CN106824040A - A kind of high-speed gas reactor and its application method - Google Patents
A kind of high-speed gas reactor and its application method Download PDFInfo
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- CN106824040A CN106824040A CN201710050420.4A CN201710050420A CN106824040A CN 106824040 A CN106824040 A CN 106824040A CN 201710050420 A CN201710050420 A CN 201710050420A CN 106824040 A CN106824040 A CN 106824040A
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- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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Abstract
The present invention relates to a kind of high-speed gas reactor and its application method, belong to hydrodynamics and metallurgical crossing domain.The high-speed gas reactor includes main flow caliber and the jet orifice of its surface distributed, main flow caliber is a logical heart cylindrical tube, one of cylindrical tube is mainstream gas entrance, the other end of cylindrical tube is mixed gas outlet, and multiple jet orifices are distributed between 1~1.5 times of caliber of mainstream gas entrance in cylindrical tube.Mainstream gas are passed through particular by the mainstream gas porch of main flow caliber, intake velocity is 2~6m/s, and jet orifice is passed through Gas Jet, and intake velocity is 3~25m/s, i.e., obtain mixed gas or fully reacted product in mixed gas outlet.The device structure is simple, and incorporation time is short, efficiency high, reaches two kinds of gases quick well mixed effect in 0.5 second, and the technical method can optimize the design of oxidation reactor, be prevented effectively from oxidation reactor and scab.
Description
Technical field
The present invention relates to a kind of high-speed gas reactor and its application method, belong to hydrodynamics and metallurgical intersection neck
Domain.
Background technology
High temperature and belong to strong exothermal reaction with corrosive gas and another gas reaction, two kinds of reacting gas are mixed
Closing effect difference can cause local temperature too high, cause product particle size uneven, sintering can be produced when serious or even is scabbed.And
And the control of feed operation condition is improper, backflow can be produced when reacting gas mixes and react to form molecule, caused
The jet hole plug of reactor.
Titanium dioxide is a kind of excellent basic industries raw material, using in extensive range.China's titanium white production is main with sulfuric acid
Based on method, technology is also more ripe, accounts for more than the 99% of domestic Producing Titanium Dioxide total amount, but Production By Sulfuric Acid Process titanium white technology production technology
Long flow path, pollution are big, environmental risk is high.Chloridising produce titanium white with flow it is short, product quality is high, pollution is small, automaticity
High the advantages of and by country be classified as industrial restructuring instruct encourage class catalogue, but the industry key technology by external a few institutes of company
Control, and protected as know-how.Domestic Yunnan metallurgy newly founds the companies such as titanium industry, the Li Lian of Henan one hundred and introduces German titanium health etc.
The technology of Chevron Research Company (CRC), there are problems that a lot, especially first be intake significantly lower than the world in the oxidation reactor aspect cycle such as scab
It is flat, cause continuous prodution cycle is short.
Reaction mass TiCl4And O2Reaction is completed in the oxidation reactor in several milliseconds, reaction speed is exceedingly fast, substantially
It is that a contact reacts, therefore can not be by material TiCl4And O2It is pre-mixed, can be otherwise blocked pipeline, and must
TiCl4And O2Reactor is each led into, and the well mixed of gas is completed in very short time, can otherwise influence TiO2Particle
Footpath is distributed and transformation of crystal, and then causes to sinter and scab, and influences the quality of product.Residence time is with material in oxidation reactor
In flow regime with mixing situation it is closely related, the excellent oxidation reactor of structural behaviour can be provided well for the flowing of gas
Flox condition, make material TiCl4And O2It is well mixed rapidly after into reactor, and stable and uniform ground flows through reactor.Cause
This, the application devises a kind of high-speed gas reactor, by controlling jet penetration, jet orifice hole count, aperture, Kong Jian
Away from, momentum flux than etc. critical technical parameter, reach two kinds of gases quick well mixed effect, the equipment knot in 0.5 second
Structure is simple, and incorporation time is short, efficiency high, and the technical method can optimize the design of oxidation reactor, be prevented effectively from oxidation reactor
Scab, quick for high temperature corrosion gas is mixed with great importance.
The content of the invention
The invention provides a kind of high-speed gas reactor and its application method, the reactor by control mainstream gas and
The direction of Gas Jet, realizes preliminary mixing, then coordinate the jet penetration of control Gas Jet, jet orifice hole count, aperture,
The critical technical parameters such as pitch of holes, momentum flux ratio, reach two kinds of gases quick well mixed effect within the extremely short time,
And will not sinter and scab;The reactor goes for commercial application.
