CN106833762A - A kind of low freezing point fuel and preparation method thereof - Google Patents

A kind of low freezing point fuel and preparation method thereof Download PDF

Info

Publication number
CN106833762A
CN106833762A CN201611256823.6A CN201611256823A CN106833762A CN 106833762 A CN106833762 A CN 106833762A CN 201611256823 A CN201611256823 A CN 201611256823A CN 106833762 A CN106833762 A CN 106833762A
Authority
CN
China
Prior art keywords
freezing point
liquid
low freezing
point fuel
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201611256823.6A
Other languages
Chinese (zh)
Other versions
CN106833762B (en
Inventor
孙宏华
杨振华
刘海峰
田隆丰
王慰连
陆佳
李佳
吕建强
魏刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI HABO CHEMICAL TECHNOLOGY CO LTD
Original Assignee
SHANGHAI HABO CHEMICAL TECHNOLOGY CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI HABO CHEMICAL TECHNOLOGY CO LTD filed Critical SHANGHAI HABO CHEMICAL TECHNOLOGY CO LTD
Priority to CN201611256823.6A priority Critical patent/CN106833762B/en
Publication of CN106833762A publication Critical patent/CN106833762A/en
Application granted granted Critical
Publication of CN106833762B publication Critical patent/CN106833762B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1837Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom hydroxy attached to a condensed aromatic ring system
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • C10L1/1881Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present invention relates to a kind of low freezing point fuel and preparation method thereof, the low freezing point fuel includes the component of following weight portion content:Hydrogen peroxide 60~95, ethanol 40~5, the oxyquinoline 0.01~0.2 of tartaric acid 0.01~0.2,8;The said goods are prepared by the following method and form:During tartaric acid added into hydrogen peroxide, and stir, obtain first liquid;During 8 oxyquinolines are added into ethanol, and stir, obtain second liquid.Again by first liquid and second liquid mixing and stirring, that is, obtain purpose product.Compared with prior art, there is the present invention low temperature not freeze, and low temperature adaptability is good, and good stability, corrosivity is small, combustion gas cleaning non-scaling, not carbon distribution, the advantages of production process is generated without hazardous waste.

