CN106854418A - A kind of emulsified paint and preparation method - Google Patents

A kind of emulsified paint and preparation method Download PDF

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Publication number
CN106854418A
CN106854418A CN201611179042.1A CN201611179042A CN106854418A CN 106854418 A CN106854418 A CN 106854418A CN 201611179042 A CN201611179042 A CN 201611179042A CN 106854418 A CN106854418 A CN 106854418A
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China
Prior art keywords
parts
red
intermediate blend
aerosil
defoamer
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Pending
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CN201611179042.1A
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Chinese (zh)
Inventor
曾凡跃
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Qinnan Qinzhou District Science And Technology Information Institute
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Qinnan Qinzhou District Science And Technology Information Institute
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Priority to CN201611179042.1A priority Critical patent/CN106854418A/en
Publication of CN106854418A publication Critical patent/CN106854418A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of emulsified paint and preparation method, it is made up of following mass fraction formula components:40~45 parts of bisphenol A type epoxy resin breast, 35~40 parts of nanometer rutile, 10~15 parts of ether formaldehyde condensation products, 10~15 parts of phenol formaldehyde condensate, 10~15 parts of sulfonate sodium, 5~8 parts of iron oxide red, red 5~8 parts of key, soft black 5~8 parts, 3~5 parts of dispersant, 3~5 parts of defoamer, 3~5 parts of anti-flash rusting agent, 3~5 parts of thickener, 1~3 part of boron-moisten soil, 1~3 part of aerosil, 1~3 part of polyether modified silicon oil, 5~10 parts of water, coating of the invention and metal tool is well bonded.

