CN106830222A - A kind of method that Electro Sorb removes magnesium ion in water removal - Google Patents
A kind of method that Electro Sorb removes magnesium ion in water removal Download PDFInfo
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- CN106830222A CN106830222A CN201710030631.1A CN201710030631A CN106830222A CN 106830222 A CN106830222 A CN 106830222A CN 201710030631 A CN201710030631 A CN 201710030631A CN 106830222 A CN106830222 A CN 106830222A
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- Prior art keywords
- magnesium ion
- carbon fiber
- activated carbon
- electro sorb
- water
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4691—Capacitive deionisation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4602—Treatment of water, waste water, or sewage by electrochemical methods for prevention or elimination of deposits
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/05—Conductivity or salinity
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/16—Regeneration of sorbents, filters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Molecular Biology (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Textile Engineering (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The present invention relates to a kind of method of water-treatment technology field, the method for specifically removing magnesium ion in water removal as electrode material Electro Sorb by the use of souring activity Carbon fibe.The present invention is achieved by the following technical solutions, specifically includes following steps：(1) the hydrochloric Acid Modification treatment of Activated Carbon Fiber Electrodes；(2) Activated Carbon Fiber Electrodes electric adsorption module is assembled；(3) magnesium ion in water is adsorbed and is desorbed by changing the operating voltage of electric adsorption module, flow of inlet water, water inlet magnesium ion concentration condition.The advantage of the invention is that：Method is simple for Activated Carbon Fiber Electrodes acidifying, to environment non-secondary pollution, easily makes, high to the adsorption efficiency of magnesium ion in water with Activated Carbon Fiber Electrodes, simple to operate, can continuously recycle.
Description
Technical field
The present invention relates to a kind of method of water-treatment technology field, specifically by the use of souring activity Carbon fibe as electrode material
Material Electro Sorb removes Mg in water removal2+The method of ion, the method removal rate is fast, does not produce secondary pollution.
Background technology
Hardness is excessive in industrial water, can cause during reclaiming or recycling, to be produced in duct wall and appts wall
Raw fouling, reduces the basal area of pipeline and equipment, reduces circulating water flow, or even blocks pipeline and equipment, is caused sternly to production
Weight consequence.The excessive water of hardness can cause the pipeline heat skewness in boiler, easily cause pipe deforming even to damage,
Can also be set off an explosion when serious, there is potential safety hazard, health is threatened.In life, if the hardness of water is too big, wash
Soap is not easy to spume during clothes；Hard water wash my hair is used, hair quality can be damaged；Hard water laundry clothes can make fiber be hardened to become fragile, meeting
Cause allergic；Hard water cooking is not easy ripe；Hard water can make kettle fouling, not only waste of resource, and can cause stomach not
Suitable, abdominal distension, diarrhoea, can trigger kidney stone etc. when serious.Contain substantial amounts of inorganic ion in hard water, if the utensil such as water bottle is long
Sediment can be formed after time use, and comprising multiple harmful substances, if not processing, harmful substance can be caused largely to accumulate,
And be dissolved in water, after drinking, slow poisoning can be caused even to play the role of carcinogenic, there is very big threat to health.
Capacitive deionization (capacitive deionization, CDI), also known as Electro Sorb (electrosorption), is
A kind of new type water that water intermediate ion and charged particle, purifying water body intermediate ion and charged particle are adsorbed using powered electrode surface
Treatment technology, its advantage is：Removal process is not related to redox reaction, and energy consumption is low；Electrode after adsorption saturation can be by applying
Plus backward voltage or the mode of short circuit are regenerated, regenerative operation is easy；Go during deionization that other auxiliary materials need not be added
Material, does not produce secondary pollution；Do not have to chemically react in whole removal and regenerative process, electrode life is long.Therefore phase
Than in traditional demagging handling process, capacitive deionization technology the application field containing the hardness salt ion wastewater treatment such as magnesium is great should
Use prospect.
NACF is that a kind of intensity is big, density is small, corrosion resistant novel metalloid material.Due to NACF tool
There is specific surface area big, porous body product is big and the features such as small resistivity, necessarily applied as electric adsorption electrode material.It is living
Property Carbon fibe there is continuous block structure, can be directly used as electric adsorption electrode, therefore manufacture craft and reduction can be simplified making
Use cost.
The content of the invention
The method that a kind of Electro Sorb of present invention design removes magnesium ion in water removal, including step in detail below：
(1) NACF acidification：Salt acid soak is used, substantial amounts of deionized water rinsing is then used, until pH value is
Neutrality, conductivity value is less than 5 μ Scm-1.110 DEG C of drying in baking oven are positioned over, are placed in drier and are obtained souring activity Carbon fiber
Dimension；
(2) Activated Carbon Fiber Electrodes are prepared：Souring activity Carbon fibe in step (1) is cut into block size to be lived
Property Carbon fibe electrode；
(3) Electro Sorb goes water removal during the Activated Carbon Fiber Electrodes assembling that will be obtained in step (2) is arranged on electric adsorption module
Middle hardness salt ion；
(4) Electro Sorb method removes hardness salt ion in water removal：Configuration hardness salt ion solution, measures hardness salt ion solution and exists
In beaker, the Activated Carbon Fiber Electrodes electric adsorption module assembled in step (3) is carried out into Electro Sorb experiment.Electro Sorb experiment profit
Electric adsorption module is entered into the hardness salt ion solution in peristaltic pump pumps beaker, is finally recycled in beaker, while using
The change of electrical conductivity in conductivity meter real-time monitoring solution, when electrical conductivity keeps constant, i.e., Activated Carbon Fiber Electrodes reach suction
Attached balance.
