CN106832966A - Oil plant composition and preparation method and application - Google Patents

Oil plant composition and preparation method and application Download PDF

Info

Publication number
CN106832966A
CN106832966A CN201710130905.4A CN201710130905A CN106832966A CN 106832966 A CN106832966 A CN 106832966A CN 201710130905 A CN201710130905 A CN 201710130905A CN 106832966 A CN106832966 A CN 106832966A
Authority
CN
China
Prior art keywords
oil plant
plant composition
white carbon
parts
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710130905.4A
Other languages
Chinese (zh)
Inventor
宫相勤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Zhonghaijia New Material Co., Ltd.
Original Assignee
宫相勤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 宫相勤 filed Critical 宫相勤
Priority to CN201710130905.4A priority Critical patent/CN106832966A/en
Publication of CN106832966A publication Critical patent/CN106832966A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a kind of oil plant composition and preparation method and application, the technical field for being related to refining glue material to prepare.The preparing raw material of the oil plant composition that the present invention is provided includes liquid oil plant and white carbon, is prevented from white carbon powder and is emitted in air and environment is polluted;The preparation method of the oil plant composition that the present invention is provided, to obtained oil plant composition quantitative Treatment, can reduce error, simple to operate in use without weighing again, with low cost;The application of the oil plant composition that the present invention is provided, can be avoided for white carbon and liquid oil plant being divided into two steps and individually be dosed, and air is polluted, and then is simplified and manually operated, and the health of operator is not influenceed.