Description

A kind of emulsified paint and preparation method
Technical field
The present invention relates to technical field of chemical paint, in particular to a kind of emulsified paint and preparation method.
Background technology
Seamless steel pipe easy oxidation and rusting in its natural state, there is many influences on its outward appearance and quality, particularly seamless Steel pipe is many times contributed in the equipment and pipeline of HTHP, and the corrosion on surface has very big to the compressive resistance of its own Influence, has phosphatization, passivation, application etc. to the preservative treatment of seamless steel pipe, and wherein application account for very big ratio.At present, big portion Divide all carries out application using solvent based coating, and solvent organic solvent of the plough coating containing someone's amount is polluted, to operation to environment The healthy of workman has serious influence, and well and product go out when saying has environmental issue, causes the product return of goods or fine etc. to be lost Stay problem.At present, because environmental issue, part producer has been forced to reduce out to be said order or not to go out a day product, part is seamless steel The water-based anticorrosive paint that pipe manufacturer have to use import instead is produced..
The content of the invention
Regarding to the issue above, the invention provides a kind of emulsified paint and preparation method.
To achieve the above object, the present invention provides following technical scheme:
A kind of emulsified paint, is made up of following mass fraction formula components:
40~45 parts of bisphenol A type epoxy resin breast, 35~40 parts of nanometer rutile, 10~15 parts of ether formaldehyde condensation products, phenol 10~15 parts of formaldehyde condensation products, 10~15 parts of sulfonate sodium, 5~8 parts of iron oxide red, red 5~8 parts of key, soft black 5~8 parts, dispersant 3 ~5 parts, 3~5 parts of defoamer, 3~5 parts of anti-flash rusting agent, 3~5 parts of thickener, 1~3 part of boron-moisten soil, aerosil 1~3 Part, 1~3 part of polyether modified silicon oil, 5~10 parts of water.
Further, it is made up of following mass fraction formula components:
40 parts of bisphenol A type epoxy resin breast, 35 parts of nanometer rutile, 10 parts of ether formaldehyde condensation products, phenol formaldehyde condensate 10 Part, 10 parts of sulfonate sodium, 5 parts of iron oxide red, red 5 parts of key, soft black 5 parts, 3 parts of dispersant, 3 parts of defoamer, 3 parts of anti-flash rusting agent, thickening 3 parts of agent, 1 part of boron-moisten soil, 1 part of aerosil, 1 part of polyether modified silicon oil, 5 parts of water.
Further, it is made up of following mass fraction formula components:
45 parts of bisphenol A type epoxy resin breast, 40 parts of nanometer rutile, 15 parts of ether formaldehyde condensation products, phenol formaldehyde condensate 15 Part, 15 parts of sulfonate sodium, 8 parts of iron oxide red, red 8 parts of key, soft black 8 parts, 5 parts of dispersant, 5 parts of defoamer, 5 parts of anti-flash rusting agent, thickening 5 parts of agent, 3 parts of boron-moisten soil, 3 parts of aerosil, 3 parts of polyether modified silicon oil, 10 parts of water.
Further, it is made up of following mass fraction formula components:
43 parts of bisphenol A type epoxy resin breast, 37 parts of nanometer rutile, 12 parts of ether formaldehyde condensation products, phenol formaldehyde condensate 13 Part, 11 parts of sulfonate sodium, 7 parts of iron oxide red, red 7 parts of key, soft black 6 parts, 4 parts of dispersant, 4 parts of defoamer, 4 parts of anti-flash rusting agent, thickening 4 parts of agent, 2 parts of boron-moisten soil, 2 parts of aerosil, 2 parts of polyether modified silicon oil, 8 parts of water.
Further:Preparation method of the present invention has following steps:
Step one:Heated more than 24 hours after bisphenol A type epoxy resin breast and nanometer rutile are mixed, for drying, Then continuation is heated until thawing, is subsequently adding ether formaldehyde condensation products, phenol formaldehyde condensate and sulfonic acid in putting it into reactor Sodium salt is sufficiently stirred for, and is made intermediate blend 1;
Step 2:By iron oxide red, key be red, during soft black drop adds intermediate blend 1, and constantly heating, heating-up temperature is 100~ 120 DEG C, heating 1 hour is kept after being added dropwise to complete, be made intermediate blend 2;
Step 3:By dispersant, defoamer, anti-flash rusting agent, thickener, boron-moisten soil, aerosil, polyether-modified silicon Oil is stirred continuously in sequentially adding intermediate blend 2, and mixing time is 1~1.2 hour, is made intermediate blend 3;
Step 4:Add water in intermediate blend 3, adjust concentration, be made intermediate blend 4.
Step 5:Intermediate blend 4 is tested, is filtered and packaging operation, be made finished product.
The beneficial effects of the invention are as follows:
1st, coating of the invention and metal tool are well bonded;
2nd, coating high temperature resistant of the invention, low temperature.
3rd, coating hydrophobicity of the invention is good.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of emulsified paint, is made up of following mass fraction formula components:40~45 parts of bisphenol A type epoxy resin breast, receive Rice 35~40 parts of rutile, 10~15 parts of ether formaldehyde condensation products, 10~15 parts of phenol formaldehyde condensate, 10~15 parts of sulfonate sodium, Red 5~8 parts of 5~8 parts of iron oxide red, key, soft black 5~8 parts, 3~5 parts of dispersant, 3~5 parts of defoamer, 3~5 parts of anti-flash rusting agent, increase Thick dose 3~5 parts, 1~3 part of boron-moisten soil, 1~3 part of aerosil, 1~3 part of polyether modified silicon oil, 5~10 parts of water.
Embodiment two:
A kind of emulsified paint, is made up of following mass fraction formula components:Bisphenol A type epoxy resin breast 40 parts, nm of gold 35 parts of red stone, 10 parts of ether formaldehyde condensation products, 10 parts of phenol formaldehyde condensate, 10 parts of sulfonate sodium, 5 parts of iron oxide red, red 5 parts of key, soft black 5 Part, 3 parts of dispersant, 3 parts of defoamer, 3 parts of anti-flash rusting agent, 3 parts of thickener, 1 part of boron-moisten soil, 1 part of aerosil, polyethers change 1 part of silicone oil of property, 5 parts of water.
Embodiment three:
A kind of emulsified paint, is made up of following mass fraction formula components:Bisphenol A type epoxy resin breast 45 parts, nm of gold 40 parts of red stone, 15 parts of ether formaldehyde condensation products, 15 parts of phenol formaldehyde condensate, 15 parts of sulfonate sodium, 8 parts of iron oxide red, red 8 parts of key, soft black 8 Part, 5 parts of dispersant, 5 parts of defoamer, 5 parts of anti-flash rusting agent, 5 parts of thickener, 3 parts of boron-moisten soil, 3 parts of aerosil, polyethers change 3 parts of silicone oil of property, 10 parts of water.
Example IV:
A kind of emulsified paint, is made up of following mass fraction formula components:Bisphenol A type epoxy resin breast 43 parts, nm of gold 37 parts of red stone, 12 parts of ether formaldehyde condensation products, 13 parts of phenol formaldehyde condensate, 11 parts of sulfonate sodium, 7 parts of iron oxide red, red 7 parts of key, soft black 6 Part, 4 parts of dispersant, 4 parts of defoamer, 4 parts of anti-flash rusting agent, 4 parts of thickener, 2 parts of boron-moisten soil, 2 parts of aerosil, polyethers change 2 parts of silicone oil of property, 8 parts of water.
Embodiment five:
A kind of emulsified paint its preparation method comprises the following steps:
Step one:Heated more than 24 hours after bisphenol A type epoxy resin breast and nanometer rutile are mixed, for drying, Then continuation is heated until thawing, is subsequently adding ether formaldehyde condensation products, phenol formaldehyde condensate and sulfonic acid in putting it into reactor Sodium salt is sufficiently stirred for, and is made intermediate blend 1;
Step 2:By iron oxide red, key be red, during soft black drop adds intermediate blend 1, and constantly heating, heating-up temperature is 100~ 120 DEG C, heating 1 hour is kept after being added dropwise to complete, be made intermediate blend 2;
Step 3:By dispersant, defoamer, anti-flash rusting agent, thickener, boron-moisten soil, aerosil, polyether-modified silicon Oil is stirred continuously in sequentially adding intermediate blend 2, and mixing time is 1~1.2 hour, is made intermediate blend 3;
Step 4:Add water in intermediate blend 3, adjust concentration, be made intermediate blend 4.
Step 5:Intermediate blend 4 is tested, is filtered and packaging operation, be made finished product.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined May be appreciated other embodiment.

