CN106835717B - A kind of cotton fabric increasing is deep to increase gorgeous organic silicone finishing agent and preparation method thereof - Google Patents

A kind of cotton fabric increasing is deep to increase gorgeous organic silicone finishing agent and preparation method thereof Download PDF

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Publication number
CN106835717B
CN106835717B CN201710131535.6A CN201710131535A CN106835717B CN 106835717 B CN106835717 B CN 106835717B CN 201710131535 A CN201710131535 A CN 201710131535A CN 106835717 B CN106835717 B CN 106835717B
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coupling agent
silane coupling
agent
gorgeous
deep
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CN106835717A (en
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罗秋艳
方伟洪
黄廉居
冯俏君
麦嘉仪
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Qingyuan Hongtu Assistant Co Ltd
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Qingyuan Hongtu Assistant Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

Abstract

The present invention provides a kind of deep gorgeous organic silicone finishing agent of increasing of cotton fabric increasing, it calculates by weight, it includes: 10~60 parts of crude oil of silicon containing phenyl that the cotton fabric, which increases the deep raw material for increasing gorgeous organic silicone finishing agent, 10~30 parts of emulsifiers, 0.4~2.5 part of glacial acetic acid, 20~100 parts of water, 10~15 parts of polyoxyethylene wax emulsions；Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalyst；The organic silicon monomer includes octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy polydimethyl siloxane, hexamethyl cyclotrisiloxane, tetramethyl tetraphenyl cyclotetrasiloxane, one or more in tetraethyl cyclotetrasiloxane.

Description

A kind of cotton fabric increasing is deep to increase gorgeous organic silicone finishing agent and preparation method thereof
Technical field
The present invention relates to textile finish technical fields, more particularly it relates to which a kind of deep increasing of cotton fabric increasing is gorgeous Organic silicone finishing agent and preparation method thereof.
Background technique
It is to be covered in fiber surface using low-refraction substance that after-finishing of textile products, which increases deep, makes incident light on the fabric anti- Rate reduction is penetrated, and makes feeling of the people visually to the color generation " depth " of fabric.Polyurethane, polyacrylic acid are introduced according to document Ester, polysiloxane etc. are all the substances with low-refraction, there is different increasing depth effects to fiber.Wherein poly organo The refractive index of alkane is lower, and soft, smooth feel is also had both while increasing deep through its fabric after arranging.
Prior art CN200810163784.4 patent discloses a kind of N- (β-aminoethyl)-Y- aminopropyltriethoxy diformazan The modified amido silicon oil of oxysilane makees fabric brightening agent, and using effect is significant to dark polyester fiber, and for dye The cotton of color, polyester-cotton blend are washed the fabric effects such as viscous, wool and are not obvious.CN201010288531 patent discloses a kind of dyed cotton and knits Object increase it is deep increase gorgeous finishing agent and preparation method, with organic silicon monomer and coupling agent containing phenyl silane, amino-containing silane coupled adopt It is prepared for the group modified organic siloxane emulsion of multiple functions with cationic emulsion copolymerization method, then compounds certain proportion again Methyl Hydrogen Polysiloxane Fluid lotion.This finishing agent has dyed cotton fabric increases depth and brightening effect, and fabric hand after processing well Sense is soft smooth, and washability is good, but emulsion intercalation method is slightly worse, more demanding to technique.
Universal increasings of application is deep in the market increases gorgeous finishing agent using obtaining after amido silicon oil and 107 latex, although Using this bright finish fabric, can the increasing to fabric increase deeply, but due to being free of polarity on such silicone molecule chain Stronger group (such as amino, secondary amino group etc.), phenyl silicone oil have high refractive index, arrange for cloth cover, can obtain good Glossiness, and hydroxy-end capped phenyl silicone oil is remarkably improved the slickness and flexibility of fabric as fabric finishing agent, and Assign the good hydrophobic oil repellent of fabric.But the reactive group due to phenyl not in conjunction with fiber, with fibrous binding force compared with Difference, and the fabric feeling arranged through it is inadequate, and traditional amido silicon oil, the fabric arranged with it have it is soft, smooth, wear Comfortable performance, but low in glossiness.
In view of the above-mentioned problems, the present invention provides one kind with organic silicon monomer, polyamide polyether polymer, silane coupling agent is Raw material, equilibrium polymerization obtains amino modified methyl phenyl silicone oil under base catalysis, existing soft, sliding through its fabric after arranging The features such as refreshing, plentiful, and have good glossiness.
