CN106833256A - Modified by cardanol water-based insulating paint - Google Patents
Modified by cardanol water-based insulating paint Download PDFInfo
- Publication number
- CN106833256A CN106833256A CN201710018089.8A CN201710018089A CN106833256A CN 106833256 A CN106833256 A CN 106833256A CN 201710018089 A CN201710018089 A CN 201710018089A CN 106833256 A CN106833256 A CN 106833256A
- Authority
- CN
- China
- Prior art keywords
- water
- cardanol
- modified
- anacardol
- based insulating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/32—Modified amine-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/205—Compounds containing groups, e.g. carbamates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of modified by cardanol water-based insulating paint, include according to the raw material of percentage by weight：Anacardol 12 ~ 20%, aluminum phosphate 10 ~ 16%, M-phthalic acid 12 ~ 20%, trimethylolpropane 4 ~ 8%, neopentyl glycol 8 ~ 12%, pyromellitic dianhydride 5 ~ 8%, maleic anhydride 5 ~ 8%, Amino resin 8 ~ 12%, dimethylethanolamine 5 ~ 8%, butyl glycol ether 8 ~ 12%, carbamate pesticide 0.5 ~ 1%, pigment 0.5 ~ 2%, aqueous dispersion 0.5 ~ 1%.Paint film is plentiful, bright, hard, and water-fast, heat resistance and mechanical performance are excellent.
Description
Technical field
The invention belongs to insulated paint technical field, specifically related to a kind of modified by cardanol water-based insulating paint.
Background technology
Anacardol（cardanol）It is the natural phenolic compound obtained from natural cashew nut shell liquid, is extracted from cashew nut shell
Anacardol realizes the green economy of refuse reclamation, meets the main flow of current generation, to promote China energy diversification, can be again
Raw energy industry upgrading, the alleviation energy and environmental pressure have very far-reaching realistic meaning.Natural cashew nut shell liquid is the whole world the
The agricultural by-products of three large outlet agricultural product cashew nuts gained in process, account for the 21~26% of cashew nut weight, due to its resource
Abundant, cheap and unique properties, thus be widely used in the fields such as coating, adhesive and ion exchange resin, both may be used
Also can be that a kind of development prospect is good as the modifying agent of many macromolecular materials as the raw material of other chemical products
Green chemical industry raw material.Cashew acid and 10% cardol in natural cashew nut shell stoste containing about 90%.Containing a large amount of in anacardol
Cashew acid, a small amount of anacardol, cardol and the acid of 2- methyl cardiac stimulant, by the commodity cashew nut shell that obtains after high temperature decarboxylation treatment
Liquid, main component is anacardol, by cashew nut shell liquid in 5-10mmHg, is evaporated in vacuo under the conditions of 220 DEG C -250 DEG C, you can
To anacardol, yield is up to more than 90%.Used as the derivative of phenol, anacardol can be synthesized phenolic resin with aldehydes.With
Its novolaks for preparing has excellent gloss and richness, hardness higher, good physical and mechanical properties, can be applied to
The aspects such as wood furniture, door, window and insulating materials.Moreover, the structure of anacardol is similar with laccol, using anacardol generation
For laccol as the research of coating be coating study a big hot topic.
The content of the invention
It is an object of the present invention to provide a kind of modified by cardanol water-based insulating paint, paint film is plentiful, bright, hard and water-fast, resistance to
Hot and mechanical performance is excellent.
In order to realize the above object the technical solution adopted by the present invention is：A kind of modified by cardanol water-based insulating paint, according to
The raw material of percentage by weight includes：Anacardol 12 ~ 20%, aluminum phosphate 10 ~ 16%, M-phthalic acid 12 ~ 20%, trimethylolpropane 4
~ 8%, neopentyl glycol 8 ~ 12%, pyromellitic dianhydride 5 ~ 8%, maleic anhydride 5 ~ 8%, Amino resin 8 ~ 12%, diformazan
Ethylethanolamine 5 ~ 8%, butyl glycol ether 8 ~ 12%, carbamate pesticide 0.5 ~ 1%, pigment 0.5 ~ 2%, aqueous dispersion 0.5 ~
1%。
Preferably, described modified by cardanol water-based insulating paint, includes according to the raw material of percentage by weight：Anacardol 16%,
Aluminum phosphate 12%, M-phthalic acid 16%, trimethylolpropane 6%, neopentyl glycol 10%, pyromellitic dianhydride 6%, maleic acid
Acid anhydride 6%, Amino resin 10%, dimethylethanolamine 6%, butyl glycol ether 10%, carbamate pesticide 0.5%, pigment
1%, aqueous dispersion 0.5%.
