CN106858267A - 一种饲料原料鱼粉用抗氧化剂 - Google Patents
一种饲料原料鱼粉用抗氧化剂 Download PDFInfo
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- CN106858267A CN106858267A CN201611255492.4A CN201611255492A CN106858267A CN 106858267 A CN106858267 A CN 106858267A CN 201611255492 A CN201611255492 A CN 201611255492A CN 106858267 A CN106858267 A CN 106858267A
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- fish meal
- feedstuff
- preservative
- feedstuff fish
- acid
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- 235000019733 Fish meal Nutrition 0.000 title claims abstract description 57
- 239000004467 fishmeal Substances 0.000 title claims abstract description 57
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 36
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 35
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 34
- 239000003755 preservative agent Substances 0.000 claims abstract description 18
- 230000002335 preservative effect Effects 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 13
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 13
- AZJQQNWSSLCLJN-UHFFFAOYSA-N 2-ethoxyquinoline Chemical compound C1=CC=CC2=NC(OCC)=CC=C21 AZJQQNWSSLCLJN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims abstract description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 14
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 8
- 235000010199 sorbic acid Nutrition 0.000 claims description 8
- 239000004334 sorbic acid Substances 0.000 claims description 8
- 229940075582 sorbic acid Drugs 0.000 claims description 8
- 239000005711 Benzoic acid Substances 0.000 claims description 7
- 235000010233 benzoic acid Nutrition 0.000 claims description 7
- WMBWREPUVVBILR-WIYYLYMNSA-N (-)-Epigallocatechin-3-o-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=C(O)C=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-WIYYLYMNSA-N 0.000 claims description 6
- WMBWREPUVVBILR-UHFFFAOYSA-N GCG Natural products C=1C(O)=C(O)C(O)=CC=1C1OC2=CC(O)=CC(O)=C2CC1OC(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-UHFFFAOYSA-N 0.000 claims description 6
- XMOCLSLCDHWDHP-IUODEOHRSA-N epi-Gallocatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-IUODEOHRSA-N 0.000 claims description 6
- 229940030275 epigallocatechin gallate Drugs 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- PFTAWBLQPZVEMU-ZFWWWQNUSA-N (+)-epicatechin Natural products C1([C@@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-ZFWWWQNUSA-N 0.000 claims description 4
- PFTAWBLQPZVEMU-UKRRQHHQSA-N (-)-epicatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UKRRQHHQSA-N 0.000 claims description 4
- LPTRNLNOHUVQMS-UHFFFAOYSA-N epicatechin Natural products Cc1cc(O)cc2OC(C(O)Cc12)c1ccc(O)c(O)c1 LPTRNLNOHUVQMS-UHFFFAOYSA-N 0.000 claims description 4
