CN106861423A - A kind of organic gas catalyst oxidative system - Google Patents
A kind of organic gas catalyst oxidative system Download PDFInfo
- Publication number
- CN106861423A CN106861423A CN201710090709.9A CN201710090709A CN106861423A CN 106861423 A CN106861423 A CN 106861423A CN 201710090709 A CN201710090709 A CN 201710090709A CN 106861423 A CN106861423 A CN 106861423A
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- China
- Prior art keywords
- reactor
- photodissociation
- cabin
- ultraviolet lamp
- lamp tube
- Prior art date
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/22—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/91—Bacteria; Microorganisms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/804—UV light
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The invention discloses a kind of organic gas catalyst oxidative system, including:Some groups of reactors in parallel;It is characterized in that:The reactor is by some groups of photodissociation cabins, ultraviolet lamp tube, catalyst network is constituted, each photodissociation cabin is connected by adpting flange, catalyst network is to being clipped between adpting flange, the inwall in photodissociation cabin is provided with sprayed coating, ultraviolet lamp tube is fixed with each photodissociation cabin, angle between two adjacent groups ultraviolet lamp tube is 90 °, one end of reactor communicates with air inlet pipe, the other end of reactor is communicated with escaping pipe, between reactor and air inlet pipe, switching valve is equipped between reactor and escaping pipe, the present invention has operating cost low, equipment is simple and reliable, clean environment firendly, strong adaptability, advantage easy to use, can be widely applied for the treatment of all kinds of organic exhaust gas.
Description
Technical field
The invention belongs to the deodorization technique field that sterilizes, and in particular to a kind of organic gas catalyst oxidative system.
Background technology
With the fast development of the industry such as petrochemical industry, pharmaceuticals industry, paint spraying, sewage disposal, the air matter in the world
Amount is generally seriously threatened, and atmosphere pollution turns into one of current most prominent environmental problem.Atmosphere pollution have particulate matter and
The class of gaseous state thing two, wherein predominantly gaseous contaminant, accounts for more than the 75% of atmosphere pollution total amount.Gaseous contaminant is divided into nothing again
Organic pollutants and the major class of organic pollution two, wherein organic pollution account for the overwhelming majority.
Organic exhaust gas not only have stimulation to human body and various sense organs, and with certain toxicity, some can produce " three
Cause effect ", accumulated in human body, cause canceration and gene mutation, high risks are caused to health.Meanwhile, can also cause
Environmental pollution, forms acid rain, causes photochemical fog, damage the ozone layer, cause climate warming in an atmosphere;Tire out in soil
Product, destroys ecological environment;Polluted underground water, so as to influence health indirectly.Therefore, seek cost-effective governance way and
Control program has hot issue to be solved as countries in the world.
According to physical form final after treatment come point, pollutant abatement technology can be divided into two classes to organic exhaust gas, and a class is
Non-destructive technique is absorption method, can make concentration and separation by changing the physical condition such as temperature, pressure in certain technical process,
It is final to be recycled with former physical form, prevented from source or reduce environmental pollution, it is a green for comprehensive utilization of resources
Green technology, mainly including solution absorption method, active carbon adsorption, UF membrane and common technique etc. condensation method.It is another kind of to be broken
Bad property technology is destruction technology, and the general technology by chemistry or biology makes to be converted into carbon dioxide, water and nontoxic or toxicity
Small inorganic matter, mainly this kind of method of technology belongs to environment including heat damage, light degradation, plasma oxidation, biodegradation etc.
Friendly technology, the carbon dioxide and vapor of generation do not have toxic action to human body.It is generally organic in organic exhaust gas
The concentration of thing is low, and recovery value is limited, and non-destructive treatment technology is because of deficiency in economic performance, it is difficult to large-scale promotion application.And it is hot
Often there is the big defect of high energy consumption, floor space in destruction, plasma oxidation, biodegradation, it is difficult to suitable for low concentration, greatly
The treatment of flow organic exhaust gas.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of organic gas catalyst oxidative system.