Summary of the invention
The present invention provides a kind of deep gorgeous organic silicone finishing agent of increasing of cotton fabric increasing, calculates by weight, the cotton fabric increases deep The raw material for increasing gorgeous organic silicone finishing agent includes:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer includes octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, ω-dihydroxy Base dimethyl silicone polymer, hexamethyl cyclotrisiloxane, tetramethyl tetraphenyl cyclotetrasiloxane, one in tetraethyl cyclotetrasiloxane Kind is a variety of.
In one embodiment, the raw material for preparing of the polyamide polyether polymer includes adipic acid, hexamethylene diamine, α-ammonia Base-ω-carboxy polyethylene glycol.
In one embodiment, the silane coupling agent includes silane coupling agent and amino-containing silane idol containing phenyl Join agent.
In one embodiment, the weight of the silane coupling agent containing phenyl and the amino-containing silane coupling agent Than for 1:(0.5~2).
In one embodiment, the silane coupling agent containing phenyl includes phenyltrimethoxysila,e, phenyl diformazan Oxysilane, it is one or more in phenyl triethoxysilane.
In one embodiment, the amino-containing silane coupling agent includes γ-aminopropyltrimethoxysilane, γ- Aminopropyl triethoxysilane, N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane, N- β-aminoethyl-γ-aminopropyl Trimethoxy silane, it is one or more in diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane.
In one embodiment, the catalyst includes potassium hydroxide, one kind in tetramethylammonium hydroxide, lithium hydroxide Or it is a variety of.
In one embodiment, the organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxygen silicon of aminophenyl Alkane), α, alpha, omega-dihydroxy polydimethyl siloxane.
In one embodiment, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), described α, the weight ratio of alpha, omega-dihydroxy polydimethyl siloxane are 1:(0.05~0.5): (0.5~2).
Another aspect of the present invention provides a kind of deep preparation method for increasing gorgeous organic silicone finishing agent of cotton fabric increasing, including following step It is rapid:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent, is warming up to 70 DEG C, and decompression vacuum pumping to -0.06~-0.08MPa is continuously heating to 100~110 DEG C, under the conditions of nitrogen protection 4~6h is reacted, 145~150 DEG C of 0.5~1h of heat preservation is warming up to, is cooled to room temperature, and low-boiling point material is removed under reduced pressure, is contained Phenyl silicon crude oil；
(2) emulsifier is added into mulser by weight, is then added portionwise the crude oil of silicon containing phenyl, stirring 3~ Glacial acetic acid is added portionwise in 10min, stirs 2~10min, and water is added portionwise, and stirs 2~10min, and polyoxyethylene wax emulsion is added, 0.5~1h is stirred, the cotton fabric is obtained and increases the deep gorgeous organic silicone finishing agent of increasing.
The above-mentioned of the application and other features, aspects and advantages are more readily understood with reference to following detailed description.
Specific embodiment
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily to understand Bright content.Unless otherwise defined, all technologies used herein and scientific term have common with fields of the present invention The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... preparation " it is synonymous with "comprising".Term "comprising" used herein, " comprising ", " having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or Such composition, step, method, product or the intrinsic element of device.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this Phrase will make claim closed, so that it is not included the material in addition to the material of those descriptions, but relative normal Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body, It is only limited to element described in the clause；Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit When the Range Representation that choosing value limits, this should be understood as specifically disclosing by any range limit or preferred value and any range Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise the range is intended to include its end Value and all integers and score in the range.
Singular includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " any It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.
Approximate term in specification and claims is used to modify quantity, and it is specific to indicate that the present invention is not limited to this Quantity further includes the acceptable modified part without will lead to the change of dependency basis this function close with the quantity.Phase It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate Term likely corresponds to the precision of the instrument of measurement numerical value.In present specification and claims, range limits can be with Combination and/or exchange, these ranges if not stated otherwise include all subranges contained therebetween.
In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component (i.e. frequency of occurrence) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number The element or component of form also include plural form, unless the obvious purport of the quantity refers to singular.
" polymer " means polymerizable compound prepared by the monomer by the identical or different type of polymerization.Generic term " polymer " includes term " homopolymer ", " copolymer ", " terpolymer " and " copolymer ".
