CN106834839A - A kind of metal for strengthening fluorescence - Google Patents

A kind of metal for strengthening fluorescence Download PDF

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Publication number
CN106834839A
CN106834839A CN201611062629.4A CN201611062629A CN106834839A CN 106834839 A CN106834839 A CN 106834839A CN 201611062629 A CN201611062629 A CN 201611062629A CN 106834839 A CN106834839 A CN 106834839A
Authority
CN
China
Prior art keywords
fluorescence
metal
impurity
balance
molecule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611062629.4A
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Chinese (zh)
Inventor
刘正英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Still Good Door And Window Co Ltd
Original Assignee
Foshan Still Good Door And Window Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Still Good Door And Window Co Ltd filed Critical Foshan Still Good Door And Window Co Ltd
Priority to CN201611062629.4A priority Critical patent/CN106834839A/en
Publication of CN106834839A publication Critical patent/CN106834839A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/18Alloys based on aluminium with copper as the next major constituent with zinc
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/14Alloys based on aluminium with copper as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/16Alloys based on aluminium with copper as the next major constituent with magnesium

Abstract

The present invention relates to metal material field, more particularly to a kind of metal for strengthening fluorescence, its material composition for including following mass percent:Cu:10‑25%;Mg:5‑10%;Mn:0.5‑2%;Si:3‑8%;Pt:1‑5%;Mo:1‑2%;Zn:5‑15%;Cr:4‑8%;Balance of Al and a small amount of impurity.The surface plasma body resonant vibration that metallic particles is produced under electromagnetic field effect plays humidification to the local electromagnetic field of particle periphery, improves the service efficiency of fluorescence molecule, and fluorescence intensity is greatly enhanced, but fluorescence lifetime is unaffected;The presence of metallic particles causes that fluorogen quantum yield increases, and fluorescent emission intensity is strengthened.So can be used to improve metal structure fluorescence molecule by the enhancing rule of fluorescence.

Description

A kind of metal for strengthening fluorescence
Technical field
The present invention relates to metal material field, more particularly to a kind of metal for strengthening fluorescence.
Background technology
The fields such as material, chemistry, medical science, noble metal table are related to the study on the modification that the surface of electromagnetic field carries out fluorescence using metal There is more material impact in face of fluorescence property, with the extensive use of measuring technology, the technology of metal-enhanced fluorescence is in fluorescence Self-quenching elimination, FRET immunoassay, metal enhancing multiphoton excitation, Metal Substrate enhancing fluorescence probe, liquid The multiple fields such as phase Metal Substrate enhancing fluorescence sense platform development obtain important application.
The content of the invention
It is an object of the invention to be directed to the existing state of the art, there is provided an a kind of metal for strengthening fluorescence.
To reach above-mentioned purpose, the present invention is adopted the following technical scheme that:
It is a kind of strengthen fluorescence metal, including following mass percent material composition:
Cu:10-25%;
Mg:5-10%;
Mn:0.5-2%;
Si:3-8%;
Pt:1-5%;
Mo:1-2%;
Zn:5-15%;
Cr:4-8%;
Balance of Al and a small amount of impurity.
Further, the metal of the enhancing fluorescence includes the material composition of following mass percent:
Cu:15%;
Mg:8%;
Mn:0.8%;
Si:4.5%;
Pt:3.5%;
Mo:1.1%;
Zn:8.9%;
Cr:7.5%;
Balance of Al and a small amount of impurity.
Between metal surface and fluorescence molecule is 9 nm.
Beneficial effects of the present invention are:The surface plasma body resonant vibration that metallic particles is produced under electromagnetic field effect is to particle The local electromagnetic field of surrounding plays humidification, improves the service efficiency of fluorescence molecule, and fluorescence intensity, but fluorescence is greatly enhanced Life-span is unaffected;The presence of metallic particles causes that fluorogen quantum yield increases, and fluorescent emission intensity is strengthened.So can Can be used to improve metal structure fluorescence molecule with the enhancing rule by fluorescence.
Specific embodiment
In order that juror can be further understood that to the purpose of the present invention, feature and function, preferred embodiment is hereby lifted detailed Carefully it is described as follows:
Embodiment 1:It is a kind of strengthen fluorescence metal, including following mass percent material composition:
Cu:20%;
Mg:9%;
Mn:1.2%;
Si:3.5%;
Pt:4.2%;
Mo:1.5%;
Zn:10.5%;
Cr:7.1%;
Balance of Al and a small amount of impurity.
Between metal surface and fluorescence molecule is 9 nm.
Embodiment 2:It is a kind of strengthen fluorescence metal, including following mass percent material composition:
Cu:12%;
Mg:6%;
Mn:0.55%;
Si:7.5%;
Pt:4.2%;
Mo:1.5%;
Zn:12.5%;
Cr:6.2%;
Balance of Al and a small amount of impurity.
Between metal surface and fluorescence molecule is 9 nm.
Embodiment 3:It is a kind of strengthen fluorescence metal, including following mass percent material composition:
Cu:22%;
Mg:9.5%;
Mn:1.7%;
Si:6.2%;
Pt:2.2%;
Mo:1.5%;
Zn:12%;
Cr:5.1%;
Balance of Al and a small amount of impurity.
Between metal surface and fluorescence molecule is 9 nm.
Embodiment 4:It is a kind of strengthen fluorescence metal, including following mass percent material composition:
Cu:23.5%;
Mg:8.5%;
Mn:0.7%;
Si:3.2%;
Pt:3.5%;
Mo:1.7%;
Zn:12.8%;
Cr:7.1%;
Balance of Al and a small amount of impurity.
Between metal surface and fluorescence molecule is 9 nm.
Embodiment 5:It is a kind of strengthen fluorescence metal, including following mass percent material composition:
Cu:15%;
Mg:8%;
Mn:0.8%;
Si:4.5%;
Pt:3.5%;
Mo:1.1%;
Zn:8.9%;
Cr:7.5%;
Balance of Al and a small amount of impurity.
Acted on from metallic particles and fluorogen, the approach of metal-enhanced fluorescence is excited by increasing fluorescence molecule Rate, the enhanced local electromagnetic field of metal surface plasmon resonance;Increase the radiation decrement of fluorescence molecule, fluorescence quantum yield Increase, the lost of life, molecular fluorescence enhancing can obtain certain effect, therefore can select metal substrate according to fluorescent places, to take The effect that must be selected.Because the cost of metal is relatively low low, molecular fluorescence intensity is sufficient, can reach expected effect.Due to metal Structure can be played a role to the decay of fluorogen, cause the shortening of fluorescence lifetime, but Mo, Cr and Pt can retrieve decay and make With.
General principle of the invention and principal character and advantages of the present invention, the technology of the industry has been shown and described above Personnel it should be appreciated that the present invention is not limited to the above embodiments, simply explanation described in above-described embodiment and specification this The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention, the claimed scope of the invention by appending claims and its Equivalent thereof.

