CN106833835A - A kind of ultralow temperature diesel engine oil - Google Patents

A kind of ultralow temperature diesel engine oil Download PDF

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Publication number
CN106833835A
CN106833835A CN201611187073.1A CN201611187073A CN106833835A CN 106833835 A CN106833835 A CN 106833835A CN 201611187073 A CN201611187073 A CN 201611187073A CN 106833835 A CN106833835 A CN 106833835A
Authority
CN
China
Prior art keywords
diesel engine
engine oil
ultralow temperature
parts
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611187073.1A
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Chinese (zh)
Inventor
叶小娟
凌云
邓冰
杨绳政
腾开伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGXI BEIHAI YUCHAIMA OIL ADVANCED LUBRICANTS Co Ltd
Original Assignee
GUANGXI BEIHAI YUCHAIMA OIL ADVANCED LUBRICANTS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGXI BEIHAI YUCHAIMA OIL ADVANCED LUBRICANTS Co Ltd filed Critical GUANGXI BEIHAI YUCHAIMA OIL ADVANCED LUBRICANTS Co Ltd
Priority to CN201611187073.1A priority Critical patent/CN106833835A/en
Publication of CN106833835A publication Critical patent/CN106833835A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022Ethene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024Propene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/252Diesel engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention belongs to lubricating oil research and development technology field, more particularly to a kind of ultralow temperature diesel engine oil.A kind of ultralow temperature diesel engine oil, it is characterised in that be made up of following components by weight:6.0 6.5 parts of 20 22 parts of 4 base oils of PAO, 51 55 parts of 6 base oils of PAO, 5 parts of esters base oil, 15.1 parts of compound additive, 0.45 part of auxiliary agent and tackifier.Ultralow temperature diesel engine oil of the invention is combined using the base oil and additive of high-quality, and oil pour point is low, reaches 66 DEG C, can meet the use in China's all region winters;Ultralow temperature diesel engine oil of the invention can meet the viscosity grade requirements of 0W 30;Ultralow temperature diesel engine oil of the invention can meet the requirement of the credit ratings of API CI 4.