Description

Oil plant composition and preparation method and application
Technical field
The present invention relates to refining glue technical field of material, more particularly, to a kind of oil plant composition and preparation method and should With.
Background technology
Rubber is a kind of resilient polymer, is the base stock of rubber industry, be widely used in manufacture tire, sebific duct, Adhesive tape, cable and other various rubbers.Rubber is divided into natural rubber and synthetic rubber by raw material.It is divided into block life by form Glue, latex, liquid rubber and powdered rubber.Rubber or sizing material are carried out into the operation of kneading refining glue with rubber mixing machine.Rubber is independent Kneading, to improve its plasticity.The rubber plasticated is collectively referred to as mixing with compounding ingredient refining.
Calendering process is the first step of rubber production process, and its task is exactly by the rubber in formula and various originals Material is well mixed, and is made the elastomeric compound sizing material for meeting performance requirement, including plasticate processing and the sizing material of rubber mixed refining process Two main process.Processing plasticate for mixed refining process is prepared.Therefore plasticate and mixing is commonly referred to as rubber mixing technique.Elastomeric compound exists By after the operation such as calendering, extrusion, die-filling, the quality of following process and product to sizing material plays conclusive effect.Mixing Bad, sizing material occurs that compounding ingredient disperses the phenomenons such as too high or too low uneven, plasticity, incipient scorch, bloom, makes postorder difficult processing To be normally carried out, and product quality can be caused uneven.So, calendering process is most important basic technology in rubber production One of process.
At this stage, mixing action is to start to lift floating weight, will be formulated various raw material by specify charging sequence successively In input banburying chamber, floating weight pressurization mixing certain hour must be all put down after feeding intake every time, floating weight then be lifted again and is added Next batch materials, until mixing is finished, open lower top bolt, discharge to bottom sheet machine slice, cool down, park.Wherein, charging sequence is Influence the deciding factor of the sizing material quality of mixing.It is common charging order be:First dose rubber, broken-down rubber, masterbatch, The sizing materials such as reclaimed rubber, dose solid softener (such as ancient horse drop resin, rosin, solid paraffin), then add accelerator, work afterwards Property agent, age resistor and antiscorching agent etc., filler (carbon black, potter's clay, calcium carbonate etc.) is added afterwards, add liquid oil plant, finally plus Enter Sulfur.
Wherein, filler and liquid oil plant are divided into two steps and are individually dosed, and the pulverulent filler coefficient of expansion is high, what is added During can float in air, cause severe contamination to air, operative is difficult, and operator is susceptible to suffer from anthraco-silicosis, shadow Ring health.Meanwhile, liquid oil plant is added after filler is added, there is measurement problem during adding every time, easily cause Error, and then have impact on the properties of the sizing material for kneading out.
Therefore, how to solve the above problems and be also increasingly becoming the focus of research.
In view of this, it is special to propose the present invention.
The content of the invention
First purpose of the invention is to provide a kind of oil plant composition;
Second object of the present invention is to provide a kind of preparation method of oil plant composition;
Third object of the present invention is the application for providing a kind of oil plant composition in rubber mixing technique, existing to alleviate Pulverulent filler present in technology and liquid oil plant are divided into two steps and are individually dosed, and severe contamination, workman are caused to air Operating difficulties, it is unhealthful, and the inaccurate technical problem of liquid POL measuring.
A kind of oil plant composition that the present invention is provided, the preparing raw material of the oil plant composition includes following components:Liquid Oil plant and white carbon.
Further, the oil plant composition is made up of the raw material of following weight portion:2-14 parts of liquid oil plant, white carbon 5-25 parts.
Further, the oil plant composition is made up of the raw material of following weight portion:4-12 parts of liquid oil plant, white carbon 10-20 parts.
Further, the oil plant composition is made up of the raw material of following weight portion:6-10 parts of liquid oil plant, white carbon 12-28 parts.
Further, the oil plant composition is made up of the raw material of following weight portion:8 parts of liquid oil plant, 15 parts of white carbon.
Further, the liquid oil plant is paraffin oil, the one kind in naphthenic oil and aromatic naphtha.
In addition, present invention also offers a kind of preparation method of above-mentioned oil plant composition, comprising the following steps:
A () will account for the white carbon heating of the component of cumulative volume 90%, heating-up temperature is 140-160 DEG C;
B () heats the liquid oil plant, heating-up temperature is 140-160 DEG C;
(c) by heating after the white carbon and heating after the liquid oil plant mix, obtain mixture;
D () will be accounted in the white carbon addition mixture of cumulative volume 10% component of residue, obtain the oil plant group Compound;
The e oil plant composition that () will obtain in step (d) is quantitatively deposited.
Further, the heating-up temperature is 150 DEG C.
In addition, the application present invention also offers above-mentioned oil plant composition in rubber mixing technique.
Further, the application is to prepare the big bottom of footwear.