A kind of organic gas catalyst oxidative system, including:Some groups of reactors in parallel;It is characterized in that:The reaction
Device is made up of some groups of photodissociation cabins, ultraviolet lamp tube, catalyst networks, and each photodissociation cabin is connected by adpting flange, and catalyst network is to being clipped in
Between adpting flange, the inwall in photodissociation cabin is provided with sprayed coating, and ultraviolet lamp tube, two adjacent groups uviol lamp are fixed with each photodissociation cabin
Angle between pipe is 90 °, and one end of reactor communicates with air inlet pipe, and the other end of reactor is communicated with escaping pipe, reactor
Between air inlet pipe, switching valve is equipped between reactor and escaping pipe.
Preferably, the material of the catalyst network is titanium or titanium dioxide.
Preferably, the material of the sprayed coating spraying is titanium or titanium dioxide.
Operation principle of the invention is:
TiO2Or the catalyst network of Ti materials, sprayed coating, when being penetrated by UV illumination, the electronics on titanium atom is by ultraviolet light
Excite, produce electronics-hole pair, this electron-hole pair is combined with water and oxygen in air, can produce a kind of with super
The O of strong oxdiative power2-With hydroxyl free radical OH-, can make to decompose generation CO containing the organic matter in organic gas waste gas2And H2O,
And the nontoxic inorganic compound of Partial cleansing degraded generation, so as to reach the mesh of the degraded of organic exhaust gas, deodorization, sterilizing
's.
Compared with prior art, beneficial effects of the present invention:
1)By TiO2Or the catalyst network of Ti materials, sprayed coating realize the treatment of organic exhaust gas, without adding other chemical drugs
Product, have the advantages that operating cost is low, equipment is simple and reliable, clean environment firendly;
2)By setting some groups of reactors in parallel, while switching valve is installed at the two ends of reactor, can be according to exhausted air quantity
Size adjust switching reactor quantity, so as to greatly improve the adaptability of system;Need to safeguard in reactor simultaneously
When, turn off switching valve, you can realize the dismounting and maintenance of reactor, it is greatly convenient for users to use.
Brief description of the drawings
Fig. 1 is a kind of structural representation of organic gas catalyst oxidative system of the invention.
Fig. 2 is the partial enlarged drawing at A in Fig. 1.
In figure, 1, air inlet pipe, 2, switching valve, 3, reactor, 4, escaping pipe, 301, photodissociation cabin, 302, sprayed coating, 303, purple
Outer fluorescent tube, 304, catalyst network.
Specific embodiment
Referring to Fig. 1, Fig. 2, a kind of organic gas catalyst oxidative system, including:Some groups of reactors 3 in parallel;Its feature
It is:The reactor 3 is made up of some groups of photodissociation cabins 301, ultraviolet lamp tube 302, catalyst network 304, and each photodissociation cabin 301 is by connecting
Acting flange is connected, and catalyst network 304 pairs is clipped between adpting flange, and the inwall in photodissociation cabin 301 is provided with sprayed coating 302, each light
Solution cabin 301 in is fixed with ultraviolet lamp tube 303, the angle between two adjacent groups ultraviolet lamp tube 303 is 90 °, one end of reactor 3 with
Air inlet pipe 1 is communicated, and the other end of reactor 3 is communicated with escaping pipe 4, between reactor 3 and air inlet pipe 1, reactor 3 and escaping pipe
Switching valve 2 is equipped between 4.
The material of the catalyst network 304 is titanium or titanium dioxide.
The material of the spraying of the sprayed coating 302 is titanium or titanium dioxide.
