CN106833436A - Glue and its application method are remembered in a kind of high molecular nanometer selfreparing - Google Patents
Glue and its application method are remembered in a kind of high molecular nanometer selfreparing Download PDFInfo
- Publication number
- CN106833436A CN106833436A CN201710173050.3A CN201710173050A CN106833436A CN 106833436 A CN106833436 A CN 106833436A CN 201710173050 A CN201710173050 A CN 201710173050A CN 106833436 A CN106833436 A CN 106833436A
- Authority
- CN
- China
- Prior art keywords
- parts
- selfreparing
- high molecular
- glue
- molecular nanometer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003292 glue Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 20
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 19
- 229910015900 BF3 Inorganic materials 0.000 claims abstract description 10
- 229920005549 butyl rubber Polymers 0.000 claims abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000006229 carbon black Substances 0.000 claims abstract description 10
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 10
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 9
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 9
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 4
- 230000000903 blocking effect Effects 0.000 abstract description 3
- 230000035939 shock Effects 0.000 abstract description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 150000004702 methyl esters Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 229910000846 In alloy Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- -1 poly- isobutyl Alkene Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2421/00—Presence of unspecified rubber
- C09J2421/006—Presence of unspecified rubber in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a kind of high molecular nanometer selfreparing memory glue, constituted according to following mass parts:48 54 parts of butyl rubber, 24 32 parts of polyisobutene, 5 10 parts of styrene-butadiene-copolymer, 16 parts of polyacrylate, 0.05 0.15 parts of boron trifluoride, 39 parts of calcium carbonate, 0.5 1.7 parts of aerosil, 0.05 0.15 parts of carbon black.Using memory glue energy quick blocking tire leak of the invention, with more preferable ductility and shock resistance, while the addition of this memory glue can increase the intensity of tackifier and the bonding with tire;The selfreparing of this high molecular nanometer memory glue rebuild a tyre prick nail after gas leakage, can play leakproof effect, can preferably bond, with more preferable ductility and impact resistance, never degumming.
Description
Technical field
The present invention relates to tyre repair technical field, specifically a kind of high molecular nanometer selfreparing memory glue and its user
Method.
Background technology
Tire is the annular elastic rubber product rolled in various vehicles or the ground connection mechanically assembled.It is typically mounted on
In alloy rim, vehicle body can be supported, buffer foreign impacts, realized the contact with road surface and ensure the driving performance of vehicle.Tire
Often used under complicated and exacting terms, it subjects the effect of various modifications, load, power and high/low temperature in motion, because
This must have load-carrying properties higher, hauling ability, shock-absorbing capacity.Meanwhile, also require possess high-wearing feature and flexible resistance,
And low rolling resistance and heat generation.The half that the world consumes rubber mass is used for tire production, it is seen that tire consumes rubber
Ability.
Tire occurs the broken situation that is pinned when in use, usually, and pinned the breaking of tire is accomplished by carrying out tire patching afterwards,
Existing glue often occurs that poor ductility, impact resistance be weak, easy degumming situation after tire patching, and what is given people normal uses band
Very big puzzlement is carried out.
The content of the invention
It is above-mentioned to solve it is an object of the invention to provide a kind of high molecular nanometer selfreparing memory glue and its application method
The problem proposed in background technology.
To achieve the above object, the present invention provides following technical scheme:
Glue is remembered in a kind of high molecular nanometer selfreparing, is constituted according to following mass parts:Butyl rubber 48-54 parts, poly- isobutyl
Alkene 24-32 parts, styrene-butadiene-copolymer 5-10 parts, polyacrylate 1-6 parts, boron trifluoride 0.05-0.15 parts, calcium carbonate
3-9 parts, aerosil 0.5-1.7 parts, carbon black 0.05-0.15 parts.
As further scheme of the invention:The polyacrylate is made up of following raw material according to formula:Metering system
Sour methyl esters 5-15 parts, butyl acrylate 8-16 parts, Isooctyl acrylate monomer 10-20 parts, N hydroxymethyl acrylamide 0.5-3.5 parts.
