CN106835262B - A method of growth aluminium tetraborate salt crystal - Google Patents
A method of growth aluminium tetraborate salt crystal Download PDFInfo
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- CN106835262B CN106835262B CN201710071990.1A CN201710071990A CN106835262B CN 106835262 B CN106835262 B CN 106835262B CN 201710071990 A CN201710071990 A CN 201710071990A CN 106835262 B CN106835262 B CN 106835262B
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B9/00—Single-crystal growth from melt solutions using molten solvents
- C30B9/04—Single-crystal growth from melt solutions using molten solvents by cooling of the solution
- C30B9/08—Single-crystal growth from melt solutions using molten solvents by cooling of the solution using other solvents
- C30B9/12—Salt solvents, e.g. flux growth
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/16—Oxides
- C30B29/22—Complex oxides
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Abstract
The present invention relates to the growing methods of aluminium tetraborate salt crystal.This method uses new NaF-AlF3‑B2O3Chemical combination objects system can weaken the volatilization of the certain ingredients of solution in crystal growing process as fluxing agent growth aluminium tetraborate salt crystal, to effectively avoid the crystal growth due to caused by the volatilization of the certain ingredients of solution unstable and crystal defect.The aluminium tetraborate single-crystal of salt for obtaining large scale and high optical quality can be grown using technical solution of the present invention, be conducive to improve the performance of the laser and device for non-linear optical using monocrystalline production.
Description
Technical field
The present invention relates to a kind of growing method of monocrystalline, the flux growth metrhod for particularly relating to aluminium tetraborate salt crystal is raw
It is long.
Background technique
Aluminium tetraborate salt crystal RAl3(BO3)4With good physical and chemical performance and higher thermal conductivity and lesser
Thermal expansion anisotropy, strong alkali-acid resistance do not deliquesce.The crystalloid has biggish nonlinear optical coefficients, and moderate is two-fold
Rate and wide transmission region are penetrated, is a kind of outstanding non-linear optical crystal material.Part R in the crystalloid3+Ion lattice
If position is by certain rare earth ion (such as Nd3+, Yb3+And Er3+Deng) occupied, fundamental wave can be achieved under semiconductor laser pumping and swash
Light, therefore be also a kind of outstanding laser crystal material;It, can also be further real if the crystal is cut along certain phase matching angle
Existing self frequency-changing's laser output, thus referred to as self frequency-changing's laser crystal material.Since the crystalloid is off-congruent fusing, so
It must be grown using flux growth metrhod.What is generallyd use at present is the fluxing agent system based on molybdenum trioxide, is being grown
Molybdenum trioxide is readily volatilized in the process, not only causes crystal growth unstable, but also Mo3+Can enter crystal in become impurity from
Son, to reduce the optical quality of grown crystal.
Summary of the invention
The purpose of the present invention is to provide a kind of new fluxing agent systems for growing aluminium tetraborate single-crystal of salt.The fluxing agent
System can be effectively reduced volatilization of the pyrosol ingredient in crystal growing process, improve the stability of crystal growth, thus
Obtain the aluminium tetraborate single-crystal of salt of centimeter-scale and high optical quality.
The present invention includes following technical solution:
1. a kind of method for growing aluminium tetraborate salt crystal, it is characterised in that: use NaF-AlF3-B2O3Chemical combination objects system
It is fluxing agent growth aluminium tetraborate salt crystal RAl3(BO3)4, wherein R is certain in Y, Gd, Lu, Er, Yb, Nd, Dy, Tb, Sm element
The combination of one element or several elements;By aluminium tetraborate salt compound and NaF-AlF3-B2O3Chemical combination objects system mixes by a certain percentage
Conjunction is uniformly placed in platinum crucible, is heated to 1050-1150 DEG C of fusing and constant temperature certain time, then be down to solution saturation temperature point
Solution temperature after obtaining accurate saturation temperature point, is increased to saturation temperature by the test for nearby carrying out accurate saturation temperature point
5-15 DEG C of degree or more, then the seed crystal being fixed on seed rod is put into solution, with 0.5-3 DEG C/day after constant temperature 10-30 hours
Rate cooling, while with 5-30 revs/min of rate rotate crystal.After crystal growth is to required size, stop operating crystal
And lift-off liquid level, then room temperature is down to 5-40 DEG C/h of rate, it can be obtained aluminium tetraborate salt crystal.