The technical effects of the invention are that：Anacardol is water insoluble, dissolves in organic solvent.Anacardol is that have unsaturation
The natural phenolic compound of C15 side chains long, its structure is similar to laccol.This unique texture of anacardol makes it both have fragrance
The feature of compounds of group, resistance to elevated temperatures；Again with aliphatic compound feature, good pliability, excellent hydrophobicity,
Hypotonicity and from dryness；In addition, the phenolic hydroxyl group on phenyl ring makes it have the property of phenols again.Aluminum phosphate has high temperature resistant, resists
The characteristics of shake, anti-strip, high temperature resistant airflow scouring, strong infrared ray absorption ability and good insulating properties.Carbamate desinsection
Agent is carbamic derivative.Carbamate pesticide is sufficiently stable insecticide.The waist obtained using said ratio
Fruit phenol modified water-based insulating paint, paint film is plentiful, bright, hard and water-fast, heat resistance and mechanical performance are excellent.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1：A kind of modified by cardanol water-based insulating paint, includes according to the raw material of percentage by weight：Anacardol 16%,
Aluminum phosphate 12%, M-phthalic acid 16%, trimethylolpropane 6%, neopentyl glycol 10%, pyromellitic dianhydride 6%, maleic acid
Acid anhydride 6%, Amino resin 10%, dimethylethanolamine 6%, butyl glycol ether 10%, carbamate pesticide 0.5%, pigment
1%, aqueous dispersion 0.5%.
Anacardol is water insoluble, dissolves in organic solvent.Anacardol is the natural phenolic with unsaturation C15 side chains long
Compound, its structure is similar to laccol.This unique texture of anacardol makes its both feature with aromatic compound, high temperature resistant
Performance；Feature with aliphatic compound again, good pliability, excellent hydrophobicity, hypotonicity and from dryness；Separately
Outward, the phenolic hydroxyl group on phenyl ring makes it have the property of phenols again.Aluminum phosphate has high temperature resistant, antidetonation, anti-strip, high temperature resistant air-flow
Wash away, strong infrared ray absorption ability and the characteristics of good insulating properties.Carbamate pesticide is carbamic derivative.
Carbamate pesticide is sufficiently stable insecticide.The modified by cardanol water-based insulating paint obtained using said ratio, paint
Film is plentiful, bright, hard, and water-fast, heat resistance and mechanical performance are excellent.
Embodiment 2：A kind of modified by cardanol water-based insulating paint, includes according to the raw material of percentage by weight：Anacardol 18%,
Aluminum phosphate 14%, M-phthalic acid 14%, trimethylolpropane 5%, neopentyl glycol 9%, pyromellitic dianhydride 5%, maleic anhydride
6%, Amino resin 9%, dimethylethanolamine 6%, butyl glycol ether 10%, carbamate pesticide 1%, pigment 2%, water
Property dispersant 1%.
The modified by cardanol water-based insulating paint obtained using said ratio, paint film is plentiful, bright, hard and water-fast, heat-resisting
Property and mechanical performance are excellent.
Embodiment 3：A kind of modified by cardanol water-based insulating paint, includes according to the raw material of percentage by weight：Anacardol 18%,
Aluminum phosphate 14%, M-phthalic acid 14%, trimethylolpropane 5%, neopentyl glycol 10%, pyromellitic dianhydride 6%, maleic acid
Acid anhydride 6%, Amino resin 10%, dimethylethanolamine 5%, butyl glycol ether 9%, carbamate pesticide 0.5%, pigment
1.5%, aqueous dispersion 1%.
