CN106832941A - A kind of insulating resin of Anti-vibration cable - Google Patents

A kind of insulating resin of Anti-vibration cable Download PDF

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Publication number
CN106832941A
CN106832941A CN201710070722.8A CN201710070722A CN106832941A CN 106832941 A CN106832941 A CN 106832941A CN 201710070722 A CN201710070722 A CN 201710070722A CN 106832941 A CN106832941 A CN 106832941A
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parts
standby
poured
reactor
insulating resin
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李聪
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/42—Insulated conductors or cables characterised by their form with arrangements for heat dissipation or conduction
    • H01B7/421—Insulated conductors or cables characterised by their form with arrangements for heat dissipation or conduction for heat dissipation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/1895—Internal space filling-up means
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/46—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes silicones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/02—Disposition of insulation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/189—Radial force absorbing layers providing a cushioning effect
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/22—Metal wires or tapes, e.g. made of steel
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/24—Devices affording localised protection against mechanical force or pressure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/40—Insulated conductors or cables characterised by their form with arrangements for facilitating mounting or securing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/42—Insulated conductors or cables characterised by their form with arrangements for heat dissipation or conduction
    • H01B7/428—Heat conduction
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00—Power cables
    • H01B9/02—Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention discloses a kind of insulating resin of Anti-vibration cable, the insulating resin is by 20 22 parts of polysiloxanes matching by weight, 48 parts of sulfur monochloride, 11 13 parts of chlorosulfonic acid, 23 25 parts of diphenol propane, 46 parts of alchlor, 14 16 parts of chlorobenzene, 68 parts of polyamidoimide, 24 parts of ATBC, 13 parts of manganous oxide, 13 15 parts of silicone emulsion, 13 parts of lithium carbonate, 57 parts of boron nitride, 24 parts of chromium nitride, 13 parts of boron oxide, 24 parts of compositions of 35 parts of glass fibre and titanium nitride, the insulating resin of the Anti-vibration cable has the advantages that effectiveness is good.