2. method as described in item 1, it is characterised in that: aluminium tetraborate salt compound and NaF-AlF3-B2O3Chemical combination objects system
Between mass percent be (20-30): 100.
3. method as described in item 1, it is characterised in that: NaF-AlF3-B2O3NaF, AlF in chemical combination objects system3And B2O3Change
Closing the mass percent between object is 1:(1-2): (1.5-2.5).
Aluminium tetraborate salt crystal is grown using the fluxing agent system that technical solution of the present invention proposes, crystal growth can be weakened
The volatilization of the certain ingredients of solution in the process, therefore it is possible to prevente effectively from the crystal due to caused by the volatilization of the certain ingredients of solution is raw
Long unstable and crystal defect.The tetraboric acid aluminium salt for obtaining large scale and high optical quality can be grown using technical solution of the present invention
Monocrystalline is conducive to improve the performance of the laser and device for non-linear optical using monocrystalline production.
Specific embodiment
Example 1: NaF-AlF is used3-B2O3Chemical combination objects system is fluxing agent growth YAl3(BO3)4Crystal
The Y of 43g is weighed respectively2O3, 514.3g H3BO3, 58.2g Al2O3, 333.4g AlF3·3H2O and 142.9g
NaF be placed in agate mortar together and grind and be uniformly mixed.Uniformly mixed raw material by high temperature melt furnace at 1100 DEG C
70 × 70mm of φ is poured into after melting several times3Platinum crucible in, and be placed in crystal growing furnace, growth furnace be warming up to 1150
DEG C 1050 DEG C are down to after constant temperature 20 hours.The saturation temperature point that solution is determined with continuous seeding down crystal method, then heats up solution
More than to saturation temperature point after 10 DEG C, the seed crystal being fixed on seed rod in advance is slowly dropped into liquid level hereinafter, constant temperature half
Saturation temperature point is down to after hour.Constant temperature is cooled down after growing 24 hours with the rate of 1 DEG C/day, and with the rotation of 15 revs/min of rate
Crystal.When cooling amount is up to 80 DEG C, stop operating crystal and lift-off liquid level, terminates growth.It is annealed again with 40 DEG C/h of rate
To room temperature, obtains size and be greater than 15 × 20 × 30mm3High-quality transparent YAl3(BO3)4Crystal.
Example 2: NaF-AlF is used3-B2O3Chemical combination objects system is fluxing agent growth GdAl3(BO3)4Crystal
The Gd of 64g is weighed respectively2O3, 514.3g H3BO3, 58.2g Al2O3, 333.4g AlF3·3H2O and 104.5g
NaF be placed in agate mortar together and grind and be uniformly mixed.Uniformly mixed raw material by high temperature melt furnace at 1100 DEG C
70 × 70mm of φ is poured into after melting several times3Platinum crucible in, and be placed in crystal growing furnace, growth furnace be warming up to 1150
DEG C 1080 DEG C are down to after constant temperature 15 hours.The saturation temperature point that solution is determined with continuous seeding down crystal method, then heats up solution
More than to saturation temperature point after 7 DEG C, the seed crystal being fixed on seed rod in advance is slowly dropped into liquid level hereinafter, constant temperature half is small
When after be down to saturation temperature point.Constant temperature is cooled down after growing 20 hours with the rate of 0.5 DEG C/day, and with the rotation of 20 revs/min of rate
Crystal.When cooling amount is up to 80 DEG C, stop operating crystal and lift-off liquid level, terminates growth.It is annealed again with 30 DEG C/h of rate
To room temperature, obtains size and be greater than 10 × 25 × 25mm3High-quality transparent GdAl3(BO3)4Crystal.