Description

A kind of low freezing point fuel and preparation method thereof
Technical field
The present invention relates to a kind of fuel, more particularly, to a kind of low freezing point fuel and preparation method thereof.
Background technology
The usage history of hydrogen peroxide is alreadyd exceed more than 100 years, and it is obtained extremely in industrial circles such as Aero-Space, national defence It is widely applied.Militarily it is initially paid attention to and is developed due to being applied to rocketry and national defence weapon, particularly During the Second World War and the cold war initial stage.With carrying space expense, propellant for a long time can depot, security, nontoxic pollution-free, can Reuse, rapid fire etc. require more and more higher, and high-strength hydrogen peroxide receives more and more wider again in propulsion field General concern.
At present, hydrogen peroxide Push Technology is widely studied in Deng Guoge mechanisms of American and Britain, such as:NASA, USAF, Boeing, Aerojet, railway technology company, Orbital Sciences Corporation, Purdue University, Surrey satellite technologies company etc..And, fire One of developing direction of arrow propulsion field propellant is to reduce hydrazine, the use of dinitrogen tetroxide, so hydrogen peroxide would is that mesh One of preceding and propulsion field in the future research and development emphasis.
Hydrogen peroxide have high density specific impulse, environmental protection, normal temperature can store, easy-to-operate, can single group unit decompose With can spontaneous combustion the advantages of, be highly suitable as the propellant of modern rocket engine.Hydrogen peroxide has as liquid propellant Following significant good characteristic:
(1) it is nontoxic, pollution-free.
(2) can for a long time be stored under the normal temperature condition in ground or space.
(3) density and density ratio are leapt high.
(4) oxidant of bipropellant is can not only be used for, again can be as SP.
(5) good hot physical property.
(6) multipurpose.
But the freezing point of hydrogen peroxide propellant, such as 85% hydrogen peroxide are -15 DEG C, 95% hydrogen peroxide is -5 DEG C, is held The inferior position for easily freezing limits extensive use, takes Insulation to increased system weight and complexity, use environment temperature It is required that making its advantage to be embodied.
The content of the invention
The purpose of the present invention is exactly to provide a kind of with low-temperature adaptation for the defect for overcoming above-mentioned prior art to exist Property it is good, corrosivity is small, combustion gas cleaning non-scaling, not carbon distribution, low freezing point combustion the advantages of production process is generated without hazardous waste Material and preparation method thereof, the fuel can be applied to aero-engine, airspace engine, vehicle, robot, gas generating unit, Energy generating apparatus, carbon dioxide generating device and other extraordinary power-equipments.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of low freezing point fuel, including following weight portion content component:
Each component is reagent grade materials.
Preferably, its freezing point is -60~-10 DEG C.
Preferably, the low freezing point fuel includes the component of following weight portion content:
Preferably, its freezing point is -60~-50 DEG C.
The preparation method of the low freezing point fuel, comprises the following steps:
(1) in tartaric acid being added into hydrogen peroxide by proportioning, and stir, obtain first liquid;
(2) in 8-hydroxyquinoline being added into ethanol by proportioning, and stir, obtain second liquid;
(3) first liquid and second liquid are mixed and stirred for uniformly obtaining described low freezing point fuel.
Preferably, rotating speed is 60~4000 revs/min in each step whipping process, and mixing time is 60~200 minutes, temperature Degree control is at -20 DEG C~50 DEG C.
The present invention reduces peroxidating by adding the relatively low ethanol of freezing point (freezing point is less than -100 DEG C) in hydrogen peroxide The freezing point of hydrogen, ethanol is cheap and easy to get, is dissolved each other with hydrogen peroxide, can effectively reduce its freezing point so that the freezing point of hydrogen peroxide compared with It is adjustable in big scope, while ethanol can also be good as fuel, fuel oxidizer mixing compatibility, comprising double elements and list Constituent element fuel advantage.
Because hydrogen peroxide has oxidisability, store and during spacecraft use, external environment is changeful, peroxide Change hydrogen unstable, easily decompose, a small amount of tartaric acid and 8-hydroxyquinoline carry out stable peroxide hydrogen, prevented as stabilizer The decomposition of hydrogen oxide., by complex reaction come stable peroxide hydrogen, tartaric acid is a kind of good for tartaric acid and 8-hydroxyquinoline Stabilizer of hydrogen peroxide, while in acidity, which increasing the meltage of 8-hydroxyquinoline.In preparation process, respectively by tartaric acid In addition hydrogen peroxide, and by 8-hydroxyquinoline addition ethanol, the compatibility between material is make use of, make to be not easy directly The 8-hydroxyquinoline being dissolved in hydrogen peroxide is by being first dissolved in ethanol, then mixes with hydrogen peroxide, is allowed to be dissolved in body In system.
Compared with prior art, the invention has the advantages that:
(1) low freezing point:As a result of the proportioning of science, the freezing point of the fuel product drops than the freezing point of single hydrogen peroxide It is low 5~20 DEG C, -60~-10 DEG C are reached, can normally use at low ambient conditions.
(2) good stability, can for a long time preserve the fuel product at ambient temperature.
(3) fuel small toxicity of the invention, corrosivity are small, environmental protection, product cleaning non-scaling, not carbon distribution, production after burning Process is generated without hazardous waste.
(4) fuel oxidizer mixing compatibility is good, comprising double elements and monoreactant chemical advantage.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1
A kind of low freezing point fuel, including following weight portion content component:
The preparation method of the low freezing point fuel, comprises the following steps:
(1) in tartaric acid being added into hydrogen peroxide by proportioning, and stir, obtain first liquid;
(2) in 8-hydroxyquinoline being added into ethanol by proportioning, and stir, obtain second liquid;
(3) first liquid and second liquid are mixed and stirred for uniformly obtaining described low freezing point fuel.
Rotating speed is 60~4000 revs/min in each step whipping process, and mixing time is 60~200 minutes, is controlled normal Carried out under temperature.
Embodiment 2
A kind of low freezing point fuel, including following weight portion content component:
The preparation method of the low freezing point fuel, comprises the following steps:
(1) in tartaric acid being added into hydrogen peroxide by proportioning, and stir, obtain first liquid;
(2) in 8-hydroxyquinoline being added into ethanol by proportioning, and stir, obtain second liquid;
(3) first liquid and second liquid are mixed and stirred for uniformly obtaining described low freezing point fuel.
Rotating speed is 60~4000 revs/min in each step whipping process, and mixing time is 60~200 minutes, is controlled normal Carried out under temperature.
Embodiment 3
A kind of low freezing point fuel, including following weight portion content component:
The preparation method of the low freezing point fuel, comprises the following steps:
(1) in tartaric acid being added into hydrogen peroxide by proportioning, and stir, obtain first liquid;
(2) in 8-hydroxyquinoline being added into ethanol by proportioning, and stir, obtain second liquid;
(3) first liquid and second liquid are mixed and stirred for uniformly obtaining described low freezing point fuel.
Rotating speed is 60~4000 revs/min in each step whipping process, and mixing time is 60~200 minutes, is controlled normal Carried out under temperature.
Embodiment 4
This implementation is substantially the same manner as Example 1, and difference is that temperature is controlled in the present embodiment preparation process at 0 DEG C.
Embodiment 5
This implementation is substantially the same manner as Example 1, and difference is that temperature is controlled in the present embodiment preparation process -20 ℃。
Embodiment 6
This implementation is substantially the same manner as Example 1, and difference is that temperature is controlled in the present embodiment preparation process 50 ℃。
Comparative example 1
By hydrogen peroxide and ethanol according to 30:70 mass ratio stirs.
Comparative example 2
95% hydrogen peroxide.
The low freezing point fuel of the hydrogen peroxide mixture of above-mentioned comparative example 1~2 and embodiment 1~3 is detected, as a result It is shown in Table 1.
Table 1
As seen from the above table, the present invention is produced low temperature resistant, fuel oxidizer mixing compatibility is good, comprising double elements and The low freezing point fuel product of monoreactant chemical advantage has the advantages that good low freezing point, high stability, according to the performance to it Test and practice principle, the freezing point reduction by 5~20 DEG C of the freezing point than single hydrogen peroxide of the fuel product, reach -60~-10 DEG C, can normally use at low ambient conditions, the fuel product can be for a long time preserved at ambient temperature.Suitable for aviation Engine, airspace engine, vehicle, robot, gas generating unit, energy generating apparatus, carbon dioxide generating device, other The use of the high-end fields such as extraordinary power-equipment, military project, scientific research.

