CN106832088B - A kind of nucleocapsid water lock material and its preparation method and application - Google Patents
A kind of nucleocapsid water lock material and its preparation method and application Download PDFInfo
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- CN106832088B CN106832088B CN201710082108.3A CN201710082108A CN106832088B CN 106832088 B CN106832088 B CN 106832088B CN 201710082108 A CN201710082108 A CN 201710082108A CN 106832088 B CN106832088 B CN 106832088B
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
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- C08J2305/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
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Abstract
The invention belongs to new material technology field, and in particular to a kind of nucleocapsid water lock material and its preparation method and application;The particle diameter of nucleocapsid water lock material of the present invention is 80~160 μm, and housing is that thickness is 10~50 μm of Calcium alginate films, and nucleome is the mixture of anionic monomer and non-ionic monomer;Preparation method is:First acrylic acid and/or methacrylic acid are neutralized with sodium hydroxide solution, then acrylamide and/or hydroxy-ethyl acrylate are added, then sequentially add sodium alginate make shell agent, crosslinking agent and initiator it is well mixed after obtain reaction solution, finally reaction solution instillation profit is mutually reacted;Washing is dried to obtain product after reaction terminates;The present invention can effectively control the outer casing thickness of water lock micro-sphere material, and so as to control, the light shineization after material water suction is water-based and water lock performance, product can be widely applied to the water suction purposes of arid soil water-retaining, health care and daily aspect.
Description
Technical field
The invention belongs to new material technology field, a kind of nucleocapsid water lock material and its preparation method and application.
Background technology
High hydroscopic resin (Super Absorbent Polymer, abbreviation SAP) is a kind of suction of invention the 1960s
Water high polymer material, its primary raw material used are starch, but due to poor performance and unstable, are not valued by the people always.With
21 century rapid development of economy and the raising of people's living standard, the synthetic technology of SAP materials and application are sent out rapidly
Exhibition, raw material have been changed to acrylic acid by starch.It is developed so far, polyacrylate type high water absorption resin is that current research and production are most
A kind of synthesizing super absorbent resin, this kind of product water absorbent rate is higher, and up to more than thousand times, performance is relatively stable, thus obtains
Extensive use.
However, the super absorbent resin fat prod that acrylic acid is synthesized for main material is used at present, after generally existing water suction, by
Illumination facilitation water and cause moisture content can not locking the defects of;And the complexity of recycling design, dispersant in preparation process be present
Process.
The content of the invention
In order to solve the above problems, an object of the present invention is that the water-based energy of light shineization and water can be improved by providing one kind
The nucleocapsid water lock material of part Locking property.The present invention, by the protection of microballoon shell, is made using core-shell type water suction microballoon is prepared
Product has the water-based energy of excellent light shineization, greatly improves the moisture content Locking property after its saturation that absorbs water.
The second object of the present invention is the preparation method for providing the nucleocapsid water lock material, and this method can effectively control lock
The outer casing thickness of water micro-sphere material, so as to control the light shineization after material water suction water-based and water lock performance.
The present invention is achieved through the following technical solutions:
A kind of nucleocapsid water lock material, the particle diameter of the nucleocapsid water lock material is 80~160 μm, and housing is that thickness is 10~50
μm Calcium alginate film;The nucleome of the nucleocapsid water lock material is the mixture of anionic monomer and non-ionic monomer, in mass ratio
Calculate, anionic monomer:Non-ionic monomer is 2~4: 1.Wherein described anionic monomer is acrylic acid and/or methacrylic acid,
The non-ionic monomer is acrylamide and/or hydroxy-ethyl acrylate.Water lock material microspherulite diameter is excessive, and absorption speed is low, grain
Footpath is too small, the water conservation being unfavorable under pressure;For microballoon outer casing thickness, the usual blocked up influence absorption speed of shell membrane, shell membrane crosses book,
The water-based energy of protection illuminationization is not had, it is 10~50 μm, more preferably 15~25 μm that the present invention, which controls microballoon shell thickness,.
The method for preparing the nucleocapsid water lock material, it is described to comprise the steps of:
(1), first anionic monomer is added in deionized water, neutralized under normal temperature with sodium hydroxide solution, control neutralizes
25~30 DEG C of reaction temperature, it is 55~75% to control degree of neutralization, i.e. the mol ratio of acrylic or methacrylic acid and sodium hydroxide
For 100: 55~75, neutralizer is obtained;Then non-ionic monomer is added in neutralizer, the dosage of non-ionic monomer is neutralizer
The 1~10% of quality, obtain reaction solution A;It is anionic monomer: non-ionic monomer=2~4: 1 to control monomer mass.