Description

A kind of insulating resin of Anti-vibration cable
Technical field
The present invention relates to a kind of insulating resin of Anti-vibration cable.
Background technology
Cable be used to transmit electric (magnetic) can, information and realize the wire product of electromagnetic energy conversion, the cable of broad sense is also referred to as It is cable, the cable of narrow sense refers to insulated cable, and it may be defined as:The aggregate being made up of following part；One or more is exhausted Edge core, and the clad that each of which may have, total protective layer and outer jacket, cable can also have additional without insulation Conductor.It is used to transmit electric (magnetic) energy, information and the wire product for realizing electromagnetic energy conversion.
The electromagnetic wave of radiation and the leakage of cable not only other electronic equipment normal works of severe jamming, cause functions of the equipments Disorderly, error of transmission.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of insulation tree of the Anti-vibration cable good with effectiveness Fat.
A kind of insulating resin of Anti-vibration cable, by polysiloxanes 20-22 parts, sulfur monochloride 4-8 matching by weight Part, chlorosulfonic acid 11-13 parts, diphenol propane 23-25 parts, alchlor 4-6 parts, chlorobenzene 14-16 parts, polyamidoimide 6-8 Part, ATBC 2-4 parts, manganous oxide 1-3 parts, silicone emulsion 13-15 parts, lithium carbonate 1-3 parts, boron nitride 5-7 parts, nitrogen Change 2-4 parts, boron oxide 1-3 parts, glass fibre 3-5 parts and titanium nitride 2-4 parts composition of chromium, comprise the following steps：
1) A parts and B parts are divided into by chlorobenzene 14-16 parts, it is standby；
2) by step 1) in A parts be poured into together with chlorosulfonic acid 11-13 parts in reactor, be sufficiently stirred for, make its abundant Reaction, generates white crystal, and white crystal is obtained, standby；
3) by step 2) obtained in white crystal and step 1) B parts be poured into together in reactor, be subsequently adding trichlorine Change 4-6 parts of aluminium to be condensed, fully reaction, crystallization is obtained, it is standby；
4) by step 3) obtained crystallization is poured into reactor with diphenol propane 23-25 part carries out polycondensation reaction, system Amber solid is obtained, it is standby；
5) by manganous oxide 1-3, lithium carbonate 1-3 parts, boron nitride 5-7 parts, chromium nitride 2-4 parts, boron oxide 1-3 parts and nitridation Titanium 2-4 parts is poured into nano grinder and carries out pulverization process together, and nanometer powder is obtained, standby；
6) by silicone emulsion 13-15 parts, polyamidoimide 6-8 parts, ATBC 2-4 parts, glass fibre 3-5 parts With step 5) obtained in nanometer powder be poured into mixer together in be stirred 20 minutes, be obtained paste, it is standby；
7) by polysiloxanes 20-22 parts, sulfur monochloride 4-8 parts and step 4) obtained in amber solid be poured into together instead Answer in kettle, being heated to 110 DEG C carries out vulcanizing treatment 20 minutes, is subsequently adding step 6) obtained in paste, stir, Sticky jelly is obtained, it is standby；
8) by step 7) obtained in sticky jelly be poured into extrusion forming in rubber pipe extruder, you can use.
Beneficial effects of the present invention are：Insulating resin has the advantages that effectiveness is good.
Brief description of the drawings
Fig. 1 is a kind of overall structure diagram of Anti-vibration cable of the invention.
Specific embodiment
Embodiment one：
As shown in figure 1, a kind of Anti-vibration cable, including shell 1, inner casing 2, carbon bellows 3 and core 4, on the shell 1 Extension spring (not shown) is provided with, steel wire rope 5 is provided with the extension spring, the steel wire rope 5 is integral type with inner casing 2 Set, snap joint 6 is provided with the inner casing 2, the snap joint 6 sets through shell 1, is provided with the inner casing 2 Silicon rubber bar 7 and EMI shell fragments (not shown), are provided with hanging belt 8 on the EMI shell fragments, the carbon bellows 3 is equipped on and hangs On dress band 8, helium (not shown) is filled with the carbon bellows 3, the core 4 sets for plating niobium, set on the core 4 Insulating barrier (not shown) is equipped with, the insulating barrier includes highly-conductive hot carbon fiber cloth 9, silver fiber fabric 10 and insulating resin 11.
Between the shell 1 and inner casing 2 be filled with chopped carbon fiber (not shown), thermal coefficient of expansion it is small and with each to different Property, good corrosion resistance additionally provides good heat conductivility and capability of electromagnetic shielding.
The silicon rubber bar 7 is hollow setting, alleviates overall weight, and can play good buffering effect.
To vacuumize setting between the inner casing 2 and carbon bellows 3, the sky between inner casing 2 and carbon bellows 3 is removed Gas (not shown), prevents hydrogenesis in air into the globule.
The surface of carbon bellows 3 scribbles heat radiation coating (not shown), can strengthen the thermal diffusivity of carbon bellows 3 Energy.
For sealing is set between the snap joint 6 and shell 1, can prevent moisture from entering into inside cable.
Aluminium foil composite glass fiber cloth is provided between the highly-conductive hot carbon fiber cloth 9 and silver fiber fabric 10 (not scheme Show), airtight, waterproof, good seal performance.
The invention solves the problems that another technical problem be that a kind of manufacture method of insulating resin is provided.
To solve the above problems, the present invention is adopted the following technical scheme that：
