CN106833836A - A kind of enhanced heavy duty automobile gear oil - Google Patents

A kind of enhanced heavy duty automobile gear oil Download PDF

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Publication number
CN106833836A
CN106833836A CN201611201135.XA CN201611201135A CN106833836A CN 106833836 A CN106833836 A CN 106833836A CN 201611201135 A CN201611201135 A CN 201611201135A CN 106833836 A CN106833836 A CN 106833836A
Authority
CN
China
Prior art keywords
heavy duty
gear oil
automobile gear
duty automobile
base oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611201135.XA
Other languages
Chinese (zh)
Inventor
叶小娟
凌云
邓冰
刘仁雄
腾开伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGXI BEIHAI YUCHAIMA OIL ADVANCED LUBRICANTS Co Ltd
Original Assignee
GUANGXI BEIHAI YUCHAIMA OIL ADVANCED LUBRICANTS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGXI BEIHAI YUCHAIMA OIL ADVANCED LUBRICANTS Co Ltd filed Critical GUANGXI BEIHAI YUCHAIMA OIL ADVANCED LUBRICANTS Co Ltd
Priority to CN201611201135.XA priority Critical patent/CN106833836A/en
Publication of CN106833836A publication Critical patent/CN106833836A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/003Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of enhanced heavy duty automobile gear oil, percentage includes following components:150BS base oils:37~41%, 500N base oils:53~58%, compound additive:5~5.5%, pour-point depressant:0.8~1.0%.The enhanced heavy duty automobile gear oil of the present invention, its formula is reasonable.Performance is better than the grades of API GL 5, improves the thermo oxidative stability of oil product, is performed better than in thermal oxide experiment, and greasy filth is less;The extreme pressure and antiwear behavior of oil product is improved, abrasion can be reduced, extend the drain period;The seal compatibility of oil product is improved, leakage is reduced, extends the replacement cycle;Increase synchronizer adaptability, the manual transmission with tape synchronizer can be applied;Product is reached more than 100,000 kilometers drain periods, and can apply simultaneously in the manual transmission of back axle and tape synchronizer.

