CN106832726A - A kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox - Google Patents
A kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox Download PDFInfo
- Publication number
- CN106832726A CN106832726A CN201710023676.6A CN201710023676A CN106832726A CN 106832726 A CN106832726 A CN 106832726A CN 201710023676 A CN201710023676 A CN 201710023676A CN 106832726 A CN106832726 A CN 106832726A
- Authority
- CN
- China
- Prior art keywords
- hips
- inner container
- icebox
- materials
- ice crystal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
Abstract
The invention discloses a kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox, including following weight percent composition：Matrix HIPS materials 48~62%；Mica 10~50%；Compatilizer 1~20%；Nucleator 0.5~8%, other compositions 0.3~10%, selected matrix HIPS materials are the general HIPS materials of inner container of icebox, like that ACE Semi HIPS 1175, Dao Daer HIPS 8265, platform HIPS 8250, Chevron HIPS D6007, strange U.S. HIPS PH 88, Samsung HIPS HG 1760S, bright and beautiful lake HIPS HI 4450PG, one or more in the Japanese grades of Asahi Chemical Industry HIPS 408.Modified HIPS materials of the present invention have glossiness higher, the characteristic of ice crystal effect, can well reflect light in refrigerator, and the taste quality of lifting inner container of icebox, reaches national wastewater discharge standard well, meets actual operation requirements.
Description
Technical field
The present invention relates to a kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox, belong to macromolecular material
Technical field.
Background technology
Current refrigerator liner material is mainly ABS and HIPS materials, and ABS plate glossiness is high, durability and chemical resistance
Can preferably, and it has the features such as wear-resistant, mechanical performance is high, but it is only applicable to pentamethylene foaming system.In polynary foaming
In system, the liner cracking phenomenon of ABS materials is serious, and cracking ratio is up to more than 95%, HIPS sheet materials by PE/PS alloy materials
Material it is compound, in can be used on polynary foaming system, but the surface gloss/photo sensitivity of HIPS sheet materials is poor compared to ABS plate.
The method that current industry is used is to be combined superficial layer of the bloom HIPS materials as inner container of icebox, surface light again in plate surface
Although damp degree is slightly improved, photo sensitivity（Taste）Still have much room for improvement.
For problem above, the present invention is designed, using mica to height from macromolecular material key property by being formulated
Gloss HIPS materials carry out chemical modification, grope to develop a kind of HIPS modified materials with high glaze ice crystal effect, can be very well
Reflection refrigerator in light, well lifting inner container of icebox taste quality.
The content of the invention
The present invention is exactly in view of the shortcomings of the prior art, there is provided a kind of special high glaze ice crystal effect of inner container of icebox
HIPS modified materials, this modified HIPS material has glossiness higher, the characteristic of ice crystal effect, can reflect in refrigerator well
Light, the taste quality of lifting inner container of icebox, reaches national wastewater discharge standard well, meets actual operation requirements.
To solve the above problems, the technical solution used in the present invention is as follows：
A kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox, specifically include following steps：
Matrix HIPS materials 48~62%
Mica 3~20%
Compatilizer 1~20%
Nucleator 0.5~8%
Other compositions 0.3~10%,
Selected matrix HIPS materials are the general HIPS materials of inner container of icebox, like that ACE Semi HIPS-1175, Dao Daer HIPS-
8265, platform HIPS-8250, Chevron HIPS-D6007, strange U.S. HIPS PH-88, Samsung HIPS HG-1760S, bright and beautiful lake HIPS
One or more in HI-4450PG, Japanese Asahi Chemical Industry HIPS-408 etc..
Used as the improvement of above-mentioned technical proposal, the mica material can be two kinds of hexagonal muscovite and phlogopite,
Wherein, the muscovite has glassy lustre, and cleavage surface is in pearly luster, is water white transparency, and transparency is 72%~89%, and thin
Piece has certain elasticity, and the phlogopite has metallic luster and semimetallic lustre, such as golden yellow, brown, light green color, black
Deng with glassy lustre, cleavage surface is in pearl or semimetallic lustre, is non-transparent material.
