CN106835687A - A kind of method for preparing polycarbonate conductive material of aluminizing - Google Patents
A kind of method for preparing polycarbonate conductive material of aluminizing Download PDFInfo
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- CN106835687A CN106835687A CN201710067403.1A CN201710067403A CN106835687A CN 106835687 A CN106835687 A CN 106835687A CN 201710067403 A CN201710067403 A CN 201710067403A CN 106835687 A CN106835687 A CN 106835687A
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- CN
- China
- Prior art keywords
- polycarbonate
- conductive material
- ito
- sensitized treatment
- aluminizing
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- 239000004417 polycarbonate Substances 0.000 title claims abstract description 34
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 34
- 239000004020 conductor Substances 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000005269 aluminizing Methods 0.000 title claims abstract description 8
- 239000000835 fiber Substances 0.000 claims abstract description 13
- 229910002666 PdCl2 Inorganic materials 0.000 claims abstract description 7
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims abstract description 7
- 235000011150 stannous chloride Nutrition 0.000 claims abstract description 7
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000011259 mixed solution Substances 0.000 claims abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 5
- 239000004411 aluminium Substances 0.000 abstract description 4
- 239000002131 composite material Substances 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 238000003475 lamination Methods 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 239000004332 silver Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/20—Halides of elements of Groups 4 or 14 of the Periodic Table, e.g. zirconyl chloride
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/28—Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Chemically Coating (AREA)
Abstract
The invention discloses a kind of method for preparing polycarbonate conductive material of aluminizing, it is characterised in that comprise the following steps：（1）Polycarbonate is washed（2）ITO colloidal sols soak（3）Sensitized treatment（4）Washing；The present invention introduces ITO sol layers, the binding strength for introducing the compatibility that on the one hand can solve the problem that between metal simple-substance and fibre-forming polymer, lifting silver layer and fiber of ITO layer between aluminium lamination and polycarbonate；On the other hand, the introducing of this layer is realized and builds ITO Al composite constructions in fiber surface, is remarkably improved the electric conductivity of Conductive Silver-Coated PET Fibers using the structure while reducing thickness of coating.In addition, sensitized treatment, so that fiber surface has the relatively low slaine of SnCl2 and PdCl2 activity, preferable environment is provided with for sequential reduction aluminium using being carried out in the mixed solution of SnCl2 and PdCl2.
Description
Technical field
The present invention relates to conductive material field, more particularly to a kind of side for preparing polycarbonate conductive material of aluminizing
Method.
Background technology
Composite polymer conductive material, by general macromolecular material and various conductive materials by filled composite,
The mode such as surface recombination or lamination be compound and be obtained.Principal item has conductive plastics, conductive rubber, conductive fibers, conduction
Coating, conductive adhesive and transparent conductive film etc..
Conductive fiber prepared by the market, is embedded in fibrous material by the material using high conductivity such as silver-colored monomers,
Make it have good conductive effect.But due to higher using silver-colored production cost so that the preparation cost of material rises, and does not apply to
In the growth requirement of modern industry.
The content of the invention
The technical problem to be solved in the present invention is：For above-mentioned the deficiencies in the prior art, there is provided one kind prepares poly- carbon of aluminizing
The method of acid esters fibrous conductive material.
The present invention solve its technical problem solution be：A kind of side for preparing polycarbonate conductive material of aluminizing
Method, it is characterised in that it is comprised the following steps：
（1）Polycarbonate is washed：Polycarbonate is immersed acetone, organic solvent soluble in water successively carries out ultrasound
Cleaning 10-30 minutes, is then cleaned with deionized water, is dried；
（2）ITO colloidal sols soak：Polycarbonate after treatment is soaked into 5-20min in ITO colloidal sols, through 50-60 after taking-up
Slowly dried at a temperature of DEG C；
（3）Sensitized treatment：By step（2）In polycarbonate through sensitized treatment after, be soaked on aluminum plating liquid, and be added dropwise also
Former agent, in carrying out insulation 20-60min at 40-60 DEG C；
（4）Washing：By step（3）In polycarbonate, through distilled water flushing, final products are obtained after drying.
As one of preferred technical scheme, it is characterised in that described polycarbonate is aromatic copolycarbonate
Fiber.
As one of preferred technical scheme, it is characterised in that described step（3）Sensitized treatment specific steps
For：Impregnated in mixed solution by polycarbonate using SnCl2 and PdCl2；
As one of preferred technical scheme, it is characterised in that described step（3）In reducing agent be organic reducing agent.
The beneficial effects of the invention are as follows：
（1）ITO sol layers are introduced between aluminium lamination and polycarbonate with the present invention, on the one hand the introducing of ITO layer can solve
Certainly the compatibility between metal simple-substance and fibre-forming polymer, lifts the binding strength of silver layer and fiber；On the other hand, this layer draws
Enter to realize and build ITO-Al composite constructions in fiber surface, the electric conductivity of Conductive Silver-Coated PET Fibers is remarkably improved using the structure
Thickness of coating can simultaneously be reduced.