The oil plant composition that the present invention is provided, with white carbon and liquid oil plant as raw material, is prevented from white carbon powder and dissipates Escape in air and environment is polluted;The preparation method of the oil plant composition that the present invention is provided, combines to obtained oil plant Thing quantitative Treatment, can reduce error, simple to operate in use without weighing again, with low cost;The present invention is provided Oil plant composition application, can avoid for white carbon and liquid oil plant being divided into two steps and individually be dosed, air is caused Pollution, and then simplify artificial operation, the health of operator is not influenceed.
Specific embodiment
In order to illustrate more clearly of the present invention, with reference to preferred embodiment, the present invention is described further.Ability Field technique personnel should be appreciated that following specifically described content is illustrative and be not restrictive, and should not limit this with this The protection domain of invention.Unreceipted actual conditions person in embodiment, the condition advised according to normal condition or manufacturer is carried out.Institute With reagent, instrument or the unreceipted production firm person of instrument, the conventional products that can be obtained by commercially available purchase are.
The invention provides a kind of oil plant composition, the preparing raw material of the oil plant composition includes following components:Liquid oil Material and white carbon.
White carbon is broadly divided into precipitated silica gentle as a kind of environmental protection, the auxiliary agent of excellent performance by production method Phase method white carbon, precipitated silica is divided into traditional precipitated silica and special precipitation white carbon again, used by the present invention White carbon is the white carbon of traditional precipitation method production, that is, refer to sulfuric acid, hydrochloric acid, CO2With two that waterglass is base stock production Silica.White carbon carries out reinforcement in being used in colorful rubber product with alternative carbon black, the need for meeting white or translucent product. White carbon has superpower adhesion, tear-proof and heat-resisting ageing resistace simultaneously, so can also be replaced in black rubber product For part carbon black, to obtain high-quality rubber, such as off-the-highway tire, engineering tyre, radial-ply tyre.
In the present invention, oil plant composition is made up of the raw material of following weight portion:2-14 parts of liquid oil plant, white carbon 5- 25 parts.
Wherein, liquid oil plant for example can be, but be not limited to 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts or 14 parts;White carbon for example can be, but be not limited to 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts or 25 parts.
In one preferred embodiment, oil plant composition is made up of the raw material of following weight portion:Liquid oil plant 4-12 Part, white carbon 10-20 parts.
In a preferred implementation method, oil plant composition is made up of the raw material of following weight portion:Liquid oil plant 6- 10 parts, white carbon 12-18 parts.
In a most preferred implementation method, oil plant composition is made up of the raw material of following weight portion:Liquid oil plant 8 Part, 15 parts of white carbon.
In the present invention, liquid oil plant is paraffin oil, the one kind in naphthenic oil or aromatic naphtha.
In rubber mixing technique, can be according to the different types of liquid oil plant of the different choice of application field.
In one preferred embodiment, liquid oil plant is paraffin oil.
Paraffin oil high-flash and low-volatile provide volatile matter under more preferable weatherability and high temperature for rubber processing Small characteristic.In the every field of rubber applications, paraffine base crude oil has very outstanding performance.The characteristic arene content of paraffin oil Low, this is especially important in the application of peroxidating sulfuration process, the low consumption for reducing vulcanizing agent of arene content, so as to reduce into This.The low aromatic hydrocarbon content and low volatility of paraffine base crude oil outclass the inadequate rubber filling oil of other refinings.Also, paraffin oil Low aromatic hydrocarbon content and the application that is engaged in rubber materials of low volatility serve very important position, low aromatic hydrocarbons contains Amount improves the oxidative degradation performance of rubber, low volatility to be helped to prevent aging contraction, and is conducive to improving product Bad outward appearance (such as coarse, there is bubble), both characteristics are conducive to extending the service life of rubber.
In addition, present invention also offers a kind of preparation method of above-mentioned oil plant composition, comprising the following steps:
A () will account for the white carbon heating of the component of cumulative volume 90%, heating-up temperature is 140-160 DEG C;
B () heats liquid oil plant, heating-up temperature is 140-160 DEG C;
C () mixes the liquid oil plant after the white carbon after heating and heating, obtain mixture;
D () will be accounted in the white carbon addition mixture of cumulative volume 10% component of residue, obtain oil plant composition;
E oil plant composition that () will obtain in step (d) is quantitatively deposited.
Wherein, the time for being mixed in step (c) is 20-40 minutes.
In one preferred embodiment, the time for being mixed in step (c) is 30 minutes.
In one preferred embodiment, heating-up temperature is 150 DEG C.
Wherein, remaining white carbon is filled into step (d), cladding can be played a part of, with ensureing normal temperature, liquid oil plant Will not separate out.
Wherein, in step (e), according to purpose finished product or application field for standard is quantified.
In addition, the application present invention also offers a kind of above-mentioned oil plant composition in rubber mixing technique.
In the present invention, using to prepare the big bottom of footwear.