- 235000012734 epicatechin Nutrition 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 3
- XMOCLSLCDHWDHP-UHFFFAOYSA-N L-Epigallocatechin Natural products OC1CC2=C(O)C=C(O)C=C2OC1C1=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-UHFFFAOYSA-N 0.000 claims description 3
- 229930002878 anthoxanthin Natural products 0.000 claims description 3
- 150000004637 anthoxanthins Chemical class 0.000 claims description 3
- 229960004365 benzoic acid Drugs 0.000 claims description 3
- OPGYRRGJRBEUFK-UHFFFAOYSA-L disodium;diacetate Chemical compound [Na+].[Na+].CC([O-])=O.CC([O-])=O OPGYRRGJRBEUFK-UHFFFAOYSA-L 0.000 claims description 3
- DZYNKLUGCOSVKS-UHFFFAOYSA-N epigallocatechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3cc(O)c(O)c(O)c3 DZYNKLUGCOSVKS-UHFFFAOYSA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 229930182817 methionine Natural products 0.000 claims description 3
- 150000007965 phenolic acids Chemical class 0.000 claims description 3
- 235000010241 potassium sorbate Nutrition 0.000 claims description 3
- 239000004302 potassium sorbate Substances 0.000 claims description 3
- 229940069338 potassium sorbate Drugs 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 3
- 239000004299 sodium benzoate Substances 0.000 claims description 3
- 235000010234 sodium benzoate Nutrition 0.000 claims description 3
- 229960003885 sodium benzoate Drugs 0.000 claims description 3
- 235000017454 sodium diacetate Nutrition 0.000 claims description 3
- LSHVYAFMTMFKBA-TZIWHRDSSA-N (-)-epicatechin-3-O-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=CC=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-TZIWHRDSSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 claims description 2
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000005487 catechin Nutrition 0.000 claims description 2
- 229950001002 cianidanol Drugs 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000001540 sodium lactate Substances 0.000 claims description 2
- 235000011088 sodium lactate Nutrition 0.000 claims description 2
- 229940005581 sodium lactate Drugs 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 102000004169 proteins and genes Human genes 0.000 abstract description 6
- 108090000623 proteins and genes Proteins 0.000 abstract description 6
- 238000003860 storage Methods 0.000 abstract description 6
- ONFOSYPQQXJWGS-UHFFFAOYSA-N 2-hydroxy-4-(methylthio)butanoic acid Chemical compound CSCCC(O)C(O)=O ONFOSYPQQXJWGS-UHFFFAOYSA-N 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 238000012423 maintenance Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 abstract description 2
- NTYJJOPFIAHURM-UHFFFAOYSA-N Histamine Chemical compound NCCC1=CN=CN1 NTYJJOPFIAHURM-UHFFFAOYSA-N 0.000 description 12
- 238000001514 detection method Methods 0.000 description 9