Description

A kind of ultralow temperature diesel engine oil
Technical field
The invention belongs to lubricating oil research and development technology field, more particularly to a kind of ultralow temperature diesel engine oil.
Background technology
At present, what the viscosity grade accounting of diesel engine oil on the market was maximum is 15W-40 and 20W-50 grades, winter Ji Shihui uses 10W-30 grades, and these oil products minimum environment temperature to be used is -25 DEG C.- 25 DEG C big for China It is above this temperature, but for extremely cold area, such as Mo River in Heilungkiang, the band of Heihe one, Yi Jixin for some areas For boundary, the highlands of the band of Tibet one, the lowest temperature will can reach -50 DEG C or so well below this temperature.Meanwhile, from From in January, 2015, national Diesel engine implements in full the discharge standard of state four, and the vehicle for meeting the discharge standard of state four needs supporting making With the oil product of API CI-4 grades, the requirement of engine and tail-gas after treatment apparatus could be met.
At present, diesel engine oil on the market has following shortcoming:(1) oil pour point is higher, compared with low ambient temperature Under can solidify, it is impossible to use;(2) it is unsatisfactory for 0W-30 viscosity grades requirement (this is diesel engine oil MV minium viscosity class requirement); (3) API CI-4 grades are unsatisfactory for, it is impossible to discharge vehicle suitable for state four.Therefore, it is substantially no on Vehicles Collected from Market to meet API The diesel engine oil of the ultralow temperature of CI-4 grades.
The information for being disclosed in the background section is merely intended to increase the understanding to general background of the invention, without answering In being considered as recognizing or imply in any form that the information structure has been the prior art well known to persons skilled in the art.
The content of the invention
For above shortcomings in the prior art, the present invention provides a kind of ultralow temperature diesel engine oil, and the machine oil is chosen Base oil and the additive combination of high-quality, it is possible to decrease oil pour point, meet 0W-30 viscosity grade requirements, meet API CI-4 matter Amount class requirement.
To achieve these goals, the present invention is realized using following technical scheme:
A kind of ultralow temperature diesel engine oil, is made up of following components by weight:Base oil 20-22 parts of PAO 4, PAO 6 Base oil 51-55 parts, 5 parts of esters base oil, 15.1 parts of compound additive, 0.45 part and tackifier 6.0-6.5 parts of auxiliary agent.
Preferably, the described base oils of PAO 4 are the fully synthetic base oils of class of API IV;The described base oils of PAO 6 are The fully synthetic base oil of the classes of API IV;Described esters base oil is the -2- Propylheptyls of hexanedioic acid two.
Preferably, diesel engine oil additive LZ4987 of the described compound additive using Lu Borun additives company.
Preferably, described auxiliary agent be using Lu Borun additives company diesel engine oil additive LZ6477C, LZ1371 and LZ8658 compoundings are formed, and three kinds of mass ratioes of additive are 2:1:1.5.
Preferably, described tackifier are ethylene-propylene copolymer type viscosity index improver, its ethylene contents<50%.
Compared with prior art, the present invention has the advantages that:
(1) ultralow temperature diesel engine oil of the invention is combined using the base oil and additive of high-quality, and oil pour point is low, - 66 DEG C are reached, the use in China's all region winters can be met.
(2) ultralow temperature diesel engine oil of the invention can meet 0W-30 viscosity grade requirements.
(3) ultralow temperature diesel engine oil of the invention can meet the requirement of API CI-4 credit ratings.
Specific embodiment
Specific embodiment of the invention is described in detail with reference to specific embodiment, it is to be understood that of the invention Protection domain do not limited by specific embodiment.
Embodiment 1
A kind of ultralow temperature diesel engine oil, is made up of following components by weight:20 parts of 4 base oils of PAO, the bases of PAO 6 6.0 parts of 53.45 parts of oil, 5 parts of esters base oil, 15.1 parts of compound additive, 0.45 part of auxiliary agent and tackifier.
The described base oils of PAO 4 are the fully synthetic base oils of class of API IV;The described base oils of PAO 6 are that the classes of API IV are complete Synthetic base oil;Described esters base oil is the -2- Propylheptyls of hexanedioic acid two;Described compound additive is added using Lu Borun Plus the diesel engine oil additive LZ4987 of agent company;Described auxiliary agent is added using the diesel engine oil of Lu Borun additives company Agent LZ6477C, LZ1371 and LZ8658 compounding are formed, and three kinds of mass ratioes of additive are 2:1:1.5;Described tackifier are second Propylene copolymer type viscosity index improver, its ethylene contents<50%.
Embodiment 2
A kind of ultralow temperature diesel engine oil, is made up of following components by weight:21 parts of 4 base oils of PAO, the bases of PAO 6 6.5 parts of 51.95 parts of oil, 5 parts of esters base oil, 15.1 parts of compound additive, 0.45 part of auxiliary agent and tackifier.
The described base oils of PAO 4 are the fully synthetic base oils of class of API IV;The described base oils of PAO 6 are that the classes of API IV are complete Synthetic base oil;Described esters base oil is the -2- Propylheptyls of hexanedioic acid two;Described compound additive is added using Lu Borun Plus the diesel engine oil additive LZ4987 of agent company;Described auxiliary agent is added using the diesel engine oil of Lu Borun additives company Agent LZ6477C, LZ1371 and LZ8658 compounding are formed, and three kinds of mass ratioes of additive are 2:1:1.5;Described tackifier are second Propylene copolymer type viscosity index improver, its ethylene contents<50%.
Embodiment 3
A kind of ultralow temperature diesel engine oil, is made up of following components by weight:20.15 parts of 4 base oils of PAO, PAO 6 6.3 parts of 53 parts of base oil, 5 parts of esters base oil, 15.1 parts of compound additive, 0.45 part of auxiliary agent and tackifier.
The described base oils of PAO 4 are the fully synthetic base oils of class of API IV;The described base oils of PAO 6 are that the classes of API IV are complete Synthetic base oil;Described esters base oil is the -2- Propylheptyls of hexanedioic acid two;Described compound additive is added using Lu Borun Plus the diesel engine oil additive LZ4987 of agent company;Described auxiliary agent is added using the diesel engine oil of Lu Borun additives company Agent LZ6477C, LZ1371 and LZ8658 compounding are formed, and three kinds of mass ratioes of additive are 2:1:1.5;Described tackifier are second Propylene copolymer type viscosity index improver, its ethylene contents<50%.
The low temperature physical and chemical index of ultralow temperature diesel engine oil of the inventor to being obtained in embodiment 1-3 is measured, and as a result sees Table 1.
The low temperature physical and chemical index of the ultralow temperature diesel engine oil of the invention of table 1
As shown in Table 1, ultralow temperature diesel engine oil of the invention performance is good, its kinematic viscosity, low-temperature dynamic viscosity, inclines Point, high-temperature high shear viscosity, temperature pumping viscosity meet technical requirements, and the ultralow temperature diesel engine oil pour point is low, and average value reaches To -66 DEG C, the use in China's all region winters can be met;0W-30 viscosity grade requirements can be met;API CI-4 matter can be met Amount class requirement.
The foregoing description to specific illustrative embodiment of the invention be in order to illustrate and illustration purpose.These descriptions It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed And change.The purpose of selecting and describing the exemplary embodiment is that explaining that certain principles of the invention and its reality should With so that those skilled in the art can realize and using a variety of exemplaries of the invention and A variety of selections and change.The scope of the present invention is intended to be limited by claims and its equivalents.

