CN106854488A - A kind of prestressing force PHC tubular pile concrete parting agent specials - Google Patents
A kind of prestressing force PHC tubular pile concrete parting agent specials Download PDFInfo
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- CN106854488A CN106854488A CN201611041550.3A CN201611041550A CN106854488A CN 106854488 A CN106854488 A CN 106854488A CN 201611041550 A CN201611041550 A CN 201611041550A CN 106854488 A CN106854488 A CN 106854488A
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- Prior art keywords
- tubular pile
- prestressing force
- phc tubular
- parting agent
- pile concrete
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
- B28B7/384—Treating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
- B28B7/388—Treating surfaces of moulds, cores, or mandrels to prevent sticking with liquid material, e.g. lubricating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/288—Partial esters containing free carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Piles And Underground Anchors (AREA)
- Moulds, Cores, Or Mandrels (AREA)
Abstract
The present invention relates to a kind of prestressing force PHC tubular pile concrete parting agent specials, it is characterised in that the mass percent that its raw material components and each component account for raw material total amount is respectively:Epoxidized soybean oil 45%~58%, hydrophilic colloid compound 0.01%~0.05%, alkyl phosphonic acid complexing agent 3%~5%, organic carboxylate 0.01%~0.2%, oleate 10%~15%, water 25%~38%.The present invention can significantly improve the appearance of tubular pile concrete cement products, make the smooth bubble-free in its surface, and demoulding efficiency is high, be a kind of PHC tubular pile concretes parting agent special, can be diluted with water 8~12 times of use, with low cost, stable performances afterwards.
Description
Technical field
The present invention relates to concrete admixture application field, and in particular to a kind of prestressing force PHC tubular pile concretes are special de-
Mould agent.
Background technology
Prestressing force PHC tubular pile concretes are the moulding process using high speed centrifugation dehydration in a kind of forming process, by normal
After pressure is steam-cured, carry out the demoulding, then a kind of hollow cylinder in HTHP steam-cured " secondary maintenance " uiform section coagulation
Native component.During the adverse circumstances such as PHC pile tubes Yu Haiyang, cold, saline and alkaline, the big temperature difference, the durability to pile tube is particularly tested, its
Durability is closely related with material system, maintaining process, demoulding requirement etc..Wherein, the demoulding requirement smooth pore-free in surface, selection
Suitable releasing agent can deterioration uneven to hydrated product and pore structure causes later strength reduction, durability is affected
Problem play a role in improving.
Pure oils releasing agent (mineral oil, animal oil or vegetable oil etc.) is generally used, but it only makes concrete and mould
Smoothly separate effect, it is difficult to improve the situation of concrete surface hornet's nest.It is a kind of mixed disclosed in publication number CN103409218 A
Solidifying soil release agent and preparation method thereof, is with lard, rosin, NaOH, emulsifying agent, tributyl phosphate, formaldehyde, dodecyl
Glycine betaine and appropriate organo montmorillonite are prepared from aqueous, and the method needs saponification, technique bar at 95~105 DEG C
Part is harsh, and contains formaldehyde, is unfavorable for environmental requirement.A kind of environment-friendly type concrete structure disclosed in publication number CN 103789074B
Part releasing agent and preparation method thereof, is prepared with raw materials such as ester oil class mould oil, interface interleaving agent, emulsifying agent, defoamers
Water-based emulsion releasing agent is planted, with biological degradability, 2~8 times can be diluted and used.
The content of the invention
A kind of prestressing force PHC tubular pile concretes are provided the invention aims to improve the deficiencies in the prior art special
Releasing agent, uses special releasing agent, using the low surface of releasing agent on the precast-concrete form of PHC concrete water mud products
The effect of tension force, low viscosity and elimination interior formwork, so that prestressing force PHC tubular pile concrete surface textures reach face
Color is consistent, flat appearance, smooth imperforate purpose.
The technical scheme is that:A kind of prestressing force PHC tubular pile concrete parting agent specials, it is characterised in that its raw material
The mass percent that component and each component account for raw material total amount is respectively:
It is preferred that above-mentioned hydrophilic colloid compound is Arabic gum or agar.It is preferred that above-mentioned alkyl phosphonic acid complexing agent is 1-
Dodecyl phosphonic acid or di-n-octyl phosphonic acids.