Used as the improvement of above-mentioned technical proposal, the compatilizer is SEB, SEBS, SBS, SIS, CPE, EVA, EPDM, SBR
One or more in, wherein, because SBS belongs to block structure, can be gathered on two-phase interface well, reduce interface
Power, improves interfacial bond intensity, promotes mica to be dispersed in PS, and SBS is this material modified optimal compatilizer, while protecting
The toughness for demonstrate,proving bloom HIPS materials is not reduced.
Used as the improvement of above-mentioned technical proposal, the nucleator can be calcium carbonate, talcum powder, thin glass dust or thin glass
One or more in pearl.
As the improvement of above-mentioned technical proposal, described other compositions also include antioxidant, lubricant, stabilizer, pigment,
The compositions such as filler, are added according to different needs.
Specifically, a kind of preparation method of the HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox is such as
Under：Matrix HIPS plastic, mica, compatilizer, nucleator, other compositions auxiliary agent are well mixed, it is then pre- in mixer high
It is high by draw ratio after mixed（L/D≥36）Double screw extruder extruding pelletization.
Note 1：The basic physical properties of modified HIPS materials of the present invention are：A, surface pencil hardness >=HB（500g）, lead to
Often reach 1H；B, notch impact strength >=10KJ/M2, usually >=13 KJ/M2；C, tensile strength >=25MPa；D, extension at break
Rate >=45%；E, melt index 0.5~10（G/10min., 200 C, 5Kg）, usual 3~5；F, glossiness >=60（60 ° of surveys
Examination）.
Modified HIPS material gained inner container of icebox is mainly characterized by more than：1., high gloss, special ice crystal reflection
Effect, abnormal appearance is exquisite；2., abrasion resistance properties are good；3., the quality grade increase of inner container of icebox, and then refrigerator integral product
Class lifting；4. the special attraction of refrigerator product, is increased.
Note 2：Modified bloom HIPS raw materials involved in the present invention, must fully dry, drying temperature before for plate squeezing
80~95 DEG C, be reinforcing drying effect, is preferably vacuum dried, and due to the addition of mica, machine and die head will after extrusion board
Clean up, it is to avoid subsequent product is impacted.
Compared with prior art, implementation result of the invention is as follows for the present invention：
A kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox of the present invention, by the modified PS of mica,
Can be used for the special raw material of inner container of icebox, it can also be used to other decoration component raw material, such as glass shelf panel in refrigerator,
Lampshade etc.；By the modified PS of mica, to the light of refrigerator inside, indoor light has certain hexagonal mica in material
Reflection effect, improves the overall quality taste of inner container of icebox, and then improves the quality of refrigerator product and sample, and increases refrigerator product
New attraction；Modified HIPS materials of the invention, can meet phase according to actually used situation by adjusting each corresponding additive
The outward appearance demand answered.
Additionally, modified materials of the present invention are processed by selecting suitable mica material to be modified PS, originally change
Property HIPS materials there is glossiness higher, the characteristic of ice crystal effect, can well reflect light in refrigerator, ice is lifted well
The taste quality of case inner bag；This modified HIPS material is made up of PS+ micas+compatilizer+other compositions, is premixed in mixer high
It is high by draw ratio afterwards（L/D≥36）Double screw extruder extruding pelletization form；The characteristics of this modified HIPS material is that both had
There is the characteristic of high gloss, while refrigerator inside, indoor light can be reflected, with good ice crystal effect, greatly carry
Rise the quality taste of inner container of icebox, and then lift the overall quality taste of refrigerator, can as inner container of icebox superficial layer PP Pipe Compound,
It is also used as the PP Pipe Compound of other decorative effect components of refrigerator, such as shelf panel, refrigerator lampshade etc.；Can be transparent material,
Can be nontransparent material to it.
Specific embodiment
Illustrate present disclosure below in conjunction with specific embodiments.
Embodiment 1
The inner bag surface PP Pipe Compound of the transparent high glaze ice crystal effect of refrigerator
62 parts of HIPS-1180,8 parts of muscovites, 15 parts of SBS4303,7 parts of KN4010 are weighed, 8 parts other auxiliary agents will
SBS1301 and KN4010 is added in batch mixer, and after being sufficiently mixed uniformly, then HIPS, muscovite, other auxiliary agents are added and mixed, and are adopted
Granulated with twin-screw extruder in the same direction, obtain the special HIPS modified materials of inner bag of transparent high glaze ice crystal effect.