By match by weight 22 parts of polysiloxanes, 4 parts of sulfur monochloride, 11 parts of chlorosulfonic acid, 23 parts of diphenol propane, 4 parts of alchlor, 14 parts of chlorobenzene, 6 parts of polyamidoimide, 2 parts of ATBC, 1 part of manganous oxide, silicone emulsion 13 Part, 1 part of lithium carbonate, 5 parts of boron nitride, 2 parts of chromium nitride, 1 part of boron oxide, 3 parts of glass fibre and 2 parts of compositions of titanium nitride, including with Lower step：
1) 14 parts of chlorobenzene is divided into A parts and B parts, it is standby；
2) by step 1) in A parts be poured into reactor together with 11 parts of chlorosulfonic acid, be sufficiently stirred for, make it fully anti- Should, white crystal is generated, white crystal is obtained, it is standby；
3) by step 2) obtained in white crystal and step 1) B parts be poured into together in reactor, be subsequently adding trichlorine Change 4 parts of aluminium to be condensed, fully reaction, crystallization is obtained, it is standby；
4) by step 3) obtained crystallization carries out polycondensation reaction in being poured into reactor with 23 parts of diphenol propane, and amber is obtained Amber color solid, it is standby；
5) by 2 parts of manganous oxide 1,1 part of lithium carbonate, 5 parts of boron nitride, 2 parts of chromium nitride, 1 part of boron oxide and titanium nitride together Being poured into nano grinder carries out pulverization process, and nanometer powder is obtained, standby；
6) by 13 parts of silicone emulsion, 6 parts of polyamidoimide, 2 parts of ATBC, 3 parts of glass fibre and step 5) Obtained nanometer powder is stirred 20 minutes in being poured into mixer together, and paste is obtained, standby；
7) by 22 parts of polysiloxanes, 4 parts of sulfur monochloride and step 4) obtained in amber solid be poured into reactor together In, being heated to 110 DEG C carries out vulcanizing treatment 20 minutes, is subsequently adding step 6) obtained in paste, stir, be obtained Sticky jelly, it is standby；
8) by step 7) obtained in sticky jelly be poured into extrusion forming in rubber pipe extruder, you can use.
Embodiment two：
As shown in figure 1, a kind of Anti-vibration cable, including shell 1, inner casing 2, carbon bellows 3 and core 4, on the shell 1 Extension spring (not shown) is provided with, steel wire rope 5 is provided with the extension spring, the steel wire rope 5 is integral type with inner casing 2 Set, snap joint 6 is provided with the inner casing 2, the snap joint 6 sets through shell 1, is provided with the inner casing 2 Silicon rubber bar 7 and EMI shell fragments (not shown), are provided with hanging belt 8 on the EMI shell fragments, the carbon bellows 3 is equipped on and hangs On dress band 8, helium (not shown) is filled with the carbon bellows 3, the core 4 sets for plating niobium, set on the core 4 Insulating barrier (not shown) is equipped with, the insulating barrier includes highly-conductive hot carbon fiber cloth 9, silver fiber fabric 10 and insulating resin 11.
Between the shell 1 and inner casing 2 be filled with chopped carbon fiber (not shown), thermal coefficient of expansion it is small and with each to different Property, good corrosion resistance additionally provides good heat conductivility and capability of electromagnetic shielding.
The silicon rubber bar 7 is hollow setting, alleviates overall weight, and can play good buffering effect.
To vacuumize setting between the inner casing 2 and carbon bellows 3, the sky between inner casing 2 and carbon bellows 3 is removed Gas (not shown), prevents hydrogenesis in air into the globule.
The surface of carbon bellows 3 scribbles heat radiation coating (not shown), can strengthen the thermal diffusivity of carbon bellows 3 Energy.
For sealing is set between the snap joint 6 and shell 1, can prevent moisture from entering into inside cable.
Aluminium foil composite glass fiber cloth is provided between the highly-conductive hot carbon fiber cloth 9 and silver fiber fabric 10 (not scheme Show), airtight, waterproof, good seal performance.
The invention solves the problems that another technical problem be that a kind of manufacture method of insulating resin is provided.
To solve the above problems, the present invention is adopted the following technical scheme that：
By match by weight 20 parts of polysiloxanes, 8 parts of sulfur monochloride, 13 parts of chlorosulfonic acid, 25 parts of diphenol propane, 6 parts of alchlor, 16 parts of chlorobenzene, 8 parts of polyamidoimide, 4 parts of ATBC, 3 parts of manganous oxide, silicone emulsion 15 Part, 3 parts of lithium carbonate, 7 parts of boron nitride, 4 parts of chromium nitride, 3 parts of boron oxide, 5 parts of glass fibre and 4 parts of compositions of titanium nitride, including with Lower step：
1) 16 parts of chlorobenzene is divided into A parts and B parts, it is standby；
2) by step 1) in A parts be poured into reactor together with 13 parts of chlorosulfonic acid, be sufficiently stirred for, make it fully anti- Should, white crystal is generated, white crystal is obtained, it is standby；
3) by step 2) obtained in white crystal and step 1) B parts be poured into together in reactor, be subsequently adding trichlorine Change 6 parts of aluminium to be condensed, fully reaction, crystallization is obtained, it is standby；
4) by step 3) obtained crystallization carries out polycondensation reaction in being poured into reactor with 25 parts of diphenol propane, and amber is obtained Amber color solid, it is standby；
5) by 4 parts of manganous oxide 3,3 parts of lithium carbonate, 7 parts of boron nitride, 4 parts of chromium nitride, 3 parts of boron oxide and titanium nitride together Being poured into nano grinder carries out pulverization process, and nanometer powder is obtained, standby；
