CN106827130A - The mold-proof method of Wood plastic composite - Google Patents

The mold-proof method of Wood plastic composite Download PDF

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Publication number
CN106827130A
CN106827130A CN201611223986.4A CN201611223986A CN106827130A CN 106827130 A CN106827130 A CN 106827130A CN 201611223986 A CN201611223986 A CN 201611223986A CN 106827130 A CN106827130 A CN 106827130A
Authority
CN
China
Prior art keywords
plastic composite
wood plastic
mold
biological
proof
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611223986.4A
Other languages
Chinese (zh)
Inventor
丁建生
朱方政
闫武
姚龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NANJING JULONG TECHNOLOGY Co Ltd
NANJING JUFENG ADVANCED MATERIALS CO Ltd
Original Assignee
NANJING JULONG TECHNOLOGY Co Ltd
NANJING JUFENG ADVANCED MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NANJING JULONG TECHNOLOGY Co Ltd, NANJING JUFENG ADVANCED MATERIALS CO Ltd filed Critical NANJING JULONG TECHNOLOGY Co Ltd
Priority to CN201611223986.4A priority Critical patent/CN106827130A/en
Publication of CN106827130A publication Critical patent/CN106827130A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/50Mixtures of different organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/20Removing fungi, molds or insects

Abstract

The present invention relates to a kind of mold-proof method of material, more particularly to Wood plastic composite mold-proof method, belong to timber treatment technology field.In proportion be dissolved in the water for fungi solution and culture medium by the present invention, is made biological mildew inhibitor;Biological mildew inhibitor is sprayed on the surface of Wood plastic composite again;The Wood plastic composite of sprayed biological mould inhibitor is placed in more than 15 DEG C, treats that fungi grows in the environment of relative humidity more than 50%;After after the nutriment in the wood powder that fungi runs out of plastic-wood material, the mould proof treatment of Wood plastic composite is completed, reduce the Signs of Mould of material surface.