Under these conditions, the oil plant composition that the present invention is provided, with white carbon and liquid oil plant as raw material, is prevented from White carbon powder is emitted in air and environment is polluted;The preparation method of the oil plant composition that the present invention is provided, to system The oil plant composition quantitative Treatment for obtaining, can reduce error, in use without weigh again, simple to operate, low cost It is honest and clean;The application of the oil plant composition that the present invention is provided, can avoid for white carbon and liquid oil plant being divided into two steps and individually be filled out Plus, air is polluted, and then simplify artificial operation, the health of operator is not influenceed.
Embodiment 1
A kind of oil plant composition, is made up of the raw material of following weight portion:
8 parts of paraffin oil, 15 parts of white carbon.
Above-mentioned oil plant composition is prepared according to following preparation method, is comprised the following steps:
A () will account for the white carbon heating of the component of cumulative volume 90%, heating-up temperature is 150 DEG C;
B () heats liquid oil plant, heating-up temperature is 150 DEG C;
C () mixes the liquid oil plant after the white carbon after heating and heating, obtain mixture;
D () will be accounted in the white carbon addition mixture of cumulative volume 10% component of residue, obtain oil plant composition;
E oil plant composition that () will obtain in step (d) is quantitatively deposited.
Embodiment 2
A kind of oil plant composition, is made up of the raw material of following weight portion:
2 parts of naphthenic oil, 5 parts of white carbon.
Above-mentioned oil plant composition is prepared according to following preparation method, is comprised the following steps:
A () will account for the white carbon heating of the component of cumulative volume 90%, heating-up temperature is 140 DEG C;
B () heats liquid oil plant, heating-up temperature is 140 DEG C;
C () mixes the liquid oil plant after the white carbon after heating and heating, obtain mixture;
D () will be accounted in the white carbon addition mixture of cumulative volume 10% component of residue, obtain oil plant composition;
E oil plant composition that () will obtain in step (d) is quantitatively deposited.
Embodiment 3
A kind of oil plant composition, is made up of the raw material of following weight portion:
14 parts of aromatic naphtha, 25 parts of white carbon.
Above-mentioned oil plant composition is prepared according to following preparation method, is comprised the following steps:
A () will account for the white carbon heating of the component of cumulative volume 90%, heating-up temperature is 160 DEG C;
B () heats liquid oil plant, heating-up temperature is 160 DEG C;
C () mixes the liquid oil plant after the white carbon after heating and heating, obtain mixture;
D () adds the white carbon that residue accounts for the component of cumulative volume 10% in mixture, obtain oil plant composition;
E oil plant composition that () will obtain in step (d) is quantitatively deposited.
Embodiment 4
A kind of oil plant composition, is made up of the raw material of following weight portion:
16 parts of paraffin oil, 3 parts of white carbon.
Above-mentioned oil plant composition is prepared according to following preparation method, is comprised the following steps:
A () will account for the white carbon heating of the component of cumulative volume 90%, heating-up temperature is 160 DEG C;
B () heats liquid oil plant, heating-up temperature is 160 DEG C;
C () mixes the liquid oil plant after the white carbon after heating and heating, obtain mixture;
D () will be accounted in the white carbon addition mixture of cumulative volume 10% component of residue, obtain oil plant composition;
E oil plant composition that () will obtain in step (d) is quantitatively deposited.
Embodiment 5
A kind of oil plant composition, is made up of the raw material of following weight portion:
8 parts of paraffin oil, 15 parts of white carbon, 10 parts of calcium carbonate.
Above-mentioned oil plant composition is prepared according to following preparation method, is comprised the following steps:
A () will account for the white carbon heating of the component of cumulative volume 90%, heating-up temperature is 160 DEG C;
B () heats liquid oil plant, heating-up temperature is 160 DEG C;
C () mixes the liquid oil plant after the white carbon after heating and heating, obtain mixture;
D white carbon and calcium carbonate that () will account for cumulative volume 10% component of residue adds mixture jointly, obtains oil plant group Compound;
E oil plant composition that () will obtain in step (d) is quantitatively deposited.
Embodiment 6
Oil plant composition with the offer of above-described embodiment 1 carries out refining glue as follows as raw material:
Using mixer mixing, floating weight is lifted first, 70kg sizing materials are put into banburying chamber, put down floating weight pressurization mixing After 10 minutes, floating weight is then lifted again and doses solid softener Gu horse drop resin 5kg, put down 10 points of floating weight pressurization mixing Clock, afterwards, then lifts floating weight and doses captax (2- benzothiazolyl mercaptans) 5kg, activating agent (stearic acid polyoxy second successively Alkene ester) 5kg, age resistor (N- phenyl-α-aniline) 5kg and antiscorching agent (N- cyclohexylthiophthalimides) 5kg, Floating weight pressurization mixing 10 minutes is put down, then lifts floating weight, the fixed measured oil plant composition of the offer of embodiment 1 is directly provided 25kg, after putting down floating weight pressurization mixing 10 minutes, then lifts floating weight and doses sulphur 5kg, until mixing is finished, opens lower top Bolt, discharge to bottom sheet machine slice, cools down, parks.
Embodiment 7
Oil plant composition with the offer of above-described embodiment 2 carries out refining glue as follows as raw material:
Using mixer mixing, floating weight is lifted first, 70kg sizing materials are put into banburying chamber, put down floating weight pressurization mixing After 10 minutes, floating weight is then lifted again and doses solid softener Gu horse drop resin 5kg, put down 10 points of floating weight pressurization mixing Clock, afterwards, then lifts floating weight and doses captax (2- benzothiazolyl mercaptans) 5kg, activating agent (stearic acid polyoxy second successively Alkene ester) 5kg, age resistor (N- phenyl-α-aniline) 5kg and antiscorching agent (N- cyclohexylthiophthalimides) 5kg, Floating weight pressurization mixing 10 minutes is put down, then lifts floating weight, the fixed measured oil plant composition of the offer of embodiment 2 is directly provided 25kg, after putting down floating weight pressurization mixing 10 minutes, then lifts floating weight and doses sulphur 5kg, until mixing is finished, opens lower top Bolt, discharge to bottom sheet machine slice, cools down, parks.
Embodiment 8
Oil plant composition with the offer of above-described embodiment 3 carries out refining glue as follows as raw material:
Using mixer mixing, floating weight is lifted first, 70kg sizing materials are put into banburying chamber, put down floating weight pressurization mixing After 10 minutes, floating weight is then lifted again and doses solid softener Gu horse drop resin 5kg, put down 10 points of floating weight pressurization mixing Clock, afterwards, then lifts floating weight and doses captax (2- benzothiazolyl mercaptans) 5kg, activating agent (stearic acid polyoxy second successively Alkene ester) 5kg, age resistor (N- phenyl-α-aniline) 5kg and antiscorching agent (N- cyclohexylthiophthalimides) 5kg, Floating weight pressurization mixing 10 minutes is put down, then lifts floating weight, the fixed measured oil plant composition of the offer of embodiment 3 is directly provided 25kg, after putting down floating weight pressurization mixing 10 minutes, then lifts floating weight and doses sulphur 5kg, until mixing is finished, opens lower top Bolt, discharge to bottom sheet machine slice, cools down, parks.
Embodiment 9
Oil plant composition with the offer of above-described embodiment 4 carries out refining glue as follows as raw material:
Using mixer mixing, floating weight is lifted first, 70kg sizing materials are put into banburying chamber, put down floating weight pressurization mixing After 10 minutes, floating weight is then lifted again and doses solid softener Gu horse drop resin 5kg, put down 10 points of floating weight pressurization mixing Clock, afterwards, then lifts floating weight and doses captax (2- benzothiazolyl mercaptans) 5kg, activating agent (stearic acid polyoxy second successively Alkene ester) 5kg, age resistor (N- phenyl-α-aniline) 5kg and antiscorching agent (N- cyclohexylthiophthalimides) 5kg, Floating weight pressurization mixing 10 minutes is put down, then lifts floating weight, the fixed measured oil plant composition of the offer of embodiment 4 is directly provided 25kg, after putting down floating weight pressurization mixing 10 minutes, then lifts floating weight and doses sulphur 5kg, until mixing is finished, opens lower top Bolt, discharge to bottom sheet machine slice, cools down, parks.
Embodiment 10
Oil plant composition with the offer of above-described embodiment 5 carries out refining glue as follows as raw material:
Using mixer mixing, floating weight is lifted first, 70kg sizing materials are put into banburying chamber, put down floating weight pressurization mixing After 10 minutes, floating weight is then lifted again and doses solid softener Gu horse drop resin 5kg, put down 10 points of floating weight pressurization mixing Clock, afterwards, then lifts floating weight and doses captax (2- benzothiazolyl mercaptans) 5kg, activating agent (stearic acid polyoxy second successively Alkene ester) 5kg, age resistor (N- phenyl-α-aniline) 5kg and antiscorching agent (N- cyclohexylthiophthalimides) 5kg, Floating weight pressurization mixing 10 minutes is put down, then lifts floating weight, the fixed measured oil plant composition of the offer of embodiment 5 is directly provided 25kg, after putting down floating weight pressurization mixing 10 minutes, then lifts floating weight and doses sulphur 5kg, until mixing is finished, opens lower top Bolt, discharge to bottom sheet machine slice, cools down, parks.
In order to verify the oil plant composition provided with each embodiment as raw material, to the properties of the sizing material obtained by preparation Influence, tests the sizing material that embodiment 6, embodiment 7, embodiment 8, embodiment 9, embodiment 10 are provided, and set existing skill Sizing material obtained by art manufacture is control group, and test result is shown in Table 1.
The properties test result of the sizing material of table 1
Result above shows that sizing material prepared by the oil plant composition provided using the embodiment of the present invention 1 in such as density, draws Stretch intensity, elongation at break, shore hardness and tearing strength aspect and good performance is presented, the control group phase with prior art It is more more excellent than even each performance.Meanwhile, compared with substantial amounts of dust granules are produced in control group preparation process, using the present invention The oil plant composition of offer, because white carbon and liquid oil plant have been prepared into oil plant composition, thus avoids causing air Pollution, and due to before sizing material is added, having set the amount of white carbon and oil, thus can be directly added into operation, letter Change artificial operation, improve efficiency, and do not influence the health of operator.
Finally it should be noted that:Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations;To the greatest extent Pipe has been described in detail with reference to foregoing embodiments to the present invention, it will be understood by those within the art that:Its according to The technical scheme described in foregoing embodiments can so be modified, or which part or all technical characteristic are entered Row equivalent;And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology The scope of scheme.