Claims (3)

1. it is a kind of strengthen fluorescence metal, it is characterised in that the material composition including following mass percent:
Cu:10-25%;
Mg:5-10%;
Mn:0.5-2%;
Si:3-8%;
Pt:1-5%;
Mo:1-2%;
Zn:5-15%;
Cr:4-8%;
Balance of Al and a small amount of impurity.
2. it is according to claim 1 it is a kind of strengthen fluorescence metal, it is characterised in that:Thing including following mass percent Matter composition:
Cu:15%;
Mg:8%;
Mn:0.8%;
Si:4.5%;
Pt:3.5%;
Mo:1.1%;
Zn:8.9%;
Cr:7.5%;
Balance of Al and a small amount of impurity.
3. it is according to claim 1 and 2 it is a kind of strengthen fluorescence metal, it is characterised in that:Metal surface and fluorescence molecule Between be 9 nm.
CN201611062629.4A 2016-11-28 2016-11-28 A kind of metal for strengthening fluorescence Pending CN106834839A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611062629.4A CN106834839A (en) 2016-11-28 2016-11-28 A kind of metal for strengthening fluorescence

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611062629.4A CN106834839A (en) 2016-11-28 2016-11-28 A kind of metal for strengthening fluorescence

Publications (1)

Publication Number Publication Date
CN106834839A true CN106834839A (en) 2017-06-13

Family

ID=59145337

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611062629.4A Pending CN106834839A (en) 2016-11-28 2016-11-28 A kind of metal for strengthening fluorescence

Country Status (1)

Country Link
CN (1) CN106834839A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5122196A (en) * 1990-06-11 1992-06-16 Alusuisse-Lonza Services Ltd. Superplastic sheet metal made from an aluminum alloy
CN104264010A (en) * 2014-09-30 2015-01-07 国网河南省电力公司周口供电公司 High-strength aluminum alloy wire and preparation method thereof
CN105154754A (en) * 2015-08-21 2015-12-16 无锡乐华自动化科技有限公司 Super-hard aluminum alloy for wheel hub
CN105886859A (en) * 2016-05-25 2016-08-24 湖北永金精密机械设备股份有限公司 High-performance air cylinder seat material for refrigerator compressor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5122196A (en) * 1990-06-11 1992-06-16 Alusuisse-Lonza Services Ltd. Superplastic sheet metal made from an aluminum alloy
CN104264010A (en) * 2014-09-30 2015-01-07 国网河南省电力公司周口供电公司 High-strength aluminum alloy wire and preparation method thereof
CN105154754A (en) * 2015-08-21 2015-12-16 无锡乐华自动化科技有限公司 Super-hard aluminum alloy for wheel hub
CN105886859A (en) * 2016-05-25 2016-08-24 湖北永金精密机械设备股份有限公司 High-performance air cylinder seat material for refrigerator compressor

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Application publication date: 20170613