It is preferred that above-mentioned organic carboxylate is sodium formate, sodium acetate or sodium oxalate.It is preferred that above-mentioned oleate is three oil
Acid glyceride, glycerine oleic acid ester or glycerin mono-fatty acid ester.
Each raw material that will be weighed is placed in agitator and is well mixed, and obtains final product a kind of prestressing force PHC tubular pile concretes special de-
Mould agent.
Beneficial effect:
The present invention chooses hydrophilic colloid compound, and unique macromolecule network shape structure is effective by alkyl phosphoric acid complexing agent
Win over by any means in releasing agent system, can concrete surface formed adsorption layer, with concrete in silica form hydrophilic suction
Complexing agent in attached releasing network, accelerates concrete uniformity aquation, forms fine and close adsorbed film.Epoxidized soybean oil and oleic acid
Ester has strong water-soluble, can enhance its paintability and greasy property so that the demoulding easily easily, is also largely eliminated
The bubble of concrete surface, improves the appearance of prestressing force PHC tubular pile concrete cement products, significantly increases its later stage anti-
Compressive Strength and endurance quality.Be not in lamination, 8~12 times can be diluted with water and used, preparation process is simple, environmental protection are without dirt
Dye, has resistance rust effect to steel template, and suitable large-scale promotion is used.
Specific embodiment
Example 1
Epoxidized soybean oil 450g
Arabic gum 0.5g
1- dodecyl phosphonic acids 40g
Sodium oxalate 2g
Olein 130g
Water 377.5g
Each raw material that will be weighed is placed in agitator and is well mixed, and obtains final product a kind of prestressing force PHC tubular pile concretes special de-
Mould agent.
Gained releasing agent through JC/T945-2005 standard testing demolding performaces, concrete adhesive capacity 1.6g/m after the demoulding2, it is right
Punching block non-corroding, viscosity is 80.3mPa.s, in -20 DEG C~45 DEG C storage-stable stabilizations.
Example 2
Epoxidized soybean oil 480g
Arabic gum 0.1g
Di-n-octyl phosphonic acids 50g
Sodium formate 0.1g
Glycerine oleic acid ester 150g
Water 319.8g
Each raw material that will be weighed is placed in agitator and is well mixed, and obtains final product a kind of prestressing force PHC tubular pile concretes special de-
Mould agent.
Gained releasing agent through JC/T945-2005 standard testing demolding performaces, concrete adhesive capacity 1.8g/m after the demoulding2, it is right
Punching block non-corroding, viscosity is 78.6mPa.s, in -20 DEG C~45 DEG C storage-stable stabilizations.
Example 3
Epoxidized soybean oil 550g
Agar 0.2g
Di-n-octyl phosphonic acids 30g
Sodium oxalate 1g
Glycerin mono-fatty acid ester 100g
Water 318.8g
Each raw material that will be weighed is placed in agitator and is well mixed, and obtains final product a kind of prestressing force PHC tubular pile concretes special de-
Mould agent.
Gained releasing agent through JC/T945-2005 standard testing demolding performaces, concrete adhesive capacity 1.6g/m after the demoulding2, it is right
Punching block non-corroding, viscosity is 82.1mPa.s, in -20 DEG C~45 DEG C storage-stable stabilizations.
Example 4
Epoxidized soybean oil 580g
Agar 0.4g
1- dodecyl phosphonic acids 50g
Sodium acetate 2g
Olein 110g
Water 257.6g
Each raw material that will be weighed is placed in agitator and is well mixed, and obtains final product a kind of prestressing force PHC tubular pile concretes special de-
Mould agent.
Gained releasing agent through JC/T945-2005 standard testing demolding performaces, concrete adhesive capacity 2.1g/m after the demoulding2, it is right
Punching block non-corroding, viscosity is 83.6mPa.s, in -20 DEG C~45 DEG C storage-stable stabilizations.