6) by 15 parts of silicone emulsion, 8 parts of polyamidoimide, 4 parts of ATBC, 5 parts of glass fibre and step 5) Obtained nanometer powder is stirred 20 minutes in being poured into mixer together, and paste is obtained, standby；
7) by 20 parts of polysiloxanes, 8 parts of sulfur monochloride and step 4) obtained in amber solid be poured into reactor together In, being heated to 110 DEG C carries out vulcanizing treatment 20 minutes, is subsequently adding step 6) obtained in paste, stir, be obtained Sticky jelly, it is standby；
8) by step 7) obtained in sticky jelly be poured into extrusion forming in rubber pipe extruder, you can use.
Embodiment three：
As shown in figure 1, a kind of Anti-vibration cable, including shell 1, inner casing 2, carbon bellows 3 and core 4, on the shell 1 Extension spring (not shown) is provided with, steel wire rope 5 is provided with the extension spring, the steel wire rope 5 is integral type with inner casing 2 Set, snap joint 6 is provided with the inner casing 2, the snap joint 6 sets through shell 1, is provided with the inner casing 2 Silicon rubber bar 7 and EMI shell fragments (not shown), are provided with hanging belt 8 on the EMI shell fragments, the carbon bellows 3 is equipped on and hangs On dress band 8, helium (not shown) is filled with the carbon bellows 3, the core 4 sets for plating niobium, set on the core 4 Insulating barrier (not shown) is equipped with, the insulating barrier includes highly-conductive hot carbon fiber cloth 9, silver fiber fabric 10 and insulating resin 11.
Between the shell 1 and inner casing 2 be filled with chopped carbon fiber (not shown), thermal coefficient of expansion it is small and with each to different Property, good corrosion resistance additionally provides good heat conductivility and capability of electromagnetic shielding.
The silicon rubber bar 7 is hollow setting, alleviates overall weight, and can play good buffering effect.
To vacuumize setting between the inner casing 2 and carbon bellows 3, the sky between inner casing 2 and carbon bellows 3 is removed Gas (not shown), prevents hydrogenesis in air into the globule.
The surface of carbon bellows 3 scribbles heat radiation coating (not shown), can strengthen the thermal diffusivity of carbon bellows 3 Energy.
For sealing is set between the snap joint 6 and shell 1, can prevent moisture from entering into inside cable.
Aluminium foil composite glass fiber cloth is provided between the highly-conductive hot carbon fiber cloth 9 and silver fiber fabric 10 (not scheme Show), airtight, waterproof, good seal performance.
The invention solves the problems that another technical problem be that a kind of manufacture method of insulating resin is provided.
To solve the above problems, the present invention is adopted the following technical scheme that：
By match by weight 21 parts of polysiloxanes, 6 parts of sulfur monochloride, 12 parts of chlorosulfonic acid, 24 parts of diphenol propane, 5 parts of alchlor, 15 parts of chlorobenzene, 7 parts of polyamidoimide, 3 parts of ATBC, 2 parts of manganous oxide, silicone emulsion 14 Part, 2 parts of lithium carbonate, 6 parts of boron nitride, 3 parts of chromium nitride, 2 parts of boron oxide, 4 parts of glass fibre and 3 parts of compositions of titanium nitride, including with Lower step：
1) 15 parts of chlorobenzene is divided into A parts and B parts, it is standby；
2) by step 1) in A parts be poured into reactor together with 12 parts of chlorosulfonic acid, be sufficiently stirred for, make it fully anti- Should, white crystal is generated, white crystal is obtained, it is standby；
3) by step 2) obtained in white crystal and step 1) B parts be poured into together in reactor, be subsequently adding trichlorine Change 5 parts of aluminium to be condensed, fully reaction, crystallization is obtained, it is standby；
4) by step 3) obtained crystallization carries out polycondensation reaction in being poured into reactor with 24 parts of diphenol propane, and amber is obtained Amber color solid, it is standby；
5) by 3 parts of manganous oxide 2,2 parts of lithium carbonate, 6 parts of boron nitride, 3 parts of chromium nitride, 2 parts of boron oxide and titanium nitride together Being poured into nano grinder carries out pulverization process, and nanometer powder is obtained, standby；
6) by 14 parts of silicone emulsion, 7 parts of polyamidoimide, 3 parts of ATBC, 4 parts of glass fibre and step 5) Obtained nanometer powder is stirred 20 minutes in being poured into mixer together, and paste is obtained, standby；
7) by 21 parts of polysiloxanes, 6 parts of sulfur monochloride and step 4) obtained in amber solid be poured into reactor together In, being heated to 110 DEG C carries out vulcanizing treatment 20 minutes, is subsequently adding step 6) obtained in paste, stir, be obtained Sticky jelly, it is standby；
8) by step 7) obtained in sticky jelly be poured into extrusion forming in rubber pipe extruder, you can use.
Experimental example：
Using Anti-vibration cable of the invention as experimental group, existing common cable one, existing electromagnetic screen as a control group Cover cable as a control group two, existing high heat conduction cable as a control group three is tested, and concrete outcome is as shown in the table：
Detected by 4 groups of experiments, the Anti-vibration cable of experimental group and existing common cable, electromagnetic shielded cable and High heat conduction cable is compared to electromagnetic wave shielding performance is outstanding, antidetonation shock-absorbing capacity is outstanding, electrical conductivity is high and good heat dissipation effect.
The above, specific embodiment only of the invention, but protection scope of the present invention is not limited thereto, and it is any The change or replacement expected without creative work, should all be included within the scope of the present invention.