" copolymer " means the polymer by polymerization at least two different monomers preparation.Generic term " copolymer " includes (it is general with term " terpolymer " for term " copolymer " (it is generally to refer to the polymer prepared by two kinds of different monomers) To refer to the polymer prepared by three kinds of different monomers).It also includes the polymer manufactured by polymerizeing more kinds of monomers. " blend " means that two or more polymer mixes the polymer to be formed by physics or chemical method jointly.
The present invention provides a kind of deep gorgeous organic silicone finishing agent of increasing of cotton fabric increasing, calculates by weight, the cotton fabric increases deep The raw material for increasing gorgeous organic silicone finishing agent includes:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer includes octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, ω-dihydroxy Base dimethyl silicone polymer, hexamethyl cyclotrisiloxane, tetramethyl tetraphenyl cyclotetrasiloxane, one in tetraethyl cyclotetrasiloxane Kind is a variety of.
In one embodiment, the raw material for preparing of the polyamide polyether polymer includes adipic acid, hexamethylene diamine, α-ammonia Base-ω-carboxy polyethylene glycol.
In one embodiment, the adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight Amount is than being 1:(0.8~2): (0.05~0.2)；Preferably, the adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxyl Polyethylene glycol weight ratio is 1:(0.9~1.5): (0.05~0.1)；It is highly preferred that the adipic acid and the hexamethylene diamine, described Alpha-amido-ω-carboxy polyethylene glycol weight ratio is 1:1.15:0.07.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, be warming up to 240 DEG C of progress polycondensation reactions 3~ 6h is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid be 1:(0.02~ 0.05)。
In one embodiment, the silane coupling agent includes silane coupling agent and amino-containing silane idol containing phenyl Join agent.
In one embodiment, the weight of the silane coupling agent containing phenyl and the amino-containing silane coupling agent Than for 1:(0.5~2)；Preferably, the weight ratio of the silane coupling agent containing phenyl and the amino-containing silane coupling agent For 1:(0.8~1.2)；It is highly preferred that the weight of the silane coupling agent containing phenyl and the amino-containing silane coupling agent Than for 1:0.9.
In one embodiment, the silane coupling agent containing phenyl includes phenyltrimethoxysila,e, phenyl diformazan Oxysilane, it is one or more in phenyl triethoxysilane；Preferably, the silane coupling agent containing phenyl is phenyl diformazan Oxysilane.
In one embodiment, the amino-containing silane coupling agent includes γ-aminopropyltrimethoxysilane, γ- Aminopropyl triethoxysilane, N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane, N- β-aminoethyl-γ-aminopropyl Trimethoxy silane, it is one or more in diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane；Preferably, described to contain ammonia The silane coupling agent of base includes γ-aminopropyltrimethoxysilane, N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane, It is one or more in diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane；It is highly preferred that the amino-containing silane is even Connection agent is N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxy silicon Alkane.
In one embodiment, the N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane and the divinyl Three amido-γ-hydroxypropyl methyl dimethoxysilane weight ratio is 1:(0.5~1.6)；Preferably, the N- β-aminoethyl- γ-aminopropyltriethoxy dimethoxysilane and the weight ratio of the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane are 1:1.3.
In one embodiment, the catalyst includes potassium hydroxide, one kind in tetramethylammonium hydroxide, lithium hydroxide Or it is a variety of；Preferably, the catalyst is tetramethylammonium hydroxide.
In one embodiment, the organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxygen silicon of aminophenyl Alkane), α, alpha, omega-dihydroxy polydimethyl siloxane.
In one embodiment, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), described α, the weight ratio of alpha, omega-dihydroxy polydimethyl siloxane are 1:(0.05~0.5): (0.5~2)；Preferably, the prestox ring The weight ratio of tetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy polydimethyl siloxane is 1: (0.06~0.3): (0.8~1.2)；It is highly preferred that the octamethylcy-clotetrasiloxane and described eight (three oxygen silicon of aminophenyl Alkane), the α, the weight ratio of alpha, omega-dihydroxy polydimethyl siloxane is 1:0.08:0.95.