(2) sodium alginate 1~3%, the crosslinking agent of relative response liquid A mass ratioes, are sequentially added in above-mentioned reaction solution A
0.25~1%, initiator 0.01~0.5% and pore-foaming agent 5~20%, obtain reaction solution B;
(3) dimethicone for, taking viscosity to be 50~100mPas is placed in reactor, then adds mass percent
For 5~15% calcium chloride solution, reaction medium is made, the reaction medium is the multiphase liquid layer being made up of water layer and oil reservoir;
(4), after the profit of reaction medium in (3) is mutually layered, heating oil phase instills reaction solution B, preferably to 60~80 DEG C
The reaction solution B of atomization will be instilled;
(5) after, reaction terminates, washing, desciccate, the porous nucleocapsid water lock material of pearl is obtained;The drying
Temperature is 80~130 DEG C, and drying time is 2~10h.
Wherein, reaction medium is divided into the multiphase liquid layer of water layer and oil reservoir in described (3), and upper strata is that water layer calcium chloride is water-soluble
Liquid, lower floor are oil reservoir dimethicone.To ensure that microballoon shell curing reaction is abundant, upper strata aqueous phase height of liquid layer should be greater than 5cm.
Reaction drop initially enters aqueous layer (upper strata), and the alginic acid contained by reaction solution sends cross-linking reaction with calcium chloride and solidified immediately
Spherical shell is formed, after microballoon is lowered into oil reservoir (lower floor) by gravity, oil phase can prevent the adhesion between spherical shell, so as to there is abundance
Time makes the reaction solution transmission polymerisation inside microballoon solidify and form water uptake core material.Reaction drop is introduced into aqueous layer, shape
Into solidification shell, enter oil phase after forming microballoon state particle, under oil phase peptizaiton and insulation effect, be enclosed in anti-in shell
Liquid is answered to continue to react.
It is preferred that the crosslinking agent is polynary pi-allyl, diolefin crosslinking agent or both compound.
It is preferred that the polynary allyl based cross-linker is allylation starch, allylation cellulose, tetraallyl epoxide
Ethane;Diolefin crosslinking agent is N, N '-methylene-bisacrylamide.
It is preferred that the initiator is azo-initiator, persulfuric acid salt initiator or both compound, wherein compounding
In thing, if compound, the control of its mass ratio is azo-initiator: persulfuric acid salt initiator is 3~5: 1.It is it is preferred that even
Nitrogen class is the isobutyl imidazole hydrochloride of azo two, and persulfate is potassium peroxydisulfate or/and ammonium persulfate.
It is preferred that the pore-foaming agent is one in sodium acid carbonate, saleratus, carbamide peroxide, urea, ethanol, acetone
Kind or several mixtures.It is preferred that mix compound, can pore-foaming agent to be summarized as three class a be one kind in sodium acid carbonate, saleratus
Or two kinds, b is urea or carbamide peroxide, and c is the compound of one or both of ethanol, acetone.Further preferred a: b: c
Mass ratio is 1: 3: 2 or 1: 3: 1 or 1: 2: 2 or 1: 2: 3.The pore-foaming agent of the present invention is ternary mixture, it is desirable to not only Ying Keyu
Carboxyl reaction itself can decompose generation gas, and need to water at 100 DEG C or so generated reactive gas, while should be easy to wave
Hair and not with monomer reaction.Pore-foaming agent can pass through caused gas and form foam with carboxylic acid reaction or being thermally decomposed to generate gas
Gel is so as to pore.
Coloring agent, aromatic, fertilizer, magnetisable material etc. can be added in pore-foaming agent adition process simultaneously.
It is preferred that filter vat moving up and down is installed in (3) in reactor, filter vat sieve mesh number is 80~
100 mesh.Residence time of the microballoon in water layer and oil reservoir is controlled by controlling the position of filter vat.
It is preferred that be set forth in reaction solution B is added dropwise in reaction medium by orifice device, the size droplet diameter is controlled to be
0.5~3mm.
