CN106833436A - Glue and its application method are remembered in a kind of high molecular nanometer selfreparing - Google Patents

Glue and its application method are remembered in a kind of high molecular nanometer selfreparing Download PDF

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Publication number
CN106833436A
CN106833436A CN201710173050.3A CN201710173050A CN106833436A CN 106833436 A CN106833436 A CN 106833436A CN 201710173050 A CN201710173050 A CN 201710173050A CN 106833436 A CN106833436 A CN 106833436A
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CN
China
Prior art keywords
parts
selfreparing
high molecular
glue
molecular nanometer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710173050.3A
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Chinese (zh)
Inventor
施能响
龚青山
尹诗璐
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Xinghua Security Technology (guangzhou) Co Ltd
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Xinghua Security Technology (guangzhou) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Xinghua Security Technology (guangzhou) Co Ltd filed Critical Xinghua Security Technology (guangzhou) Co Ltd
Priority to CN201710173050.3A priority Critical patent/CN106833436A/en
Publication of CN106833436A publication Critical patent/CN106833436A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C09J123/22Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/02Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2421/00Presence of unspecified rubber
    • C09J2421/006Presence of unspecified rubber in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The invention discloses a kind of high molecular nanometer selfreparing memory glue, constituted according to following mass parts:48 54 parts of butyl rubber, 24 32 parts of polyisobutene, 5 10 parts of styrene-butadiene-copolymer, 16 parts of polyacrylate, 0.05 0.15 parts of boron trifluoride, 39 parts of calcium carbonate, 0.5 1.7 parts of aerosil, 0.05 0.15 parts of carbon black.Using memory glue energy quick blocking tire leak of the invention, with more preferable ductility and shock resistance, while the addition of this memory glue can increase the intensity of tackifier and the bonding with tire;The selfreparing of this high molecular nanometer memory glue rebuild a tyre prick nail after gas leakage, can play leakproof effect, can preferably bond, with more preferable ductility and impact resistance, never degumming.

