CN106835725A - A kind of negative ion flame-retardant non-woven fabrics and preparation method thereof - Google Patents
A kind of negative ion flame-retardant non-woven fabrics and preparation method thereof Download PDFInfo
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- CN106835725A CN106835725A CN201611242984.XA CN201611242984A CN106835725A CN 106835725 A CN106835725 A CN 106835725A CN 201611242984 A CN201611242984 A CN 201611242984A CN 106835725 A CN106835725 A CN 106835725A
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- Prior art keywords
- retardant
- woven fabrics
- negative ion
- parts
- ion flame
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0038—Polyolefin fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention belongs to textile material technical field, it is related to a kind of negative ion flame-retardant non-woven fabrics and preparation method thereof.The negative ion flame-retardant non-woven fabrics, polypropylene as negative ion flame-retardant non-woven fabrics matrix, matrix surface cover one layer of negative ion flame-retardant slurry；It is formulated by following constituent mass percentage：5 10 parts of fire retardant, 0.1 5 parts of coupling agent, 12 parts of tourmaline, 8 15 parts of vector resin, 12 parts of auxiliary agent, 200 220 parts of water.Present invention process is simple, and product can be degradable, with it is ultra-thin, intensity is big the characteristics of, and have good insulation, moisturizing, permeability.Addition magnesium hydroxide and tourmaline so that non-woven fabrics is provided with fire-retardant and anion characteristic simultaneously.
Description
Technical field
The invention belongs to textile material technical field, it is related to a kind of negative ion flame-retardant non-woven fabrics and preparation method thereof.
Background technology
Non-woven fabrics is made up of fiber orient or random, is environment-friendly materials.Compared with traditional weaving cloth, have
Technological process is short, speed of production is fast, yield is high, low cost the features such as.It is widely used in health care, home decoration, automobile
The fields such as industry, garment accessories.Raw material such as polypropylene due to non-woven fabrics etc. is hydrocarbon class material, and oxygen index (OI) is low, only 17.4,
Easily burning, and combustion heating amount is big, produces a large amount of molten drops, easily propagating flame.Polyacrylic burning is few cigarette type, not into
Charcoal, but with molten drop and curtain coating phenomenon on fire, and produce substantial amounts of unsaturated fuel gas, these gases to each contribute to poly- third
The burning of alkene.With the improvement of people ' s living standards with the enhancing of awareness of safety, the anti-flammability of non-woven fabrics increasingly becomes people
Focus of attention.
Currently, non-woven fabrics mainly by increase brominated, antimony compound realize it is fire-retardant, or by add hydroxide,
The halogen-free material such as phosphonium flame retardant realizes fire-retardant, generation harmful substance pollution environment after the former burning, and the latter's fire resistance is not
Reach, reduce the processing performance of pp material.And with the enhancing of people's environmental consciousness, the non-woven fabrics of health environment-friendly is also
Following developing direction.
The content of the invention
The purpose of the present invention is directed to the deficiencies in the prior art, there is provided a kind of negative ion flame-retardant non-woven fabrics and its preparation side
Method, is characterized in good flame retardation effect, environment protection health, low cost, it is easy to operate.
The technical solution adopted in the present invention is summarized as follows：
A kind of negative ion flame-retardant non-woven fabrics, polypropylene as negative ion flame-retardant non-woven fabrics matrix, matrix surface covering one
Layer negative ion flame-retardant slurry.Described environmental-protection flame-retardant slurry is formulated by following constituent mass percentage：Fire retardant 5-10 parts,
Coupling agent 0.1-5 parts, tourmaline 1-2 parts, vector resin 8-15 parts, auxiliary agent 1-2 parts, water 200-220 parts.
Further, described fire retardant is magnesium hydroxide, and the magnesium hydroxide of selection is pattern rule, and particle diameter be 0.10~
60.00μm。
Further, described coupling agent is selected from vinyltrimethoxy silane, VTES, the second of methyl three
TMOS, poly- MTES, γ-glycydoxy front three oxosilane, γ-glycidyl ether oxygen
Propyl-triethoxysilicane, γ-fourth vinegar of glycidyl ether oxygen propyl methyldiethoxysilane metatitanic acid four, the isopropyl vinegar of metatitanic acid four,
One or more mixture in tetra-tert metatitanic acid vinegar.
Further, described tourmaline, size controlling is in below 1mm.