By sodium alginate, the rapid curing in the case where calcium chloride crosslinked action forms Calcium alginate film forms shell to the present invention,
The shell has certain elasticity and hardness.The solidification of sodium alginate makes granulation process be completed before polymerisation, and makes
Microballoon forms the Calcium alginate film with certain elasticity with hardness after grain;Shell is entered once being formed by the reaction solution that shell wraps up
Enter after oil phase without by stirring-granulating and will not adhesion it is blocking, therefore without using suspension stabilizer.Calcium alginate is thin
Shell membrane can also make microballoon still keep certain intensity after absorbing water, and greatly improve the water-based energy of illuminationization and the water-based energy of one-way lock, expand
Big application.The present invention uses a variety of pore-foaming agents, is used in combination especially with a variety of pore-foaming agents, and the cause of three kinds of pore-foaming agents
Hole mechanism is different, compared to the effect of single pore-foaming agent, the pore structure size reasonable obtained by the present invention, is evenly distributed, can
Ensure the quantity of pore structure.Filter vat is installed, reaction can directly lift filter vat receipts after terminating in the reaction unit in the present invention
Collect product, easy to operate, safety.
In a word, nucleocapsid water lock material of the invention not only high water absorption, while there is the water-based energy of excellent light shineization, significantly
Improve the moisture content Locking property after its saturation that absorbs water;Especially solve the problems, such as resin after absorbing water by photochemical water.
Brief description of the drawings
Fig. 1 is the external form figure of product of the present invention.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, is managed to help those skilled in the art
The solution present invention.
Embodiment 1
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 65%.Then add
24.02g hydroxy-ethyl acrylates.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:2g, tetraallyl epoxide ethane:0.48g, azo
Two isobutyl imidazole hydrochlorides:0.2g, potassium peroxydisulfate:0.05g, sodium acid carbonate:1.6g, urea:4.8g, ethanol:3.2g;Mixing is equal
It is even standby.
3. the dimethicone that 300g viscosity is 100mPas is taken, by the calcium chloride solution that 100g mass fractions are 10%
It is poured slowly into dimethicone.After profit layering, reaction solution is added dropwise to 70 DEG C in heating oil phase.After reaction terminates, lift
Filter vat collects product, is washed three times with ethyl acetate, is then placed into drying 8h in 85 DEG C of constant temperature blast drying oven, finally
Obtain hud typed porous water-absorbing microballoon.
Embodiment 2
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 65%.Then add
24.02g acrylamides.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:2g, tetraallyl epoxide ethane:0.48g, azo
Two isobutyl imidazole hydrochlorides:0.2g, ammonium persulfate:0.05g, sodium acid carbonate:1.6g, urea:4.8g, ethanol:3.2g;Mixing is equal
It is even standby.
3. the dimethicone that 300g viscosity is 100mPas is taken, by the calcium chloride solution that 100g mass fractions are 10%
It is poured slowly into dimethicone.After profit layering, reaction solution is added dropwise to 70 DEG C in heating oil phase.After reaction terminates, lift
Filter vat collects product, is washed three times with ethyl acetate, is then placed into drying 8h in 85 DEG C of constant temperature blast drying oven, finally
Obtain hud typed porous water-absorbing microballoon.
Embodiment 3
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 65%.Then add
24.02g acrylamides.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:2g, tetraallyl epoxide ethane:0.48g, azo
Two isobutyl imidazole hydrochlorides:0.2g, potassium peroxydisulfate:0.05g, saleratus:1.6g, urea:4.8g, acetone:3.2g;Mixing is equal
It is even standby.
3. the dimethicone that 300g viscosity is 100mPas is taken, by the calcium chloride solution that 100g mass fractions are 10%
It is poured slowly into dimethicone.After profit layering, reaction solution is added dropwise to 70 DEG C in heating oil phase.After reaction terminates, lift
Filter vat collects product, is washed three times with ethyl acetate, is then placed into drying 8h in 85 DEG C of constant temperature blast drying oven, finally
Obtain hud typed porous water-absorbing microballoon.
Embodiment 4
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 65%.Then add
24.02g acrylamides.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:2g, tetraallyl epoxide ethane:0.24g, N,
N '-methylene-bisacrylamide 0.24g, the isobutyl imidazole hydrochloride of azo two:0.2g, potassium peroxydisulfate:0.05g, saleratus:
1.6g, urea:4.8g, ethanol:3.2g;It is well mixed standby.
3. the dimethicone that 300g viscosity is 100mPas is taken, by the calcium chloride solution that 100g mass fractions are 15%
It is poured slowly into dimethicone.After profit layering, reaction solution is added dropwise to 70 DEG C in heating oil phase.After reaction terminates, lift
Filter vat collects product, is washed three times with ethyl acetate, is then placed into drying 8h in 85 DEG C of constant temperature blast drying oven, finally
Obtain hud typed porous water-absorbing microballoon.