Description

The mold-proof method of Wood plastic composite
Technical field
The present invention relates to a kind of mold-proof method of material, more particularly to a kind of mold-proof method of Wood plastic composite, belong to Timber treatment technology field.
Background technology
Wood plastic composite be with plant fiber powders such as plastics, wood powders as primary raw material, along with other auxiliary agents are extruded, A kind of advanced composite material (ACM) of the technological formings such as molding, injection, it have be not cracked, indeformable, corrosion-resistant, plasticity is strong, energy Particularly simple realize that personalized moulding, high-environmental, pollution-free, nuisanceless, product are free of the materials such as benzene, formaldehyde, are recycled Utilize, be a kind of brand-new Green Product, be also a kind of ecological clean composite, just causing in the last few years more next More concerns.Wood plastic composite can be used as the packaging material such as pallet, packing case, the storage material such as bed board, paving beam, house, The leisure material such as outdoor tables and chairs, stool that the occasions such as the finishings such as floor, building template, ornament materials, park, court, street are used Material, automobile inside decoration materials, tubing etc..
Wood plastic composite in use, can usually occur the situation of surface from mildewing, general processing mode Shi Sumu factories Family adds chemical anti mildew agent or the mould proof composition feelings mouldy to reduce product surface when product is produced in formula Condition.
But this method has following shortcoming:
1st, mould inhibitor is a kind of biocide, and addition in the product, with the use of product, can be produced certain to environment Harmful effect.If species and adding proportion are improper, can also certain harm be caused to human body and environment;
2nd, mould inhibitor is relatively costly, and mould inhibitor is intended merely to prevent product surface mouldy, but is added in product formula Mould inhibitor causes that product entire body contains mould inhibitor, and those additions mould inhibitor that center portion is divided in the material does not play effect, wastes Cost.
The content of the invention
The purpose of the present invention is directed to the defect of prior art presence, proposes a kind of mold-proof method of Wood plastic composite, It is surface-treated by Wood plastic composite, reduces the Signs of Mould of material surface.
Biological mould proof treatment does not influence not only on human body and environment, while simplifying process step, has saved cost.
The present invention solves technical problem by the following technical programs:The mold-proof method of Wood plastic composite, including by fungi Solution and culture medium are dissolved in the water in proportion, are made biological mildew inhibitor;The biological mildew inhibitor is sprayed in confined space to enter Row fungal culture is used as biological mould proof room;Wood plastic composite is placed in biological mould proof room and treats that fungi runs out of plastic-wood material After nutriment in wood powder, the mould proof treatment of Wood plastic composite is completed.
Fungi in the fungi solution of the above method includes koning trichoderma, trichoderma pseudokiningii, Trichoderma atroviride, spine spore wood Mould, tangerine green trichoderma, trichoderma aureoviride.
Fungal spore concentration is (0.1~1) × 10 in the fungi solution6CFU/ml。
The culture medium include peptone, beef extract, bean sprouts, potato, flour, soluble starch, sucrose, glucose, Maltose.
The concentration of the culture medium is (0.1~1) g/L.
25 DEG C~30 DEG C of the temperature of the biological mould proof room, relative humidity more than 85%.Preferably, the biological mould proof room Inside set wind circulating system.
The biological mildew inhibitor is by peptone 0.35g, dehydrated potato powder 0.35g and concentration 1 × 106The Kang Shi wood of CFU/ml Mould stoste 100ml is obtained in being dissolved in 1L water.
The reason for modeling wood products surface from mildewing is that mould is touching modeling wood products surface free bag in air or environment During the wood-fibred for covering, grow under certain environmental conditions, cause product surface to change colour.
Modeling wood products are put into mould proof room and are pre-processed by the present invention, in advance in some the easy lifes of modeling wood products surface seeding Grow, endanger low, non-discoloring fungi, the nutriment in the wood powder of consumption modeling wood products surface.Treat that product surface nutriment disappears After the completion of consumption, these fungies are most of dead, so that nutriment of the modeling wood products surface without fungus growth, while Remaining a part of fungi also has certain rejection ability to the growth of mould, and fungicidal properties is substantially improved.These are true simultaneously Bacterium is the type being widely present in natural environment, does not have any influence to human body and environment.
Advantages of the present invention is as follows:
1. prevent product mouldy using biotechnology, overcome the mould proof environmental risk of conventional chemical method and high cost Shortcoming;
2. the characteristics of make use of Wood plastic composite surface wood-fibred limited amount, is disappeared nutriment using fungi in advance Consumption, breaks off mould production environment;
3. the suppression principle that make use of fungi to grow, promotes beneficial bacteria growing, suppresses harmful bacteria growing;