Claims (8)

1. a kind of ultralow temperature diesel engine oil, it is characterised in that be made up of following components by weight:The base oil 20-22 of PAO 4 Part, base oil 51-55 parts of PAO 6,5 parts of esters base oil, 15.1 parts of compound additive, 0.45 part and tackifier 6.0- of auxiliary agent 6.5 parts.
2. ultralow temperature diesel engine oil according to claim 1, it is characterised in that the described base oils of PAO 4 are API IV The fully synthetic base oil of class.
3. ultralow temperature diesel engine oil according to claim 1, it is characterised in that the described base oils of PAO 6 are API IV The fully synthetic base oil of class.
4. ultralow temperature diesel engine oil according to claim 1, it is characterised in that described esters base oil is hexanedioic acid Two -2- Propylheptyls.
5. ultralow temperature diesel engine oil according to claim 1, it is characterised in that described compound additive uses Lu Borun The diesel engine oil additive LZ4987 of additive company.
6. ultralow temperature diesel engine oil according to claim 1, it is characterised in that described auxiliary agent is added using Lu Borun Diesel engine oil additive LZ6477C, LZ1371 and LZ8658 compounding of agent company are formed, and three kinds of mass ratioes of additive are 2:1: 1.5。
7. ultralow temperature diesel engine oil according to claim 6, it is characterised in that diesel engine oil additive in described auxiliary agent The mass ratio of LZ6477C, LZ1371 and LZ8658 is 2:1:1.5.
8. ultralow temperature diesel engine oil according to claim 1, it is characterised in that described tackifier are ethylene-propylene copolymer type Viscosity index improver, its ethylene contents<50%.
CN201611187073.1A 2016-12-20 2016-12-20 A kind of ultralow temperature diesel engine oil Pending CN106833835A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611187073.1A CN106833835A (en) 2016-12-20 2016-12-20 A kind of ultralow temperature diesel engine oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611187073.1A CN106833835A (en) 2016-12-20 2016-12-20 A kind of ultralow temperature diesel engine oil

Publications (1)

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CN106833835A true CN106833835A (en) 2017-06-13

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1525392A (en) * 1974-12-16 1978-09-20 Stauffer Chemical Co Synthetic crankcase lubricant
EP0088453A1 (en) * 1982-03-10 1983-09-14 UNIROYAL CHEMICAL COMPANY, Inc. Lubricating composition
JPS6479299A (en) * 1987-09-22 1989-03-24 Idemitsu Kosan Co Base oil and composition for internal combustion engine lubricating oil
US4992183A (en) * 1987-04-01 1991-02-12 Ethyl Corporation Multigrade hydrogenated decene-1 oligomer engine oils
CN1346397A (en) * 1999-03-24 2002-04-24 埃克森美孚石油公司 High performance engine oil
CN104498144A (en) * 2014-12-01 2015-04-08 新疆福克油品股份有限公司 Universal type synthetic gasoline-diesel lubrication oil and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1525392A (en) * 1974-12-16 1978-09-20 Stauffer Chemical Co Synthetic crankcase lubricant
EP0088453A1 (en) * 1982-03-10 1983-09-14 UNIROYAL CHEMICAL COMPANY, Inc. Lubricating composition
US4992183A (en) * 1987-04-01 1991-02-12 Ethyl Corporation Multigrade hydrogenated decene-1 oligomer engine oils
JPS6479299A (en) * 1987-09-22 1989-03-24 Idemitsu Kosan Co Base oil and composition for internal combustion engine lubricating oil
CN1346397A (en) * 1999-03-24 2002-04-24 埃克森美孚石油公司 High performance engine oil
CN104498144A (en) * 2014-12-01 2015-04-08 新疆福克油品股份有限公司 Universal type synthetic gasoline-diesel lubrication oil and preparation method thereof

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Application publication date: 20170613

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