Example 3: NaF-AlF is used3-B2O3Chemical combination objects system is fluxing agent growth LuAl3(BO3)4Crystal
The Lu of 71.8g is weighed respectively2O3, 509.3g H3BO3, 55.1g Al2O3, 333.4g AlF3·3H2O and
The NaF of 126.3g is placed in agate mortar together and grinds and be uniformly mixed.Uniformly mixed raw material is existed by high temperature melt furnace
70 × 70mm of φ is poured into after 1150 DEG C of fusings several times3Platinum crucible in, and be placed in crystal growing furnace, growth furnace heated up
1060 DEG C are down to after constant temperature 30 hours to 1150 DEG C.The saturation temperature point that solution is determined with continuous seeding down crystal method, then will be molten
After liquid is warming up to 15 DEG C of saturation temperature point or more, the seed crystal being fixed on seed rod in advance is slowly dropped into liquid level hereinafter,
Saturation temperature point is down to after constant temperature half an hour.Constant temperature is cooled down after growing 30 hours with the rate of 2 DEG C/day, and with 25 revs/min of speed
Rate rotates crystal.When cooling amount is up to 80 DEG C, stop operating crystal and lift-off liquid level, terminates growth.Again with 20 DEG C/h of speed
Rate is annealed to room temperature, obtains size and is greater than 20 × 30 × 25mm3High-quality transparent LuAl3(BO3)4Crystal.
Example 4: NaF-AlF is used3-B2O3Chemical combination objects system is fluxing agent growth Nd0.04Y0.96Al3(BO3)4Crystal
The Nd of 2.56g is weighed respectively2O3, 41.28g Y2O3, 514.3g H3BO3, 58.2g Al2O3, 333.4g
AlF3·3H2The NaF of O and 142.9g is placed in agate mortar together and grinds and be uniformly mixed.Uniformly mixed raw material is passed through height
Warm melt furnace pours into 70 × 70mm of φ after melting several times at 1100 DEG C3Platinum crucible in, and be placed in crystal growing furnace, will
Growth furnace is warming up to 1150 DEG C of constant temperature and is down to 1050 DEG C after 20 hours.The saturation temperature of solution is determined with continuous seeding down crystal method
Point slowly drops to the seed crystal being fixed on seed rod in advance after solution is then warming up to 8 DEG C of saturation temperature point or more
Liquid level is hereinafter, be down to saturation temperature point after constant temperature half an hour.Constant temperature is cooled down after growing 30 hours with the rate of 1.5 DEG C/day, and with
20 revs/min of rate rotates crystal.When cooling amount is up to 80 DEG C, stop operating crystal and lift-off liquid level, terminates growth.Again with 35
DEG C/h rate be annealed to room temperature, obtain size and be greater than 20 × 20 × 30mm3High-quality transparent single crystal Nd0.04Y0.96Al3
(BO3)4Crystal.
Example 5: NaF-AlF is used3-B2O3Chemical combination objects system is fluxing agent growth Yb0.1Gd0.9Al3(BO3)4Crystal
The Yb of 7.5g is weighed respectively2O3, 57.7g Gd2O3, 514.3g H3BO3, 58.2g Al2O3, 333.4g
AlF3·3H2The NaF of O and 142.9g is placed in agate mortar together and grinds and be uniformly mixed.Uniformly mixed raw material is passed through height
Warm melt furnace pours into 70 × 70mm of φ after melting several times at 1100 DEG C3Platinum crucible in, and be placed in crystal growing furnace, will
Growth furnace is warming up to 1150 DEG C of constant temperature and is down to 1060 DEG C after 20 hours.The saturation temperature of solution is determined with continuous seeding down crystal method
Point slowly declines the seed crystal being fixed on seed rod in advance after solution is then warming up to 10 DEG C of saturation temperature point or more
To liquid level hereinafter, being down to saturation temperature point after constant temperature half an hour.Constant temperature is cooled down after growing 24 hours with the rate of 2 DEG C/day, and with
20 revs/min of rate rotates crystal.When cooling amount is up to 80 DEG C, stop operating crystal and lift-off liquid level, terminates growth.Again with 40
DEG C/h rate be annealed to room temperature, obtain size and be greater than 15 × 15 × 30mm3High-quality transparent Yb0.1Gd0.9Al3(BO3)4It is brilliant
Body.