Another aspect of the present invention provides a kind of deep preparation method for increasing gorgeous organic silicone finishing agent of cotton fabric increasing, including following step It is rapid:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent, is warming up to 70 DEG C, and decompression vacuum pumping to -0.06~-0.08MPa is continuously heating to 100~110 DEG C, under the conditions of nitrogen protection 4~6h is reacted, 145~150 DEG C of 0.5~1h of heat preservation is warming up to, is cooled to room temperature, and low-boiling point material is removed under reduced pressure, is contained Phenyl silicon crude oil；
(2) emulsifier is added into mulser by weight, is then added portionwise the crude oil of silicon containing phenyl, stirring 3~ Glacial acetic acid is added portionwise in 10min, stirs 2~10min, and water is added portionwise, and stirs 2~10min, and polyoxyethylene wax emulsion is added, 0.5~1h is stirred, the cotton fabric is obtained and increases the deep gorgeous organic silicone finishing agent of increasing.
In one embodiment, the weight ratio of the organic silicon monomer and the catalyst is 1:(0.001~0.01)； Preferably, the weight ratio of the organic silicon monomer and the catalyst is 1:0.005.
In one embodiment, the organic silicon monomer and the polyamide polyether polymer, the silane coupling agent Weight ratio be 10:(0.5~5): (0.5~1)；Preferably, the organic silicon monomer and the polyamide polyether polymer, institute The weight ratio for stating silane coupling agent is 10:2:0.7.
Emulsifier is can to improve the various surface tension constituted between phase in emulsion, is allowed to form uniform and stable point The substance of granular media system or emulsion.Emulsifier is surface reactive material, has hydrophilic group and lipophilic group simultaneously in molecule, it assembles On oil/water interface, interfacial tension can be reduced and reduction forms energy required for emulsion, to improve the energy of emulsion Amount.
In one embodiment, the emulsifier includes in AEO-3, AEO-4, AEO-5, AEO-7, AEO-9, AEO-10 It is one or more；Preferably, the emulsifier is AEO-5, AEO-7, AEO-9.
In one embodiment, the AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:(0.2~3): (0.8~1.2)；Preferably, the AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
Polyester polyether-type hydrophilic finishing agent can significantly improve the hydrophilicity of dacron, and washability is good, but apply Specific aim is stronger, and when polyamine and the exclusive use of polyamide-based hydrophilic finishing agent, the washability for processing fabric is poor, and has yellowing Phenomenon.
Polyamide component (eutectic composition) and polyether component (hydrophilic component) content ratio directly affect the parent of finish fabric Aqueous and washability.If polyether component ratio is excessively high, finish fabric washability is reduced；If eutectic composition ratio is excessively high, whole It manages fabric hydrophilic to be deteriorated, and also will affect finishing agent water solubility.
The present invention is raw material by alpha-amido-ω-carboxy polyethylene glycol, adipic acid and hexamethylene diamine, obtains polyamide polyether Polymer, polyamide polyether polymer carry out polymerization reaction with organic silicon monomer again, the crude oil of silicon containing phenyl are obtained, by structure The regularity for introducing organosilicon flexible segment destruction polyamide polyether copolymer macromolecular is mentioned with reducing the crystallinity of copolymer The dissolubility of high copolymer；The introducing of organosilicon simultaneously assigns the soft effect of finishing agent finish fabric, and not influencing, its is hydrophilic Property and washability in the case where, make the finishing agent have preferable softness, with reach improve cotton fabric it is hydrophilic while, tool There is the purpose of certain soft effect, and there is certain washability.
In addition, the polyamino introduced on the crude oil molecular structure of silicon containing phenyl can be reacted with the hydroxyl on cotton fabric, in fabric Surface forms the elastic membrane with low-refraction, reduces the reflectivity of incident light, hence it is evident that increase the depth of dyed cotton fabric, and Polysiloxane macromolecular main chain is directionally adsorbed on fiber, reduces interfibrous coefficient of friction, and it is ideal to assign fabric Soft, smooth feel；The introducing of phenyl can make that the color of dyed fabric is more bright-coloured, more light on the crude oil molecular structure of silicon containing phenyl It is bright.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field The some nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used to be all commercially available, it is purchased from traditional Chinese medicines chemical reagent.