(5) desorption and regeneration of Activated Carbon Fiber Electrodes：When Activated Carbon Fiber Electrodes reach adsorption saturation, electric suction will be applied to
Voltage short circuit or removal in attached module, the electrical conductivity in solution will be gradually restored to initial value, and electrode has obtained desorption and regeneration.
The concentration of the hydrochloric acid described in step (1) is 1molL-1, soak time is 3h, and pH value is close to 6.9.
Activated Carbon Fiber Electrodes size described in step (2) is 5cm × 5cm.
The hardness salt ion that Activated Carbon Fiber Electrodes Electro Sorb described in step (3) is gone in water removal is Mg2+。
Hardness salt ion Mg described in step (4)2+Concentration be 100mg/L, operating voltage is 1.4V, and flow of inlet water is
15ml/min。
The advantage of the invention is that：Method is simple for NACF acidified modified, easily makes and environmental protection is without two
Secondary pollution, has efficiency high by the use of modified Activated Carbon Fiber Electrodes as the electrode of electric adsorption module, simple to operate, material
Easily it is obtained and the recycling performance of material has greatly improved with without modified material tool.
Brief description of the drawings
The present invention is further described below in conjunction with the accompanying drawings.
Fig. 1 is the modified scanning electron microscope (SEM) photograph (SEM figures) of the NACF prepared in embodiment one；
Fig. 2 is solution Mg in embodiment two2+Initial concentration is to Mg2+The influence of clearance；
Fig. 3 be embodiment three in operating voltage to Mg2+The influence of clearance；
Fig. 4 be example IV in flow of inlet water to Mg2+The influence of clearance；
Fig. 5 is the adsorption/desorption regeneration times of Activated Carbon Fiber Electrodes in embodiment five to being adsorbed in the influence of desorption rate.
Specific embodiment
Embodiments of the invention are elaborated below：The present embodiment is carried out under premised on technical solution of the present invention
Implement, give detailed implementation method, but protection scope of the present invention is not limited to following embodiments.
Embodiment one
The pretreatment of NACF：NACF is cut into the size of 5cm × 5cm, 1molL is used-1Hydrochloric acid
Immersion 3h, to remove the ash content on NACF surface, then uses substantial amounts of deionized water rinsing, until pH value is neutrality, electricity
Conductivity value is less than 5 μ Scm-1.110 DEG C of drying in baking oven are positioned over, are placed in drier.
Embodiment two
The acidified modified rear electrode production process of NACF is identical with embodiment one.
Electric adsorption module to Activated Carbon Fiber Electrodes composition carries out the experiment that Electro Sorb removes magnesium ion in water removal.Electricity is inhaled
Attached experiment condition is arranged to voltage for 1.0V, and flow of inlet water is 10mL/min, and pole plate spacing is controlled under conditions of 1mm, respectively
Have studied magnesium ion initial concentration NACF Electro Sorb in 150mg/L, 120mg/L, 100mg/L, 70mg/L and go demagging
The effect of ion.Experimental result is as shown in Figure 2, it is seen that modified activated fibre electrode pair Mg2+With preferable adsorption effect.
Embodiment three
The acidified modified rear electrode production process of NACF is identical with embodiment one.
It is the magnesium ion solution of 150mg/L to choose initial concentration, and electrode spacing is isolated by being clipped in two interelectrode non-woven fabrics,
Spacing is controlled in 1mm, controls flow of inlet water for 10ml/min, and the work electricity of 0V, 1.0V, 1.2V, 1.4V, 1.6V is applied respectively
Pressure, electric adsorption module is assembled into Activated Carbon Fiber Electrodes carries out Electro Sorb removal magnesium ion experiment, as a result as Fig. 3 shows.It can be seen that
Modified activated fibre electrode pair Mg in the case of operating voltage is suitable2+With preferable adsorption effect.
Example IV
The acidified modified rear electrode production process of NACF is identical with embodiment one.
Experiment condition have chosen magnesium ion concentration for 100mg/L, and operating voltage is controlled in 1.4V, and electrode spacing is by being clipped in two
Interelectrode non-woven fabrics isolation, spacing control have studied the adsorption effect of Activated Carbon Fiber Electrodes in 1mm.
Embodiment five
The acidified modified rear electrode production process of NACF is identical with embodiment one.