- 229960001340 histamine Drugs 0.000 description 6
- 241000251468 Actinopterygii Species 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 241000442132 Lactarius lactarius Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- ZONYXWQDUYMKFB-UHFFFAOYSA-N SJ000286395 Natural products O1C2=CC=CC=C2C(=O)CC1C1=CC=CC=C1 ZONYXWQDUYMKFB-UHFFFAOYSA-N 0.000 description 2
- 241001290266 Sciaenops ocellatus Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229930003949 flavanone Natural products 0.000 description 2
- 150000002207 flavanone derivatives Chemical class 0.000 description 2
- 235000011981 flavanones Nutrition 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 244000080767 Areca catechu Species 0.000 description 1
- 235000006226 Areca catechu Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 235000019730 animal feed additive Nutrition 0.000 description 1
- -1 anthocyan Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 210000000496 pancreas Anatomy 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3499—Organic compounds containing oxygen with doubly-bound oxygen
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3508—Organic compounds containing oxygen containing carboxyl groups
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3526—Organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3544—Organic compounds containing hetero rings
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/358—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Microbiology (AREA)
- Inorganic Chemistry (AREA)
- Fodder In General (AREA)
Abstract
本发明提供了一种饲料原料鱼粉用抗氧化剂，由以下重量百分比的组分充分混合制成：防腐剂0～40％，乙氧基喹啉2～20％，二丁基羟基甲苯(BHT)0.5～10％，茶多酚1～20％，蛋氨酸羟基类似物0.5～2％，其余为二氧化硅。本发明提供的一种饲料原料鱼粉用抗氧化剂，同时采用具有抗氧化与抑菌防腐功能的复配添加剂，克服了鱼粉实际生产及储存中蛋白质腐败和油脂氧化的问题，将其添加到鱼粉中能够更高效的维持鱼粉的新鲜度。
Description
技术领域
本发明涉及动物饲料添加剂的技术领域，具体涉及一种饲料原料鱼粉用抗氧化剂。
背景技术
鱼粉蛋白质含量丰富，氨基酸组成与全鱼鱼体氨基酸组成类似，是饲料中重要的蛋白质来源，同时富含多种必须脂肪酸、矿物质、维生素等动物所需营养物质，以及低的碳水合物含量和较好的适口性等优点，使其成为重要的动物性饲料原料之一，特别是在水产饲料中比重极高，可以达到50％的用量，而我国是水产养殖大国，鱼粉年用量最近几年一直处于400万吨以上，用量很大，但鱼粉在实际生产及储存中不可避免的会遇到变质问题，主要是蛋白质的腐败和油脂类的氧化变质。使用变质鱼粉会对养殖鱼类的肠道和肝胰脏造成损害，影响养殖鱼类的健康成长。
对于鱼粉的保存问题，一般通过合理科学的仓储环境设计和严格的仓储制度规范来延长鱼粉的储藏时间，或者选用特定季节的鱼获制作鱼粉来得到保质期长的鱼粉，但上述方法都无法避免受到季节性的影响很大，因此更多人选用添加剂来达到保鲜的作用。自1953年开始就有关于在鱼粉生产中加入亚硝酸钠和福尔马林作为防腐剂使用，用来防止鱼粉腐败的报道；后来人们改用酸类物质来进行防腐，能够在防腐的同时最大程度的保存营养物质，诸如甲酸和硫酸等。发展到现在，也已经有了更多更为安全高效的食品类防腐剂。
然而就目前来说，如何同时有效解决鱼粉实际生产及储存中蛋白质腐败和油脂氧化的问题，尚有待研究。
发明内容
本发明的目的在于克服现有技术存在的不足之处而提供了一种饲料原料鱼粉用抗氧化剂。
为实现上述目的，所采取的技术方案：一种饲料原料鱼粉用抗氧化剂，由以下重量百分比的组分制成：防腐剂0～40％，乙氧基喹啉2～20％，二丁基羟基甲苯(BHT)0.5～10％，茶多酚1～20％，蛋氨酸羟基类似物0.5～2％，其余为二氧化硅。
优选地，所述防腐剂的含量为10％～35％。更优选地，所述防腐剂的含量为30％。
优选地，其中乙氧基喹啉的含量为5％～10％。更优选地，所述乙氧基喹啉的含量为8％。
优选地，其中BHT的含量为2％～6％。更优选地，所述BHT的含量为4％。
优选地，其中茶多酚的含量为5％～10％。更优选地，所述茶多酚含量为8％。
优选地，其中蛋氨酸羟基类似物的含量为0.5％～1.5％。更优选地，所述蛋氨酸羟基类似物的含量为1％。
优选地，所述防腐剂选自苯甲酸、苯甲酸钠、山梨酸、山梨酸钾、双乙酸钠、乳酸，乳酸钠其中的至少一种。更优选地，所述防腐剂为苯甲酸、山梨酸中的至少一种。