Embodiment 1
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy Dimethyl silicone polymer, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy The weight ratio of dimethyl silicone polymer is 1:0.08:0.95；The polyamide polyether polymer prepare raw material include adipic acid, Hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes silane coupling agent containing phenyl and amino-containing The weight ratio of silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:0.9, described Silane coupling agent containing phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-ammonia Hydroxypropyl methyl dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-aminoethyl-γ- The weight ratio of aminopropyltriethoxy dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane is 1: 1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 2
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane；The polyamide polyether polymer prepares raw material packet Include adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent include silane coupling agent containing phenyl and The weight ratio of amino-containing silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1: 0.9, the silane coupling agent containing phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-ammonia second Base-γ-aminopropyltriethoxy dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-ammonia The weight of ethyl-γ-aminopropyltriethoxy dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane Amount is than being 1:1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 3
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is α, alpha, omega-dihydroxy polydimethyl siloxane；The polyamide polyether polymer Preparing raw material includes adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes the silicon containing phenyl Alkane coupling agent and amino-containing silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent Weight ratio is 1:0.9, and the silane coupling agent containing phenyl is phenyidimethoxysilane, the amino-containing silane coupling agent For N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, N- β-aminoethyl-γ-aminopropyltriethoxy the dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxy The weight ratio of base silane is 1:1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 4
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy Dimethyl silicone polymer, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy The weight ratio of dimethyl silicone polymer is 1:0.08:0.95；The polyamide polyether polymer prepare raw material include adipic acid, Hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes silane coupling agent containing phenyl and amino-containing The weight ratio of silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:0.5, described Silane coupling agent containing phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-ammonia Hydroxypropyl methyl dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-aminoethyl-γ- The weight ratio of aminopropyltriethoxy dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane is 1: 1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 5
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy Dimethyl silicone polymer, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy The weight ratio of dimethyl silicone polymer is 1:0.08:0.95；The polyamide polyether polymer prepare raw material include adipic acid, Hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes silane coupling agent containing phenyl and amino-containing The weight ratio of silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:2, described to contain The silane coupling agent of phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-ammonia third Ylmethyl dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-aminoethyl-γ-ammonia The weight ratio of hydroxypropyl methyl dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane is 1: 1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 6
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy Dimethyl silicone polymer, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy The weight ratio of dimethyl silicone polymer is 1:0.08:0.95；The polyamide polyether polymer prepare raw material include adipic acid, Hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes silane coupling agent containing phenyl and amino-containing The weight ratio of silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:0.9, described Silane coupling agent containing phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-ammonia Hydroxypropyl methyl dimethoxysilane；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 7
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy Dimethyl silicone polymer, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy The weight ratio of dimethyl silicone polymer is 1:0.08:0.95；The polyamide polyether polymer prepare raw material include adipic acid, Hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes silane coupling agent containing phenyl and amino-containing The weight ratio of silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:0.9, described Silane coupling agent containing phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is diethylenetriamine base-γ- Hydroxypropyl methyl dimethoxysilane；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 8
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer be octamethylcy-clotetrasiloxane, α, alpha, omega-dihydroxy polydimethyl siloxane, described eight Methyl cyclotetrasiloxane and the α, the weight ratio of alpha, omega-dihydroxy polydimethyl siloxane are 1:0.95；The polyamide polyether The raw material for preparing of polymer includes adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes containing The silane coupling agent of phenyl and amino-containing silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane The weight ratio of coupling agent is 1:0.9, and the silane coupling agent containing phenyl is phenyidimethoxysilane, the amino-containing silicon Alkane coupling agent is N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxy Base silane, the N- β-aminoethyl-γ-aminopropyltriethoxy dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl The weight ratio of dimethoxysilane is 1:1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 9
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy Dimethyl silicone polymer, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy The weight ratio of dimethyl silicone polymer is 1:0.05:2；The polyamide polyether polymer prepare raw material include adipic acid, oneself Diamines, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes silane coupling agent and amino-containing silicon containing phenyl The weight ratio of alkane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:0.9, described to contain The silane coupling agent of phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-ammonia third Ylmethyl dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-aminoethyl-γ-ammonia The weight ratio of hydroxypropyl methyl dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane is 1: 1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 10
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy Dimethyl silicone polymer, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy The weight ratio of dimethyl silicone polymer is 1:0.5:0.5；The polyamide polyether polymer prepare raw material include adipic acid, oneself Diamines, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes silane coupling agent and amino-containing silicon containing phenyl The weight ratio of alkane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:0.9, described to contain The silane coupling agent of phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-ammonia third Ylmethyl dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-aminoethyl-γ-ammonia The weight ratio of hydroxypropyl methyl dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane is 1: 1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.07.
