CN106832689A - A kind of preparation method of acceptable packaging material - Google Patents
A kind of preparation method of acceptable packaging material Download PDFInfo
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- CN106832689A CN106832689A CN201611078795.3A CN201611078795A CN106832689A CN 106832689 A CN106832689 A CN 106832689A CN 201611078795 A CN201611078795 A CN 201611078795A CN 106832689 A CN106832689 A CN 106832689A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/08—Homopolymers or copolymers of vinylidene chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7246—Water vapor barrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/80—Medical packaging
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/08—Homopolymers or copolymers of vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2427/08—Homopolymers or copolymers of vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/02—Applications for biomedical use
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of preparation method of acceptable packaging material, comprise the following steps:(1) melting is heated after mixing medicine or food-grade polyvinylidene chloride (PVDC), ethylene propylene copolymer, thereafter carboxymethylcellulose calcium is added, gypsum is added after being well mixed to three, carry out high shear agitation, stir speed (S.S.) is reduced again, polyvinylpyrrolidone and dibutyl hydroxy toluene are added, uniform and natural cooling is again stirring for, pre-composition is obtained;(2) pre-composition that step (1) is obtained is coextruded with metallocene PE, is shaped to membranaceous;(3) film layer for obtaining step (2) is combined by tack coat with aluminium foil layer, that is, obtain the acceptable packaging material.Packaging material property obtained in of the invention is homogeneous, stabilization, and the wet, choke of resistance, oxidation proof propertiess are excellent, and medicine can be deposited under hygrothermal environment for a long time, while the good processability of packaging, is molded difficulty low.
Description
Technical field
The present invention relates to the technical field of acceptable packaging material, the technical field of more particularly to aluminum-plastic packaged material.
Background technology
Aluminium-plastic bubble plate packing is widely used in the packaging of medicine tablet, capsule, and this based packaging material leads in the prior art
It is commonly present barrier property not good enough, particularly hinders that wet, gas barrier properties are not ideal, causes medicine to occur rotten showing in storage
As.
The content of the invention
It is a kind of with the acceptable packaging material for efficiently hindering wet, choke, oxidation proof propertiess it is an object of the invention to propose
Preparation method.
Technical scheme is as follows:
A kind of preparation method of acceptable packaging material, comprises the following steps:
(1) melting is heated after mixing medicine or food-grade polyvinylidene chloride (PVDC), ethylene-propylene copolymer, and
Carboxymethylcellulose calcium is added under stirring, it is well mixed to three, gypsum is added in its backward fused mass, cut at a high speed
Stirring is cut, then reduces stir speed (S.S.), to polyvinylpyrrolidone and dibutyl hydroxy toluene is added in mixture, be again stirring for
Even and natural cooling, obtains pre-composition;
(2) pre-composition that step (1) is obtained is coextruded with metallocene PE, is shaped to membranaceous;
(3) film layer for obtaining step (2) is combined by tack coat with aluminium foil layer, that is, obtain the acceptable packaging material.
Preferably:The pre-composition in parts by mass, including 15~20 parts of polyvinylidene chloride, ethylene-propylene copolymer
3~5 parts of thing, 1~1.5 part of carboxymethylcellulose calcium, 0.8~1.2 part of polyvinylpyrrolidone, dibutyl hydroxy toluene 0.1~0.3
Part, 0.5~1 part of gypsum.
It is also preferred that:In parts by mass, the pre-composition in parts by mass, including gathers inclined two chloroethene to the pre-composition
15 parts of alkene, 3 parts of ethylene-propylene copolymer, 1.2 parts of carboxymethylcellulose calcium, 1.0 parts of polyvinylpyrrolidone, butylated hydroxy-a
0.2 part of benzene, 0.8 part of gypsum.
Obtained packaging material property of the invention is homogeneous, stabilization, can be used for the packaging of the formulations such as tablet, pill, capsule, hinders
Wet, choke, oxidation proof propertiess are excellent, and medicine can be deposited under hygrothermal environment for a long time, while the good processability of packaging, shaping hardly possible
Degree is low.
Specific embodiment
Embodiment 1
(1) will be heated after medicine or 15 parts of food-grade polyvinylidene chloride (PVDC), 3 parts of mixing of ethylene-propylene copolymer
Melting, and 1 part of carboxymethylcellulose calcium is added under stirring, it is well mixed to three, add gypsum in its backward fused mass
0.5 part, high shear agitation is carried out, then reduce stir speed (S.S.), to addition 0.8 part of polyvinylpyrrolidone and two fourths in mixture
0.1 part of base hydroxy-methylbenzene, is again stirring for uniform and natural cooling, obtains pre-composition;
(2) pre-composition that step (1) is obtained is coextruded with metallocene PE, is shaped to membranaceous;
(3) film layer for obtaining step (2) is combined by tack coat with aluminium foil layer, that is, obtain the acceptable packaging material.
