CN106840786A - A kind of online low concentration chlorine analysis system - Google Patents

A kind of online low concentration chlorine analysis system Download PDF

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Publication number
CN106840786A
CN106840786A CN201710257538.4A CN201710257538A CN106840786A CN 106840786 A CN106840786 A CN 106840786A CN 201710257538 A CN201710257538 A CN 201710257538A CN 106840786 A CN106840786 A CN 106840786A
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CN
China
Prior art keywords
chlorine analysis
chlorine
analysis system
semicircle
low concentration
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710257538.4A
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Chinese (zh)
Inventor
范连军
黄金义
熊凯
刘聪
陈飞
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Chengdu Nanfang Electronic Meter Co Ltd
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Chengdu Nanfang Electronic Meter Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201710257538.4A priority Critical patent/CN106840786A/en
Publication of CN106840786A publication Critical patent/CN106840786A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/24Suction devices
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/28Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/34Purifying; Cleaning
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Combustion & Propulsion (AREA)
  • Medicinal Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The present invention relates to chlorine analysis field, more particularly to a kind of online low concentration chlorine analysis system.Its technical scheme is:A kind of online low concentration chlorine analysis system, including polytetrafluoroethylene (PTFE) sampling line, teflon seal joint is installed, sampling valve, sampling pump, moisture trap, impurity removal means, certificated valve, chlorine analysis machine that teflon seal joint is sequentially connected away from one end of polytetrafluoroethylene (PTFE) sampling line by polytetrafluoroethylene (PTFE) conveyance conduit on polytetrafluoroethylene (PTFE) sampling line;The gas chamber of chlorine analysis machine uses polytetrafluoroethylmaterial material, it is to avoid absorption influences on measurement.The invention provides a kind of chlorine analysis system that accurate measurement can be carried out to low concentration chlorine, solve the problems, such as that existing chlorine analysis system can adsorb chlorine, sealing difference and cause chlorine measured value relatively low.