Embodiment 11
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, polyamide polyether polymer, silane idol Join agent, catalyst；The organic silicon monomer is octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy Dimethyl silicone polymer, the octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy The weight ratio of dimethyl silicone polymer is 1:0.08:0.95；The polyamide polyether polymer prepare raw material include adipic acid, Hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol；The silane coupling agent includes silane coupling agent containing phenyl and amino-containing The weight ratio of silane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:0.9, described Silane coupling agent containing phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-ammonia Hydroxypropyl methyl dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-aminoethyl-γ- The weight ratio of aminopropyltriethoxy dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane is 1: 1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalysis are added by weight into reactor Agent is warming up to 70 DEG C, and decompression vacuum pumping to -0.08MPa is continuously heating to 110 DEG C, 5h is reacted under the conditions of nitrogen protection, heats up To 145 DEG C of heat preservation 1h, it is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The organic silicon monomer Weight ratio with the catalyst is 1:0.005；The organic silicon monomer and the polyamide polyether polymer, the silane are even The weight ratio for joining agent is 10:2:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
The polyamide polyether polymer the preparation method is as follows:
Adipic acid, hexamethylene diamine, alpha-amido-ω-carboxy polyethylene glycol are added into reactor, under nitrogen protection, slowly rises Temperature keeps the temperature 0.5h to 170 DEG C or so at this temperature, and antioxidant phosphorous acid is added, is warming up to 240 DEG C of progress polycondensation reaction 4h, It is cooled to room temperature, obtains polyamide polyether polymer；The weight ratio of the adipic acid and the phosphorous acid is 1:0.025；It is described Adipic acid and the hexamethylene diamine, the alpha-amido-ω-carboxy polyethylene glycol weight ratio are 1:1.15:0.05.
Comparative example 1
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, silane coupling agent, catalyst；It is described Organic silicon monomer be octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy polydimethyl siloxane, The octamethylcy-clotetrasiloxane and described eight (three oxosilanes of aminophenyl), the α, alpha, omega-dihydroxy polydimethyl siloxane Weight ratio be 1:0.08:0.95；The silane coupling agent includes silane coupling agent containing phenyl and amino-containing silane coupled Agent, the weight ratio of the silane coupling agent containing phenyl and the amino-containing silane coupling agent be 1:0.9, described containing phenyl Silane coupling agent is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-aminopropyltriethoxy Dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-aminoethyl-γ-aminopropyl first The weight ratio of base dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane is 1:1.3；It is described Catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, silane coupling agent, catalyst are added by weight into reactor, is warming up to 70 DEG C, decompression It is evacuated to -0.08MPa, 110 DEG C is continuously heating to, 5h is reacted under the conditions of nitrogen protection, is warming up to 145 DEG C of heat preservation 1h, is cooled down To room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The weight of the organic silicon monomer and the catalyst Than for 1:0.005；The weight ratio of the organic silicon monomer and the silane coupling agent is 10:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
Comparative example 2
The cotton fabric increases the deep raw material for increasing gorgeous organic silicone finishing agent, calculates by weight, comprising:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, silane coupling agent, catalyst；It is described Organic silicon monomer is octamethylcy-clotetrasiloxane；The silane coupling agent includes silane coupling agent and amino-containing silicon containing phenyl The weight ratio of alkane coupling agent, the silane coupling agent containing phenyl and the amino-containing silane coupling agent is 1:0.9, described to contain The silane coupling agent of phenyl is phenyidimethoxysilane, and the amino-containing silane coupling agent is N- β-aminoethyl-γ-ammonia third Ylmethyl dimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane, the N- β-aminoethyl-γ-ammonia The weight ratio of hydroxypropyl methyl dimethoxysilane and the diethylenetriamine base-γ-hydroxypropyl methyl dimethoxysilane is 1: 1.3；The catalyst is tetramethylammonium hydroxide.
The cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent, comprising the following steps:
(1) organic silicon monomer, silane coupling agent, catalyst are added by weight into reactor, is warming up to 70 DEG C, decompression It is evacuated to -0.08MPa, 110 DEG C is continuously heating to, 5h is reacted under the conditions of nitrogen protection, is warming up to 145 DEG C of heat preservation 1h, is cooled down To room temperature, and low-boiling point material is removed under reduced pressure, obtains the crude oil of silicon containing phenyl；The weight of the organic silicon monomer and the catalyst Than for 1:0.005；The weight ratio of the organic silicon monomer and the silane coupling agent is 10:0.7；
(2) emulsifier is added into mulser by weight, then divides 10 addition crude oil of silicon containing phenyl, stirs 5min, Every minor tick 2min is added three times glacial acetic acid, stirs 5min, every minor tick 2min, is added three times water, stirs 5min, every time It is spaced 5min, polyoxyethylene wax emulsion is added, stirs 1h, the cotton fabric increasing is obtained and increases gorgeous organic silicone finishing agent deeply；The cream Agent is AEO-5, AEO-7, AEO-9；The AEO-5 and the AEO-7, the AEO-9 weight ratio be 1:0.25:1.1.