The present invention in use, works in the following way:
Organic exhaust gas branch to each reactor 3, TiO from air inlet pipe 12Or catalyst network 304, the sprayed coating 302 of Ti materials are by purple
When outer fluorescent tube 303 sends ultraviolet light, the electronics on titanium atom is excited by ultraviolet light, produces electronics-hole pair, this
Electron-hole pair is combined with water and oxygen in air, can produce a kind of O with superpower oxidizing force2-With hydroxyl freedom
Base OH-, can make to decompose generation CO containing the organic matter in organic gas waste gas2And H2O, and Partial cleansing degraded generation is nontoxic
Harmless inorganic compound, so as to reach the purpose of the degraded of organic exhaust gas, deodorization, sterilizing, waste gas after treatment is from escaping pipe 4
Discharge.By setting some groups of reactors 3 in parallel, while switching valve 2 is installed at the two ends of reactor 3, can be according to waste gas
The size of amount adjusts the quantity of reactor 3 of switching, so as to greatly improve the adaptability of system;Needed in reactor 3 simultaneously
When safeguarding, shut-off needs the two ends switching valve 2 of reactor maintenance 3, you can realizes the dismounting and maintenance of reactor 3, greatly facilitates
The use of user.
Technical solution of the present invention is exemplarily described above in conjunction with accompanying drawing to invention, it is clear that the present invention is implemented
It is not subject to the restrictions described above, as long as employ the various unsubstantialities that the method for the present invention is conceived and technical scheme is carried out changing
Enter, or it is not improved the design of invention and technical scheme are directly applied into other occasions, in protection scope of the present invention
Within.
Claims (3)
1. a kind of organic gas catalyst oxidative system, including:Some groups of reactors in parallel(3);It is characterized in that:The reaction
Device(3)By some groups of photodissociation cabins(301), ultraviolet lamp tube(302), catalyst network(304)Composition, each photodissociation cabin(301)By connection
Flange is connected, catalyst network(304)To being clipped between adpting flange, photodissociation cabin(301)Inwall be provided with sprayed coating(302),
Each photodissociation cabin(301)Inside it is fixed with ultraviolet lamp tube(303), two adjacent groups ultraviolet lamp tube(303)Between angle be 90 °, reaction
Device(3)One end and air inlet pipe(1)Communicate, reactor(3)The other end and escaping pipe(4)Communicate, reactor(3)With air inlet pipe
(1)Between, reactor(3)With escaping pipe(4)Between be equipped with switching valve(2).
2. a kind of organic gas catalyst oxidative system as claimed in claim 1, it is characterised in that:The catalyst network(304)'s
Material is titanium or titanium dioxide.
3. a kind of organic gas catalyst oxidative system as claimed in claim 1, it is characterised in that:The sprayed coating(302)Spray
The material of painting is titanium or titanium dioxide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710090709.9A CN106861423A (en) | 2017-02-20 | 2017-02-20 | A kind of organic gas catalyst oxidative system |
Applications Claiming Priority (1)
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CN201710090709.9A CN106861423A (en) | 2017-02-20 | 2017-02-20 | A kind of organic gas catalyst oxidative system |
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CN106861423A true CN106861423A (en) | 2017-06-20 |
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CN201710090709.9A Pending CN106861423A (en) | 2017-02-20 | 2017-02-20 | A kind of organic gas catalyst oxidative system |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1843953A (en) * | 2006-04-21 | 2006-10-11 | 陈克敏 | A combined labyrinth gas liquid sterilization and disinfection apparatus |
CN102824830A (en) * | 2012-09-22 | 2012-12-19 | 浙江工业大学 | Tubular reactor and method for degrading waste gases with ultraviolet (UV) |
CN205392180U (en) * | 2016-03-03 | 2016-07-27 | 四川希望环保工程技术有限公司 | Organic waste gas's photodissociation free radical equipment |
-
2017
- 2017-02-20 CN CN201710090709.9A patent/CN106861423A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1843953A (en) * | 2006-04-21 | 2006-10-11 | 陈克敏 | A combined labyrinth gas liquid sterilization and disinfection apparatus |
CN102824830A (en) * | 2012-09-22 | 2012-12-19 | 浙江工业大学 | Tubular reactor and method for degrading waste gases with ultraviolet (UV) |
CN205392180U (en) * | 2016-03-03 | 2016-07-27 | 四川希望环保工程技术有限公司 | Organic waste gas's photodissociation free radical equipment |
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Application publication date: 20170620 |