Claims (5)

1. a kind of emulsified paint, it is characterised in that:It is made up of following mass fraction formula components:
40~45 parts of bisphenol A type epoxy resin breast, 35~40 parts of nanometer rutile, 10~15 parts of ether formaldehyde condensation products, phenol formaldehyde 10~15 parts of condensation product, 10~15 parts of sulfonate sodium, 5~8 parts of iron oxide red, red 5~8 parts of key, soft black 5~8 parts, dispersant 3~5 Part, 3~5 parts of defoamer, 3~5 parts of anti-flash rusting agent, 3~5 parts of thickener, 1~3 part of boron-moisten soil, 1~3 part of aerosil, 1~3 part of polyether modified silicon oil, 5~10 parts of water.
2. a kind of emulsified paint according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
40 parts of bisphenol A type epoxy resin breast, 35 parts of nanometer rutile, 10 parts of ether formaldehyde condensation products, 10 parts of phenol formaldehyde condensate, sulphur 10 parts of acid sodium-salt, 5 parts of iron oxide red, red 5 parts of key, soft black 5 parts, 3 parts of dispersant, 3 parts of defoamer, 3 parts of anti-flash rusting agent, 3 parts of thickener, 1 part of boron-moisten soil, 1 part of aerosil, 1 part of polyether modified silicon oil, 5 parts of water.
3. a kind of emulsified paint according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
45 parts of bisphenol A type epoxy resin breast, 40 parts of nanometer rutile, 15 parts of ether formaldehyde condensation products, 15 parts of phenol formaldehyde condensate, sulphur 15 parts of acid sodium-salt, 8 parts of iron oxide red, red 8 parts of key, soft black 8 parts, 5 parts of dispersant, 5 parts of defoamer, 5 parts of anti-flash rusting agent, 5 parts of thickener, 3 parts of boron-moisten soil, 3 parts of aerosil, 3 parts of polyether modified silicon oil, 10 parts of water.
4. a kind of emulsified paint according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
43 parts of bisphenol A type epoxy resin breast, 37 parts of nanometer rutile, 12 parts of ether formaldehyde condensation products, 13 parts of phenol formaldehyde condensate, sulphur 11 parts of acid sodium-salt, 7 parts of iron oxide red, red 7 parts of key, soft black 6 parts, 4 parts of dispersant, 4 parts of defoamer, 4 parts of anti-flash rusting agent, 4 parts of thickener, 2 parts of boron-moisten soil, 2 parts of aerosil, 2 parts of polyether modified silicon oil, 8 parts of water.
5. the preparation method of a kind of emulsified paint according to claim 1, it is characterised in that:Comprise the following steps:
Step one:Heating more than 24 hours after bisphenol A type epoxy resin breast and nanometer rutile are mixed, for drying, then Continuation is heated until thawing, is subsequently adding ether formaldehyde condensation products, phenol formaldehyde condensate and sulfonate sodium in putting it into reactor It is sufficiently stirred for, is made intermediate blend 1;
Step 2:By iron oxide red, key be red, during soft black drop adds intermediate blend 1, and constantly heat, heating-up temperature is 100~120 DEG C, heating 1 hour is kept after being added dropwise to complete, it is made intermediate blend 2;
Step 3:By dispersant, defoamer, anti-flash rusting agent, thickener, boron-moisten soil, aerosil, polyether modified silicon oil according to It is stirred continuously in secondary addition intermediate blend 2, mixing time is 1~1.2 hour, is made intermediate blend 3;
Step 4:Add water in intermediate blend 3, adjust concentration, be made intermediate blend 4.
Step 5:Intermediate blend 4 is tested, is filtered and packaging operation, be made finished product.
CN201611179042.1A 2016-12-19 2016-12-19 A kind of emulsified paint and preparation method Pending CN106854418A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107227098A (en) * 2017-07-07 2017-10-03 佛山市正略信息科技有限公司 A kind of steel pipe top layer emulsified paint and its preparation technology
CN107418356A (en) * 2017-08-01 2017-12-01 合肥图森工业设计有限公司 A kind of family expenses finishing paint of porous formaldehyde adsorption and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899256A (en) * 2010-05-21 2010-12-01 资阳赛特化工有限公司 Water-based transparent anticorrosive paint, preparation method and application method thereof
CN102057902A (en) * 2010-12-23 2011-05-18 青岛润生农化有限公司 Tebuconazole-contained water dispersible granule and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899256A (en) * 2010-05-21 2010-12-01 资阳赛特化工有限公司 Water-based transparent anticorrosive paint, preparation method and application method thereof
CN102057902A (en) * 2010-12-23 2011-05-18 青岛润生农化有限公司 Tebuconazole-contained water dispersible granule and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107227098A (en) * 2017-07-07 2017-10-03 佛山市正略信息科技有限公司 A kind of steel pipe top layer emulsified paint and its preparation technology
CN107418356A (en) * 2017-08-01 2017-12-01 合肥图森工业设计有限公司 A kind of family expenses finishing paint of porous formaldehyde adsorption and preparation method thereof

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Application publication date: 20170616