Example 6: NaF-AlF is used3-B2O3Chemical combination objects system is fluxing agent growth Er0.015Yb0.15Lu0.835Al3(BO3)4It is brilliant
Body
The Er of 1.03g is weighed respectively2O3, 10.67g Yb2O3, 60g Lu2O3, 509.3g H3BO3, 55.1g
Al2O3, 333.4g AlF3·3H2The NaF of O and 126.3g is placed in agate mortar together and grinds and be uniformly mixed.Mixing
Uniform raw material pours into 70 × 70mm of φ after melting several times by high temperature melt furnace at 1100 DEG C3Platinum crucible in, and place
In crystal growing furnace, 1060 DEG C are down to after growth furnace is warming up to 1150 DEG C of constant temperature 20 hours.It is true with continuous seeding down crystal method
The saturation temperature point for determining solution after solution is then warming up to 12 DEG C of saturation temperature point or more, will be fixed on seed rod in advance
Seed crystal slowly drop to liquid level hereinafter, being down to saturation temperature point after constant temperature half an hour.With 1.5 after constant temperature growth 30 hours
The rate of DEG C/day cools down, and rotates crystal with 30 revs/min of rate.When cooling amount is up to 80 DEG C, stop operating crystal and lift-off
Liquid level terminates growth.Room temperature is annealed to 40 DEG C/h of rate again, size is obtained and is greater than 15 × 20 × 25mm3It is high-quality
Bright Er0.015Yb0.15Lu0.835Al3(BO3)4Crystal.
Claims (7)
1. a kind of method for growing aluminium tetraborate salt crystal, it is characterised in that: use NaF-AlF3-B2O3Chemical combination objects system helps
Flux growth aluminium tetraborate salt crystal RAl3(BO3)4, wherein R is certain unitary in Y, Gd, Lu, Er, Yb, Nd, Dy, Tb, Sm element
The combination of plain or several elements;By aluminium tetraborate salt compound and NaF-AlF3-B2O3Chemical combination objects system is by mass percentage
(20-30): 100 are uniformly mixed and are placed in platinum crucible, are heated to 1050-1150 DEG C of fusing and constant temperature certain time, then are down to
Solution saturation temperature point nearby carries out the test of accurate saturation temperature point, after obtaining accurate saturation temperature point, by solution temperature
Degree is increased to above 5-15 DEG C of saturation temperature point, then the seed crystal being fixed on seed rod is put into solution, constant temperature 10-30 hours
Cooled down afterwards with 0.5-3 DEG C/day of rate, while crystal is rotated with 5-30 revs/min of rate;When crystal growth to required size
Afterwards, stop operating crystal and lift-off liquid level, then is down to room temperature with 5-40 DEG C/h of rate, and it is brilliant to can be obtained tetraboric acid aluminium salt
Body;The NaF-AlF3-B2O3NaF, AlF in chemical combination objects system3And B2O3Mass percent between compound is 1:(1-2):
(1.5-2.5)。
2. a kind of method for growing aluminium tetraborate salt crystal, it is characterised in that: weigh the Y of 43g respectively2O3, 514.3g H3BO3、
58.2g Al2O3, 333.4g AlF3·3H2The NaF of O and 142.9g is placed in agate mortar together and grinds and be uniformly mixed;
70 × 70mm of φ is poured into after uniformly mixed raw material is melted by high temperature melt furnace at 1100 DEG C several times3Platinum crucible in,
And be placed in crystal growing furnace, 1050 DEG C are down to after growth furnace is warming up to 1150 DEG C of constant temperature 20 hours;With continuous lower seed crystal
Method determines that the saturation temperature point of solution will be fixed on seed after solution is then warming up to 10 DEG C of saturation temperature point or more in advance
Seed crystal on crystalline style slowly drops to liquid level hereinafter, being down to saturation temperature point after constant temperature half an hour;After constant temperature is grown 24 hours
Cooled down with the rate of 1 DEG C/day, and crystal is rotated with 15 revs/min of rate;When cooling amount is up to 80 DEG C, crystal is stopped operating simultaneously
Lift-off liquid level terminates growth.