Description

A kind of online low concentration chlorine analysis system
Technical field
The present invention relates to chlorine analysis field, more particularly to a kind of online low concentration chlorine analysis system.
Background technology
In Chemical Manufacture, the purposes of chlorine is quite varied.Chlorine is a kind of gas with extremely strong chemical affinity, chlorine Gas can be combustion-supporting, after chlorine is with many material mixings, can corrode container, or even set off an explosion.Meanwhile, the chlorine under normality is one Plant hypertoxic gas, the respiratory tract and eye schneiderian membrane of energy intense stimulus people, or even threat to life.Aborning in order to prevent accident There is and ensure the personal safety of operating personnel, it is necessary to be monitored on-line to the chlorine gas concentration in environment.
For example, it is necessary to detected to the chlorine gas concentration of tail gas in titanium white chloride production, to ensure the tail gas energy of discharge Enough reach discharge standard.In present exhaust gas analysis system, using stainless steel pipeline, connector, analysis chamber typically to adopt pipeline more Use stainless steel material.Because stainless steel has adsorptivity to chlorine, in the chlorine analysis measurement of low concentration, pipeline, connector After being adsorbed to chlorine so that the concentration of chlorine further declines, and causes analytical equipment to measure or cannot accurately measure, Measured chlorine content can be reduced.In chlorine analysis, often need to dismount pipeline, therefore, the sealing of connector Property cannot be guaranteed, at present, the still connector for chlorine analysis without easy disassembly and good airproof performance.
The content of the invention
Instant invention overcomes the deficiencies in the prior art, there is provided a kind of chlorine point that accurate measurement can be carried out to low concentration chlorine Analysis system, solves the problems, such as that existing chlorine analysis system can adsorb chlorine, sealing difference and cause chlorine measured value relatively low.
To solve above-mentioned technical problem, the present invention uses following technical scheme:
A kind of online low concentration chlorine analysis system, including polytetrafluoroethylene (PTFE) sampling line, polytetrafluoroethylene (PTFE) sampling line On teflon seal joint is installed, teflon seal joint passes through away from one end of polytetrafluoroethylene (PTFE) sampling line Sampling valve, sampling pump, moisture trap, impurity removal means, certificated valve, chlorine that polytetrafluoroethylene (PTFE) conveyance conduit is sequentially connected Analysis machine;The gas chamber of chlorine analysis machine uses polytetrafluoroethylmaterial material, it is to avoid absorption influences on measurement.
Used as preferred scheme of the invention, the teflon seal joint includes sealing male and sealing female, close Slot and snap fit tabs are respectively arranged with the outer circumference surface for sealing male, sealing female includes semicircle connector, semicircle connection Slot and snap fit tabs are provided with the inner peripheral surface of head, the snap fit tabs of slot and semicircle connector in sealing male Engaging, the snap fit tabs for sealing male engage with the slot of semicircle connector;Semicircle capping, half are also associated with sealing male Slot and snap fit tabs are provided with the inner peripheral surface of circle capping, the slot engaging with semicircle is covered in sealing male is convex Engaging is played, the slot that the snap fit tabs of sealing male are covered with semicircle engages;Semicircle connector and semicircle cover combination Cheng Yuan Sleeve is threaded with ring, semicircle connector and semicircle capping.
Used as preferred scheme of the invention, the moisture trap includes cylinder, be respectively arranged with cylinder air inlet and Gas outlet, is fixed with cyclone pipe in cylinder, eddy flow spiral is provided with cyclone pipe, and the inner chamber of cyclone pipe connects with gas outlet, rotation Exocoel between flow tube and cylinder is connected with air inlet, and cyclone pipe lower section is provided with afflux lid, and afflux lid is arranged in cylinder, cylinder Body bottom is provided with discharge outlet, and cylinder body bottom is equipped with Seal Oil.
Used as preferred scheme of the invention, the impurity removal means include glass core filter bulb, in glass core filter bulb It is provided with the filter layer of two and the above.
As preferred scheme of the invention, blowback lines, anti-blowpipe are also communicated with the polytetrafluoroethylene (PTFE) sampling line Back-flushing valve is installed on line.
Used as preferred scheme of the invention, the discharge outlet of the moisture trap is connected with draining pump.
As preferred scheme of the invention, stability of flow is installed between the moisture trap and impurity removal means Device, flow stabilizer is provided between certificated valve and chlorine analysis machine.
Compared with prior art, the beneficial effects of the invention are as follows:
1st, pipeline of the invention, joint, the gas chamber of chlorine analysis machine use polytetrafluoroethylmaterial material, it is to avoid conventional Stainless steel material situation about being adsorbed to chlorine, it is ensured that the stability of chlorine content, so as to ensure the standard of chlorine analysis True property.Teflon seal joint energy fast assembling-disassembling, is easy to the use of chlorine analysis;The company of teflon seal joint Connect reliability, it is ensured that sealing of the invention, it is ensured that chlorine analysis accuracy.
2nd, first engage semicircle connector in the sealing male of teflon seal joint, then semicircle is covered, most Semicircle connector is connected to bush whorl and semicircle is covered, realize quick connection afterwards.Teflon seal joint can be fast Speed connection, when facilitating chlorine analysis the need for, also, in sealing male there are slot and snap fit tabs simultaneously, be capable of achieving two Place is tightly connected, it is ensured that sealed reliable.
3rd, when gas to be detected enters the cylinder of moisture trap from air inlet, gas is through eddy flow spiral from cyclone pipe bottom Portion enters cyclone pipe, then from gas outlet outflow, during this, the moisture in gas can be collected and drop onto cylinder body bottom, Realize gas-water separation.Water in conventional moisture trap causes a certain degree of absorption to chlorine, and air water of the invention divides Afflux lid is provided with device, can exclusion of water and gas, absorption of the reduction water to chlorine.Cylinder body bottom is equipped with Seal Oil, sealing Oil can thoroughly isolation be opened with gas by water, it is to avoid absorption of the water to chlorine, it is ensured that the stabilization of chlorine content.
4th, the multiple layers of filters in glass core filter bulb can fully be removed to impurity, by the thickness for reducing single layer filter layer Ensure that gas passes through filter layer.
5th, before using the chlorine analysis system, first the chlorine analysis system is carried out blowing helium using blowback lines, is protected Chlorine is free of in card chlorine analysis system, makes measured value during chlorine analysis more accurate.