Description

A kind of enhanced heavy duty automobile gear oil
Technical field
The present invention relates to petrochemical industry, more particularly to a kind of enhanced heavy duty automobile gear oil.
Background technology
The credit rating of heavy duty automobile gear oil uses the classifying rules of American Petroleum Institute (API) API, is GL-5 grades, should Oil product under grade is commonly utilized in rear axle gear, differential mechanism and the manual transmission of heavy load diesel vehicle at home.This The gear oil most common drain period under individual grade is ten thousand kilometers of 5-6.With the continuous extension of engine oil drain period, visitor Family it is also proposed requirement to the drain period of gear oil, it would be desirable to be promoted to more than 100,000 kilometers, and this is just to heavy duty automobile tooth The permanent seal cooling for taking turns oil proposes new requirement, and various aspects of performance is both needed to lifting, could meet extension more than 2 times of effect of drain period Really.
It is no synchronizer in old-fashioned manual transmission, therefore original GL-5 grade gear oils apply to not tape synchronizer Manual transmission, if there is synchronizer, its is wear-resistant to require it is different, if still can go out using if GL-5 grade oil products Existing gearbox abnormal sound and the situation of skidding of putting into gear.But manual transmission new-type in recent years carries synchronizer, and material is brass It is in the majority with carbon-based.Understanding from the market finds that the manual transmission major part of present heavy load Diesel engine is loaded Synchronizer, therefore gear oil need to possess the adaptability of synchronizer.
The information for being disclosed in the background section is merely intended to increase the understanding to general background of the invention, without answering In being considered as recognizing or imply in any form that the information structure has been the prior art well known to persons skilled in the art.
The content of the invention
It is an object of the invention to provide a kind of enhanced heavy duty automobile gear oil, so as to overcome GL-5 grade vehicle teeth Take turns thermo oxidative stability, extreme pressure anti-wear, the seal compatibility performance deficiency of oil, it is impossible to meet more than 100,000 kilometers and change oil week Phase;It does not have synchronizer adaptability, it is impossible to the shortcoming in the manual transmission of tape synchronizer.
To achieve the above object, the invention provides a kind of enhanced heavy duty automobile gear oil, percentage Including following components:150BS base oils:37~41%, 500N base oils:53~58%, compound additive:5~5.5%, drop Solidifying agent:0.8~1.0%.
Preferably, in above-mentioned technical proposal, described enhanced heavy duty automobile gear oil, percentage includes Following components:150BS base oils:38.1%th, 500N base oils:56%th, compound additive:5%th, pour-point depressant:0.9%.
Preferably, in above-mentioned technical proposal, the 150BS base oils are the class cycloalkyl bright stocks of API I.
Preferably, in above-mentioned technical proposal, the 500N base oils are the class hydrofinishing naphthenic base oils of API II,
Preferably, in above-mentioned technical proposal, the compound additive is added using the gear oil of Lu Borun additives company Agent GO3230.
Preferably, in above-mentioned technical proposal, the pour-point depressant is polymethacrylates solution.
Preferably, in above-mentioned technical proposal, the concentration of the polymethacrylates solution is 30~50%.
Compared with prior art, the present invention has the advantages that:
The enhanced heavy duty automobile gear oil of the present invention, its formula is reasonable.Performance is better than API GL-5 grades, improves oil product Thermo oxidative stability, thermal oxide experiment in perform better than, greasy filth is less;The extreme pressure and antiwear behavior of oil product is improved, can be reduced Abrasion, extends the drain period;The seal compatibility of oil product is improved, leakage is reduced, extends the replacement cycle;Increase synchronizer to adapt to Property, the manual transmission with tape synchronizer can be applied;Product is reached more than 100,000 kilometers drain periods, and can apply simultaneously In the manual transmission of back axle and tape synchronizer.
Brief description of the drawings
Fig. 1 is the greasy filth photo that enhanced heavy duty automobile gear oil of the invention carries out thermo oxidative stability experiment Figure.
Fig. 2 is the greasy filth photo figure that former GL-5 oil products carry out thermo oxidative stability experiment.
Fig. 3 is enhanced heavy duty automobile gear oil of the invention and original GL-5 oil products on carbon-based material synchronizer 100,000 endurancings comparing result figure.
Fig. 4 is enhanced heavy duty automobile gear oil of the invention and original GL-5 oil products on copper-based material synchronizer 100,000 endurancings comparing result figure.
Specific embodiment
Below in conjunction with the accompanying drawings, specific embodiment of the invention is described in detail, it is to be understood that guarantor of the invention Shield scope is not limited by specific embodiment.
Explicitly indicated that unless otherwise other, otherwise in entire disclosure and claims, term " including " or its change Change such as "comprising" or " including " etc. and will be understood to comprise stated element or part, and do not exclude other units Part or other parts.
Embodiment 1
A kind of enhanced heavy duty automobile gear oil, percentage includes following components:150BS base oils: 38.1%th, 500N base oils:56%th, compound additive:5%th, pour-point depressant:0.9%.
The 150BS base oils are the class cycloalkyl bright stocks of API I.
The 500N base oils are the class hydrofinishing naphthenic base oils of API II,
The compound additive uses the gear oil additive GO3230 of Lu Borun additives company.
The pour-point depressant is polymethacrylates solution, and the concentration of the polymethacrylates solution is 40%.
Embodiment 2
A kind of enhanced heavy duty automobile gear oil, percentage includes following components:150BS base oils: 37%th, 500N base oils:57%th, compound additive:5%th, pour-point depressant:1.0%.
The 150BS base oils are the class cycloalkyl bright stocks of API I.
The 500N base oils are the class hydrofinishing naphthenic base oils of API II,
The compound additive uses the gear oil additive GO3230 of Lu Borun additives company.
The pour-point depressant is polymethacrylates solution, and the concentration of the polymethacrylates solution is 30%.
Embodiment 3
A kind of enhanced heavy duty automobile gear oil, percentage includes following components:150BS base oils: 40.7%th, 500N base oils:53.2%th, compound additive:5.3%th, pour-point depressant:0.8%.
The 150BS base oils are the class cycloalkyl bright stocks of API I.
The 500N base oils are the class hydrofinishing naphthenic base oils of API II,
The compound additive uses the gear oil additive GO3230 of Lu Borun additives company.
The pour-point depressant is polymethacrylates solution, the concentration of the polymethacrylates solution for 30~ 50%.
Particular condition in use
The thermo oxidative stability contrast of oil product
The thermal oxide for carrying out oil product using enhanced heavy duty automobile gear oil obtained in embodiment 1 and original GL-5 oil products is steady It is qualitative to be contrasted.Comparing result is as shown in table 1.
Table 1:The thermo oxidative stability contrast of oil product
The extreme pressure and antiwear behavior contrast of oil product
The extreme-pressure anti-wear of oil product is carried out using enhanced heavy duty automobile gear oil obtained in embodiment 1 and original GL-5 oil products Performance is contrasted.Comparing result is as shown in table 2.
Table 2:Oil product extreme pressure and antiwear behavior is contrasted
Seal compatibility
Seal compatibility is carried out using enhanced heavy duty automobile gear oil obtained in embodiment 1 and original GL-5 oil products to enter Row contrast.Comparing result is as shown in table 3.
Table 3:Seal compatibility contrast table
Former GL-5 oil products result Enhanced formula result
Seal compatibility test 1 (the No leakage time, h) 375 1000
Seal compatibility test 2 (the No leakage time, h) 668 1000
Synchronizer adaptability
Carbon-based material synchronizer is carried out using enhanced heavy duty automobile gear oil obtained in embodiment 1 and original GL-5 oil products On 100,000 endurancings.Experimental result is as shown in Figure 3.In Fig. 31 for enhanced heavy duty automobile gear oil carry out it is carbon-based 100,000 empirical curves of durability on material synchronizer, 2 carry out 100,000 on carbon-based material synchronizer for original GL-5 oil products The empirical curve of secondary durability.
Copper-based material synchronizer is carried out using enhanced heavy duty automobile gear oil obtained in embodiment 1 and original GL-5 oil products On 100,000 endurancings.Experimental result is as shown in Figure 4.In Fig. 43 for enhanced heavy duty automobile gear oil carry out it is copper-based 100,000 empirical curves of durability on material synchronizer, 4 carry out 100,000 on copper-based material synchronizer for original GL-5 oil products The empirical curve of secondary durability.
The foregoing description to specific illustrative embodiment of the invention be in order to illustrate and illustration purpose.These descriptions It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed And change.The purpose of selecting and describing the exemplary embodiment is that explaining that certain principles of the invention and its reality should With so that those skilled in the art can realize and using a variety of exemplaries of the invention and A variety of selections and change.The scope of the present invention is intended to be limited by claims and its equivalents.

