Reclaimed water desalter and desalination process
Technical field
The invention belongs to chemical field, and in particular to a kind of reclaimed water desalter and desalination process.
Background technology
China is a country for water resources shortage, and per capita water is only ranked first 28 in the world.And due to water money
Source spatial and temporal distributions otherness is big, causes have more than 400 serious water shortage in Chinese more than 600 city, wherein than more serious water shortage
Up to 110, China's urban water shortage total amount is 6,000,000,000 m in city3.And with expanding economy, a large amount of exhaust emissions of " three wastes "
Surface water and groundwater.According to statistics, China's industrial wastewater annual emissions are up to more than 20,000,000,000 tons, if can enter industrial wastewater
Row Treated sewage reusing, will be that country and society save substantial amounts of water resource, reduce the imbalance between supply and demand of limited water resources.But it is most up to standard
Contain substantial amounts of salinity and a certain amount of organic pollution in the industrial wastewater of discharge, therefore be unsatisfactory for《Regeneration of urban sewage profit
Use urban reclaimed water water quality》(GB/T 18920-2002)The requirement of standard.
The content of the invention
Contain substantial amounts of salinity and a certain amount of organic dirt it is an object of the invention to be directed to industrial wastewater in the prior art
Contaminate the problem of thing, there is provided the industrial wastewater of qualified discharge is carried out desalination by a kind of reclaimed water desalter and desalination process, the device
With the treatment of removing organic matter, the requirement for making it meet Treated sewage reusing, for saving water resource contributes.
To realize the object of the invention, the technical solution adopted by the present invention is:A kind of reclaimed water desalter, including multimedium mistake
Filter module, active carbon filter component, hyperfiltration membrane assembly, ultrafiltration water tank, feed water by reverse osmosis pump, backwash water pump, security personnel's filtering
Device, RO reverse osmosis membrane assemblies and cleaning water tank, the more medium filter component inputs connect waste water output end, multimedium
Filter assemblies output end connects active carbon filter component, and active carbon filter component output end connection hyperfiltration membrane assembly surpasses
Filter membrane component output end connects ultrafiltration water tank, and ultrafiltration water tank output end connection cartridge filter, the feed water by reverse osmosis pump is installed
On connecting line between ultrafiltration water tank and cartridge filter, backwash water pump one end connection ultrafiltration water tank output end, the other end
Multi-medium filtering device assembly, active carbon filter component and milipore filter group are connected respectively through total output pipe and each branch line
Part;The cartridge filter output end connects RO reverse osmosis membrane assemblies, RO reverse osmosis membrane assemblies output end point two-way:Connect all the way
Water tank is cleaned in reuse water tank, all the way connection;Cleaning agent is placed with the cleaning water tank, the flushing water pump is arranged on cleaning
On water tank output pipe, and cleaning filter is installed on cleaning water tank output pipe, cleaning water tank output pipe connects respectively
Hyperfiltration membrane assembly and RO reverse osmosis membrane assemblies are connect, cleaning water tank is back to through the backwater of hyperfiltration membrane assembly and RO reverse osmosis membrane assemblies
In.
Based on above-mentioned technical proposal, the multi-medium filtering device assembly includes two or more multi-medium filterings
Device, the input of each more medium filter is connected with waste water input respectively, and the output end of each more medium filter collects
Active carbon filter component is connected afterwards.
Based on above-mentioned technical proposal, the active carbon filter component is filtered including two or more activated carbons
Device, the output end of the input of each active carbon filter respectively with multi-medium filtering device assembly is connected, the filtering of each activated carbon
The output end of device connects hyperfiltration membrane assembly after collecting.
Based on above-mentioned technical proposal, the membrane component of the hyperfiltration membrane assembly uses external-compression type PVDF material membrane components.
Based on above-mentioned technical proposal, the core filter of the cartridge filter is fusion-jet type pp silk flosses.
Based on above-mentioned technical proposal, the filter medium in the multi-medium filtering device assembly is quartz sand and anthracite, its
Middle quartz sand particle size:0.5-1mm, anthracite granule size:0.8-1.2mm, both proportion of composing are 1:1-2.
Based on above-mentioned technical proposal, the filter medium in the active carbon filter component is high iodine-containing cocoanut active charcoal,
High iodine-containing cocoanut active charcoal particle diameter is 2-4mm, iodine number more than 1000mg/L.