Claims (1)

1. a kind of insulating resin of Anti-vibration cable, it is characterised in that：The insulating resin is by the poly- silica that matches by weight Alkane 20-22 parts, sulfur monochloride 4-8 parts, chlorosulfonic acid 11-13 parts, diphenol propane 23-25 parts, alchlor 4-6 parts, chlorobenzene 14- 16 parts, polyamidoimide 6-8 parts, ATBC 2-4 parts, manganous oxide 1-3 parts, silicone emulsion 13-15 parts, lithium carbonate 1-3 parts, boron nitride 5-7 parts, chromium nitride 2-4 parts, boron oxide 1-3 parts, glass fibre 3-5 parts and titanium nitride 2-4 parts composition；Including Following steps：
1) A parts and B parts are divided into by chlorobenzene 14-16 parts, it is standby；
2) by step 1) in A parts be poured into together with chlorosulfonic acid 11-13 parts in reactor, be sufficiently stirred for, it is fully reacted, Generation white crystal, is obtained white crystal, standby；
3) by step 2) obtained in white crystal and step 1) B parts be poured into together in reactor, be subsequently adding alchlor 4-6 parts is condensed, fully reaction, and crystallization is obtained, standby；
4) by step 3) obtained crystallization is poured into reactor with diphenol propane 23-25 part carries out polycondensation reaction, prepared amber Amber color solid, it is standby；
5) by manganous oxide 1-3, lithium carbonate 1-3 parts, boron nitride 5-7 parts, chromium nitride 2-4 parts, boron oxide 1-3 parts and titanium nitride 2- 4 parts are poured into nano grinder and carry out pulverization process together, and nanometer powder is obtained, standby；
6) by silicone emulsion 13-15 parts, polyamidoimide 6-8 parts, ATBC 2-4 parts, glass fibre 3-5 parts and walk It is rapid 5) obtained in nanometer powder be poured into mixer together in be stirred 20 minutes, be obtained paste, it is standby；
7) by polysiloxanes 20-22 parts, sulfur monochloride 4-8 parts and step 4) obtained in amber solid be poured into reactor together In, being heated to 110 DEG C carries out vulcanizing treatment 20 minutes, is subsequently adding step 6) obtained in paste, stir, be obtained Sticky jelly, it is standby；
8) by step 7) obtained in sticky jelly be poured into extrusion forming in rubber pipe extruder, you can use.
CN201710070722.8A 2015-11-10 2015-11-10 A kind of insulating resin of Anti-vibration cable Withdrawn CN106832941A (en)

Priority Applications (1)

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CN106847399A (en) 2017-06-13
CN106683767A (en) 2017-05-17
CN105261416B (en) 2017-05-03
CN106782818A (en) 2017-05-31
CN106803445A (en) 2017-06-06

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