The present invention is modified PS by mica, can be used for the special raw material of inner container of icebox, it can also be used in refrigerator other
Decoration component raw material, such as glass shelf panel, lampshade etc.；By the modified PS of mica, hexagonal mica is to refrigerator in material
Internal light, indoor light has certain reflection effect, improves the overall quality taste of inner container of icebox, and then improve ice
The quality taste of case product, increases the new attraction of refrigerator product；Modified HIPS materials of the invention, can be according to actually used feelings
Condition, corresponding outward appearance demand is met by adjusting each corresponding additive.
Embodiment 2
White high glaze ice crystal effect inner container of icebox PP Pipe Compound.
48 parts of HIPS-888G, 12 parts of muscovites, 18 parts of SBS792,10 parts of KN4010,12 parts of titanium dioxides are weighed, will
SBS4303 and KN4010 is added in batch mixer, and after being sufficiently mixed uniformly, then HIPS, muscovite, titanium dioxide are added and mixed, and are passed through
Twin-screw extruder extrusion in the same direction, pelletizing, obtain the special HIPS modified materials of white high glaze ice crystal effect, dry, packaging.
The present invention is modified PS by mica, can be used for the special raw material of inner container of icebox, it can also be used in refrigerator other
Decoration component raw material, such as glass shelf panel, lampshade etc.；By the modified PS of mica, hexagonal mica is to refrigerator in material
Internal light, indoor light has certain reflection effect, improves the overall quality taste of inner container of icebox, and then improve ice
The quality taste of case product, increases the new attraction of refrigerator product；Modified HIPS materials of the invention, can be according to actually used feelings
Condition, corresponding outward appearance demand is met by adjusting each corresponding additive.
Embodiment 3
Golden inner container of icebox PP Pipe Compound
By HIPS-82345, phlogopite, SBS1301, KG16C, brightener and other auxiliary agents according to 53：15：15：7：7：3（Quality
Than）Batch mixer mixing is added, is granulated with parallel dual-screw extruding machine after being well mixed, obtain that there is golden high glaze ice crystal effect
PS modified materials.
The present invention is modified PS by mica, can be used for the special raw material of inner container of icebox, it can also be used in refrigerator other
Decoration component raw material, such as glass shelf panel, lampshade etc.；By the modified PS of mica, hexagonal mica is to refrigerator in material
Internal light, indoor light has certain reflection effect, improves the overall quality taste of inner container of icebox, and then improve ice
The quality taste of case product, increases the new attraction of refrigerator product；Modified HIPS materials of the invention, can be according to actually used feelings
Condition, corresponding outward appearance demand is met by adjusting each corresponding additive.
Embodiment 4
Golden yellow inner container of icebox PP Pipe Compound
By HIPS-1180, phlogopite, SBS792, KG16C, brightener and other auxiliary agents according to 60：9：13：7：10：1（Quality
Than）Batch mixer mixing is added, is granulated with parallel dual-screw extruding machine after being well mixed, obtain that there is golden yellow high glaze ice crystal effect
The PS modified materials of fruit.
The present invention is modified PS by mica, can be used for the special raw material of inner container of icebox, it can also be used in refrigerator other
Decoration component raw material, such as glass shelf panel, lampshade etc.；By the modified PS of mica, hexagonal mica is to refrigerator in material
Internal light, indoor light has certain reflection effect, improves the overall quality taste of inner container of icebox, and then improve ice
The quality taste of case product, increases the new attraction of refrigerator product；Modified HIPS materials of the invention, can be according to actually used feelings
Condition, corresponding outward appearance demand is met by adjusting each corresponding additive.
Described in comprehensive 1,2,3,4：Modified materials of the present invention are added by selecting suitable mica material to be modified PS
Work is formed, and this modified HIPS material has glossiness higher, the characteristic of ice crystal effect, can well reflect light in refrigerator,
The taste quality of inner container of icebox is lifted well；This modified HIPS material is made up of PS+ micas+compatilizer+other compositions, in height
It is high by draw ratio after being premixed in mixer（L/D≥36）Double screw extruder extruding pelletization form；This modified HIPS material
The characteristics of be both characteristics with high gloss, while refrigerator inside, indoor light can be reflected, with good ice crystal effect
Really, the greatly quality taste of lifting inner container of icebox, and then the overall quality taste of refrigerator is lifted, can be as inner container of icebox table
Surface layer PP Pipe Compound, it is also possible to the PP Pipe Compound as other decorative effect components of refrigerator, such as shelf panel, refrigerator lampshade etc.；Can be with
It is transparent material, it is also possible to be nontransparent material to it.