（2）Sensitized treatment using being carried out in the mixed solution of SnCl2 and PdCl2 so that fiber surface has SnCl2
The slaine relatively low with PdCl2 activity, preferable environment is provided with for sequential reduction aluminium.
Specific embodiment
The technique effect of design of the invention, concrete thought and generation is carried out below with reference to embodiment clear, complete
Ground description, to be completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is of the invention one
Section Example, rather than whole embodiments, based on embodiments of the invention, those skilled in the art is not paying creativeness
The other embodiment obtained on the premise of work, belongs to the scope of protection of the invention.
Embodiment：
A kind of method for preparing polycarbonate conductive material of aluminizing, it is characterised in that it is comprised the following steps：
（1）Polycarbonate is washed：Polycarbonate is immersed acetone, organic solvent soluble in water successively carries out ultrasound
Cleaning 20 minutes, is then cleaned with deionized water, is dried；
（2）ITO colloidal sols soak：Polycarbonate after treatment is soaked into 20min in ITO colloidal sols, through 50 DEG C after taking-up
At a temperature of slowly dry；
（3）Sensitized treatment：By step（2）In polycarbonate through sensitized treatment after, be soaked on aluminum plating liquid, and be added dropwise also
Former agent, in carrying out insulation 30min at 50 DEG C；
（4）Washing：By step（3）In polycarbonate, through distilled water flushing, final products are obtained after drying.
As one of preferred embodiment, it is characterised in that described polycarbonate is aromatic copolycarbonate
Fiber.
As one of preferred embodiment, it is characterised in that described step（3）Sensitized treatment specific steps
For：Impregnated in mixed solution by polycarbonate using SnCl2 and PdCl2.
As one of preferred embodiment, it is characterised in that described step（3）In reducing agent be organic reduction
Agent.
Better embodiment of the invention is illustrated above, but the invention is not limited to the implementation
Example, those of ordinary skill in the art can also make a variety of equivalent modifications or replace on the premise of without prejudice to spirit of the invention
Change, these equivalent modifications or replacement are all contained in the application claim limited range.
Claims (4)
1. a kind of method for preparing polycarbonate conductive material of aluminizing, it is characterised in that it is comprised the following steps：
（1）Polycarbonate is washed：Polycarbonate is immersed acetone, organic solvent soluble in water successively carries out ultrasound
Cleaning 10-30 minutes, is then cleaned with deionized water, is dried；
（2）ITO colloidal sols soak：Polycarbonate after treatment is soaked into 5-20min in ITO colloidal sols, through 50-60 after taking-up
Slowly dried at a temperature of DEG C；
（3）Sensitized treatment：By step（2）In polycarbonate through sensitized treatment after, be soaked on aluminum plating liquid, and be added dropwise also
Former agent, in carrying out insulation 20-60min at 40-60 DEG C；
（4）Washing：By step（3）In polycarbonate, through distilled water flushing, final products are obtained after drying.
2. preparation according to claim 1 is aluminized the method for polycarbonate conductive material, it is characterised in that described
Polycarbonate is aromatic copolycarbonate fiber.
3. preparation according to claim 1 is aluminized the method for polycarbonate conductive material, it is characterised in that described
Step（3）Sensitized treatment concretely comprise the following steps：Impregnated in mixed solution by polycarbonate using SnCl2 and PdCl2.
4. the preparation according to claim 1,2 or 3 any one claims is aluminized polycarbonate conductive material
Method, it is characterised in that described step（3）In reducing agent be organic reducing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710067403.1A CN106835687A (en) | 2017-02-07 | 2017-02-07 | A kind of method for preparing polycarbonate conductive material of aluminizing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710067403.1A CN106835687A (en) | 2017-02-07 | 2017-02-07 | A kind of method for preparing polycarbonate conductive material of aluminizing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106835687A true CN106835687A (en) | 2017-06-13 |
Family
ID=59121447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710067403.1A Withdrawn CN106835687A (en) | 2017-02-07 | 2017-02-07 | A kind of method for preparing polycarbonate conductive material of aluminizing |
Country Status (1)
| Country | Link |
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| CN (1) | CN106835687A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101978006A (en) * | 2008-03-18 | 2011-02-16 | 印可得株式会社 | Multi-functional coating solution composition |
| CN102899886A (en) * | 2012-10-25 | 2013-01-30 | 中原工学院 | Preparation method for bacterial cellulose based generating fiber and yarn |
| CN104179004A (en) * | 2014-08-21 | 2014-12-03 | 大连工业大学 | Silver-plated conductive polyester fiber and preparation method thereof |
-
2017
- 2017-02-07 CN CN201710067403.1A patent/CN106835687A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101978006A (en) * | 2008-03-18 | 2011-02-16 | 印可得株式会社 | Multi-functional coating solution composition |
| CN102899886A (en) * | 2012-10-25 | 2013-01-30 | 中原工学院 | Preparation method for bacterial cellulose based generating fiber and yarn |
| CN104179004A (en) * | 2014-08-21 | 2014-12-03 | 大连工业大学 | Silver-plated conductive polyester fiber and preparation method thereof |
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| PB01 | Publication | ||
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170613 |
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| WW01 | Invention patent application withdrawn after publication |