3. a kind of method for growing aluminium tetraborate salt crystal, it is characterised in that: weigh the Gd of 64g respectively2O3, 514.3g H3BO3、
58.2g Al2O3, 333.4g AlF3·3H2The NaF of O and 104.5g is placed in agate mortar together and grinds and be uniformly mixed;
70 × 70mm of φ is poured into after uniformly mixed raw material is melted by high temperature melt furnace at 1100 DEG C several times3Platinum crucible in,
And be placed in crystal growing furnace, 1080 DEG C are down to after growth furnace is warming up to 1150 DEG C of constant temperature 15 hours;With continuous lower seed crystal
Method determines that the saturation temperature point of solution will be fixed on seed crystal after solution is then warming up to 7 DEG C of saturation temperature point or more in advance
Seed crystal on bar slowly drops to liquid level hereinafter, being down to saturation temperature point after constant temperature half an hour;Constant temperature grow 20 hours after with
The rate of 0.5 DEG C/day cools down, and rotates crystal with 20 revs/min of rate;When cooling amount is up to 80 DEG C, crystal is stopped operating simultaneously
Lift-off liquid level terminates growth.
4. a kind of method for growing aluminium tetraborate salt crystal, it is characterised in that: weigh the Lu of 71.8g respectively2O3, 509.3g
H3BO3, 55.1g Al2O3, 333.4g AlF3·3H2The NaF of O and 126.3g is placed in agate mortar together and grinds and mix
Uniformly;70 × 70mm of φ is poured into after uniformly mixed raw material is melted by high temperature melt furnace at 1150 DEG C several times3Platinum earthenware
It in crucible, and is placed in crystal growing furnace, is down to 1060 DEG C after growth furnace is warming up to 1150 DEG C of constant temperature 30 hours;Under constantly
Seed crystal method determines that the saturation temperature point of solution will be fixed in advance after solution is then warming up to 15 DEG C of saturation temperature point or more
Seed crystal on seed rod slowly drops to liquid level hereinafter, being down to saturation temperature point after constant temperature half an hour;Constant temperature growth 30 is small
When after cooled down with the rates of 2 DEG C/day, and crystal is rotated with 25 revs/min of rate;When cooling amount is up to 80 DEG C, stop operating crystalline substance
Body and lift-off liquid level terminate growth.
5. a kind of method for growing aluminium tetraborate salt crystal, it is characterised in that: weigh the Nd of 2.56g respectively2O3, 41.28g
Y2O3, 514.3g H3BO3, 58.2g Al2O3, 333.4g AlF3·3H2The NaF of O and 142.9g is placed in agate mortar together
Middle grinding is simultaneously uniformly mixed;Uniformly mixed raw material by high temperature melt furnace 1100 DEG C several times melt after pour into φ 70 ×
70mm3Platinum crucible in, and be placed in crystal growing furnace, be down to 1050 after growth furnace is warming up to 1150 DEG C of constant temperature 20 hours
℃;The saturation temperature point that solution is determined with continuous seeding down crystal method, after solution is then warming up to 8 DEG C of saturation temperature point or more,
The seed crystal being fixed on seed rod in advance is slowly dropped into liquid level hereinafter, being down to saturation temperature point after constant temperature half an hour;It is permanent
Temperature growth is cooled down after 30 hours with the rate of 1.5 DEG C/day, and rotates crystal with 20 revs/min of rate;When cooling amount is up to 80 DEG C
When, stop operating crystal and lift-off liquid level, terminates growth.