As further scheme of the invention:Constituted according to following mass parts:Butyl rubber 50-52 parts, polyisobutene 26-
30 parts, styrene-butadiene-copolymer 7-8 parts, polyacrylate 2-5 parts, boron trifluoride 0.07-0.13 parts, calcium carbonate 4-8 parts,
Aerosil 0.3-1.5 parts, carbon black 0.07-0.13 parts.
As further scheme of the invention:Constituted according to following mass parts:51 parts of butyl rubber, 28 parts of polyisobutene,
7.5 parts of styrene-butadiene-copolymer, 3.5 parts of polyacrylate, 0.1 part of boron trifluoride, 6 parts of calcium carbonate, aerosil
0.9 part, 0.1 part of carbon black.
As further scheme of the invention:The polyacrylate is made up of following raw material according to formula:Metering system
Sour methyl esters 8-12 parts, butyl acrylate 10-14 parts, Isooctyl acrylate monomer 14-16 parts, N hydroxymethyl acrylamide 1-3 parts.
As further scheme of the invention:The polyacrylate is made up of following raw material according to formula:Metering system
10 parts of sour methyl esters, 12 parts of butyl acrylate, 15 parts of Isooctyl acrylate monomer, 2 parts of N hydroxymethyl acrylamide.
Its application method of glue is remembered in high molecular nanometer selfreparing in a kind of such as above technical scheme:Received using macromolecule
The oily matter of surface of tyre is first cleaned before rice selfreparing memory glue with tire cleaners, it is uniform in surface of tyre after the completion of cleaning
One layer of tackifier coating is smeared, high molecular nanometer selfreparing memory glue is then pasted again.
Compared with prior art, using memory glue energy quick blocking tire leak of the invention, with more preferable ductility
And shock resistance, while the addition of this memory glue can increase the intensity of tackifier and the bonding with tire;This macromolecule is received
Rice selfreparing memory glue rebuild a tyre prick nail after gas leakage, can play leakproof effect, can preferably bond, with more preferable court of a feudal ruler exhibition
Property and impact resistance, never degumming.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
Glue is remembered in a kind of high molecular nanometer selfreparing, is constituted according to following mass parts:54 parts of butyl rubber, polyisobutene 32
Part, 10 parts of styrene-butadiene-copolymer, 6 parts of polyacrylate, 0.15 part of boron trifluoride, 9 parts of calcium carbonate, aerosil
1.7 parts, 0.15 part of carbon black.
The polyacrylate is made up of following raw material according to formula:15 parts of methyl methacrylate, butyl acrylate 16
Part, 20 parts of Isooctyl acrylate monomer, 3.5 parts of N hydroxymethyl acrylamide.
The oily matter of surface of tyre is first cleaned with tire cleaners before glue is remembered using high molecular nanometer selfreparing, clearly
In one layer of tackifier coating of surface of tyre uniform application after the completion of washing, high molecular nanometer selfreparing memory glue is then pasted again.
Embodiment 2
Glue is remembered in a kind of high molecular nanometer selfreparing, is constituted according to following mass parts:48 parts of butyl rubber, polyisobutene 24
Part, 5 parts of styrene-butadiene-copolymer, 1 part of polyacrylate, 0.05 part of boron trifluoride, 3 parts of calcium carbonate, aerosil
0.5 part, 0.05 part of carbon black.
The polyacrylate is made up of following raw material according to formula:5 parts of methyl methacrylate, 8 parts of butyl acrylate,
10 parts of Isooctyl acrylate monomer, 0.5 part of N hydroxymethyl acrylamide.
The oily matter of surface of tyre is first cleaned with tire cleaners before glue is remembered using high molecular nanometer selfreparing, clearly
In one layer of tackifier coating of surface of tyre uniform application after the completion of washing, high molecular nanometer selfreparing memory glue is then pasted again.