A kind of reclaimed water desalination process, multi-medium filtering device assembly is initially entered by the waste water after advanced treating, is being situated between more
Suspension and colloid in mass filter component in preliminary removal waste water, suspension is reduced to 5mg/L in making the water outlet after filtering
Below;Subsequently into active carbon filter component, partial organic substances in removing waste water in active carbon filter component and remaining
Chlorine, and waste water is decolourized, it is less than 0.1mg/L through the suspension in the water outlet after active carbon filter component filters;Then
Water outlet through active carbon filter component enters hyperfiltration membrane assembly, and under effect of water pressure, waste water is in hyperfiltration membrane assembly by surpassing
Filter membrane outside enters inside milipore filter, and particulate matter of the particle diameter in waste water more than 0.01 micron or solute molecule etc. are isolated in super
On filter membrane, clean water enters in milipore filter hollow pipeline, and conveys storage in ultrafiltration water tank;Clear water is divided to two in ultrafiltration water tank
Road:All the way under feed water by reverse osmosis pumping action enter cartridge filter, another road through branch line respectively control valve action under
Into multi-medium filtering device assembly, active carbon filter component and hyperfiltration membrane assembly, for multi-medium filtering device assembly, activity
Carbon filter component and hyperfiltration membrane assembly are backwashed;Enter RO reverse osmosis membrane assemblies, RO reverse osmosis through the water outlet after cartridge filter
Permeable membrane component is used to the salinity in water removal, and 400mg/L is less than through the total salinity of the water outlet after RO reverse osmosis membrane assemblies;Through RO reverse osmosis
Water outlet after permeable membrane component enters reuse water tank reuse, and is drawn on the outlet pipeline of RO reverse osmosis membrane assemblies and be partly into
Reuse water tank reuse, clear water mixes with cleaning agent in water tank is cleaned, and then cleaned water pump and cleaning filter difference are defeated
Hyperfiltration membrane assembly and RO reverse osmosis membrane assemblies are delivered to, to the effluent recycling after hyperfiltration membrane assembly and the cleaning of RO reverse osmosis membrane assemblies extremely
Cleaning water tank.
Based on above-mentioned technical proposal, the intake pressure of ultrafiltration apparatus<0.2Mpa.
Based on above-mentioned technical proposal, the intake pressure of RO reverse osmosis membrane assemblies<1.8Mpa.
The present invention possesses following beneficial effect:1. can be by COD concentration using water desalination device combination desalination process of the present invention
It is 50-400mg/L, wastewater treatment to the COD concentration of salt content 50000-20000mg/L, concentration of suspension 30-70mg/L is less than
10mg/L, salt content is less than 500mg/L, and suspension is almost 0.2. taken into full account in apparatus of the present invention running backwash and
Cleaning function, membrane module long service life, replacement frequency is low.System operation cost is low.
Brief description of the drawings
Fig. 1 is reclaimed water desalter structural representation of the present invention.
Label in figure:1- more medium filters, 2- active carbon filters, 3- hyperfiltration membrane assemblies, 4- ultrafiltration water tanks, 5- reverse osmosis
Penetrate into water pump;6- backwash water pumps, 7- cartridge filters, 8-RO reverse osmosis membrane assemblies, 9- cleaning water tanks, 10- flushing water pumps, 11-
Cleaning filter, 12- reuse water tanks.
Specific embodiment
With reference to specific embodiment and Fig. 1, the present invention will be further described, to more fully understand skill of the present invention
Art scheme.
Embodiment 1:A kind of reclaimed water desalter, referring to Fig. 1, including two more medium filters, 1, two activated carbon filterings
Device 2, hyperfiltration membrane assembly 3, ultrafiltration water tank 4, feed water by reverse osmosis pump 5, backwash water pump 6, cartridge filter 7, RO reverse osmosis membrane assemblies 8
And cleaning water tank 9, two inputs of more medium filter are connected with waste water input respectively, two more medium filters
Output end connects two inputs of active carbon filter respectively after collecting, the output end of two active carbon filters connects after collecting
Hyperfiltration membrane assembly is connect, the membrane component of hyperfiltration membrane assembly uses external-compression type PVDF material membrane components, its effect is that removal particle diameter is more than
0.01 micron particulate matter or solute molecule etc., the intake pressure of hyperfiltration membrane assembly<0.2Mpa.Hyperfiltration membrane assembly output end is divided to two
Road, connects ultrafiltration water tank all the way, and the feed water by reverse osmosis pump is arranged on the connecting line between ultrafiltration water tank and cartridge filter
On, another road connects backwash water pump, and the backwash water pump other end connects multimedium mistake respectively through total output pipe and each branch line
Filter module, active carbon filter component and hyperfiltration membrane assembly;For example:When hyperfiltration membrane assembly needs backwash, in ultrafiltration water tank
Clear water can enter inside milipore filter under the effect of backwash water pump 6, backwash is continued to it, so that milipore filter keeps clean shape
State.
Ultrafiltration water tank output end connects cartridge filter 7, and the core filter in cartridge filter is continuous for fusion-jet type pp,
Main purpose is to protect membrane component not damaged by large particulate matter.The cartridge filter output end connects RO reverse osmosis membrane groups
Part, the membrane component of RO reverse osmosis membrane assemblies uses anti-pollution reverse osmosis membrane, and material is:Aromatic polyamides, surface micropore diameter exists
Between 0.5-10nm;Operating pressure:Intake pressure<1.8Mpa, Main Function:The salinity gone in water removal, to the clearance of salinity
More than 98% is reached, the total salinity of water outlet is less than 400mg/L.