4. biomembrane principle make use of, and fungi passes through the breeding and growth of itself, gradually all surfaces of covering product, i.e., After making to be subjected to rainwater or friction loss, moreover it is possible to gradually recover.The mould proof middle surface mould inhibitor of chemistry is overcome with rain water runoff Afterwards, the situation of fungicidal properties reduction.
5. modeling wood products are processed using mould proof room, make fungi own growth in suitable environmental conditions, be not required to Biological mildew inhibitor is persistently prepared, further simplifies operation.
Specific embodiment
Embodiment 1
1. Wood plastic composite is prepared
HDPE 200g, Poplar Powder 300g;
Kneaded 10 minutes in two-roll mill, 170 DEG C of temperature;
The thick modeling planks of 5mm are pressed into after the completion of mixing on vulcanizing press;
Surface plastic materials layer is ground off using sand paper, as implementation sample.
2. biological mildew inhibitor is prepared
Following Nutrient medium and fungi solution are dissolved in 1L water, biological mildew inhibitor is configured to:
Peptone 0.35g
Dehydrated potato powder 0.35g
Koning trichoderma stoste 100ml (concentration 1 × 106CFU/ml)。
3. mould proof room is prepared
Biological mildew inhibitor is sprayed in environmental cabinet, environmental cabinet is set to 30 DEG C of temperature, relative humidity 85% is cultivated 7 days.
4. mould proof treatment
The wooden model of modeling is put into environmental cabinet 24 hours, is placed 7 days in room temperature environment after taking-up;
5. performance test
Tested by ASTM G21-15, fungicidal properties is 0 grade.
Embodiment 2
1. Wood plastic composite is prepared
HDPE 200g, Poplar Powder 300g;
Kneaded 10 minutes in two-roll mill, 170 DEG C of temperature;
The thick modeling planks of 5mm are pressed into after the completion of mixing on vulcanizing press;
Surface plastic materials layer is ground off using sand paper, as implementation sample.
2. biological mildew inhibitor is prepared
Following Nutrient medium and fungi solution are dissolved in 1L water, biological mildew inhibitor is configured to:
Peptone 0.35g
Dehydrated potato powder 0.35g
Koning trichoderma stoste 100ml (concentration 1 × 106CFU/ml)。
3. mould proof room is prepared
Biological mildew inhibitor is sprayed in environmental cabinet, environmental cabinet is set to 30 DEG C of temperature, relative humidity 85% is cultivated 7 days.
4. mould proof treatment
The wooden model of modeling is put into environmental cabinet 24 hours, is tested immediately;
5. performance test
Tested by ASTM G21-15, fungicidal properties is 1 grade.
Embodiment 3
1. Wood plastic composite is prepared
HDPE 200g, Poplar Powder 300g;
Kneaded 10 minutes in two-roll mill, 170 DEG C of temperature;
The thick modeling planks of 5mm are pressed into after the completion of mixing on vulcanizing press;
Surface plastic materials layer is ground off using sand paper, as implementation sample.
2. biological mildew inhibitor is prepared
Following Nutrient medium and fungi solution are dissolved in 1L water, biological mildew inhibitor is configured to:
Peptone 0.35g
Dehydrated potato powder 0.35g
Tangerine green trichoderma stoste 100ml (concentration 1 × 106CFU/ml)。
3. mould proof room is prepared
Biological mildew inhibitor is sprayed in environmental cabinet, environmental cabinet is set to 30 DEG C of temperature, relative humidity 85% is cultivated 7 days.
4. mould proof treatment
The wooden model of modeling is put into environmental cabinet 24 hours, is placed 7 days in room temperature environment after taking-up;
5. performance test
Tested by ASTM G21-15, fungicidal properties is 0 grade.
Embodiment 4
1. Wood plastic composite is prepared
HDPE 200g, Poplar Powder 300g;
Kneaded 10 minutes in two-roll mill, 170 DEG C of temperature;
The thick modeling planks of 5mm are pressed into after the completion of mixing on vulcanizing press;
Surface plastic materials layer is ground off using sand paper, as implementation sample.
2. biological mildew inhibitor is prepared
Following Nutrient medium and fungi solution are dissolved in 1L water, biological mildew inhibitor is configured to:
Peptone 0.35g
Dehydrated potato powder 0.35g
Tangerine green trichoderma stoste 100ml (concentration 1 × 106CFU/ml)。
3. mould proof room is prepared
Biological mildew inhibitor is sprayed in environmental cabinet, environmental cabinet is set to 30 DEG C of temperature, relative humidity 85% is cultivated 7 days.
4. mould proof treatment
The wooden model of modeling is put into environmental cabinet 24 hours, is placed 7 days in room temperature environment after taking-up;
5. weather-proof treatment
Sample is carried out into laboratory accelerated ageing by xenon lamp aging method in GB/T 29365 to test 500 hours, simulation is certainly Right boundary ageing process
6. performance test
Tested by ASTM G21-15, fungicidal properties is 0 grade.
Comparative example 1
1. Wood plastic composite is prepared
HDPE 200g, Poplar Powder 300g;
Kneaded 10 minutes in two-roll mill, 170 DEG C of temperature;
The thick modeling planks of 5mm are pressed into after the completion of mixing on vulcanizing press;
Surface plastic materials layer is ground off using sand paper, as implementation sample.
2. performance test
Tested by ASTM G21-15, fungicidal properties is 4 grades.
Comparative example 2
1. Wood plastic composite is prepared
HDPE 200g, Poplar Powder 300g, the wooden mould inhibitor 2.5g of modeling;
Kneaded 10 minutes in two-roll mill, 170 DEG C of temperature;
The thick modeling planks of 5mm are pressed into after the completion of mixing on vulcanizing press;
Surface plastic materials layer is ground off using sand paper, as implementation sample.
2. performance test
Tested by ASTM G21-15, fungicidal properties is 0 grade.
In addition to above-mentioned implementation, the present invention can also have other embodiment.All use equivalents or equivalent transformation are formed Technical scheme, all fall within the protection domain of application claims.