Embodiment 3
Glue is remembered in a kind of high molecular nanometer selfreparing, is constituted according to following mass parts:51 parts of butyl rubber, polyisobutene 28
Part, 7.5 parts of styrene-butadiene-copolymer, 3.5 parts of polyacrylate, 0.1 part of boron trifluoride, 6 parts of calcium carbonate, gas phase titanium dioxide
0.9 part of silicon, 0.1 part of carbon black.
The polyacrylate is made up of following raw material according to formula:10 parts of methyl methacrylate, butyl acrylate 12
Part, 15 parts of Isooctyl acrylate monomer, 2 parts of N hydroxymethyl acrylamide.
The oily matter of surface of tyre is first cleaned with tire cleaners before glue is remembered using high molecular nanometer selfreparing, clearly
In one layer of tackifier coating of surface of tyre uniform application after the completion of washing, high molecular nanometer selfreparing memory glue is then pasted again.
Using memory glue energy quick blocking tire leak of the invention, with more preferable ductility and shock resistance, together
When this memory glue addition can increase the intensity of tackifier and the bonding with tire;This high molecular nanometer selfreparing memory glue is repaiied
Gas leakage after multiple tyre prick, can play leakproof effect, can preferably bond, with more preferable ductility and impact resistance, forever
Not degumming.
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of this patent objective not be departed from
Make a variety of changes.
Claims (7)
1. glue is remembered in a kind of high molecular nanometer selfreparing, it is characterised in that constituted according to following mass parts:Butyl rubber 48-54
Part, polyisobutene 24-32 parts, styrene-butadiene-copolymer 5-10 parts, polyacrylate 1-6 parts, boron trifluoride 0.05-0.15
Part, calcium carbonate 3-9 parts, aerosil 0.5-1.7 parts, carbon black 0.05-0.15 parts.
2. high molecular nanometer selfreparing according to claim 1 memory glue, it is characterised in that the polyacrylate by with
Lower raw material is constituted according to formula:Methyl methacrylate 5-15 parts, butyl acrylate 8-16 parts, Isooctyl acrylate monomer 10-20 parts,
N hydroxymethyl acrylamide 0.5-3.5 parts.
3. glue is remembered in high molecular nanometer selfreparing according to claim 2, it is characterised in that according to following mass parts group
Into:Butyl rubber 50-52 parts, polyisobutene 26-30 parts, styrene-butadiene-copolymer 7-8 parts, polyacrylate 2-5 parts, three
Boron fluoride 0.07-0.13 parts, calcium carbonate 4-8 parts, aerosil 0.3-1.5 parts, carbon black 0.07-0.13 parts.
4. glue is remembered in high molecular nanometer selfreparing according to claim 3, it is characterised in that according to following mass parts group
Into:51 parts of butyl rubber, 28 parts of polyisobutene, 7.5 parts of styrene-butadiene-copolymer, 3.5 parts of polyacrylate, boron trifluoride
0.1 part, 6 parts of calcium carbonate, 0.9 part of aerosil, 0.1 part of carbon black.
5. high molecular nanometer selfreparing according to claim 4 memory glue, it is characterised in that the polyacrylate by with
Lower raw material is constituted according to formula:Methyl methacrylate 8-12 parts, butyl acrylate 10-14 parts, Isooctyl acrylate monomer 14-16
Part, N hydroxymethyl acrylamide 1-3 parts.
6. high molecular nanometer selfreparing according to claim 5 memory glue, it is characterised in that the polyacrylate by with
Lower raw material is constituted according to formula:10 parts of methyl methacrylate, 12 parts of butyl acrylate, 15 parts of Isooctyl acrylate monomer, N- hydroxyl first
2 parts of base acrylamide.