Embodiment 5
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 65%.Then add
12.01g acrylamides, 12.01g hydroxy-ethyl acrylates.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:2g, tetraallyl epoxide ethane:0.24g, N,
N '-methylene-bisacrylamide 0.24g, the isobutyl imidazole hydrochloride of azo two:0.2g, potassium peroxydisulfate:0.05g, saleratus:
1.6g, urea:4.8g, ethanol:3.2g;It is well mixed standby.
3. the dimethicone that 200g viscosity is 100mPas is taken, by the calcium chloride solution that 100g mass fractions are 15%
It is poured slowly into dimethicone.After profit layering, reaction solution is added dropwise to 70 DEG C in heating oil phase.After reaction terminates, lift
Filter vat collects product, is washed three times with ethyl acetate, is then placed into drying 8h in 100 DEG C of constant temperature blast drying oven, most
Hud typed porous water-absorbing microballoon is obtained eventually.
Embodiment 6
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 65%.Then add
12.01g acrylamides, 12.01g hydroxy-ethyl acrylates.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:2g, N, N '-methylene-bisacrylamide 0.48g,
The isobutyl imidazole hydrochloride of azo two:0.2g, potassium peroxydisulfate:0.05g, sodium acid carbonate:1.6g, urea:4.8g, ethanol:3.2g;It is mixed
Close uniformly standby.
3. taking the dimethicone that 200g viscosity is 50mPas, the calcium chloride solution that 100g mass fractions are 15% is delayed
Slowly pour into dimethicone.After profit layering, reaction solution is added dropwise to 70 DEG C in heating oil phase.After reaction terminates, lifted
Lauter tub collects product, is washed three times with ethyl acetate, is then placed into drying 8h in 100 DEG C of constant temperature blast drying oven, finally
Obtain hud typed porous water-absorbing microballoon.
Embodiment 7
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 55%.Then add
20.04g hydroxy-ethyl acrylates.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:1g, tetraallyl epoxide ethane:0.25g, azo
Two isobutyl imidazole hydrochlorides:0.05g, carbamide peroxide:5g;It is well mixed standby.
3. the dimethicone that 300g viscosity is 100mPas is taken, by the calcium chloride solution that 100g mass fractions are 10%
It is poured slowly into dimethicone.After profit layering, reaction solution is added dropwise to 60 DEG C in heating oil phase.After reaction terminates, lift
Filter vat collects product, is washed three times with ethyl acetate, is then placed into drying 6h in 90 DEG C of constant temperature blast drying oven, finally
Obtain hud typed porous water-absorbing microballoon.
Embodiment 8
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 60%.Then add
14.01g acrylamides, 14.01g hydroxy-ethyl acrylates.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:2g, tetraallyl epoxide ethane:0.50g, N,
N '-methylene-bisacrylamide 5g, potassium peroxydisulfate:0.35g, saleratus:16g;It is well mixed standby.
3. the dimethicone that 200g viscosity is 100mPas is taken, by the calcium chloride solution that 100g mass fractions are 15%
It is poured slowly into dimethicone.After profit layering, reaction solution is added dropwise to 80 DEG C in heating oil phase.After reaction terminates, lift
Filter vat collects product, is washed three times with ethyl acetate, is then placed into drying 10h in 110 DEG C of constant temperature blast drying oven, most
Hud typed porous water-absorbing microballoon is obtained eventually.
Embodiment 9
The preparation method of nucleocapsid water lock material:
1. 72.06g acrylic acid is added in 38.88g deionized waters, it is well mixed, is with mass fraction under normal temperature
30% sodium hydroxide solution (sodium hydroxide 26g+ deionized water 60.67g) is neutralized to degree of neutralization as 75%.Then add
12.01g acrylamides, 12.01g hydroxy-ethyl acrylates.
2. liquid to be neutralized is cooled to room temperature, sodium alginate is sequentially added:2g, N, N '-methylene-bisacrylamide 0.62g,
The isobutyl imidazole hydrochloride of azo two:0.2g, potassium peroxydisulfate:0.15g, sodium acid carbonate:2.6g, urea:4.8g, ethanol:6.2g;It is mixed
Close uniformly standby.
3. taking the dimethicone that 200g viscosity is 50mPas, the calcium chloride solution that 100g mass fractions are 15% is delayed
Slowly pour into dimethicone.After profit layering, reaction solution is added dropwise to 80 DEG C in heating oil phase.After reaction terminates, lifted
Lauter tub collects product, is washed three times with ethyl acetate, is then placed into drying 5h in 130 DEG C of constant temperature blast drying oven, finally
Obtain hud typed porous water-absorbing microballoon.