The modified by cardanol water-based insulating paint obtained using said ratio, paint film is plentiful, bright, hard and water-fast, heat-resisting
Property and mechanical performance are excellent.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.
Claims (2)
1. a kind of modified by cardanol water-based insulating paint, it is characterised in that the raw material according to percentage by weight includes：Anacardol 12 ~
20%, aluminum phosphate 10 ~ 16%, M-phthalic acid 12 ~ 20%, trimethylolpropane 4 ~ 8%, neopentyl glycol 8 ~ 12%, pyromellitic dianhydride
5 ~ 8%, maleic anhydride 5 ~ 8%, Amino resin 8 ~ 12%, dimethylethanolamine 5 ~ 8%, butyl glycol ether 8 ~ 12%, ammonia
Carbamate insecticide 0.5 ~ 1%, pigment 0.5 ~ 2%, aqueous dispersion 0.5 ~ 1%.
2. modified by cardanol water-based insulating paint according to claim 1, it is characterised in that according to the raw material of percentage by weight
Including：Anacardol 16%, aluminum phosphate 12%, M-phthalic acid 16%, trimethylolpropane 6%, neopentyl glycol 10%, Pyromellitic Acid
Acid anhydride 6%, maleic anhydride 6%, Amino resin 10%, dimethylethanolamine 6%, butyl glycol ether 10%, carbamate
Insecticide 0.5%, pigment 1%, aqueous dispersion 0.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710018089.8A CN106833256A (en) | 2017-01-11 | 2017-01-11 | Modified by cardanol water-based insulating paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710018089.8A CN106833256A (en) | 2017-01-11 | 2017-01-11 | Modified by cardanol water-based insulating paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106833256A true CN106833256A (en) | 2017-06-13 |
Family
ID=59118593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710018089.8A Pending CN106833256A (en) | 2017-01-11 | 2017-01-11 | Modified by cardanol water-based insulating paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106833256A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164941A (en) * | 2017-11-30 | 2018-06-15 | 芜湖林电子科技有限公司 | A kind of PLA composite materials of 3D printing and preparation method thereof |
| CN115073996A (en) * | 2021-08-09 | 2022-09-20 | 东莞市项华电子科技有限公司 | Antistatic coating and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371507A (en) * | 2014-08-13 | 2015-02-25 | 山东奔腾漆业股份有限公司 | High performance water-based industrial anti-corrosion coating and preparation method thereof |
| CN105670469A (en) * | 2016-02-02 | 2016-06-15 | 嘉兴市嘉盛绝缘材料有限公司 | Cardanol modified waterborne insulating varnish and preparation method thereof |
| CN105733412A (en) * | 2016-05-12 | 2016-07-06 | 武汉赫斯特涂层材料股份有限公司 | Epoxy polysiloxane anticorrosive paint |
-
2017
- 2017-01-11 CN CN201710018089.8A patent/CN106833256A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371507A (en) * | 2014-08-13 | 2015-02-25 | 山东奔腾漆业股份有限公司 | High performance water-based industrial anti-corrosion coating and preparation method thereof |
| CN105670469A (en) * | 2016-02-02 | 2016-06-15 | 嘉兴市嘉盛绝缘材料有限公司 | Cardanol modified waterborne insulating varnish and preparation method thereof |
| CN105733412A (en) * | 2016-05-12 | 2016-07-06 | 武汉赫斯特涂层材料股份有限公司 | Epoxy polysiloxane anticorrosive paint |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164941A (en) * | 2017-11-30 | 2018-06-15 | 芜湖林电子科技有限公司 | A kind of PLA composite materials of 3D printing and preparation method thereof |
| CN115073996A (en) * | 2021-08-09 | 2022-09-20 | 东莞市项华电子科技有限公司 | Antistatic coating and application |
| CN115073996B (en) * | 2021-08-09 | 2023-09-05 | 东莞市项华电子科技有限公司 | Antistatic coating and application |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170613 |
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| RJ01 | Rejection of invention patent application after publication |