优选地，所述茶多酚选自表没食子儿茶素没食子酸酯、表没食子儿茶素、表儿茶素没食子酸酯、表儿茶素、儿茶素、黄烷酮类、花青素类、花黄素类、酚酸类中的至少一种。
一种饲料原料鱼粉用抗氧化剂的制备方法，所述抗氧化剂由上述组分物质混合均匀制成。
本发明的有益效果在于：本发明提供了一种饲料原料鱼粉用抗氧化剂，同时采用具有抗氧化与抑菌防腐功能的复配添加剂，克服了鱼粉实际生产及储存中蛋白质腐败和油脂氧化的问题，将其添加到鱼粉中能够更高效的维持鱼粉的新鲜度。
具体实施方式
为更好的说明本发明的目的、技术方案和优点，下面将结合具体实施例对本发明作进一步说明。
实施例1
本发明所述的一种饲料原料鱼粉用抗氧化剂，其中1kg所述抗氧化剂由以下组分及其含量充分混合制成：防腐剂(苯甲酸)200g，乙氧基喹啉200g，BHT50g，茶多酚10g，蛋氨酸羟基类似物10g，二氧化硅530g。
实施例2
本发明所述的一种饲料原料鱼粉用抗氧化剂，其中1kg所述抗氧化剂由以下组分及其含量充分混合制成：防腐剂350g(其中包括苯甲酸150g，山梨酸200g)，乙氧基喹啉20g，BHT100g，茶多酚80g，蛋氨酸羟基类似物10g，二氧化硅440g。
实施例3
本发明所述的一种饲料原料鱼粉用抗氧化剂，其中1kg所述抗氧化剂由以下组分及其含量充分混合制成：防腐剂(山梨酸)100g，乙氧基喹啉50g，BHT20g，茶多酚200g，蛋氨酸羟基类似物20g，二氧化硅610g。
实施例4
本发明所述的一种饲料原料鱼粉用抗氧化剂，其中1kg所述抗氧化剂由以下组分及其含量充分混合制成：防腐剂350g(其中苯甲酸100g，山梨酸250g)，乙氧基喹啉100g，BHT60g，茶多酚30g，蛋氨酸羟基类似物5g，二氧化硅455g。
实施例5
本发明实施例1-4中的防腐剂选自国家允许的食品或饲料添加剂防腐剂，可以是选自苯甲酸、苯甲酸钠、山梨酸、山梨酸钾、双乙酸钠、乳酸，乳酸钠其中的至少一种。茶多酚选自表没食子儿茶素没食子酸酯、表没食子儿茶素、表儿茶素没食子酸酯、表儿茶素、儿茶素、黄烷酮类、花青素类、花黄素类、酚酸类中的至少一种。
实施例6
为说明本发明产品的抗氧化与抑菌防腐性能，本实施例对上述实施例1及实施例2进行检测。
将上述实施例1-2的抗氧化剂按照1000g/t的添加量分别添加到新鲜鱼粉1、新鲜鱼粉2和新鲜鱼粉3中，并对其添加抗氧化剂前，和之后30天，90天，180天的VBN值、组胺和油脂酸价平均值进行检测来评价鱼粉的新鲜度。
1、挥发性盐基氮(VBN)的检测
试样处理：取鱼粉样品10.0g置于具塞锥形瓶中，加100mL水，超声浸渍30min，过滤得滤液置于冰箱备用。检测方法按GB/T 5009.44-2003中4.1.2.4微量扩散法检测。检测结果如表1所示：
表1
如表1所示，鱼粉样品1、2、3的初始VBN值(VBN值低于110mg/100g为特级)都达到特级标准，加入上述实施例1、2制备的抗氧化剂后鱼粉腐败程度很低，放置半年后VBN值仍能达到特级。
2、组胺的检测
试样处理：取鱼粉样品10.0g置于具塞锥形瓶中，加入20mL100g/L三氯乙酸溶液，浸泡3h，过滤。吸取2.0mL滤液，置于分液漏斗中，加250g/L氢氧化钠溶液是溶液呈碱性，每次加入3mL正戊醇，振摇5min，提取三次，合并正戊醇并稀释至10.0mL。吸取2.0mL正戊醇提取液于分液漏斗中，每次加入3mL盐酸(1+11)振摇提取三次，合并盐酸提取液并稀释至10.0mL备用。检测方法按GB/T 5009.45-2003中4.4.3.2方法进行检测。检测结果如下表所示：
表2
如表2所示，鱼粉样品1、2、3的组胺值(其中鱼粉1、3为红鱼粉，鱼粉2为白鱼粉；红鱼粉组胺值低于300mg/kg为特级，白鱼粉组胺值低于40mg/kg为特级)，加入上述实施例1、2制备的抗氧化剂后鱼粉腐败程度很低，放置半年后组胺值仍能达到特级。
3、酸价的检测
检测方法按GB/T 19164-2003中附录B方法进行检测。检测结果如下表所示：
表3
如表3所示，鱼粉样品1、2的油脂酸价值(酸价值低于3mg/g为特级)，加入上述实施例1、2、3制备的抗氧化剂后鱼粉腐败程度很低，放置半年后油脂酸价仍能达到特级。
本发明的实施例3、4的仍采用上述检测方法，由于检测结果与上述表格相近，此处不再赘述。
最后所应当说明的是，以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制，尽管参照较佳实施例对本发明作了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的实质和范围。
Claims (10)
1.一种饲料原料鱼粉用抗氧化剂，其特征在于，包括以下重量百分比的组分：防腐剂0～40％，乙氧基喹啉2～20％，二丁基羟基甲苯(BHT)0.5～10％，茶多酚1～20％，蛋氨酸羟基类似物0.5～2％，其余为二氧化硅。
2.根据权利要求1所述的一种饲料原料鱼粉用抗氧化剂，其特征在于，其中防腐剂的含量为10％～35％。
3.根据权利要求1所述的一种饲料原料鱼粉用抗氧化剂，其特征在于，其中乙氧基喹啉的含量为5％～10％。
4.根据权利要求1所述的一种饲料原料鱼粉用抗氧化剂，其特征在于，其中BHT的含量为2％～6％。
5.根据权利要求1所述的一种饲料原料鱼粉用抗氧化剂，其特征在于，其中茶多酚的含量为5％～10％。
6.根据权利要求1所述的一种饲料原料鱼粉用抗氧化剂，其特征在于，其中蛋氨酸羟基类似物的含量为0.5％～1.5％。
7.根据权利要求1所述的一种饲料原料鱼粉用抗氧化剂，其特征在于，所述防腐剂选自苯甲酸、苯甲酸钠、山梨酸、山梨酸钾、双乙酸钠、乳酸，乳酸钠其中的至少一种。
8.根据权利要求7所述的一种饲料原料鱼粉用抗氧化剂，其特征在于，所述防腐剂为苯甲酸、山梨酸中的至少一种。
9.根据权利要求1所述的一种饲料原料鱼粉用抗氧化剂，其特征在于，所述茶多酚选自表没食子儿茶素没食子酸酯、表没食子儿茶素、表儿茶素没食子酸酯、表儿茶素、儿茶素、黄烷酮类、花青素类、花黄素类、酚酸类中的至少一种。
10.一种饲料原料鱼粉用抗氧化剂的制备方法，其特征在于，由权利要求1-9的组分物质混合均匀制成。
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| CN115736159A (zh) * | 2022-11-09 | 2023-03-07 | 奕威能生物科技(江苏)有限公司 | 一种饲料用耐高温高湿抗氧化剂及其制备方法 |
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