Embodiment 2
(1) will be heated after medicine or 20 parts of food-grade polyvinylidene chloride (PVDC), 5 parts of mixing of ethylene-propylene copolymer
Melting, and 1.5 parts of carboxymethylcellulose calcium is added under stirring, it is well mixed to three, add stone in its backward fused mass
1 part of cream, carries out high shear agitation, then reduces stir speed (S.S.), to addition 1.2 parts of polyvinylpyrrolidone and two fourths in mixture
0.3 part of base hydroxy-methylbenzene, is again stirring for uniform and natural cooling, obtains pre-composition;
(2) pre-composition that step (1) is obtained is coextruded with metallocene PE, is shaped to membranaceous;
(3) film layer for obtaining step (2) is combined by tack coat with aluminium foil layer, that is, obtain the acceptable packaging material.
Embodiment 3
(1) will be heated after medicine or 15 parts of food-grade polyvinylidene chloride (PVDC), 3 parts of mixing of ethylene-propylene copolymer
Melting, and 1.2 parts of carboxymethylcellulose calcium is added under stirring, it is well mixed to three, add stone in its backward fused mass
0.8 part of cream, carries out high shear agitation, then reduces stir speed (S.S.), to adding 1.0 parts of polyvinylpyrrolidone and two in mixture
0.2 part of butylated hydroxytoluene, is again stirring for uniform and natural cooling, obtains pre-composition;
(2) pre-composition that step (1) is obtained is coextruded with metallocene PE, is shaped to membranaceous;
(3) film layer for obtaining step (2) is combined by tack coat with aluminium foil layer, that is, obtain the acceptable packaging material.
Claims (3)
1. a kind of preparation method of acceptable packaging material, it is characterised in that:Comprise the following steps:
(1) melting is heated after mixing medicine or food-grade polyvinylidene chloride (PVDC), ethylene-propylene copolymer, and is being stirred
Mix and add carboxymethylcellulose calcium under state, it is well mixed to three, gypsum is added in its backward fused mass, carry out high speed shear and stir
Mix, then reduce stir speed (S.S.), to polyvinylpyrrolidone and dibutyl hydroxy toluene is added in mixture, be again stirring for uniformly simultaneously
Natural cooling, obtains pre-composition;
(2) pre-composition that step (1) is obtained is coextruded with metallocene PE, is shaped to membranaceous;
(3) film layer for obtaining step (2) is combined by tack coat with aluminium foil layer, that is, obtain the acceptable packaging material.
2. the preparation method of acceptable packaging material according to claim 1, it is characterised in that:The pre-composition presses mass parts
Meter, including 15~20 parts of polyvinylidene chloride, 3~5 parts of ethylene-propylene copolymer, 1~1.5 part of carboxymethylcellulose calcium, polyethylene
0.8~1.2 part of pyrrolidones, 0.1~0.3 part of dibutyl hydroxy toluene, 0.5~1 part of gypsum.
3. the preparation method of acceptable packaging material according to claim 1, it is characterised in that:The pre-composition presses mass parts
Meter, including 15 parts of polyvinylidene chloride, 3 parts of ethylene-propylene copolymer, 1.2 parts of carboxymethylcellulose calcium, polyvinylpyrrolidone
1.0 parts, 0.2 part of dibutyl hydroxy toluene, 0.8 part of gypsum.
Priority Applications (1)
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CN201611078795.3A CN106832689A (en) | 2016-11-30 | 2016-11-30 | A kind of preparation method of acceptable packaging material |
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CN201611078795.3A CN106832689A (en) | 2016-11-30 | 2016-11-30 | A kind of preparation method of acceptable packaging material |
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CN106832689A true CN106832689A (en) | 2017-06-13 |
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CN201611078795.3A Pending CN106832689A (en) | 2016-11-30 | 2016-11-30 | A kind of preparation method of acceptable packaging material |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102001486A (en) * | 2009-08-28 | 2011-04-06 | 翁文桂 | Barrier-property lapped polymer film packaging material |
CN102443231A (en) * | 2011-11-07 | 2012-05-09 | 中国科学院宁波材料技术与工程研究所 | Manufacturing method of PVDC film with crystal point eliminated and barrier property improved |
CN103756095A (en) * | 2014-01-15 | 2014-04-30 | 佛山市南方包装有限公司 | High-barrier colorful plastic product capable of retarding moisture and air |
-
2016
- 2016-11-30 CN CN201611078795.3A patent/CN106832689A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102001486A (en) * | 2009-08-28 | 2011-04-06 | 翁文桂 | Barrier-property lapped polymer film packaging material |
CN102443231A (en) * | 2011-11-07 | 2012-05-09 | 中国科学院宁波材料技术与工程研究所 | Manufacturing method of PVDC film with crystal point eliminated and barrier property improved |
CN103756095A (en) * | 2014-01-15 | 2014-04-30 | 佛山市南方包装有限公司 | High-barrier colorful plastic product capable of retarding moisture and air |
Non-Patent Citations (1)
Title |
---|
骆光林: "《包装材料》", 31 December 1996, 印刷工业出版社 * |
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Application publication date: 20170613 |
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