The electric adsorption electrode being made modified to NACF is circulated Electro Sorb experiment.By Activated Carbon Fiber Electrodes
In electric adsorption module, applying operating voltage is 1.4V, and flow of inlet water control is desorbed concentration in 15ml/min circulation absorptions
It is the Mg of 100mg/L2+Solution, calculates its adsorption rate and desorption rate.Experimental result is as shown in Figure 5.First time circulation absorption is desorbed
After experiment, the adsorption rate of NACF is 52.65%, by after five circulation absorption detachment assays, clearance reduced by only
7.84%, illustrate that the material has high regenerability.
Claims (6)
1. a kind of method that Electro Sorb removes magnesium ion in water removal, it is characterised in that specifically include following steps：
(1) NACF acidification：Salt acid soak is used, substantial amounts of deionized water rinsing is then used, until pH value is neutrality,
Conductivity value is less than 5 μ Scm-1.110 DEG C of drying in baking oven are positioned over, are placed in drier and are obtained souring activity Carbon fibe；
(2) Activated Carbon Fiber Electrodes are prepared：Souring activity Carbon fibe in step (1) is cut into block size and obtains activated carbon
Fiber electrode；
(3) Electro Sorb is gone in water removal firmly during the Activated Carbon Fiber Electrodes assembling that will be obtained in step (2) is arranged on electric adsorption module
Degree magnesium ion；
(4) Electro Sorb method removes hardness magnesium ion in water removal：Configuration hardness magnesium ion solution, measures magnesium ion solution in beaker,
The Activated Carbon Fiber Electrodes electric adsorption module assembled in step (3) is carried out into Electro Sorb experiment.Electro Sorb experiment is using wriggling
The magnesium ion solution that pumping is taken in beaker enters into electric adsorption module, is finally recycled in beaker, while using conductivity meter reality
When monitoring solution in electrical conductivity change, when electrical conductivity keep it is constant when, i.e., Activated Carbon Fiber Electrodes reach adsorption equilibrium.
(5) desorption and regeneration of Activated Carbon Fiber Electrodes：When Activated Carbon Fiber Electrodes reach adsorption saturation, Electro Sorb mould will be applied to
Voltage short circuit or removal on block, the electrical conductivity in solution will be gradually restored to initial value, and electrode has obtained desorption and regeneration.
2. the method that a kind of Electro Sorb as described in claim 1 step removes magnesium ion in water removal, it is characterised in that step (1)
Described in hydrochloric acid concentration be 1molL-1, soak time is 3h, and pH value is close to 6.9.
3. the method that a kind of Electro Sorb as claimed in claim 1 removes magnesium ion in water removal, it is characterised in that institute in step (2)
The Activated Carbon Fiber Electrodes size stated is 5cm × 5cm.
4. the method that a kind of Electro Sorb as described in right 1 removes magnesium ion in water removal, it is characterised in that the work described in step (3)
Property Carbon fibe electrode Electro Sorb go water removal in hardness salt ion be Mg2+。
5. the method that a kind of Electro Sorb as described in right 1 removes magnesium ion in water removal, it is characterised in that the electricity described in step (3)
The electrode logarithm of adsorption module is 3 pairs.
6. the method that a kind of Electro Sorb as described in right 1 removes magnesium ion in water removal, it is characterised in that hard described in step (4)
Degree salt ion Mg2+Concentration be 100mg/L, operating voltage is 1.4V, and flow of inlet water is 15ml/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710030631.1A CN106830222A (en) | 2017-01-17 | 2017-01-17 | A kind of method that Electro Sorb removes magnesium ion in water removal |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710030631.1A CN106830222A (en) | 2017-01-17 | 2017-01-17 | A kind of method that Electro Sorb removes magnesium ion in water removal |
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| CN106830222A true CN106830222A (en) | 2017-06-13 |
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| CN201710030631.1A Pending CN106830222A (en) | 2017-01-17 | 2017-01-17 | A kind of method that Electro Sorb removes magnesium ion in water removal |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111689556A (en) * | 2019-03-15 | 2020-09-22 | 国家能源投资集团有限责任公司 | Salt production method and device and salt-containing wastewater treatment system |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103708587A (en) * | 2014-01-03 | 2014-04-09 | 长沙皓龙环保科技有限公司 | Preparation method of composite electrode for removing arsenic in water based on electro-adsorption and method for removing arsenic |
-
2017
- 2017-01-17 CN CN201710030631.1A patent/CN106830222A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103708587A (en) * | 2014-01-03 | 2014-04-09 | 长沙皓龙环保科技有限公司 | Preparation method of composite electrode for removing arsenic in water based on electro-adsorption and method for removing arsenic |
Non-Patent Citations (2)
| Title |
|---|
| 李海红 等: "盐酸预处理对ACF结构及其电化学性能的影响", 《材料科学与工程学报》 * |
| 王翠 等: "活性炭纤维电极对不同阳离子电吸附行为的试验研究", 《中国新技术新产品》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111689556A (en) * | 2019-03-15 | 2020-09-22 | 国家能源投资集团有限责任公司 | Salt production method and device and salt-containing wastewater treatment system |
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Application publication date: 20170613 |
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