6th, moisture trap connection draining pump the water of condensation can be taken away, be easy to moisture trap continue use.
7th, the gas flow that flow stabilizer can be in systems stabilisation.
Brief description of the drawings
Fig. 1 is arrangement schematic diagram of the invention;
Fig. 2 is the partial sectional view of teflon seal joint;
Structural representation when Fig. 3 is teflon seal joint non-installation sleeve;
Fig. 4 is the structural representation of moisture trap;
Fig. 5 is the structural representation of glass core filter bulb.
In figure, 1- polytetrafluoroethylene (PTFE) sampling lines, 2- teflon seal joints, 3- sampling valves, 4- sampling pumps, 5- gas Separator, 6- impurity removal means, 7- certificated valves, 8- chlorine analysis machines, 9- blowback lines, 21- sealing males, 22- sealings Female, the capping of 23- semicircles, 24- sleeves, 51- cylinders, 52- air inlets, 53- gas outlets, 54- cyclone pipes, 55- eddy flow spirals, 56- afflux lids, 57- discharge outlet, 58- draining pumps, 61- glass core filter bulbs, 62- filter layers, 91- back-flushing valves, 221- semicircles connect Joint.
Specific embodiment
Below in conjunction with the accompanying drawings, the present invention is described in detail.
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only used to explain the present invention, not For limiting the present invention.
Embodiment one
As shown in figure 1, the present invention includes polytetrafluoroethylene (PTFE) sampling line 1, it is provided with polytetrafluoroethylene (PTFE) sampling line 1 poly- Tetrafluoroethene seal nipple 2, teflon seal joint 2 passes through polytetrafluoro away from one end of polytetrafluoroethylene (PTFE) sampling line 1 Sampling valve 3, sampling pump 4, moisture trap 5, impurity removal means 6, certificated valve 7, chlorine that ethene conveyance conduit is sequentially connected Analysis machine 8;The gas chamber of chlorine analysis machine 8 uses polytetrafluoroethylmaterial material, it is to avoid absorption influences on measurement.
Pipeline of the invention, joint, the gas chamber of chlorine analysis machine 8 use polytetrafluoroethylmaterial material, it is to avoid conventional Stainless steel material situation about being adsorbed to chlorine, it is ensured that the stability of chlorine content, so as to ensure the standard of chlorine analysis True property.The energy fast assembling-disassembling of teflon seal joint 2, is easy to the use of chlorine analysis;Teflon seal joint 2 Connection is reliable, it is ensured that sealing of the invention, it is ensured that chlorine analysis accuracy.
Embodiment two
On the basis of embodiment one, as shown in Figures 2 and 3, the teflon seal joint 2 includes sealing male 21 and sealing female 22, it is respectively arranged with slot and snap fit tabs on the outer circumference surface for sealing male 21, sealing female 22 is wrapped Semicircle connector 221 is included, slot and snap fit tabs is provided with the inner peripheral surface of semicircle connector 221, in sealing male 21 Slot engage with the snap fit tabs of semicircle connector 221, seal the card of snap fit tabs and the semicircle connector 221 of male 21 Close groove engaging;Sealing male 21 on be also associated with semicircle capping 23, semicircle capping 23 inner peripheral surface on be provided with slot and Snap fit tabs, the slot in sealing male 21 engages with the snap fit tabs of semicircle capping 23, seals the snap fit tabs of male 21 Slot with semicircle capping 23 engages;Semicircle connector 221 and semicircle capping 23 are combined into annulus, the He of semicircle connector 221 Sleeve 24 is threaded with semicircle capping 23.
Semicircle connector 221 is first engaged in the sealing male 21 of teflon seal joint 2, then semicircle capping 23 is covered On, finally it is threaded in semicircle connector 221 with sleeve 24 and semicircle is covered on 23, realize quick connection.Polytetrafluoroethylene (PTFE) Seal nipple 2 can be connected quickly, when facilitating chlorine analysis the need for, also, in sealing male 21 there is slot and card simultaneously Close raised, be capable of achieving to be tightly connected at two, it is ensured that sealed reliable.
Embodiment three
On the basis of embodiment one or embodiment two, as shown in figure 4, the moisture trap 5 includes cylinder 51, cylinder It is respectively arranged with 51 in air inlet 52 and gas outlet 53, cylinder 51 and is fixed with cyclone pipe 54, eddy flow is provided with cyclone pipe 54 Spiral 55, the inner chamber of cyclone pipe 54 is connected with gas outlet 53, and the exocoel between cyclone pipe 54 and cylinder 51 is connected with air inlet 52, The lower section of cyclone pipe 54 is provided with afflux lid 56, and afflux lid 56 is arranged in cylinder 51, and the bottom of cylinder 51 is provided with discharge outlet 57, cylinder The bottom of body 51 is equipped with Seal Oil.
When gas to be detected enters the cylinder of moisture trap 5 from air inlet 52, gas is through eddy flow spiral 55 from eddy flow The bottom of pipe 54 enters cyclone pipe 54, then is flowed out from gas outlet 53, and during this, the moisture in gas can be collected and drop onto The bottom of cylinder 51, realizes gas-water separation.Water in conventional moisture trap 5 causes a certain degree of absorption to chlorine, and originally Afflux lid 56 is provided with the moisture trap 5 of invention, can exclusion of water and gas, absorption of the reduction water to chlorine.The bottom of cylinder 51 Portion is equipped with Seal Oil, and Seal Oil can thoroughly completely cut off water and gas be opened, it is to avoid absorption of the water to chlorine, it is ensured that chlorine content it is steady It is fixed.
Example IV
On the basis of above-mentioned any one embodiment, as shown in figure 5, the impurity removal means 6 include glass core The filter layer 62 of two and the above is provided with filter bulb 61, glass core filter bulb 61.Multiple filtration in glass core filter bulb 61 Layer 62 can fully be removed to impurity, ensure that gas passes through filter layer 62 by the thickness for reducing single layer filter layer 62.
Embodiment five
On the basis of above-mentioned any one embodiment, anti-blowpipe is also communicated with the polytetrafluoroethylene (PTFE) sampling line 1 Line 9, installs back-flushing valve 91 in blowback lines 9.Before using the chlorine analysis system, 9 pairs of chlorine of blowback lines point are first used Analysis system carries out blowing helium, it is ensured that chlorine is free of in chlorine analysis system, makes measured value during chlorine analysis more accurate.
Embodiment six
On the basis of above-mentioned any one embodiment, the discharge outlet 57 of the moisture trap 5 is connected with draining pump 58. Moisture trap 5 connection draining pump 58 water of condensation can be taken away, be easy to moisture trap 5 continue use.
Embodiment seven
On the basis of above-mentioned any one embodiment, it is provided between the moisture trap 5 and impurity removal means 6 Flow stabilizer, flow stabilizer is provided between certificated valve 7 and chlorine analysis machine 8.Flow stabilizer energy being capable of systems stabilisation Interior gas flow.