Performance test
1, soaping fastness: by GB/T3921-2008 " textile color stability test: soaping fastness " method measurement；
2, crock fastness: by GB/T3920-2008 " textile color stability test: crock fastness " method measurement；
3, feel is tested: being closed the fabric that mesh touches after arranging and is graded using 10 people as a small group, according to different hands PRINTED FABRIC is carried out hand feel evaluation, specific assessment method by sense are as follows: feel grading is carried out in terms of flexibility, smooth feeling two, altogether Divide 5 grades, 1 grade worst, and fabric feeling is harder, and sliding glutinous sense is poor.5 grades preferably, and fabrics feel soft, cunning are glutinous.
4, stability
(1) heat-resistant stability
Test method is as follows: a certain amount of arrangement agent emulsion being put into the container of sealing, 80 DEG C of thermostatted water is placed on In bath, 6h is kept the temperature, observes emulsion appearance, no floating oil, lamination illustrate that arrangement agent emulsion heat-resistant stability is good, there is a small amount of drift Oil, lamination illustrate that arrangement agent emulsion heat-resistant stability is general, have floating oil, lamination to illustrate to arrange agent emulsion Heat-resistant stable Property is poor.
(2) resistance to freezing stability
Test method is as follows: a certain amount of arrangement agent emulsion being put into the container of sealing, -20 DEG C of thermostatted water is placed on In bath, 6h is kept the temperature, after natural thaw, its state change is observed and records, no floating oil, lamination illustrate to arrange the resistance to jelly of agent emulsion Stability is good, has a small amount of floating oil, lamination to illustrate that the arrangement resistance to freezing stability of agent emulsion is general, there is a large amount of floating oils, lamination Illustrate that the arrangement resistance to freezing stability of agent emulsion is poor.
(3) acid-resistant stability
Test method is as follows: a certain amount of arrangement agent emulsion being put into the container of sealing, the pH value of 50 times of weight is added It is static to place 1 day for 3 aqueous hydrochloric acid solutions, it observes its state change and records, no floating oil, lamination illustrate to arrange agent emulsion Acid-resistant stability is good, has a small amount of floating oil, lamination to illustrate that arrangement agent emulsion acid-resistant stability is general, there is floating oil, lamination Illustrate that arrangement agent emulsion acid-resistant stability is poor.
(4) alkali stability
Test method is as follows: a certain amount of arrangement agent emulsion being put into the container of sealing, the pH value of 50 times of weight is added It is static to place 1 day for 12 sodium hydrate aqueous solution, it observes its state change and records, no floating oil, lamination illustrate to arrange Agent emulsion alkali stability is good, has a small amount of floating oil, lamination to illustrate that arrangement agent emulsion alkali stability is general, has floating oil, divides Layer phenomenon illustrates that arrangement agent emulsion alkali stability is poor.
5, washability
After fabric washing 100 times, observe the color of fabric, evaluation method: the color of fabric keeps 96% before washing The washability of fabric described above is good；The color of fabric keeps 80~95% before washing, illustrates the washability of fabric；Fabric Color keeps 80% or less before washing to illustrate that the washability of fabric is poor.
1 the performance test results of table
It is seen from the above data that preparing in raw material with the crude oil of silicon containing phenyl without polyamide polyether polymer, containing benzene Preparing in raw material for base silicon crude oil is compared without polyamide polyether polymer and organic silicon monomer for octamethylcy-clotetrasiloxane, this hair The cotton fabric of bright offer increases the deep gorgeous organic silicone finishing agent of increasing and assigns fabric ideal soft, smooth feel, and makes dyed fabric Color it is more bright-coloured, brighter；In addition, preparation method simple process of the invention, convenient operation and control, quality are stablized, production It is high-efficient, it can large-scale industrial production.