The preparation method of described negative ion flame-retardant non-woven fabrics is comprised the following steps：
(1) polypropylene bulk material is sprayed by screw extruding, into net, milling train flower roller is rolled into cloth；
(2) fire retardant, coupling agent, tourmaline, vector resin, auxiliary agent, water are taken and pours into mixing；
(3) above-mentioned flame-retardant slurry is poured into the size barrel with agitating device, makes non-woven base cloth in pressure roller and sizing roller
In pass through, through screen frame be transferred in base fabric the slurry in stock tank by sizing roller；
(4) the upper nonwoven for crossing slurry is arranged between two rubber rollers of roller machine and is extruded, remove unnecessary liquid
Body；
(5) by above-mentioned non-woven fabrics drying negative ion flame-retardant non-woven fabrics.
Present invention process is simple, and product can be degradable, with it is ultra-thin, intensity is big the characteristics of, and have good insulation, protect
Wet, permeability.Using flame retardant of magnesium hydroxide, good flame retardation effect is pollution-free, is conducive to preserving the ecological environment, and can be complete
Degraded.Tourmaline is used in non-woven fabrics, has been processed by calcination, with flourishing hole, in addition using alundum (Al2O3), with remote
Infrared, anion and antibacterial, deodorant function, health environment-friendly.Add the collocation of other auxiliary agents and be mixed and made into slurries, directly using spray
The mode of painting, on cloth body, forms good fire retardant nonwoven fabric process is simple, and production efficiency is high, and does not result in fire retardant
Waste.
Specific embodiment
Embodiment 1：
(1) 80 parts of polypropylene bulk material is sprayed by screw extruding, into net, milling train flower roller is rolled into cloth；(2) 6 are taken
Part fire retardant, 0.2 part of coupling agent, 1 part of tourmaline, 10 parts of vector resin, 1 part of auxiliary agent, 210 parts of water pour into mixing；(3) will be upper
State flame-retardant slurry to pour into the size barrel with agitating device, non-woven base cloth is passed through in pressure roller and sizing roller, sizing roller will
Slurry in stock tank is transferred in base fabric through screen frame；(4) the upper nonwoven for crossing slurry is arranged in two rubber rollers of roller machine
Between extruded, remove unnecessary liquid；(5) by above-mentioned non-woven fabrics drying negative ion flame-retardant non-woven fabrics.
Embodiment 2：
(1) 85 parts of polypropylene bulk material is sprayed by screw extruding, into net, milling train flower roller is rolled into cloth；(2) 9 are taken
Part fire retardant, 2 parts of coupling agents, 1.5 parts of tourmaline, 12 parts of vector resin, 1 part of auxiliary agent, 215 parts of water pour into mixing；(3) will be upper
State flame-retardant slurry to pour into the size barrel with agitating device, non-woven base cloth is passed through in pressure roller and sizing roller, sizing roller will
Slurry in stock tank is transferred in base fabric through screen frame；(4) the upper nonwoven for crossing slurry is arranged in two rubber rollers of roller machine
Between extruded, remove unnecessary liquid；(5) by above-mentioned non-woven fabrics drying negative ion flame-retardant non-woven fabrics.
Fire retardant 5-10 parts, coupling agent 0.1-5 parts, tourmaline 1-2 parts, vector resin 8-15 parts, auxiliary agent 1-2 parts, water
200-220 parts.
Embodiment 3：
(1) 90 parts of polypropylene bulk material is sprayed by screw extruding, into net, milling train flower roller is rolled into cloth；(2) 10 are taken
Part fire retardant, 2.5 parts of coupling agents, 1.8 parts of tourmaline, 12 parts of vector resin, 1 part of auxiliary agent, 210 parts of water pour into mixing；(3) will
Above-mentioned flame-retardant slurry is poured into the size barrel with agitating device, non-woven base cloth is passed through in pressure roller and sizing roller, sizing roller
Slurry in stock tank is transferred in base fabric through screen frame；(4) the upper nonwoven for crossing slurry is arranged in two rubber pressures of roller machine
Extruded between roller, removed unnecessary liquid；(5) by above-mentioned non-woven fabrics drying negative ion flame-retardant non-woven fabrics.
Claims (6)
1. a kind of negative ion flame-retardant non-woven fabrics, polypropylene as negative ion flame-retardant non-woven fabrics matrix, matrix surface covers one layer
Negative ion flame-retardant slurry；Described environmental-protection flame-retardant slurry is formulated by following constituent mass percentage：It is fire retardant 5-10 parts, even
0.1-5 parts, tourmaline 1-2 parts, vector resin 8-15 parts, auxiliary agent 1-2 parts, water 200-220 parts of agent of connection.
2. a kind of negative ion flame-retardant non-woven fabrics according to claim 1, it is characterised in that described fire retardant is hydroxide
Magnesium, magnesium hydroxide is pattern rule, and particle diameter is 0.10~60.00 μm.