Claims (10)

1. a kind of oil plant composition, it is characterised in that the preparing raw material of the oil plant composition includes following components:Liquid oil plant And white carbon.
2. oil plant composition according to claim 1, it is characterised in that the oil plant composition by following weight portion original Material is made:2-14 parts, white carbon 5-25 parts of liquid oil plant.
3. oil plant composition according to claim 2, it is characterised in that the oil plant composition by following weight portion original Material is made:4-12 parts, white carbon 10-20 parts of liquid oil plant.
4. oil plant composition according to claim 3, it is characterised in that the oil plant composition by following weight portion original Material is made:6-10 parts, white carbon 12-18 parts of liquid oil plant.
5. oil plant composition according to claim 4, it is characterised in that the oil plant composition by following weight portion original Material is made:8 parts of liquid oil plant, 15 parts of white carbon.
6. oil plant composition according to claim 5, it is characterised in that the liquid oil plant is paraffin oil, naphthenic oil and One kind in aromatic naphtha.
7. the preparation method of oil plant composition as claimed in any one of claims 1 to 6, it is characterised in that including following step Suddenly:
A () will account for the white carbon heating of the component of cumulative volume 90%, heating-up temperature is 140-160 DEG C;
B () heats the liquid oil plant, heating-up temperature is 140-160 DEG C;
(c) by heating after the white carbon and heating after the liquid oil plant mix, obtain mixture;
D () will be accounted in the white carbon addition mixture of cumulative volume 10% component of residue, obtain the oil plant composition;
The e oil plant composition that () will obtain in step (d) is quantitatively deposited.
8. preparation method according to claim 7, it is characterised in that the heating-up temperature is 150 DEG C.
9. application of the oil plant composition as described in claim any one of 1-6 in rubber mixing technique.
10. application according to claim 9, it is characterised in that the application is to prepare the big bottom of footwear.
CN201710130905.4A 2017-03-07 2017-03-07 Oil plant composition and preparation method and application Pending CN106832966A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710130905.4A CN106832966A (en) 2017-03-07 2017-03-07 Oil plant composition and preparation method and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710130905.4A CN106832966A (en) 2017-03-07 2017-03-07 Oil plant composition and preparation method and application