6. a kind of method for growing aluminium tetraborate salt crystal, it is characterised in that: weigh the Yb of 7.5g respectively2O3, 57.7g Gd2O3、
The H of 514.3g3BO3, 58.2g Al2O3, 333.4g AlF3·3H2The NaF of O and 142.9g is placed in agate mortar together to be ground
It grinds and is uniformly mixed;Uniformly mixed raw material by high temperature melt furnace 1100 DEG C several times melt after pour into φ 70 ×
70mm3Platinum crucible in, and be placed in crystal growing furnace, be down to 1060 after growth furnace is warming up to 1150 DEG C of constant temperature 20 hours
℃;The saturation temperature point that solution is determined with continuous seeding down crystal method, after solution is then warming up to 10 DEG C of saturation temperature point or more,
The seed crystal being fixed on seed rod in advance is slowly dropped into liquid level hereinafter, being down to saturation temperature point after constant temperature half an hour;It is permanent
Temperature growth is cooled down after 24 hours with the rate of 2 DEG C/day, and rotates crystal with 20 revs/min of rate;When cooling amount is up to 80 DEG C,
Stop operating crystal and lift-off liquid level, terminates growth.
7. a kind of method for growing aluminium tetraborate salt crystal, it is characterised in that: weigh the Er of 1.03g respectively2O3, 10.67g
Yb2O3, 60g Lu2O3, 509.3g H3BO3, 55.1g Al2O3, 333.4g AlF3·3H2The NaF of O and 126.3g is together
It is placed in agate mortar and grinds and be uniformly mixed;Uniformly mixed raw material is melted by high temperature melt furnace at 1100 DEG C several times
After pour into 70 × 70mm of φ3Platinum crucible in, and be placed in crystal growing furnace, it is small that growth furnace is warming up to 1150 DEG C of constant temperature 20
When after be down to 1060 DEG C;The saturation temperature point that solution is determined with continuous seeding down crystal method, is then warming up to saturation temperature for solution
Or more after 12 DEG C, the seed crystal being fixed on seed rod in advance is slowly dropped into liquid level hereinafter, being down to after constant temperature half an hour
Saturation temperature point;Constant temperature is cooled down after growing 30 hours with the rate of 1.5 DEG C/day, and rotates crystal with 30 revs/min of rate;When
When cooling amount is up to 80 DEG C, stop operating crystal and lift-off liquid level, terminates growth.
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CN114686982B (en) * | 2020-12-29 | 2024-04-12 | 中国科学院福建物质结构研究所 | Gallium tetraborate nonlinear optical crystal and preparation method and application thereof |
CN115182047A (en) * | 2021-04-06 | 2022-10-14 | 中国科学院福建物质结构研究所 | Self-activated gallium tetraborate crystal, bonded crystal, and preparation method and application of crystal |
CN115161770A (en) * | 2021-04-06 | 2022-10-11 | 中国科学院福建物质结构研究所 | Rare earth ion doped gallium tetraborate crystal, bonded crystal, and preparation method and application of crystal |
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CN1780074A (en) * | 2004-11-28 | 2006-05-31 | 中国科学院福建物质结构研究所 | Laser crystal materials doped with thulium borate rolled aluminium, preparation and use thereof |
CN1778999A (en) * | 2004-11-28 | 2006-05-31 | 中国科学院福建物质结构研究所 | Aluminium borate with non-linear optical materials |
CN1958881A (en) * | 2005-11-01 | 2007-05-09 | 中国科学院福建物质结构研究所 | Boratory laser crystal Li6R(1-x)REx(B03)3 and preparation method, and application |
CN101545137A (en) * | 2008-03-25 | 2009-09-30 | 中国科学院福建物质结构研究所 | Erbium ion activated borate laser crystal and method for preparing same and application thereof |
CN101831706A (en) * | 2009-03-13 | 2010-09-15 | 中国科学院福建物质结构研究所 | Growth method of low ultraviolet absorption YA13(BO3)4 crystal |
CN101831705A (en) * | 2009-03-13 | 2010-09-15 | 中国科学院福建物质结构研究所 | Method for growing YAl3(BO3)4 crystals by tungstate cosolvent system |
CN102140690A (en) * | 2010-12-31 | 2011-08-03 | 陈哲艮 | Photoluminescent wafer as well as preparation method and application thereof |
CN103290475A (en) * | 2012-02-27 | 2013-09-11 | 中国科学院理化技术研究所 | GdAl3(BO3)4 crystal growth fluxing agent and GdAl3(BO3)4 crystal growth method |
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