Note 1：The basic physical properties of modified HIPS materials of the present invention are：A, surface pencil hardness >=HB（500g）, lead to
Often reach 1H；B, notch impact strength >=10KJ/M2, usually >=13 KJ/M2；C, tensile strength >=25MPa；D, extension at break
Rate >=45%；E, melt index 0.5~10（G/10min., 200 C, 5Kg）, usual 3~5；F, glossiness >=60（60 ° of surveys
Examination）.
Modified HIPS material gained inner container of icebox is mainly characterized by more than：1., high gloss, special ice crystal reflection
Effect, abnormal appearance is exquisite；2., abrasion resistance properties are good；3., the quality grade increase of inner container of icebox, and then refrigerator integral product
Class lifting；4. the special attraction of refrigerator product, is increased.
Note 2：Modified bloom HIPS raw materials involved in the present invention, must fully dry, drying temperature before for plate squeezing
80~95 DEG C, be reinforcing drying effect, is preferably vacuum dried, and due to the addition of mica, machine and die head will after extrusion board
Clean up, it is to avoid subsequent product is impacted.
Above content is detailed description made for the present invention in conjunction with specific embodiments, it is impossible to assert that the present invention is specific real
Apply and be only limitted to these explanations.For those skilled in the art, before present inventive concept is not departed from
Put, some simple deduction or replace can also be made, should all be considered as belonging to the scope of protection of the invention.
Claims (6)
1. HIPS modified materials of the special high glaze ice crystal effect of a kind of inner container of icebox, it is characterised in that：Specifically include following step
Suddenly：
Matrix HIPS materials 48~62%
Mica 3~20%
Compatilizer 1~20%
Nucleator 0.5~8%
Other compositions 0.3~10%,
Selected matrix HIPS materials are the general HIPS materials of inner container of icebox, like that ACE Semi HIPS-1175, Dao Daer HIPS-
8265, platform HIPS-8250, Chevron HIPS-D6007, strange U.S. HIPS PH-88, Samsung HIPS HG-1760S, bright and beautiful lake HIPS
One or more in HI-4450PG, Japanese Asahi Chemical Industry HIPS-408 etc..
2. a kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox according to claim 1, its feature exists
In：The mica material can be two kinds of hexagonal muscovite and phlogopite, wherein, the muscovite has glassy lustre,
Cleavage surface is in pearly luster, is water white transparency, and transparency is 72%~89%, and thin slice has certain elasticity, the phlogopite
There are metallic luster and semimetallic lustre, such as golden yellow, brown, light green color, black etc., with glassy lustre, cleavage surface is in pearl
Or semimetallic lustre, it is non-transparent material.
3. a kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox according to claim 1, its feature exists
In：The compatilizer is one or more in SEB, SEBS, SBS, SIS, CPE, EVA, EPDM, SBR etc., wherein, due to SBS
Belong to block structure, can be gathered on two-phase interface well, reduce interfacial tension, improve interfacial bond intensity, promote mica
It is dispersed in PS, SBS is this material modified optimal compatilizer, while ensure the toughness of bloom HIPS materials not reducing.
4. a kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox according to claim 1, its feature exists
In：The nucleator can be one or more in calcium carbonate, talcum powder, thin glass dust or micro glass beads.
5. a kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox according to claim 1, its feature exists
In：Described other compositions composition also including antioxidant, lubricant, stabilizer, pigment, filler etc., according to it is different need into
Row addition.