High-speed gas reactor of the invention includes main flow caliber and the jet orifice (2) of its surface distributed, and main flow caliber is
A piece logical heart cylindrical tube, of cylindrical tube is mainstream gas entrance (1), and the other end of cylindrical tube is mixed gas outlet (3),
Multiple jet orifices (2) are distributed between (1) 1~1.5 times of mainstream gas entrance in cylindrical tube.Mainstream gas refer to gaseous mixture
The big gas of volume ratio in body, the Gas Jet that jet orifice (2) is passed through is the small gas of volume ratio in mixed gas.Intersect
In jet mixing, the diffusion of Convention diffusion, DIFFUSION IN TURBULENCE and molecule acts on the mixing of fluid simultaneously.Jet orifice is by TiCl4Fluid
Multiple jetses are divided into, main flow O is entered in Convention diffusion mode2In be mixed with.And then, due to the effect of DIFFUSION IN TURBULENCE, stream
Body forms the tiny gas group of smaller yardstick.Finally by the effect that molecule spreads, fluid is set to reach microcosmic well mixed effect.
The high speed reactor can be equipped with sealable shell and/or port structure, and shell can be the arbitrary shape for needing.
Multiple is evenly distributed with the cylindrical tube within one week along caliber everywhere apart from (1) one times of caliber of mainstream gas entrance to penetrate
Discharge orifice (2).The jet orifice of single circle distribution is by TiCl4Fluid is divided into multiple jetses, and main flow O is entered in Convention diffusion mode2
In be mixed with.And then, due to the effect of DIFFUSION IN TURBULENCE, fluid forms the tiny gas group of smaller yardstick.Expand finally by molecule
Scattered effect, makes fluid reach microcosmic well mixed effect.This jet orifice distributed architecture is simple, and mixing efficiency is high, can reach
To optimal mixed effect.
The diameter of the multiple jet orifice (2) is identical.
The number of the jet orifice (2) is 16~32, and the ratio of jet bore dia and cylinder caliber is 0.05~0.02:
0.12~0.05.
Proved by checking computations, in larger J/n when hole count is more2In the range of, the value of mixing unevenness M can be less than
0.05, and hole count it is less when, this scope also reduce (wherein J be momentum flux ratio, n be jet orifice hole count).This is due to protecting
When holding identical pitch of holes, hole count is more, and bore size is smaller.TiCl of the less jet orifice in aperture radial inflow4Gas
Thinner jet is divided into, itself and O2The micromixing yardstick that main flow is mixed to form accordingly reduces, and is more beneficial for mixing quick
Carry out.Therefore, in the reaction tube of a diameter of 0.2m, in order that mixing more Quick uniform, jet orifice hole count at least take 16 holes with
On, and keep J/n2Value scope be 0.38~0.75.
The application method of the reactor is:Mainstream gas are passed through at mainstream gas entrance (1) place of main flow caliber, enter gas velocity
It is 2~6m/s to spend, and jet orifice (2) is passed through Gas Jet, and intake velocity is 3~25m/s, i.e., mixed in mixed gas outlet
Gas or fully reacted product.
The temperature of the mainstream gas and Gas Jet is determined according to two kinds of reaction temperatures of gas.
The operation pressure of the reactor is 380~420kPa.
The jet penetration of the Gas Jet is 0.32~1.Jet penetration refers in reaction tube on cross section
The distance (h) of temperature minimum point distance reaction tube wall and the ratio of reaction tube radius (R).Temperature in reaction tube cross section is equivalent
The minimum point of temperature on line chart, as shown in Fig. 2 obtaining it apart from reaction tube wall apart from h, can calculate exit flow and penetrate depth
Degree (h/R).
The volume flow ratio of the Gas Jet and mainstream gas is 0.0313~0.106:1.With jet TiCl4And master
Stream O2Volume flow ratio increase, TiCl4The momentum of jet also increasingly comes greatly, and it penetrates into O2The depth of main flow also can
Increase.There is the moderate value of a comparing in jet penetration, jet penetration is not enough or excessive, under all causing jet orifice
Trip area's temperature distributing disproportionation is even, and TiCl4And O2Mixed effect it is undesirable.(it may be said that volume flow ratio is influence jet wearing
One factor of saturating depth, jet penetration determines mixed effect.Therefore, rational jet penetration scope is controlled.)