The performance of the different extension rate releasing agents of table 1
Product type | Extension rate | Stability/24h | The drying and forming-film time/min | |
Reference examples | Stoste | Uniformly | 36 | 3.8 |
Reference examples | 12 | Layering | 128 | 6.4 |
Example 1 | Stoste | Uniformly | 15 | 1.6 |
Example 1 | 8 | Uniformly | 28 | 2.3 |
Example 2 | 9 | Uniformly | 35 | 3.1 |
Example 3 | 10 | Uniformly | 42 | 4.2 |
Example 4 | 12 | Uniformly | 58 | 5.3 |
Claims (5)
1. a kind of prestressing force PHC tubular pile concrete parting agent specials, it is characterised in that it is total that its raw material components and each component account for raw material
The mass percent of amount is respectively:
2. prestressing force PHC tubular pile concrete parting agent specials according to claim 1, it is characterised in that described hydrophilic gel
Body compound is Arabic gum or agar.
3. prestressing force PHC tubular pile concrete parting agent specials according to claim 1, it is characterised in that described alkylphosphines
Sour complexing agent is 1- dodecyl phosphonic acids or di-n-octyl phosphonic acids.
4. prestressing force PHC tubular pile concrete parting agent specials according to claim 1, it is characterised in that described organic carboxylic
Hydrochlorate is sodium formate, sodium acetate or sodium oxalate.
5. prestressing force PHC tubular pile concrete parting agent specials according to claim 1, it is characterised in that described oleate
It is olein, glycerine oleic acid ester or glycerin mono-fatty acid ester.
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CN201611041550.3A CN106854488B (en) | 2016-11-24 | 2016-11-24 | A kind of prestressing force PHC tubular pile concrete parting agent special |
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CN201611041550.3A CN106854488B (en) | 2016-11-24 | 2016-11-24 | A kind of prestressing force PHC tubular pile concrete parting agent special |
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CN106854488A true CN106854488A (en) | 2017-06-16 |
CN106854488B CN106854488B (en) | 2019-10-22 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111117751A (en) * | 2019-12-30 | 2020-05-08 | 北京盛大风华科技有限公司 | Normal-temperature preparation method of high-concentration water-based concrete release agent stock solution |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20050083156A (en) * | 2005-08-05 | 2005-08-25 | 성영모 | Method of manufacturing emulsified release agent |
CN101096114A (en) * | 2007-08-10 | 2008-01-02 | 中山市三和建材有限公司 | High-durability prestressed high-strength concrete pipe pile |
CN102372459A (en) * | 2010-08-24 | 2012-03-14 | 上海台界化工有限公司 | Method for enhancing workability of concrete |
CN104277901A (en) * | 2014-09-05 | 2015-01-14 | 青岛佳尚创意文化有限公司 | Concrete release agent |
CN104498162A (en) * | 2014-12-18 | 2015-04-08 | 蒙城县科技创业服务中心 | Water-based concrete demoulding agent and preparation method thereof |
-
2016
- 2016-11-24 CN CN201611041550.3A patent/CN106854488B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20050083156A (en) * | 2005-08-05 | 2005-08-25 | 성영모 | Method of manufacturing emulsified release agent |
CN101096114A (en) * | 2007-08-10 | 2008-01-02 | 中山市三和建材有限公司 | High-durability prestressed high-strength concrete pipe pile |
CN102372459A (en) * | 2010-08-24 | 2012-03-14 | 上海台界化工有限公司 | Method for enhancing workability of concrete |
CN104277901A (en) * | 2014-09-05 | 2015-01-14 | 青岛佳尚创意文化有限公司 | Concrete release agent |
CN104498162A (en) * | 2014-12-18 | 2015-04-08 | 蒙城县科技创业服务中心 | Water-based concrete demoulding agent and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111117751A (en) * | 2019-12-30 | 2020-05-08 | 北京盛大风华科技有限公司 | Normal-temperature preparation method of high-concentration water-based concrete release agent stock solution |
CN111117751B (en) * | 2019-12-30 | 2022-04-05 | 北京盛大风华科技有限公司 | Normal-temperature preparation method of high-concentration water-based concrete release agent stock solution |
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Address after: Zhongshan science and Technology Park Huixin Liuhe road Nanjing District 210048 Jiangsu province No. 22 Applicant after: Jiangsu Olite New Materials Co., Ltd. Address before: Zhongshan science and Technology Park Huixin Liuhe road Nanjing District 210048 Jiangsu province No. 22 Applicant before: JIANGSU ARIT NEW MATERIALS CO., LTD. |
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