Claims (6)

1. a kind of low freezing point fuel, it is characterised in that the component including following weight portion content:
2. a kind of low freezing point fuel according to claim 1, it is characterised in that its freezing point is -60~-10 DEG C.
3. a kind of low freezing point fuel according to claim 1, it is characterised in that the component including following weight portion content:
4. a kind of low freezing point fuel according to claim 3, it is characterised in that its freezing point is -60~-50 DEG C.
5. the preparation method of a kind of low freezing point fuel according to claim 1, it is characterised in that comprise the following steps:
(1) in tartaric acid being added into hydrogen peroxide by proportioning, and stir, obtain first liquid;
(2) in 8-hydroxyquinoline being added into ethanol by proportioning, and stir, obtain second liquid;
(3) first liquid and second liquid are mixed and stirred for uniformly obtaining described low freezing point fuel.
6. the preparation method of a kind of low freezing point fuel according to claim 5, it is characterised in that in each step whipping process Rotating speed is 60~4000 revs/min, and mixing time is 60~200 minutes, and temperature control is at -20 DEG C~50 DEG C.
CN201611256823.6A 2016-12-30 2016-12-30 A kind of low freezing point fuel and preparation method thereof Expired - Fee Related CN106833762B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611256823.6A CN106833762B (en) 2016-12-30 2016-12-30 A kind of low freezing point fuel and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611256823.6A CN106833762B (en) 2016-12-30 2016-12-30 A kind of low freezing point fuel and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106833762A true CN106833762A (en) 2017-06-13
CN106833762B CN106833762B (en) 2018-09-04

Family

ID=59114052

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611256823.6A Expired - Fee Related CN106833762B (en) 2016-12-30 2016-12-30 A kind of low freezing point fuel and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106833762B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107266274A (en) * 2017-06-30 2017-10-20 上海哈勃化学技术有限公司 A kind of low temperature gas-forming agent and preparation method thereof
CN107325850A (en) * 2017-06-30 2017-11-07 上海哈勃化学技术有限公司 A kind of special fuel product and its preparation