For the tubular reactor that this cross jet mixes, an important variation is TiCl4Jet and O2Main flow
Between dimensionless group, i.e. momentum flux is shown in formula (1) than J:
ρ and v represent TiCl respectively in formula4Jet and O2Density (the kgm of main flow-3) and speed (ms-1), subscript j
Represent TiCl4Jet, subscript m represents O2Main flow.At a given temperature and pressure, flow velocity vjAnd vmCan respectively by following formula
Son is calculated:
Vj=n (π d2/4)·vj (2)
Vm=(π D2/4)·vm (3)
Wherein VjIt is all jet orifice TiCl4Total volumetric flow rate (the m of jet3·s-1), d is jet orifice aperture (m), and n is hole
Number, VmIt is O2Main flow volume flow (m3·s-1), D is reaction tube diameter (m).
Formula (2) and (3) are substituted into formula (1) abbreviation can obtain:
At a given temperature and pressure, TiCl4Jet and O2Density ratio (the ρ of main flowj/ρm) it is 15.014.By formula (4)
Understand, variable parameter has TiCl4And O2Volume flow ratio (Vj/Vm), reaction tube diameter (D), jet orifice hole count (n) and aperture
(d)。
One important parameter is dimensionless jet pitch of holes, and it is in combination with all variable geometry ginsengs on reaction tube
Number, is defined as S, sees formula (5):
The beneficial effects of the invention are as follows:
1st, the reactor can reach the time within mixing 0.5 second, at jet orifice downstream area twice caliber
The unevenness of gas mixing reaches less than 0.05, mixing can be met completely and is sufficiently required;
2nd, obtain new product after two kinds of gas reactions, the product at normal temperatures be solid-state, therefore after the reaction at a temperature of
Easily scabbed in the reactor during drop, influence follow-up reaction effect, more influence the service life of oxidation reactor.
Hydrodynamics behavior in the oxidation reactor directly affects reacting gas (TiCl4And O2) mixed effect, its determine titanium white
Pattern, quality, size distribution of product etc..Because the main chemical reactions for producing titanium white are strong exothermal reactions, reacting gas is mixed
Closing effect difference can cause local temperature too high, cause product particle size uneven, sintering can be produced when serious or even is scabbed.And
And the control of feed operation condition is improper, backflow can be produced when reacting gas mixes and react to form molecule, caused
Jet hole plug.It can be TiCl that material is well mixed in reactor4Gas phase oxidation process provides good flowing and reaction condition,
And then can make to realize TiO2Granular grows are uniform, crystalline form high conversion rate, particle are easily crystallized, uniformity of temperature profile and reduction
The purpose such as scab;
3rd, the reactor can meet requirement completely under the conditions of small test, and reactor is expanded according to corresponding proportion,
Large-scale commercial application can be realized, it is applied widely.
Brief description of the drawings
Fig. 1 is the structural representation of high-speed gas reactor of the present invention;
Fig. 2 is high speed reactor jet penetration schematic diagram of the present invention.
In figure:1- mainstream gas entrances, 2- Gas Jet entrances, 3- mixed gas outlets.
Specific embodiment
With reference to the accompanying drawings and detailed description, the invention will be further described.
Embodiment 1:The mainstream gas of the embodiment are O2, Gas Jet is TiCl4, the product of reaction is TiO2Powder.Should
High-speed gas reactor includes main flow caliber and the jet orifice (2) of its surface distributed, and main flow caliber is a logical heart cylindrical tube, circle
One of column jecket is mainstream gas entrance (1), and the other end of cylindrical tube is mixed gas outlet (3), apart from main flow in cylindrical tube
At (1) 1 times of gas access 16 jet orifices (2) are distributed with one week along caliber.
The application method of the reactor is:Mainstream gas are passed through at mainstream gas entrance (1) place of main flow caliber, enter gas velocity
It is 4m/s to spend, and jet orifice (2) is passed through Gas Jet, and intake velocity is 8m/s, i.e., mixed gas outlet obtain mixed gas or
Abundant reacted product.Specifically reaction condition is:TiCl4380 DEG C of jet temperature, O21500 DEG C of main flow temperature, reactor operation
Pressure is 390kPa, and reactor diameter is 0.2m, and jet orifice hole count is 16, and jet aperture is 0.008m, TiCl4Jet and O2It is main
When stream volume flow ratio is 0.06875, jet penetration is 0.602, when mixing 0.41 second, in jet orifice downstream area two
The temperature difference at times caliber is about 55K, and the unevenness of gas mixing is about 0.00839, can reach well mixed effect, and
And do not scab.