Publications (1)

Publication Number Publication Date
CN106832966A true CN106832966A (en) 2017-06-13

Family

ID=59138322

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710130905.4A Pending CN106832966A (en) 2017-03-07 2017-03-07 Oil plant composition and preparation method and application

Country Status (1)

Country Link
CN (1) CN106832966A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101307157A (en) * 2008-07-10 2008-11-19 广州吉必盛科技实业有限公司 Method for preparing rubber packing containing white carbon black by gas-phase method
CN101698317A (en) * 2009-10-26 2010-04-28 钟爱民 Method for mixing rubber
CN103358415A (en) * 2012-03-28 2013-10-23 北京安达信自动化科技有限公司 Energy-conserved rubber mixing method and combined equipment using same
CN103756009A (en) * 2014-01-14 2014-04-30 宫相勤 Solid granular environment-friendly rubber processing oil and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101307157A (en) * 2008-07-10 2008-11-19 广州吉必盛科技实业有限公司 Method for preparing rubber packing containing white carbon black by gas-phase method
CN101698317A (en) * 2009-10-26 2010-04-28 钟爱民 Method for mixing rubber
CN103358415A (en) * 2012-03-28 2013-10-23 北京安达信自动化科技有限公司 Energy-conserved rubber mixing method and combined equipment using same
CN103756009A (en) * 2014-01-14 2014-04-30 宫相勤 Solid granular environment-friendly rubber processing oil and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《中国鞋业大全》编委会编: "《中国鞋业大全(下)(第1版)》", 31 January 2000, 化学工业出版社 *

Similar Documents

Publication Publication Date Title
EP1690894B1 (en) Rubber composition and tire comprising thereof
US9108386B2 (en) Elastomeric compositions comprising reclaimed vulcanized elastomer particles of broad size distribution and chemically modified vulcanized elastomer particles
US6346561B1 (en) Pavement material
DE102017127834B4 (en) liquid rubber usage
JPH07500141A (en) Asphalt composition and its manufacturing method
JP5117738B2 (en) Curable rubber mixture containing silica
DE102014112647A1 (en) Rubber composition and pneumatic tires of this composition
CN101134825A (en) Color-change resistant latch-locked valve cock rubber formula and method for making same
CN106633216A (en) Wide-temperature-range high-damping blended rubber material and preparation method therefor
EP2655499B1 (en) Rubber blend with an environmentally-friendly plasticiser
Ren et al. Reinforced mechanical properties of functionalized silica and eggshell filled guayule natural rubber composites
CN109929160A (en) The application of organo silane coupling agent and rubber composition and vulcanized rubber and its preparation method and application
CN103788432A (en) Rubber composition and vulcanized rubber and preparation method thereof and application of vulcanized rubber
EP2082899B1 (en) Natural rubber mixture with improved low temperature flexibility
CN106832966A (en) Oil plant composition and preparation method and application
CN109081969A (en) Method for producing elastic composite material
CN108276622A (en) A kind of low-rolling-resistance tyre surface liner layer rubber composition and its application
CN105694152B (en) A kind of special rubber compound of printing paper paper feeding rubber roller and preparation method thereof
CN106496698A (en) Enhanced butadiene-styrene rubber of a kind of superfined flyash and preparation method thereof
US2952650A (en) Butyl rubber powder, method of making, and asphalt composition containing same
CN108003408A (en) One kind vulcanization rubber and its preparation method and application
DE112015002662B4 (en) Vulcanized rubber composition for a tire
CN107364029A (en) A kind of rubber vulcanization process
EP3844002B1 (en) Pneumatic tyre
KR20100041400A (en) Heavy dury tire bead insulation rubber composition

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20180314

Address after: 266000 Shandong city of Qingdao province Jimo City Ao Road No. 788 1208

Applicant after: Qingdao Haijia Ajuvants Co., Ltd.

Address before: 266000 room 1208, Dexin mansion, No. 788, Ao Lan Road, Jimo City, Qingdao, Shandong

Applicant before: Gong Xiangqin

TA01 Transfer of patent application right
CI02 Correction of invention patent application

Correction item: Applicant|Address

Correct: Gong Xiangqin|266000 Room 1208, Dexin Building, 788 Lanlan Road, Jimo City, Qingdao City, Shandong Province

False: Qingdao Haijia Ajuvants Co., Ltd.|266000 Households 1208, 788 Lanlan Road, Jimo City, Qingdao City, Shandong Province

Number: 14-01

Volume: 34

CI02 Correction of invention patent application
TA01 Transfer of patent application right

Effective date of registration: 20190614

Address after: 266200 Bolan Town Industrial Park, Jimo City, Qingdao City, Shandong Province

Applicant after: Qingdao Zhonghaijia New Material Co., Ltd.

Address before: 266000 Room 1208 Dexin Building, 788 Tunlan Road, Jimo City, Qingdao City, Shandong Province

Applicant before: Gong Xiangqin

TA01 Transfer of patent application right
RJ01 Rejection of invention patent application after publication

Application publication date: 20170613

RJ01 Rejection of invention patent application after publication