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001009063A2 (en) * 1999-07-29 2001-02-08 Atlantic Research Corporation Premixed liquid monopropellant solutions and mixtures
CN1775931A (en) * 2005-12-07 2006-05-24 东北大学 Fuel combined combustion method by adding hydrogen peroxide combustion adjuvant
CN1908133A (en) * 2005-08-01 2007-02-07 葛明龙 Group substituted silanes spaceflight fuel
CN102658066A (en) * 2012-04-26 2012-09-12 葛明龙 Catalytic decomposition low-concentration hydrogen peroxide reactor, combustion chamber and application thereof
KR20130133341A (en) * 2012-05-29 2013-12-09 이승현 The combusitive liquid mixed with the bio or methanol and water

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001009063A2 (en) * 1999-07-29 2001-02-08 Atlantic Research Corporation Premixed liquid monopropellant solutions and mixtures
CN1908133A (en) * 2005-08-01 2007-02-07 葛明龙 Group substituted silanes spaceflight fuel
CN1775931A (en) * 2005-12-07 2006-05-24 东北大学 Fuel combined combustion method by adding hydrogen peroxide combustion adjuvant
CN102658066A (en) * 2012-04-26 2012-09-12 葛明龙 Catalytic decomposition low-concentration hydrogen peroxide reactor, combustion chamber and application thereof
KR20130133341A (en) * 2012-05-29 2013-12-09 이승현 The combusitive liquid mixed with the bio or methanol and water

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王万军等: "绿色过氧化氢双组元自燃推进剂", 《化学推进剂与高分子材料》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107266274A (en) * 2017-06-30 2017-10-20 上海哈勃化学技术有限公司 A kind of low temperature gas-forming agent and preparation method thereof
CN107325850A (en) * 2017-06-30 2017-11-07 上海哈勃化学技术有限公司 A kind of special fuel product and its preparation

Also Published As

Publication number Publication date
CN106833762B (en) 2018-09-04

Similar Documents

Publication Publication Date Title
Sackheim et al. Green propulsion advancement: challenging the maturity of monopropellant hydrazine
Ciezki et al. Some aspects on safety and environmental impact of the German green gel propulsion technology
Wernimont et al. Past and present uses of rocket grade hydrogen peroxide
Florczuk et al. Performance evaluation of the hypergolic green propellants based on the HTP for a future next generation spacecrafts
CN101855325A (en) Nitrous oxide fuel blend monopropellants
Rarata et al. Novel liquid compounds as hypergolic propellants with HTP
Moon et al. Design specifications of H2O2/kerosene bipropellant rocket system for space missions
KR20160013922A (en) Oxidizer-rich liquid monopropellants for a dual mode chemical rocket engine
US5932837A (en) Non-toxic hypergolic miscible bipropellant
Rarata et al. Hydrogen peroxide as a high energy compound optimal for propulsive applications
CN106833762B (en) A kind of low freezing point fuel and preparation method thereof
Lauck et al. Selection of ionic liquids and characterization of hypergolicy with hydrogen peroxide
Aggarwal et al. Green propellant: A study
Remissa et al. Propulsion Systems, Propellants, Green Propulsion Subsystems and their Applications: A Review
Rang et al. Reactivity of hypergolic hybrid solid fuel with industrial grade hydrogen peroxide
Surmacz Green rocket propulsion research and development at the institute of aviation: problems and perspectives
Karp et al. A hybrid mars ascent vehicle design and FY 2016 technology development
US20120144799A1 (en) Oxidizer Compound for Rocket Propulsion
Musker et al. Hydrogen peroxide-From bridesmaid to bride
Kang et al. Difficulties of catalytic reactor for hydroxylammonium nitrate hybrid rocket
Trinh et al. Assessment of MON-25/MMH Propellant System for Deep-Space Engines
Oiknine New perspectives for hybrid propulsion
Mota et al. Novel hypergolic green fuels with hydrogen peroxide for propulsion systems
Mehendiratta et al. A review on different propellant materials for space vehicles and their characterisation
Naumann et al. Gelled green propellant rocket motor and gas generator technology at bayern-chemie-status and applications for space systems

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180904