Embodiment 2:The mainstream gas of the embodiment are O2, Gas Jet is TiCl4, the product of reaction is TiO2Powder.Should
High-speed gas reactor includes main flow caliber and the jet orifice (2) of its surface distributed, and main flow caliber is a logical heart cylindrical tube, circle
One of column jecket is mainstream gas entrance (1), and the other end of cylindrical tube is mixed gas outlet (3), apart from main flow in cylindrical tube
20 jet orifices (2) are distributed with (1) 1.2 times of gas access.
The application method of the reactor is:Mainstream gas are passed through at mainstream gas entrance (1) place of main flow caliber, enter gas velocity
It is 6m/s to spend, and jet orifice (2) is passed through Gas Jet, and intake velocity is 25m/s, i.e., mixed gas outlet obtain mixed gas or
Abundant reacted product.Specifically reaction condition is:Work as TiCl4400 DEG C of jet temperature, O21500 DEG C of main flow temperature, reactor behaviour
Make pressure for 400kPa, reactor diameter is 0.2m, jet orifice hole count is 24, and jet aperture is 0.00533m, TiCl4Jet and
O2When main flow volume flow ratio is 0.07034, jet penetration is 0.583, when mixing 0.36 second, jet orifice downstream area
The temperature difference at twice caliber is about 46K, and the unevenness of gas mixing is about 0.0214, can reach well mixed effect.
Embodiment 3:The mainstream gas of the embodiment are O2, Gas Jet is TiCl4, the product of reaction is TiO2Powder.Should
High-speed gas reactor includes main flow caliber and the jet orifice (2) of its surface distributed, and main flow caliber is a logical heart cylindrical tube, circle
One of column jecket is mainstream gas entrance (1), and the other end of cylindrical tube is mixed gas outlet (3), apart from main flow in cylindrical tube
32 jet orifices (2) are distributed with the caliber of (1) 1.5 times of gas access.
The application method of the reactor is:Mainstream gas are passed through at mainstream gas entrance (1) place of main flow caliber, enter gas velocity
It is 2m/s to spend, and jet orifice (2) is passed through Gas Jet, and intake velocity is 3m/s, i.e., mixed gas outlet obtain mixed gas or
Abundant reacted product.Specifically reaction condition is:Work as TiCl4450 DEG C of jet temperature, O21550 DEG C of main flow temperature, reactor behaviour
Make pressure for 420kPa, reactor diameter is 0.2m, jet orifice hole count is 32, and jet aperture is 0.004m, TiCl4Jet and O2
During main flow volume flow ratio 0.07475, jet penetration is 0.625, when mixing 0.32 second, in jet orifice downstream area two
The temperature difference at times caliber is about 39K, and the unevenness of gas mixing is about 0.0135, can reach well mixed degree.
Embodiment 4:Two kinds of mixed gas of the embodiment are hydrogen and chlorine, and the product of reaction is mixed gas, and this is mixed
Closing gas can explode in the case where light is seen, therefore with follow-up storage process be required for lucifuge during the course of the reaction,
Illumination is imposed when using again.
The high-speed gas reactor that the reaction is used includes main flow caliber and the jet orifice (2) of its surface distributed, main flow pipe
Footpath is a logical heart cylindrical tube, and of cylindrical tube is chlorine inlet (1), and the other end of cylindrical tube is mixed gas outlet (3),
30 jet orifices (2) are evenly distributed between (1) 1~1.5 times of mainstream gas entrance in cylindrical tube, jet orifice (2) is passed through
Hydrogen.Under the conditions of lucifuge, mainstream gas are passed through to mainstream gas entrance (1) place of main flow caliber, intake velocity is 6m/s, is penetrated
Discharge orifice (2) is passed through Gas Jet, and intake velocity is 15m/s, and the volume ratio that two kinds of gas is passed through is 1:1, i.e., in mixed gas
Outlet obtains mixed gas or fully reacted product, and the product needs to be stored under lucifuge air-proof condition.
Embodiment 5:Two kinds of mixed gas of the embodiment are nitrogen and hydrogen, and the high-speed gas reactor of use includes master
The jet orifice (2) in flow tube footpath and its surface distributed, main flow caliber is a logical heart cylindrical tube, and of cylindrical tube is mainstream gas
H2Entrance (1), the other end of cylindrical tube is mixed gas synthesis ammonia outlet (3), apart from mainstream gas entrance (1) in cylindrical tube
20 jet orifices (2) are evenly distributed with one week at 1.5 times of calibers, jet orifice is passed through N2, the ratio of jet bore dia and cylinder caliber
Example is 0.05:0.12.