Above-described embodiment, simply presently preferred embodiments of the present invention, is not used for limiting the scope of the present invention, therefore all with this
The equivalent change or modification that feature and principle described in invention claim are done, all should be included in scope of the invention as claimed
Within.
The nucleocapsid water lock material of the present invention is tested, as a result see the table below 1.
From table, the distilled water water lock amount of nucleocapsid water lock material is significantly greater than prior art in the present invention, wherein fast light
According to water time minimum 60h is changed, also it is far longer than existing SAP products (its illumination 36h after the saturation that absorbs water).
Claims (10)
1. a kind of nucleocapsid water lock material, it is characterised in that the particle diameter of the nucleocapsid water lock material is 80~160 μm, and housing is thickness
Degree is 10~50 μm of Calcium alginate films;The nucleome of the nucleocapsid water lock material is the mixing of anionic monomer and non-ionic monomer
Thing, calculate in mass ratio, anionic monomer: non-ionic monomer is 2~4: 1;The anionic monomer is acrylic acid and/or methyl
Acrylic acid, the non-ionic monomer are acrylamide and/or hydroxy-ethyl acrylate.
2. prepare the method for nucleocapsid water lock material described in claim 1, it is characterised in that comprise the steps of:
(1), first anionic monomer is added in deionized water, neutralized under normal temperature with sodium hydroxide solution, controls neutralization reaction
The mol ratio of 25~30 DEG C of temperature, anionic monomer and sodium hydroxide is 100: 55~75, obtains neutralizer;Then in neutralizer
Middle addition non-ionic monomer, obtains reaction solution A, and the dosage of the non-ionic monomer is the 1~10% of neutralizer quality;
(2) sodium alginate 1~3%, the crosslinking of relative response liquid A mass percents calculating, are sequentially added in above-mentioned reaction solution A
Agent 0.25~1%, initiator 0.01~0.5% and pore-foaming agent 5~20%, obtain reaction solution B;
(3), take viscosity be 50~100mPas dimethicone be placed in reactor, then add mass percent be 5~
15% calcium chloride solution, the reaction medium for the multiphase liquid layer being made up of water layer and oil reservoir is made;
(4), after the profit of reaction medium in (3) is mutually layered, heating oil phase instills reaction solution B to 60~80 DEG C;
(5) after, reaction terminates, washing, desciccate, the porous nucleocapsid water lock material of pearl is obtained;The drying temperature
For 80~130 DEG C, drying time is 2~10h.
3. the preparation method of nucleocapsid water lock material as claimed in claim 2, it is characterised in that the crosslinking agent is polynary allyl
Base, diolefin crosslinking agent or both compound.
4. the preparation method of nucleocapsid water lock material as claimed in claim 3, it is characterised in that the polynary allyl based cross-linker is
Allylation starch, allylation cellulose, tetraallyl epoxide ethane;Diolefin crosslinking agent is N, N '-methylene bisacrylamide
Acid amides.
5. the preparation method of nucleocapsid water lock material as claimed in claim 2, it is characterised in that the initiator triggers for azo
Agent, persulfuric acid salt initiator or both compound, in the compound, mass ratio control is azo-initiator: persulfuric acid
Salt initiator is 3~5: 1.
6. the preparation method of nucleocapsid water lock material as claimed in claim 5, it is characterised in that the azo is the isobutyl of azo two
Imidazole hydrochloride, persulfate are potassium peroxydisulfate or/and ammonium persulfate.
7. the preparation method of nucleocapsid water lock material as claimed in claim 2, it is characterised in that the pore-foaming agent be sodium acid carbonate,
One or more of mixtures in saleratus, carbamide peroxide, urea, ethanol, acetone.
8. the preparation method of nucleocapsid water lock material as claimed in claim 2, it is characterised in that installed in (3) in reactor
Filter vat moving up and down, filter vat sieve mesh number are 80~100 mesh.
9. the preparation method of nucleocapsid water lock material as claimed in claim 2, it is characterised in that be set forth in reaction solution B and pass through orifice
Device is added dropwise in reaction medium, and it is 0.5~3mm to control size droplet diameter.
10. the application of nucleocapsid water lock material as described in any one in claim 1-9, it is characterised in that the nucleocapsid water lock
Materials application is in the water suction purposes of arid soil water-retaining, health care and daily aspect.
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