3. a kind of negative ion flame-retardant non-woven fabrics according to claim 1 and 2, it is characterised in that described coupling agent is selected from
Vinyltrimethoxy silane, VTES, MTES, poly- MTES, γ-
Glycydoxy front three oxosilane, γ-glycidoxypropyltrietandysilane andysilane, γ-glycidyl ether oxygen
One or more in the fourth vinegar of hydroxypropyl methyl diethoxy silane metatitanic acid four, the isopropyl vinegar of metatitanic acid four, tetra-tert metatitanic acid vinegar
Mixture.
4. a kind of negative ion flame-retardant non-woven fabrics according to claim 1 and 2, it is characterised in that described tourmaline, particle diameter
Control is in below 1mm.
5. a kind of negative ion flame-retardant non-woven fabrics according to claim 3, it is characterised in that described tourmaline, particle diameter control
System is in below 1mm.
6. the preparation method of any described a kind of negative ion flame-retardant non-woven fabrics of claim 1-5, it is characterised in that：
(1) polypropylene bulk material is sprayed by screw extruding, into net, milling train flower roller is rolled into cloth；
(2) fire retardant, coupling agent, tourmaline, vector resin, auxiliary agent, water are taken and pours into mixing；
(3) above-mentioned flame-retardant slurry is poured into the size barrel with agitating device, non-woven base cloth is led in pressure roller and sizing roller
Cross, through screen frame be transferred in base fabric the slurry in stock tank by sizing roller；
(4) the upper nonwoven for crossing slurry is arranged between two rubber rollers of roller machine and is extruded, remove unnecessary liquid；
(5) by above-mentioned non-woven fabrics drying negative ion flame-retardant non-woven fabrics.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611242984.XA CN106835725A (en) | 2016-12-29 | 2016-12-29 | A kind of negative ion flame-retardant non-woven fabrics and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611242984.XA CN106835725A (en) | 2016-12-29 | 2016-12-29 | A kind of negative ion flame-retardant non-woven fabrics and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106835725A true CN106835725A (en) | 2017-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611242984.XA Pending CN106835725A (en) | 2016-12-29 | 2016-12-29 | A kind of negative ion flame-retardant non-woven fabrics and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107503145A (en) * | 2017-09-20 | 2017-12-22 | 重庆晋豪美耐皿制品有限公司 | A kind of environmental protection flame retardant stalk advertising cloth and preparation method thereof |
| CN109338726A (en) * | 2018-08-20 | 2019-02-15 | 蚌埠市维光塑胶制品有限公司 | A kind of preparation method of the flame-retardant modified non-woven fabrics of anti-bacterial and anti-fouling |
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| CN103668987A (en) * | 2013-10-14 | 2014-03-26 | 昆山市宝立无纺布有限公司 | Preparation method of flame retardant PP (polypropylene) non-woven fabric |
| CN104264256A (en) * | 2014-10-14 | 2015-01-07 | 张家港市安顺科技发展有限公司 | Preparation method of flame-retardant negative-ion fibers |
| CN105040448A (en) * | 2015-06-30 | 2015-11-11 | 怀宁县鑫源无纺布有限公司 | Easily-decomposed flame-resistant temperature-adjusting environmental-friendly non-woven fabric, and preparation method thereof |
| CN106147143A (en) * | 2015-04-24 | 2016-11-23 | 储金中 | A kind of preparation method of anion spun-bonded non-woven fabrics |
-
2016
- 2016-12-29 CN CN201611242984.XA patent/CN106835725A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103668987A (en) * | 2013-10-14 | 2014-03-26 | 昆山市宝立无纺布有限公司 | Preparation method of flame retardant PP (polypropylene) non-woven fabric |
| CN104264256A (en) * | 2014-10-14 | 2015-01-07 | 张家港市安顺科技发展有限公司 | Preparation method of flame-retardant negative-ion fibers |
| CN106147143A (en) * | 2015-04-24 | 2016-11-23 | 储金中 | A kind of preparation method of anion spun-bonded non-woven fabrics |
| CN105040448A (en) * | 2015-06-30 | 2015-11-11 | 怀宁县鑫源无纺布有限公司 | Easily-decomposed flame-resistant temperature-adjusting environmental-friendly non-woven fabric, and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107503145A (en) * | 2017-09-20 | 2017-12-22 | 重庆晋豪美耐皿制品有限公司 | A kind of environmental protection flame retardant stalk advertising cloth and preparation method thereof |
| CN109338726A (en) * | 2018-08-20 | 2019-02-15 | 蚌埠市维光塑胶制品有限公司 | A kind of preparation method of the flame-retardant modified non-woven fabrics of anti-bacterial and anti-fouling |
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Application publication date: 20170613 |
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