7. its application method of glue is remembered in a kind of high molecular nanometer selfreparing as described in claim 1-6 is any, and its feature exists
In, the oily matter of surface of tyre is first cleaned with tire cleaners before glue is remembered using high molecular nanometer selfreparing, clean
After in one layer of tackifier coating of surface of tyre uniform application, high molecular nanometer selfreparing memory glue is then pasted again.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710173050.3A CN106833436A (en) | 2017-03-22 | 2017-03-22 | Glue and its application method are remembered in a kind of high molecular nanometer selfreparing |
Applications Claiming Priority (1)
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CN201710173050.3A CN106833436A (en) | 2017-03-22 | 2017-03-22 | Glue and its application method are remembered in a kind of high molecular nanometer selfreparing |
Publications (1)
Publication Number | Publication Date |
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CN106833436A true CN106833436A (en) | 2017-06-13 |
Family
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CN201710173050.3A Pending CN106833436A (en) | 2017-03-22 | 2017-03-22 | Glue and its application method are remembered in a kind of high molecular nanometer selfreparing |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109515074A (en) * | 2018-11-22 | 2019-03-26 | 项晓村 | A kind of flexibility is blown out safety method of meeting an urgent need |
CN109536081A (en) * | 2017-09-21 | 2019-03-29 | 广东安通纳米科技有限公司 | A kind of adhesive glue and preparation method thereof for vehicle tyre safety upgrading |
CN111875891A (en) * | 2020-07-14 | 2020-11-03 | 浙江工业大学 | Self-repairing rubber |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1191236A (en) * | 1997-02-19 | 1998-08-26 | 陈盛桐 | Tyre puncture mending adhesive and its preparing method |
CN101823413A (en) * | 2009-02-25 | 2010-09-08 | 固特异轮胎和橡胶公司 | The environmental resistance assembly set that comprises electronics package that is used for tire |
CN105838289A (en) * | 2016-03-30 | 2016-08-10 | 广西柳州科来迪机械有限公司 | Prick-resistant explosion-proof polymer synthetic high-viscoelasticity rubber for tyre and preparation method thereof |
CN106080051A (en) * | 2016-07-28 | 2016-11-09 | 无锡安睿驰科技有限公司 | A kind of pricking-proof explosion-proof science and technology safety tread and processing method thereof |
CN205970648U (en) * | 2016-07-28 | 2017-02-22 | 无锡安睿驰科技有限公司 | Prevent pricking explosion -proof scientific and technological safety tire |
-
2017
- 2017-03-22 CN CN201710173050.3A patent/CN106833436A/en active Pending
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---|---|---|---|---|
CN1191236A (en) * | 1997-02-19 | 1998-08-26 | 陈盛桐 | Tyre puncture mending adhesive and its preparing method |
CN101823413A (en) * | 2009-02-25 | 2010-09-08 | 固特异轮胎和橡胶公司 | The environmental resistance assembly set that comprises electronics package that is used for tire |
CN105838289A (en) * | 2016-03-30 | 2016-08-10 | 广西柳州科来迪机械有限公司 | Prick-resistant explosion-proof polymer synthetic high-viscoelasticity rubber for tyre and preparation method thereof |
CN106080051A (en) * | 2016-07-28 | 2016-11-09 | 无锡安睿驰科技有限公司 | A kind of pricking-proof explosion-proof science and technology safety tread and processing method thereof |
CN205970648U (en) * | 2016-07-28 | 2017-02-22 | 无锡安睿驰科技有限公司 | Prevent pricking explosion -proof scientific and technological safety tire |
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Title |
---|
张学铭等: "《化学小辞典》", 31 August 1994 * |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109536081A (en) * | 2017-09-21 | 2019-03-29 | 广东安通纳米科技有限公司 | A kind of adhesive glue and preparation method thereof for vehicle tyre safety upgrading |
CN109515074A (en) * | 2018-11-22 | 2019-03-26 | 项晓村 | A kind of flexibility is blown out safety method of meeting an urgent need |
CN111875891A (en) * | 2020-07-14 | 2020-11-03 | 浙江工业大学 | Self-repairing rubber |
CN111875891B (en) * | 2020-07-14 | 2022-11-22 | 浙江工业大学 | Self-repairing rubber |
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Application publication date: 20170613 |