CN106861423A - A kind of organic gas catalyst oxidative system - Google Patents

A kind of organic gas catalyst oxidative system Download PDF

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Publication number
CN106861423A
CN106861423A CN201710090709.9A CN201710090709A CN106861423A CN 106861423 A CN106861423 A CN 106861423A CN 201710090709 A CN201710090709 A CN 201710090709A CN 106861423 A CN106861423 A CN 106861423A
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CN
China
Prior art keywords
reactor
photodissociation
cabin
ultraviolet lamp
lamp tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710090709.9A
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Chinese (zh)
Inventor
车继鲁
付大勇
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Individual
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Individual
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Publication date
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Priority to CN201710090709.9A priority Critical patent/CN106861423A/en
Publication of CN106861423A publication Critical patent/CN106861423A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8668Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/22Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention discloses a kind of organic gas catalyst oxidative system, including:Some groups of reactors in parallel;It is characterized in that:The reactor is by some groups of photodissociation cabins, ultraviolet lamp tube, catalyst network is constituted, each photodissociation cabin is connected by adpting flange, catalyst network is to being clipped between adpting flange, the inwall in photodissociation cabin is provided with sprayed coating, ultraviolet lamp tube is fixed with each photodissociation cabin, angle between two adjacent groups ultraviolet lamp tube is 90 °, one end of reactor communicates with air inlet pipe, the other end of reactor is communicated with escaping pipe, between reactor and air inlet pipe, switching valve is equipped between reactor and escaping pipe, the present invention has operating cost low, equipment is simple and reliable, clean environment firendly, strong adaptability, advantage easy to use, can be widely applied for the treatment of all kinds of organic exhaust gas.