RO reverse osmosis membrane assemblies output end connects back to use water tank direct reuse all the way, and another road connection cleaning water tank is described
Be placed with cleaning agent in cleaning water tank, the flushing water pump is arranged on cleaning water tank output pipe, due to hyperfiltration membrane assembly,
RO reverse osmosis membrane assemblies are required to periodic cleaning, and cleaning water tank output pipe is respectively through controlling valve connection hyperfiltration membrane assembly and RO anti-
Permeable membrane element, is back in cleaning water tank through the backwater of hyperfiltration membrane assembly and RO reverse osmosis membrane assemblies.For in preventing rinse water
Impurity enters each membrane module, and cleaning filter is provided with cleaning water tank output pipe, to protect membrane module not by impurity
Pollution and damage.
Reclaimed water desalination process based on the present embodiment reclaimed water desalter is:Initially entered by the waste water after advanced treating
Two more medium filters, suspension and colloid in preliminary removal waste water in more medium filter, make the water outlet after filtering
Middle suspension is reduced to below 5mg/L, and two filter mediums of more medium filter are quartz sand and anthracite, wherein quartz sand
Particle diameter:0.5-1mm, anthracite granule size:0.8-1.2mm, both proportion of composing are 1:1-2.Subsequently into two activated carbon filterings
Device, chlorine residue, CODcr, Cd2+, CrO42- in removing waste water in active carbon filter etc., and waste water is decolourized.Through place
Suspension is less than 0.1mg/L in waste water after reason, and COD clearances are about 20%-30%, and free chlorine is less than 0.1mg/L.Activated carbon is filtered
Filter medium in device is high iodine-containing cocoanut active charcoal, and high iodine-containing cocoanut active charcoal particle diameter is 2-4mm, iodine number more than 1000mg/
L。
Then active carbon filter water outlet enters hyperfiltration membrane assembly, and under effect of water pressure, waste water is in hyperfiltration membrane assembly
Entered inside milipore filter by milipore filter outside, particulate matter of the particle diameter in waste water more than 0.01 micron or solute molecule etc. are isolated
On milipore filter, clean water enters in milipore filter hollow pipeline, hyperfiltration membrane assembly intake pressure<0.2Mpa, through treatment after, go out
Aqueous suspension is nearly no detectable, and water outlet COD is about 10mg/L.
Through in water outlet conveying storage to the ultrafiltration water tank of hyperfiltration membrane assembly;Clear water point two-way in ultrafiltration water tank:Exist all the way
Enter cartridge filter under feed water by reverse osmosis pumping action, another road enters multimedium in the case where valve action is controlled respectively through branch line
Filter assemblies, active carbon filter component and hyperfiltration membrane assembly, for multi-medium filtering device assembly, active carbon filter group
Part and hyperfiltration membrane assembly are backwashed;For example:When hyperfiltration membrane assembly needs backwash, the clear water in ultrafiltration water tank can be in backwash water pump
Effect is lower to be entered inside milipore filter, it is backwashed, so that milipore filter keeps clean state.Through the dense of hyperfiltration membrane assembly
Water is back to Aerobic Pond.
Enter RO reverse osmosis membrane assemblies through the water outlet after cartridge filter, RO reverse osmosis membrane assembly membrane components use antipollution
Reverse osmosis membrane, material is:Aromatic polyamides, surface micropore diameter is between 0.5-10nm.Operating pressure:Intake pressure<
1.8Mpa, is mainly used in the salinity in water removal, and the clearance to salinity reaches more than 98%, and the total salinity of water outlet is less than 400mg/
L.Enter reuse water tank reuse through the water outlet after RO reverse osmosis membrane assemblies, and drawn on the outlet pipeline of RO reverse osmosis membrane assemblies
Cleaning water tank is partly into, clear water mixes with cleaning agent in water tank is cleaned, then can be cleaned in the case where valve action is controlled
Water pump and cleaning filter are delivered to many filter membrane components and RO reverse osmosis membrane assemblies, to many filter membrane components and RO reverse osmosis membrane assemblies
Effluent recycling after cleaning is to cleaning water tank.Backwash and cleaning function, membrane module service life are taken into full account in running
Long, replacement frequency is low, and system operation cost is low.Factory and municipal administration can be back to through the clear water after reverse-osmosis treated, as cooling
Water, flushing water, greening water, flushing water etc..
The industrial wastewater of qualified discharge is carried out desalination and the treatment of removing organic matter by the present embodiment, can be by COD concentration
The wastewater treatment of 50-400mg/L, salt content 50000-20000mg/L, concentration of suspension 30-70mg/L to COD concentration is less than
10mg/L, salt content is less than 500mg/L, and suspension is almost 0, the requirement for making it meet Treated sewage reusing, is done to save water resource
Go out contribution.