The above embodiments are merely illustrative, some features of feature for explaining the present invention.Appended right is wanted The range as wide as possible for being intended to require to be contemplated that is sought, and embodiments as presented herein is only according to all possible implementation The explanation of the embodiment of the combined selection of example.Therefore, the purpose of applicant is that the attached claims are not illustrated this hair The exemplary selectional restriction of bright feature, and the progress in science and technology will be formed language express it is inaccurate due to and The possible equivalent that is not presently considered or son replacement, and these variations should also be interpreted in the conceived case it is appended Claim covering.

Claims (9)

1. a kind of cotton fabric increases the deep gorgeous organic silicone finishing agent of increasing, which is characterized in that calculate by weight, the cotton fabric increases deep increase The raw material of gorgeous organic silicone finishing agent includes:
Wherein, the raw material for preparing of the crude oil of silicon containing phenyl includes organic silicon monomer, and polyamide polyether polymer is silane coupled Agent, catalyst；The organic silicon monomer includes octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy It is dimethyl silicone polymer, hexamethyl cyclotrisiloxane, tetramethyl tetraphenyl cyclotetrasiloxane, a kind of in tetraethyl cyclotetrasiloxane Or it is a variety of；The raw material for preparing of the polyamide polyether polymer includes adipic acid, hexamethylene diamine, the poly- second two of alpha-amido-ω-carboxyl Alcohol.
2. cotton fabric increases the deep gorgeous organic silicone finishing agent of increasing according to claim 1, which is characterized in that the silane coupling agent packet Include silane coupling agent and amino-containing silane coupling agent containing phenyl.
3. cotton fabric increases the deep gorgeous organic silicone finishing agent of increasing according to claim 2, which is characterized in that the silane containing phenyl The weight ratio of coupling agent and the amino-containing silane coupling agent is 1:(0.5~2).
4. cotton fabric increases the deep gorgeous organic silicone finishing agent of increasing according to claim 2, which is characterized in that the silane containing phenyl Coupling agent includes phenyltrimethoxysila,e, phenyidimethoxysilane, one or more in phenyl triethoxysilane.
5. cotton fabric increases the deep gorgeous organic silicone finishing agent of increasing according to claim 2, which is characterized in that the amino-containing silane Coupling agent includes γ-aminopropyltrimethoxysilane, gamma-aminopropyl-triethoxy-silane, N- β-aminoethyl-γ-aminopropyl first Base dimethoxysilane, N- β-aminoethyl-γ-aminopropyltrimethoxysilane, diethylenetriamine base-γ-hydroxypropyl methyl diformazan It is one or more in oxysilane.
6. cotton fabric increases the deep gorgeous organic silicone finishing agent of increasing according to claim 1, which is characterized in that the catalyst includes hydrogen Potassium oxide, it is one or more in tetramethylammonium hydroxide, lithium hydroxide.
7. cotton fabric, which increases, according to claim 1 deep increases gorgeous organic silicone finishing agent, which is characterized in that the organic silicon monomer is Octamethylcy-clotetrasiloxane, eight (three oxosilanes of aminophenyl), α, alpha, omega-dihydroxy polydimethyl siloxane.
8. cotton fabric increases the deep gorgeous organic silicone finishing agent of increasing according to claim 7, which is characterized in that four silicon of prestox ring Oxygen alkane and described eight (three oxosilanes of aminophenyl), the α, the weight ratio of alpha, omega-dihydroxy polydimethyl siloxane are 1:(0.05 ~0.5): (0.5~2).
9. any one cotton fabric increases the deep preparation method for increasing gorgeous organic silicone finishing agent according to claim 1~8, feature exists In, comprising the following steps:
(1) organic silicon monomer, polyamide polyether polymer, silane coupling agent, catalyst are added by weight into reactor, rises To 70 DEG C, decompression vacuum pumping to -0.06~-0.08MPa is continuously heating to 100~110 DEG C, 4 is reacted under the conditions of nitrogen protection temperature ~6h is warming up to 145~150 DEG C of 0.5~1h of heat preservation, is cooled to room temperature, and low-boiling point material is removed under reduced pressure, obtains silicon containing phenyl Crude oil；
(2) emulsifier is added into mulser by weight, the crude oil of silicon containing phenyl is then added portionwise, stirs 3~10min, point Addition glacial acetic acid is criticized, 2~10min is stirred, water is added portionwise, stirs 2~10min, polyoxyethylene wax emulsion, stirring 0.5 is added ~1h obtains the cotton fabric and increases the deep gorgeous organic silicone finishing agent of increasing.
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