth reinforced epoxy composite, be
Mould technology is shifted by the primary raw material of following weight portion by vacuum resin to be prepared from：5 parts of molybdenum trioxide/graphene oxide,
70 parts of epoxy resin, 50 parts of curing agent, 30 parts of fiberglass needled mat.
(1) it is 1 by weight ratio:20:5 graphene oxide, ammonium molybdate and hydrogen peroxide are put into hydrothermal reaction kettle in 150
DEG C reaction 48 hours, molybdenum trioxide/graphene oxide is made using the method for suction filtration then it is membranaceous, after frozen drying case
To be peeled off from seperation film into the molybdenum trioxide/graphene oxide of film-form；
(2) the superiors in 20 parts of fiberglass needled mats spread weight portion be 5 parts, thickness be the three of the film-form of 2mm
Molybdenum oxide/graphene oxide composite material；
(3) 70 parts of epoxy resin and 50 parts of curing agent are well mixed, vacuum defoamation；
(4) molybdenum trioxide/graphene oxide modified glass-fiber Nomex is prepared using vacuum resin transfer mould technology to increase
Strong epoxy resin-base composite material.
Embodiment 3
A kind of molybdenum trioxide of the present embodiment/nano-carbon material modified fiber cloth reinforced epoxy composite, be
Mould technology is shifted by the primary raw material of following weight portion by vacuum resin to be prepared from：Molybdenum trioxide/graphene oxide 0.1
Part, 30 parts of epoxy resin, 30 parts of curing agent, 2 parts of aramid fiber woven roving.
(1) it is 1 by weight ratio:0.1:1 graphene oxide, ammonium molybdate and hydrogen peroxide be put into hydrothermal reaction kettle in
240 DEG C are reacted 12 hours, and molybdenum trioxide/graphene oxide then is made into membranaceous, frozen drying using the method for suction filtration
To be peeled off from seperation film into the molybdenum trioxide/graphene oxide of film-form after case；
(2) the superiors in 2 parts of aramid fiber woven rovings spread that weight portion is 0.1 part, thickness is for 0.1mm's is thin
Membranaceous molybdenum trioxide/graphene oxide composite material；
(3) 30 parts of epoxy resin and 30 parts of curing agent are well mixed, vacuum defoamation；
(4) molybdenum trioxide/graphene oxide modification of aramid fiber roving is prepared using vacuum resin transfer mould technology
Fabric reinforced epoxy based composites.
Embodiment 4
A kind of molybdenum trioxide of the present embodiment/nano-carbon material modified fiber cloth reinforced epoxy composite, be
Mould technology is shifted by the primary raw material of following weight portion by vacuum resin to be prepared from：Molybdenum trioxide/oxide/carbon nanometer tube 4
Part, 50 parts of epoxy resin, 10 parts of curing agent, 25 parts of carbon fiber nonwoven fabric.
(1) it is 1 by weight ratio:15:2 oxide/carbon nanometer tube, ammonium molybdate and hydrogen peroxide be put into hydrothermal reaction kettle in
180 DEG C react 36 hours, molybdenum trioxide/oxide/carbon nanometer tube is made using the method for suction filtration then it is membranaceous, low temperature cold freeze
To be peeled off from seperation film into the molybdenum trioxide/oxide/carbon nanometer tube of film-form after dry case；
(2) the superiors in 25 parts of carbon fiber nonwoven fabrics spread weight portion be 4 parts, thickness be the three of the film-form of 1.5mm
Molybdenum oxide/oxide/carbon nanometer tube composite materials；
(3) 50 parts of epoxy resin and 10 parts of curing agent are well mixed, vacuum defoamation；
(4) molybdenum trioxide/oxide/carbon nanometer tube modified carbon fiber non-woven fabrics is prepared using vacuum resin transfer mould technology to increase
Strong epoxy resin-base composite material.
Embodiment 5
A kind of molybdenum trioxide of the present embodiment/nano-carbon material modified fiber cloth reinforced epoxy composite, be
Mould technology is shifted by the primary raw material of following weight portion by vacuum resin to be prepared from：2 parts of molybdenum trioxide/graphene oxide,
45 parts of epoxy resin, 20 parts of curing agent, 15 parts of glass fibre loop bonding chopped mat.
(1) it is 1 by weight ratio:8:3 graphene oxide, ammonium molybdate and hydrogen peroxide are put into hydrothermal reaction kettle in 190
DEG C reaction 28 hours, molybdenum trioxide/graphene oxide is made using the method for suction filtration then it is membranaceous, after frozen drying case
To be peeled off from seperation film into the molybdenum trioxide/graphene oxide of film-form；
(2) the superiors in 15 parts of glass fibre loop bonding chopped mats spread the film that weight portion is 2 parts, thickness is 1.5mm
Molybdenum trioxide/the graphene oxide composite material of shape；
(3) 45 parts of epoxy resin and 20 parts of curing agent are well mixed, vacuum defoamation；
(4) molybdenum trioxide/graphene oxide modified glass-fiber loop bonding is prepared using vacuum resin transfer mould technology to be chopped
Felt reinforced epoxy based composites.