6. the preparation side of the HIPS modified materials of the special high glaze ice crystal effect of a kind of inner container of icebox according to claim 1-4
Method, it is characterised in that：A kind of preparation method of the HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox is as follows：
Matrix HIPS plastic, mica, compatilizer, nucleator, other compositions auxiliary agent are well mixed, after then being premixed in mixer high
It is high by draw ratio（L/D≥36）Double screw extruder extruding pelletization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710023676.6A CN106832726A (en) | 2017-01-13 | 2017-01-13 | A kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710023676.6A CN106832726A (en) | 2017-01-13 | 2017-01-13 | A kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106832726A true CN106832726A (en) | 2017-06-13 |
Family
ID=59124332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710023676.6A Pending CN106832726A (en) | 2017-01-13 | 2017-01-13 | A kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106832726A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787162A (en) * | 2009-11-12 | 2010-07-28 | 上海锦湖日丽塑料有限公司 | Aesthetical resin capable of eliminating injection-molding weld lines and preparation method thereof |
| CN101796110A (en) * | 2007-08-29 | 2010-08-04 | 沙伯基础创新塑料知识产权有限公司 | The resin combination and the method that comprise special visual effect additive |
| CN105504638A (en) * | 2016-01-14 | 2016-04-20 | 安徽联科水基材料科技有限公司 | High-gloss foaming-agent-corrosion-resistant HIPS modified material special for end cover of refrigerator door |
-
2017
- 2017-01-13 CN CN201710023676.6A patent/CN106832726A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101796110A (en) * | 2007-08-29 | 2010-08-04 | 沙伯基础创新塑料知识产权有限公司 | The resin combination and the method that comprise special visual effect additive |
| CN101787162A (en) * | 2009-11-12 | 2010-07-28 | 上海锦湖日丽塑料有限公司 | Aesthetical resin capable of eliminating injection-molding weld lines and preparation method thereof |
| CN105504638A (en) * | 2016-01-14 | 2016-04-20 | 安徽联科水基材料科技有限公司 | High-gloss foaming-agent-corrosion-resistant HIPS modified material special for end cover of refrigerator door |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101717554B (en) | Plastic profiled bar decorative layer combination material with metal-like natural texture, preparation method and application thereof | |
| CN101440189B (en) | Special color master batch for refrigerator plate and preparation thereof | |
| MY151130A (en) | Zinc oxide coated particles, compositions containing the same, and methods for making the same | |
| CN102464830A (en) | Modified polypropylene material as well as preparation method and application thereof | |
| CN101173075A (en) | Low-luster polypropylene composite material and method for producing the same | |
| CN102311627B (en) | Polycarbonate/ABS alloy, its preparation method and its application | |
| CN102492234B (en) | Production method of red mud complexed polyvinyl chloride colorized rigid plastic | |
| CN104710710A (en) | Environment-friendly PVC plastic door/window profile and preparation method thereof | |
| CN103435917B (en) | Colored terpolymer EP rubber of high rigidity adapting to microwave vulcanization and preparation method thereof | |
| CN102352077A (en) | Environment-friendly aging-resistant polyvinyl chloride (PVC) section | |
| CN103160055A (en) | Outdoor ASA / PVC-M co-extrusion pipe compositions and preparation technology thereof | |
| CN104629184A (en) | Composite material containing polybutylene alloy and preparation method thereof | |
| CN105882094A (en) | Solar panel high-temperature-resistant anti-ultraviolet self-adhesive film | |
| CN104788838A (en) | Master batch with functions of toughening, chemical corrosion resistance and color matching and preparation method of master batch | |
| CN102464834A (en) | High-impact resistance and high-brightness acrylonitrile-styrene-acrylate copolymer (ASA) alloy material | |
| CN105754173B (en) | A kind of method that inexpensive, high efficiency is directly prepared rubber compound by desulfurization powder | |
| CN102731921A (en) | Weatherproof polymer alloy used for replacing ABS | |
| CN111057385A (en) | Super-wear-resistant wood-plastic co-extrusion composite material and preparation method thereof | |
| CN102690474A (en) | Weather-resistant coloured coextrusion special paint with metal decorating effect and preparation method thereof | |
| CN105969109A (en) | Super-weather-resistant polyester type powder coating and preparation method thereof | |
| CN110219434A (en) | A kind of TPU stone plastic floor of high abrasion and preparation method thereof | |
| CN106987079A (en) | A kind of low gloss for thin-walled automobile door plate, inexpensive PP composite material and preparation method thereof | |
| CN101781415A (en) | Styrene butadiene rubber sponge | |
| CN105175978A (en) | Toughening functional masterbatch of PS materials and preparation technology thereof | |
| CN106832726A (en) | A kind of HIPS modified materials of the special high glaze ice crystal effect of inner container of icebox |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170613 |
|
| RJ01 | Rejection of invention patent application after publication |