Description

Glue and its application method are remembered in a kind of high molecular nanometer selfreparing
Technical field
The present invention relates to tyre repair technical field, specifically a kind of high molecular nanometer selfreparing memory glue and its user Method.
Background technology
Tire is the annular elastic rubber product rolled in various vehicles or the ground connection mechanically assembled.It is typically mounted on In alloy rim, vehicle body can be supported, buffer foreign impacts, realized the contact with road surface and ensure the driving performance of vehicle.Tire Often used under complicated and exacting terms, it subjects the effect of various modifications, load, power and high/low temperature in motion, because This must have load-carrying properties higher, hauling ability, shock-absorbing capacity.Meanwhile, also require possess high-wearing feature and flexible resistance, And low rolling resistance and heat generation.The half that the world consumes rubber mass is used for tire production, it is seen that tire consumes rubber Ability.
Tire occurs the broken situation that is pinned when in use, usually, and pinned the breaking of tire is accomplished by carrying out tire patching afterwards, Existing glue often occurs that poor ductility, impact resistance be weak, easy degumming situation after tire patching, and what is given people normal uses band Very big puzzlement is carried out.
The content of the invention
It is above-mentioned to solve it is an object of the invention to provide a kind of high molecular nanometer selfreparing memory glue and its application method The problem proposed in background technology.
To achieve the above object, the present invention provides following technical scheme:
Glue is remembered in a kind of high molecular nanometer selfreparing, is constituted according to following mass parts:Butyl rubber 48-54 parts, poly- isobutyl Alkene 24-32 parts, styrene-butadiene-copolymer 5-10 parts, polyacrylate 1-6 parts, boron trifluoride 0.05-0.15 parts, calcium carbonate 3-9 parts, aerosil 0.5-1.7 parts, carbon black 0.05-0.15 parts.
As further scheme of the invention:The polyacrylate is made up of following raw material according to formula:Metering system Sour methyl esters 5-15 parts, butyl acrylate 8-16 parts, Isooctyl acrylate monomer 10-20 parts, N hydroxymethyl acrylamide 0.5-3.5 parts.
As further scheme of the invention:Constituted according to following mass parts:Butyl rubber 50-52 parts, polyisobutene 26- 30 parts, styrene-butadiene-copolymer 7-8 parts, polyacrylate 2-5 parts, boron trifluoride 0.07-0.13 parts, calcium carbonate 4-8 parts, Aerosil 0.3-1.5 parts, carbon black 0.07-0.13 parts.
As further scheme of the invention:Constituted according to following mass parts:51 parts of butyl rubber, 28 parts of polyisobutene, 7.5 parts of styrene-butadiene-copolymer, 3.5 parts of polyacrylate, 0.1 part of boron trifluoride, 6 parts of calcium carbonate, aerosil 0.9 part, 0.1 part of carbon black.
As further scheme of the invention:The polyacrylate is made up of following raw material according to formula:Metering system Sour methyl esters 8-12 parts, butyl acrylate 10-14 parts, Isooctyl acrylate monomer 14-16 parts, N hydroxymethyl acrylamide 1-3 parts.
As further scheme of the invention:The polyacrylate is made up of following raw material according to formula:Metering system 10 parts of sour methyl esters, 12 parts of butyl acrylate, 15 parts of Isooctyl acrylate monomer, 2 parts of N hydroxymethyl acrylamide.
Its application method of glue is remembered in high molecular nanometer selfreparing in a kind of such as above technical scheme:Received using macromolecule The oily matter of surface of tyre is first cleaned before rice selfreparing memory glue with tire cleaners, it is uniform in surface of tyre after the completion of cleaning One layer of tackifier coating is smeared, high molecular nanometer selfreparing memory glue is then pasted again.
Compared with prior art, using memory glue energy quick blocking tire leak of the invention, with more preferable ductility And shock resistance, while the addition of this memory glue can increase the intensity of tackifier and the bonding with tire;This macromolecule is received Rice selfreparing memory glue rebuild a tyre prick nail after gas leakage, can play leakproof effect, can preferably bond, with more preferable court of a feudal ruler exhibition Property and impact resistance, never degumming.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
Glue is remembered in a kind of high molecular nanometer selfreparing, is constituted according to following mass parts:54 parts of butyl rubber, polyisobutene 32 Part, 10 parts of styrene-butadiene-copolymer, 6 parts of polyacrylate, 0.15 part of boron trifluoride, 9 parts of calcium carbonate, aerosil 1.7 parts, 0.15 part of carbon black.
The polyacrylate is made up of following raw material according to formula:15 parts of methyl methacrylate, butyl acrylate 16 Part, 20 parts of Isooctyl acrylate monomer, 3.5 parts of N hydroxymethyl acrylamide.
The oily matter of surface of tyre is first cleaned with tire cleaners before glue is remembered using high molecular nanometer selfreparing, clearly In one layer of tackifier coating of surface of tyre uniform application after the completion of washing, high molecular nanometer selfreparing memory glue is then pasted again.
Embodiment 2
Glue is remembered in a kind of high molecular nanometer selfreparing, is constituted according to following mass parts:48 parts of butyl rubber, polyisobutene 24 Part, 5 parts of styrene-butadiene-copolymer, 1 part of polyacrylate, 0.05 part of boron trifluoride, 3 parts of calcium carbonate, aerosil 0.5 part, 0.05 part of carbon black.
The polyacrylate is made up of following raw material according to formula:5 parts of methyl methacrylate, 8 parts of butyl acrylate, 10 parts of Isooctyl acrylate monomer, 0.5 part of N hydroxymethyl acrylamide.
The oily matter of surface of tyre is first cleaned with tire cleaners before glue is remembered using high molecular nanometer selfreparing, clearly In one layer of tackifier coating of surface of tyre uniform application after the completion of washing, high molecular nanometer selfreparing memory glue is then pasted again.
Embodiment 3
Glue is remembered in a kind of high molecular nanometer selfreparing, is constituted according to following mass parts:51 parts of butyl rubber, polyisobutene 28 Part, 7.5 parts of styrene-butadiene-copolymer, 3.5 parts of polyacrylate, 0.1 part of boron trifluoride, 6 parts of calcium carbonate, gas phase titanium dioxide 0.9 part of silicon, 0.1 part of carbon black.
The polyacrylate is made up of following raw material according to formula:10 parts of methyl methacrylate, butyl acrylate 12 Part, 15 parts of Isooctyl acrylate monomer, 2 parts of N hydroxymethyl acrylamide.
The oily matter of surface of tyre is first cleaned with tire cleaners before glue is remembered using high molecular nanometer selfreparing, clearly In one layer of tackifier coating of surface of tyre uniform application after the completion of washing, high molecular nanometer selfreparing memory glue is then pasted again.
Using memory glue energy quick blocking tire leak of the invention, with more preferable ductility and shock resistance, together When this memory glue addition can increase the intensity of tackifier and the bonding with tire;This high molecular nanometer selfreparing memory glue is repaiied Gas leakage after multiple tyre prick, can play leakproof effect, can preferably bond, with more preferable ductility and impact resistance, forever Not degumming.
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of this patent objective not be departed from Make a variety of changes.