Description

A kind of organic gas catalyst oxidative system
Technical field
The invention belongs to the deodorization technique field that sterilizes, and in particular to a kind of organic gas catalyst oxidative system.
Background technology
With the fast development of the industry such as petrochemical industry, pharmaceuticals industry, paint spraying, sewage disposal, the air matter in the world Amount is generally seriously threatened, and atmosphere pollution turns into one of current most prominent environmental problem.Atmosphere pollution have particulate matter and The class of gaseous state thing two, wherein predominantly gaseous contaminant, accounts for more than the 75% of atmosphere pollution total amount.Gaseous contaminant is divided into nothing again Organic pollutants and the major class of organic pollution two, wherein organic pollution account for the overwhelming majority.
Organic exhaust gas not only have stimulation to human body and various sense organs, and with certain toxicity, some can produce " three Cause effect ", accumulated in human body, cause canceration and gene mutation, high risks are caused to health.Meanwhile, can also cause Environmental pollution, forms acid rain, causes photochemical fog, damage the ozone layer, cause climate warming in an atmosphere;Tire out in soil Product, destroys ecological environment;Polluted underground water, so as to influence health indirectly.Therefore, seek cost-effective governance way and Control program has hot issue to be solved as countries in the world.
According to physical form final after treatment come point, pollutant abatement technology can be divided into two classes to organic exhaust gas, and a class is Non-destructive technique is absorption method, can make concentration and separation by changing the physical condition such as temperature, pressure in certain technical process, It is final to be recycled with former physical form, prevented from source or reduce environmental pollution, it is a green for comprehensive utilization of resources Green technology, mainly including solution absorption method, active carbon adsorption, UF membrane and common technique etc. condensation method.It is another kind of to be broken Bad property technology is destruction technology, and the general technology by chemistry or biology makes to be converted into carbon dioxide, water and nontoxic or toxicity Small inorganic matter, mainly this kind of method of technology belongs to environment including heat damage, light degradation, plasma oxidation, biodegradation etc. Friendly technology, the carbon dioxide and vapor of generation do not have toxic action to human body.It is generally organic in organic exhaust gas The concentration of thing is low, and recovery value is limited, and non-destructive treatment technology is because of deficiency in economic performance, it is difficult to large-scale promotion application.And it is hot Often there is the big defect of high energy consumption, floor space in destruction, plasma oxidation, biodegradation, it is difficult to suitable for low concentration, greatly The treatment of flow organic exhaust gas.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of organic gas catalyst oxidative system.
A kind of organic gas catalyst oxidative system, including:Some groups of reactors in parallel;It is characterized in that:The reaction Device is made up of some groups of photodissociation cabins, ultraviolet lamp tube, catalyst networks, and each photodissociation cabin is connected by adpting flange, and catalyst network is to being clipped in Between adpting flange, the inwall in photodissociation cabin is provided with sprayed coating, and ultraviolet lamp tube, two adjacent groups uviol lamp are fixed with each photodissociation cabin Angle between pipe is 90 °, and one end of reactor communicates with air inlet pipe, and the other end of reactor is communicated with escaping pipe, reactor Between air inlet pipe, switching valve is equipped between reactor and escaping pipe.
Preferably, the material of the catalyst network is titanium or titanium dioxide.
Preferably, the material of the sprayed coating spraying is titanium or titanium dioxide.
Operation principle of the invention is:
TiO2Or the catalyst network of Ti materials, sprayed coating, when being penetrated by UV illumination, the electronics on titanium atom is by ultraviolet light Excite, produce electronics-hole pair, this electron-hole pair is combined with water and oxygen in air, can produce a kind of with super The O of strong oxdiative power2-With hydroxyl free radical OH-, can make to decompose generation CO containing the organic matter in organic gas waste gas2And H2O, And the nontoxic inorganic compound of Partial cleansing degraded generation, so as to reach the mesh of the degraded of organic exhaust gas, deodorization, sterilizing 's.
Compared with prior art, beneficial effects of the present invention:
1)By TiO2Or the catalyst network of Ti materials, sprayed coating realize the treatment of organic exhaust gas, without adding other chemical drugs Product, have the advantages that operating cost is low, equipment is simple and reliable, clean environment firendly;
2)By setting some groups of reactors in parallel, while switching valve is installed at the two ends of reactor, can be according to exhausted air quantity Size adjust switching reactor quantity, so as to greatly improve the adaptability of system;Need to safeguard in reactor simultaneously When, turn off switching valve, you can realize the dismounting and maintenance of reactor, it is greatly convenient for users to use.
Brief description of the drawings
Fig. 1 is a kind of structural representation of organic gas catalyst oxidative system of the invention.
Fig. 2 is the partial enlarged drawing at A in Fig. 1.
In figure, 1, air inlet pipe, 2, switching valve, 3, reactor, 4, escaping pipe, 301, photodissociation cabin, 302, sprayed coating, 303, purple Outer fluorescent tube, 304, catalyst network.
Specific embodiment
Referring to Fig. 1, Fig. 2, a kind of organic gas catalyst oxidative system, including:Some groups of reactors 3 in parallel;Its feature It is:The reactor 3 is made up of some groups of photodissociation cabins 301, ultraviolet lamp tube 302, catalyst network 304, and each photodissociation cabin 301 is by connecting Acting flange is connected, and catalyst network 304 pairs is clipped between adpting flange, and the inwall in photodissociation cabin 301 is provided with sprayed coating 302, each light Solution cabin 301 in is fixed with ultraviolet lamp tube 303, the angle between two adjacent groups ultraviolet lamp tube 303 is 90 °, one end of reactor 3 with Air inlet pipe 1 is communicated, and the other end of reactor 3 is communicated with escaping pipe 4, between reactor 3 and air inlet pipe 1, reactor 3 and escaping pipe Switching valve 2 is equipped between 4.
The material of the catalyst network 304 is titanium or titanium dioxide.
The material of the spraying of the sprayed coating 302 is titanium or titanium dioxide.
The present invention in use, works in the following way:
Organic exhaust gas branch to each reactor 3, TiO from air inlet pipe 12Or catalyst network 304, the sprayed coating 302 of Ti materials are by purple When outer fluorescent tube 303 sends ultraviolet light, the electronics on titanium atom is excited by ultraviolet light, produces electronics-hole pair, this Electron-hole pair is combined with water and oxygen in air, can produce a kind of O with superpower oxidizing force2-With hydroxyl freedom Base OH-, can make to decompose generation CO containing the organic matter in organic gas waste gas2And H2O, and Partial cleansing degraded generation is nontoxic Harmless inorganic compound, so as to reach the purpose of the degraded of organic exhaust gas, deodorization, sterilizing, waste gas after treatment is from escaping pipe 4 Discharge.By setting some groups of reactors 3 in parallel, while switching valve 2 is installed at the two ends of reactor 3, can be according to waste gas The size of amount adjusts the quantity of reactor 3 of switching, so as to greatly improve the adaptability of system;Needed in reactor 3 simultaneously When safeguarding, shut-off needs the two ends switching valve 2 of reactor maintenance 3, you can realizes the dismounting and maintenance of reactor 3, greatly facilitates The use of user.
Technical solution of the present invention is exemplarily described above in conjunction with accompanying drawing to invention, it is clear that the present invention is implemented It is not subject to the restrictions described above, as long as employ the various unsubstantialities that the method for the present invention is conceived and technical scheme is carried out changing Enter, or it is not improved the design of invention and technical scheme are directly applied into other occasions, in protection scope of the present invention Within.