Claims (7)

1. a kind of enhanced heavy duty automobile gear oil, it is characterised in that percentage includes following components:150BS Base oil:37~41%, 500N base oils:53~58%, compound additive:5~5.5%, pour-point depressant:0.8~1.0%.
2. enhanced heavy duty automobile gear oil according to claim 1, it is characterised in that percentage includes Following components:150BS base oils:38.1%th, 500N base oils:56%th, compound additive:5%th, pour-point depressant:0.9%.
3. enhanced heavy duty automobile gear oil according to claim 1, it is characterised in that the 150BS base oils are The class cycloalkyl bright stocks of API I.
4. enhanced heavy duty automobile gear oil according to claim 1, it is characterised in that the 500N base oils are The class hydrofinishing naphthenic base oils of API II.
5. enhanced heavy duty automobile gear oil according to claim 1, it is characterised in that the compound additive is used The gear oil additive GO3230 of Lu Borun additives company.
6. enhanced heavy duty automobile gear oil according to claim 1, it is characterised in that the pour-point depressant is poly- methyl Acrylate solution.
7. enhanced heavy duty automobile gear oil according to claim 6, it is characterised in that the polymethacrylates The concentration of solution is 30~50%.
CN201611201135.XA 2016-12-22 2016-12-22 A kind of enhanced heavy duty automobile gear oil Pending CN106833836A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611201135.XA CN106833836A (en) 2016-12-22 2016-12-22 A kind of enhanced heavy duty automobile gear oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611201135.XA CN106833836A (en) 2016-12-22 2016-12-22 A kind of enhanced heavy duty automobile gear oil

Publications (1)

Publication Number Publication Date
CN106833836A true CN106833836A (en) 2017-06-13

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102031185A (en) * 2010-12-30 2011-04-27 鞍山海华油脂化学有限公司 Anti micro-pitting industrial gear oil composition
CN102757837A (en) * 2011-04-29 2012-10-31 中国石油化工股份有限公司 Lubricating oil base oil composition
CN105524682A (en) * 2015-12-11 2016-04-27 东莞太平洋博高润滑油有限公司 Wear-self-repairing gear oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102031185A (en) * 2010-12-30 2011-04-27 鞍山海华油脂化学有限公司 Anti micro-pitting industrial gear oil composition
CN102757837A (en) * 2011-04-29 2012-10-31 中国石油化工股份有限公司 Lubricating oil base oil composition
CN105524682A (en) * 2015-12-11 2016-04-27 东莞太平洋博高润滑油有限公司 Wear-self-repairing gear oil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
(英)艾伦G.卢卡斯 编;周亚松等译: "《现代石油技术(卷二:下游)》", 31 March 2011, 石油工业出版社 *

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Application publication date: 20170613