Claims (7)

1. glue is remembered in a kind of high molecular nanometer selfreparing, it is characterised in that constituted according to following mass parts:Butyl rubber 48-54 Part, polyisobutene 24-32 parts, styrene-butadiene-copolymer 5-10 parts, polyacrylate 1-6 parts, boron trifluoride 0.05-0.15 Part, calcium carbonate 3-9 parts, aerosil 0.5-1.7 parts, carbon black 0.05-0.15 parts.
2. high molecular nanometer selfreparing according to claim 1 memory glue, it is characterised in that the polyacrylate by with Lower raw material is constituted according to formula:Methyl methacrylate 5-15 parts, butyl acrylate 8-16 parts, Isooctyl acrylate monomer 10-20 parts, N hydroxymethyl acrylamide 0.5-3.5 parts.
3. glue is remembered in high molecular nanometer selfreparing according to claim 2, it is characterised in that according to following mass parts group Into:Butyl rubber 50-52 parts, polyisobutene 26-30 parts, styrene-butadiene-copolymer 7-8 parts, polyacrylate 2-5 parts, three Boron fluoride 0.07-0.13 parts, calcium carbonate 4-8 parts, aerosil 0.3-1.5 parts, carbon black 0.07-0.13 parts.
4. glue is remembered in high molecular nanometer selfreparing according to claim 3, it is characterised in that according to following mass parts group Into:51 parts of butyl rubber, 28 parts of polyisobutene, 7.5 parts of styrene-butadiene-copolymer, 3.5 parts of polyacrylate, boron trifluoride 0.1 part, 6 parts of calcium carbonate, 0.9 part of aerosil, 0.1 part of carbon black.
5. high molecular nanometer selfreparing according to claim 4 memory glue, it is characterised in that the polyacrylate by with Lower raw material is constituted according to formula:Methyl methacrylate 8-12 parts, butyl acrylate 10-14 parts, Isooctyl acrylate monomer 14-16 Part, N hydroxymethyl acrylamide 1-3 parts.
6. high molecular nanometer selfreparing according to claim 5 memory glue, it is characterised in that the polyacrylate by with Lower raw material is constituted according to formula:10 parts of methyl methacrylate, 12 parts of butyl acrylate, 15 parts of Isooctyl acrylate monomer, N- hydroxyl first 2 parts of base acrylamide.
7. its application method of glue is remembered in a kind of high molecular nanometer selfreparing as described in claim 1-6 is any, and its feature exists In, the oily matter of surface of tyre is first cleaned with tire cleaners before glue is remembered using high molecular nanometer selfreparing, clean After in one layer of tackifier coating of surface of tyre uniform application, high molecular nanometer selfreparing memory glue is then pasted again.
CN201710173050.3A 2017-03-22 2017-03-22 Glue and its application method are remembered in a kind of high molecular nanometer selfreparing Pending CN106833436A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109515074A (en) * 2018-11-22 2019-03-26 项晓村 A kind of flexibility is blown out safety method of meeting an urgent need
CN109536081A (en) * 2017-09-21 2019-03-29 广东安通纳米科技有限公司 A kind of adhesive glue and preparation method thereof for vehicle tyre safety upgrading
CN111875891A (en) * 2020-07-14 2020-11-03 浙江工业大学 Self-repairing rubber

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1191236A (en) * 1997-02-19 1998-08-26 陈盛桐 Tyre puncture mending adhesive and its preparing method
CN101823413A (en) * 2009-02-25 2010-09-08 固特异轮胎和橡胶公司 The environmental resistance assembly set that comprises electronics package that is used for tire
CN105838289A (en) * 2016-03-30 2016-08-10 广西柳州科来迪机械有限公司 Prick-resistant explosion-proof polymer synthetic high-viscoelasticity rubber for tyre and preparation method thereof
CN106080051A (en) * 2016-07-28 2016-11-09 无锡安睿驰科技有限公司 A kind of pricking-proof explosion-proof science and technology safety tread and processing method thereof
CN205970648U (en) * 2016-07-28 2017-02-22 无锡安睿驰科技有限公司 Prevent pricking explosion -proof scientific and technological safety tire

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1191236A (en) * 1997-02-19 1998-08-26 陈盛桐 Tyre puncture mending adhesive and its preparing method
CN101823413A (en) * 2009-02-25 2010-09-08 固特异轮胎和橡胶公司 The environmental resistance assembly set that comprises electronics package that is used for tire
CN105838289A (en) * 2016-03-30 2016-08-10 广西柳州科来迪机械有限公司 Prick-resistant explosion-proof polymer synthetic high-viscoelasticity rubber for tyre and preparation method thereof
CN106080051A (en) * 2016-07-28 2016-11-09 无锡安睿驰科技有限公司 A kind of pricking-proof explosion-proof science and technology safety tread and processing method thereof
CN205970648U (en) * 2016-07-28 2017-02-22 无锡安睿驰科技有限公司 Prevent pricking explosion -proof scientific and technological safety tire

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Title
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熊腊森: "《粘接手册》", 31 August 2008 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109536081A (en) * 2017-09-21 2019-03-29 广东安通纳米科技有限公司 A kind of adhesive glue and preparation method thereof for vehicle tyre safety upgrading
CN109515074A (en) * 2018-11-22 2019-03-26 项晓村 A kind of flexibility is blown out safety method of meeting an urgent need
CN111875891A (en) * 2020-07-14 2020-11-03 浙江工业大学 Self-repairing rubber
CN111875891B (en) * 2020-07-14 2022-11-22 浙江工业大学 Self-repairing rubber

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Application publication date: 20170613