Claims (7)

1. a kind of online low concentration chlorine analysis system, it is characterised in that including polytetrafluoroethylene (PTFE) sampling line (1), polytetrafluoro Teflon seal joint (2) is installed, teflon seal joint (2) is away from polytetrafluoro on ethene sampling line (1) Sampling valve (3), sampling pump (4), air water that one end of ethene sampling line (1) is sequentially connected by polytetrafluoroethylene (PTFE) conveyance conduit Separator (5), impurity removal means (6), certificated valve (7), chlorine analysis machine (8).
2. a kind of online low concentration chlorine analysis system according to claim 1, it is characterised in that the polytetrafluoroethylene (PTFE) Seal nipple (2) includes sealing male (21) and sealing female (22), is respectively arranged with the outer circumference surface of sealing male (21) Slot and snap fit tabs, sealing female (22) include semicircle connector (221), on the inner peripheral surface of semicircle connector (221) Slot and snap fit tabs are provided with, the slot in sealing male (21) engages with the snap fit tabs of semicircle connector (221), The snap fit tabs of sealing male (21) engage with the slot of semicircle connector (221);Half is also associated with sealing male (21) Circle capping (23), is provided with slot and snap fit tabs, the card in sealing male (21) on the inner peripheral surface of semicircle capping (23) Close groove to engage with the snap fit tabs of semicircle capping (23), the snap fit tabs of sealing male (21) cover the slot of (23) with semicircle Engaging;Semicircle connector (221) and semicircle capping (23) are combined into annulus, on semicircle connector (221) and semicircle capping (23) It is threaded with sleeve (24).
3. a kind of online low concentration chlorine analysis system according to claim 1 and 2, it is characterised in that the air water point Include cylinder (51) from device (5), air inlet (52) and gas outlet (53) are respectively arranged with cylinder (51), it is fixed in cylinder (51) There is cyclone pipe (54), eddy flow spiral (55) be provided with cyclone pipe (54), the inner chamber of cyclone pipe (54) connects with gas outlet (53), Exocoel between cyclone pipe (54) and cylinder (51) is connected with air inlet (52), and cyclone pipe (54) lower section is provided with afflux lid (56), afflux lid (56) is arranged in cylinder (51), and cylinder (51) bottom is provided with discharge outlet (57), and cylinder (51) bottom is equipped with Seal Oil.
4. a kind of online low concentration chlorine analysis system according to claim 3, it is characterised in that the Impurity removal dress Putting (6) includes being provided with glass core filter bulb (61), glass core filter bulb (61) filter layer (62) of two and the above.
5. a kind of online low concentration chlorine analysis system according to claim 1, it is characterised in that the polytetrafluoroethylene (PTFE) Blowback lines (9) are also communicated with sampling line (1), back-flushing valve (91) is installed in blowback lines (9).
6. a kind of online low concentration chlorine analysis system according to claim 3, it is characterised in that the moisture trap (5) discharge outlet (57) is connected with draining pump (58).
7. a kind of online low concentration chlorine analysis system according to claim 1, it is characterised in that the moisture trap (5) flow stabilizer is installed and impurity removal means (6) between, stream is installed between certificated valve (7) and chlorine analysis machine (8) Amount stabilizer.
CN201710257538.4A 2017-04-19 2017-04-19 A kind of online low concentration chlorine analysis system Pending CN106840786A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710257538.4A CN106840786A (en) 2017-04-19 2017-04-19 A kind of online low concentration chlorine analysis system

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Application Number Priority Date Filing Date Title
CN201710257538.4A CN106840786A (en) 2017-04-19 2017-04-19 A kind of online low concentration chlorine analysis system

Publications (1)

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CN106840786A true CN106840786A (en) 2017-06-13

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113996129A (en) * 2021-09-16 2022-02-01 金川集团股份有限公司 Preposed treatment device for residual chlorine absorption outer discharge sample gas

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