The application method of the reactor is:The operation pressure of reactor is set as 380kPa, in the main flow gas of main flow caliber
Body entrance (1) place is passed through mainstream gas H2(iron catalyst is mixed into mainstream gas as catalyst), the temperature of mainstream gas is 500
DEG C, intake velocity is 3m/s, and jet orifice (2) is passed through Gas Jet N2, temperature is 300 DEG C, and intake velocity is 6m/s, N2And H2's
Volume ratio is 1:3, jet penetration is 0.6, i.e., obtain mixed gas or fully reacted product in mixed gas outlet
Synthesis ammonia.
Specific embodiment of the invention is explained in detail above in association with accompanying drawing, but the present invention be not limited to it is above-mentioned
Implementation method, in the ken that those of ordinary skill in the art possess, can also be before present inventive concept not be departed from
Put and make a variety of changes.
Claims (9)
1. the jet orifice of a kind of high-speed gas reactor, including main flow caliber and its surface distributed, it is characterised in that:Main flow caliber
It is a logical heart cylindrical tube, of cylindrical tube is mainstream gas entrance (1), and the other end of cylindrical tube is mixed gas outlet
(3) multiple jet orifices (2), are distributed between (1) 1~1.5 times of caliber of mainstream gas entrance in cylindrical tube.
2. high-speed gas reactor according to claim 1, it is characterised in that:Enter apart from mainstream gas in the cylindrical tube
At (1) one times of caliber of mouth multiple jet orifices (2) are evenly distributed with one week along caliber.
3. high-speed gas reactor according to claim 1 and 2, it is characterised in that:The diameter of the multiple jet orifice (2)
It is identical.
4. high-speed gas reactor according to claim 1 and 2, it is characterised in that:The number of the jet orifice (2) is 16
~32, the ratio of jet bore dia and cylinder caliber is 0.05~0.02:0.12~0.05.
5. high-speed gas reactor according to claim 3, it is characterised in that:The number of the jet orifice (2) be 16~
32, the ratio of jet bore dia and cylinder caliber is 0.05~0.02:0.12~0.05.
6. a kind of application method of high-speed gas reactor as claimed in claim 1, it is characterised in that:In the master of main flow caliber
Stream gas access (1) place is passed through mainstream gas, and intake velocity is 2~6m/s, and jet orifice (2) is passed through Gas Jet, intake velocity
It is 3~25m/s, i.e., obtains mixed gas or fully reacted product in mixed gas outlet (3).
7. the application method of high-speed gas reactor according to claim 6, it is characterised in that:The operation of the reactor
Pressure is 380~420kPa.
8. the application method of high-speed gas reactor according to claim 6, it is characterised in that:The Gas Jet is penetrated
Stream penetration depth is 0.32~1.
9. the application method of high-speed gas reactor according to claim 6, it is characterised in that:The Gas Jet and master
The volume flow ratio of gas body is 0.0313~0.106:1.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1277941A (en) * | 2000-06-13 | 2000-12-27 | 华东理工大学 | Titanium white chloride oxidation reactor |
CN1609001A (en) * | 2004-10-28 | 2005-04-27 | 中国科学院过程工程研究所 | Method and apparatus for preparing titanium dioxide by oxidation reactor |
US7771666B2 (en) * | 2002-12-17 | 2010-08-10 | E. I. Du Pont De Nemours And Company | Method of producing nanoparticles using a evaporation-condensation process with a reaction chamber plasma reactor system |
CN105271401A (en) * | 2015-12-04 | 2016-01-27 | 漯河兴茂钛业股份有限公司 | Crystal form regulation and control method for producing titanium dioxide through chlorination process |
-
2017
- 2017-01-23 CN CN201710050420.4A patent/CN106824040A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1277941A (en) * | 2000-06-13 | 2000-12-27 | 华东理工大学 | Titanium white chloride oxidation reactor |
US7771666B2 (en) * | 2002-12-17 | 2010-08-10 | E. I. Du Pont De Nemours And Company | Method of producing nanoparticles using a evaporation-condensation process with a reaction chamber plasma reactor system |
CN1609001A (en) * | 2004-10-28 | 2005-04-27 | 中国科学院过程工程研究所 | Method and apparatus for preparing titanium dioxide by oxidation reactor |
CN105271401A (en) * | 2015-12-04 | 2016-01-27 | 漯河兴茂钛业股份有限公司 | Crystal form regulation and control method for producing titanium dioxide through chlorination process |
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Application publication date: 20170613 |