Claims (3)

1. a kind of organic gas catalyst oxidative system, including:Some groups of reactors in parallel(3);It is characterized in that:The reaction Device(3)By some groups of photodissociation cabins(301), ultraviolet lamp tube(302), catalyst network(304)Composition, each photodissociation cabin(301)By connection Flange is connected, catalyst network(304)To being clipped between adpting flange, photodissociation cabin(301)Inwall be provided with sprayed coating(302), Each photodissociation cabin(301)Inside it is fixed with ultraviolet lamp tube(303), two adjacent groups ultraviolet lamp tube(303)Between angle be 90 °, reaction Device(3)One end and air inlet pipe(1)Communicate, reactor(3)The other end and escaping pipe(4)Communicate, reactor(3)With air inlet pipe (1)Between, reactor(3)With escaping pipe(4)Between be equipped with switching valve(2).
2. a kind of organic gas catalyst oxidative system as claimed in claim 1, it is characterised in that:The catalyst network(304)'s Material is titanium or titanium dioxide.
3. a kind of organic gas catalyst oxidative system as claimed in claim 1, it is characterised in that:The sprayed coating(302)Spray The material of painting is titanium or titanium dioxide.
CN201710090709.9A 2017-02-20 2017-02-20 A kind of organic gas catalyst oxidative system Pending CN106861423A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710090709.9A CN106861423A (en) 2017-02-20 2017-02-20 A kind of organic gas catalyst oxidative system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710090709.9A CN106861423A (en) 2017-02-20 2017-02-20 A kind of organic gas catalyst oxidative system

Publications (1)

Publication Number Publication Date
CN106861423A true CN106861423A (en) 2017-06-20

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Family Applications (1)

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CN201710090709.9A Pending CN106861423A (en) 2017-02-20 2017-02-20 A kind of organic gas catalyst oxidative system

Country Status (1)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1843953A (en) * 2006-04-21 2006-10-11 陈克敏 A combined labyrinth gas liquid sterilization and disinfection apparatus
CN102824830A (en) * 2012-09-22 2012-12-19 浙江工业大学 Tubular reactor and method for degrading waste gases with ultraviolet (UV)
CN205392180U (en) * 2016-03-03 2016-07-27 四川希望环保工程技术有限公司 Organic waste gas's photodissociation free radical equipment

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1843953A (en) * 2006-04-21 2006-10-11 陈克敏 A combined labyrinth gas liquid sterilization and disinfection apparatus
CN102824830A (en) * 2012-09-22 2012-12-19 浙江工业大学 Tubular reactor and method for degrading waste gases with ultraviolet (UV)
CN205392180U (en) * 2016-03-03 2016-07-27 四川希望环保工程技术有限公司 Organic waste gas's photodissociation free radical equipment

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Application publication date: 20170620