Embodiment 6
A kind of molybdenum trioxide of the present embodiment/nano-carbon material modified fiber cloth reinforced epoxy composite, be
Mould technology is shifted by the primary raw material of following weight portion by vacuum resin to be prepared from：Molybdenum trioxide/oxide/carbon nanometer tube 1
Part, 40 parts of epoxy resin, 15 parts of curing agent, 10 parts of aramid fiber non-woven fabrics.
(1) it is 1 by weight ratio:5:2.5 oxide/carbon nanometer tube, ammonium molybdate and hydrogen peroxide be put into hydrothermal reaction kettle in
220 DEG C react 18 hours, molybdenum trioxide/oxide/carbon nanometer tube is made using the method for suction filtration then it is membranaceous, low temperature cold freeze
To be peeled off from seperation film into the molybdenum trioxide/oxide/carbon nanometer tube of film-form after dry case；
(2) it is 1 part, three oxygen of the film-form that thickness is 0.5mm that the superiors in 10 parts of aramid fiber non-woven fabrics spread weight portion
Change molybdenum/oxide/carbon nanometer tube composite materials；
(3) 40 parts of epoxy resin and 15 parts of curing agent are well mixed, vacuum defoamation；
(4) preparing molybdenum trioxide/oxide/carbon nanometer tube modifying aramid fiber non-woven fabrics using vacuum resin transfer mould technology strengthens
Epoxy resin-base composite material.
Experimental example
Frictional behaviour experiment is carried out to the composite in above-described embodiment 1~6, the result of the test for obtaining is as shown in table 1：
1 molybdenum trioxide of table/nano-carbon material modified fiber cloth reinforced epoxy composite-material abrasive results of property
The preferred embodiments of the present invention are these are only, is not intended to limit the invention, for those skilled in the art
For member, the present invention can have various modifications and variations.All any modifications within the spirit and principles in the present invention, made,
Equivalent, improvement etc., should be included within the scope of the present invention.
Claims (6)
1. a kind of molybdenum trioxide/nano-carbon material modified fiber cloth reinforced resin based composites, it is characterised in that be by with
Lower raw material is prepared from by vacuum assistant resin injection：0.1~5 part of molybdenum trioxide/nano-carbon material, epoxy resin 30~70
Part, 10~50 parts of curing agent, 2~30 parts of fabric.
2. molybdenum trioxide according to claim 1/nano-carbon material modified fiber cloth reinforced resin based composites, its
Be characterised by, the molybdenum trioxide/nano-carbon material can for molybdenum trioxide/oxide/carbon nanometer tube composite materials or molybdenum trioxide/
Graphene oxide composite material；Molybdenum trioxide/the nano-carbon material is prepared into film shape；Molybdenum trioxide/the nano-sized carbon
The thickness of material can be 0.01mm~2.0mm.
3. molybdenum trioxide according to claim 1/nano-carbon material modified fiber cloth reinforced resin based composites, its
It is characterised by, the resin matrix for being used can be epoxy resin or vinylite, the resin curing agent for being used is in the market
The resin curing agent prepared with known method, without particular/special requirement.
4. molybdenum trioxide according to claim 1/nano-carbon material modified fiber cloth reinforced resin based composites, its
It is characterised by, the fabric for being used can be glass fabric, carbon fibre fabric or aramid fabric, the fibre for being used
Dimensional fabric needs first to be cut into square piece shape when in use.
5. molybdenum trioxide according to claim 4/nano-carbon material modified fiber cloth reinforced resin based composites, its
It is characterised by, the glass fabric for being used can be short for fiberglass needled mat, glass fibre continuous strand felt, glass fibre
Cut precursor felt, fiberglass surfacing mat, glass fibre loop bonding chopped mat, woven glass roving fabric weaving mat etc.；Used
Carbon fibre fabric can be woven carbon fiber cloth, knitting carbon cloth, weaving carbon fiber cloth, carbon fiber nonwoven fabric etc.；Used
Aramid fabric can be aramid fiber woven roving, aramid fiber non-woven fabrics, aramid fiber twisting crocus cloth etc..
6. any one of a kind of claim 1 to 5 molybdenum trioxide/nano-carbon material modified fiber cloth reinforced resin base composite wood
The preparation method of material, it is characterised in that comprise the following steps：
S1：Prepare oxide/carbon nanometer tube or graphene oxide；
S2：Prepare molybdenum trioxide/nano-carbon material；
S3：Assistant formation.
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| CN201710089304.3A CN106863943B (en) | 2017-02-20 | 2017-02-20 | A kind of molybdenum trioxide/nano-carbon material modified fiber cloth reinforced resin based composites and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448239A (en) * | 2014-10-11 | 2015-03-25 | 浙江大学 | High-strength epoxy resin composite material and preparation method thereof |
| CN106366443A (en) * | 2016-09-06 | 2017-02-01 | 株洲时代新材料科技股份有限公司 | Long glass fiber enhanced polypropylene material, and preparation method and application thereof |
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2017
- 2017-02-20 CN CN201710089304.3A patent/CN106863943B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448239A (en) * | 2014-10-11 | 2015-03-25 | 浙江大学 | High-strength epoxy resin composite material and preparation method thereof |
| CN106366443A (en) * | 2016-09-06 | 2017-02-01 | 株洲时代新材料科技股份有限公司 | Long glass fiber enhanced polypropylene material, and preparation method and application thereof |
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