Claims (8)

1. the mold-proof method of Wood plastic composite, including by fungi solution and culture medium press fungal spore concentration for (0.1~1) × 106CFU/ml, the concentration of culture medium is dissolved in the water for (0.1~1) g/L, is made biological mildew inhibitor;Sprayed in confined space The biological mildew inhibitor carries out fungal culture as biological mould proof room;Wood plastic composite is placed in biological mould proof room and stands 1- 7 days, complete the mould proof treatment of Wood plastic composite.
2. the mold-proof method of Wood plastic composite according to claim 1, it is characterised in that:Fungi in the fungi solution Including koning trichoderma, trichoderma pseudokiningii, Trichoderma atroviride, trichoderma asperellum, tangerine green trichoderma, trichoderma aureoviride.
3. the mold-proof method of Wood plastic composite according to claim 2, it is characterised in that:Allergenic in the fungi solution Sub- concentration is (0.1~1) × 106CFU/ml。
4. the mold-proof method of Wood plastic composite according to claim 1, it is characterised in that:The culture medium includes albumen Peptone, beef extract, bean sprouts, potato, flour, soluble starch, sucrose, glucose, maltose.
5. the mold-proof method of Wood plastic composite according to claim 4, it is characterised in that:The concentration of the culture medium is (0.1~1) g/L.
6. the mold-proof method of Wood plastic composite according to claim 1, it is characterised in that:The temperature of the biological mould proof room 25 DEG C~30 DEG C, relative humidity more than 85%.
7. the mold-proof method of Wood plastic composite according to claim 1, it is characterised in that:The biological mould proof interior sets to be followed Ring wind system.
8. the mold-proof method of Wood plastic composite according to claim 1, it is characterised in that:The biological mildew inhibitor is by egg White peptone 0.35g, dehydrated potato powder 0.35g and concentration 1 × 106The koning trichoderma stoste 100ml of CFU/ml is obtained in being dissolved in 1L water.
CN201611223986.4A 2016-12-27 2016-12-27 The mold-proof method of Wood plastic composite Pending CN106827130A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611223986.4A CN106827130A (en) 2016-12-27 2016-12-27 The mold-proof method of Wood plastic composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611223986.4A CN106827130A (en) 2016-12-27 2016-12-27 The mold-proof method of Wood plastic composite

Publications (1)

Publication Number Publication Date
CN106827130A true CN106827130A (en) 2017-06-13

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108407007A (en) * 2018-01-30 2018-08-17 桐乡市林达木业有限公司 A kind of deinsectization mildew-proof treatment method of fence board

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3329934B2 (en) * 1994-03-16 2002-09-30 石塚硝子株式会社 How to treat wood products
US20020185032A1 (en) * 2001-02-20 2002-12-12 Wampole Glenn Paul Treatment of wood, wood fiber products, and porous surfaces with periodic acid and iodic acid
CN101870776A (en) * 2010-06-07 2010-10-27 广东迪美生物技术有限公司 Wood-plastic composite material mildew-resistance bactericide and preparation method thereof
CN103182726A (en) * 2011-12-28 2013-07-03 西南林业大学 Novel decorative wood material and preparation method thereof
CN104070571A (en) * 2014-06-17 2014-10-01 福建农林大学 Method for preventing bamboo from mildewing by using aspergillus flavus

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3329934B2 (en) * 1994-03-16 2002-09-30 石塚硝子株式会社 How to treat wood products
US20020185032A1 (en) * 2001-02-20 2002-12-12 Wampole Glenn Paul Treatment of wood, wood fiber products, and porous surfaces with periodic acid and iodic acid
CN101870776A (en) * 2010-06-07 2010-10-27 广东迪美生物技术有限公司 Wood-plastic composite material mildew-resistance bactericide and preparation method thereof
CN103182726A (en) * 2011-12-28 2013-07-03 西南林业大学 Novel decorative wood material and preparation method thereof
CN104070571A (en) * 2014-06-17 2014-10-01 福建农林大学 Method for preventing bamboo from mildewing by using aspergillus flavus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108407007A (en) * 2018-01-30 2018-08-17 桐乡市林达木业有限公司 A kind of deinsectization mildew-proof treatment method of fence board

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Application publication date: 20170613

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