CN106819963A - One kind protection alliin, allinnase(Allinase)The method of active component - Google Patents

One kind protection alliin, allinnase(Allinase)The method of active component Download PDF

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Publication number
CN106819963A
CN106819963A CN201611120040.5A CN201611120040A CN106819963A CN 106819963 A CN106819963 A CN 106819963A CN 201611120040 A CN201611120040 A CN 201611120040A CN 106819963 A CN106819963 A CN 106819963A
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CN
China
Prior art keywords
garlic
alliin
allinase
cleaning
sterilization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611120040.5A
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Chinese (zh)
Inventor
孙波
包塔娜
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Sichuan Xiaoye Herbary Biological Technology Co Ltd
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Sichuan Xiaoye Herbary Biological Technology Co Ltd
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Priority to CN201611120040.5A priority Critical patent/CN106819963A/en
Publication of CN106819963A publication Critical patent/CN106819963A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23NMACHINES OR APPARATUS FOR TREATING HARVESTED FRUIT, VEGETABLES OR FLOWER BULBS IN BULK, NOT OTHERWISE PROVIDED FOR; PEELING VEGETABLES OR FRUIT IN BULK; APPARATUS FOR PREPARING ANIMAL FEEDING- STUFFS
    • A23N12/00Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts
    • A23N12/02Machines for cleaning, blanching, drying or roasting fruits or vegetables, e.g. coffee, cocoa, nuts for washing or blanching
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/144Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/80Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
    • Y02P60/85Food storage or conservation, e.g. cooling or drying

Abstract

The present invention is a kind of protection alliin, allinnase(Allinase)The method of active component, its technological process is:By garlic-splitting-and, decortication, ultrasonic wave cleaning, ozone sterilization, cut into slices in 0.1 ~ 5% citric acid and konjak portuguese gansu polyose sugar juice after, dehydration, garlic pieces or garlic powder are dried to through heated-air drying or low-temperature microwave again, alliin content is not less than 2.2%, garlic activity ratio 80 ~ 900.It is of the invention that cleaning, sterilization, sterilization have been carried out to garlic using ultrasonic wave cleaning, ozone sterilization technology, instead of traditional chemosterilant(Such as sodium hypochlorite), reduce residual of the harmful chemicals disinfectant in garlic pieces or garlic powder.And the citric acid and konjaku glucomannan of use 0.1% ~ 5% are used as alliin and the protective agent of allinase; effectively alliin and allinase in garlic slicing processes is solved to chemically react; alliin is changed into the problem of other sulfide, make it that really there is application value;Whole production technology uses state-of-the-art technological means, reach clean, the demand of industrial production of low energy consumption.

Description

One kind protection alliin, allinnase(Allinase)The method of active component
Technical field
Field is utilized the present invention relates to Food and hygienical food, more particularly to a kind of protection alliin, allinnase(Garlic Enzyme)The method of active component.
Background technology
Garlic(Aliium Sativm)It is the bulb of Liliaceae allium raw garlic, is that a kind of main medicine-food two-purpose is planted Thing, is described as " natural medicinal plant gold ".Research shows that garlic has sterilized, antiviral, reducing blood lipid, antithrombotic, resists and swell The multiple efficacies such as knurl, regulation human immunity.Therefore the research to the active component of garlic turns into the focus studied for many years both at home and abroad. Alliin is one of primary bioactivity material in garlic, is unique non-protein class sulfur-containing amino acid in garlic, dry in garlic Content 0.6%-2% in material.Allinnase is a kind of endogenous enzymes being present in garlic, is a kind of homogeneous dimer sugar egg In vain, the 10-20% of soluble protein in garlic is accounted for.
Alliin and allinase are in the different parts of Garlic cell, during alliin is present in cytoplasm in the form of the stabilization, And allinase is then present in Cell vacuoles, when garlic is acted on by external force, cell is destroyed, and allinase is contacted with alliin, and enzyme occurs Solution reaction, generates allicin, and allicin generates Allicin, i.e. allicin in the case where enzyme is further acted on;Allicin is only Produce the final active ingredient product of above-mentioned effect.And allicin, Allicin(Allicin)It is moment product, is nothing in normality What method was present.Alliin and allinase are less than in the state of 8% in moisture content, mutually stabilization and Fails To Respond, after someone is edible, Digested in the presence of human body stomach reclaimed water, allicin is absorbed rapidly by stomach and just has stronger effect.Here it is garlic oil and people Garlic is eaten for a long time and can not obtain and effect reason.Using chemical method by its single separation, do not possess commercial Application, two It is exactly two common material compositions that person separates, and does not possess garlic medical treatment and health value at all.
Konjaku glucomannan is(KGM)A kind of natural polymer heteroglycan, with excellent hydrophily, gelation, reversible Property, emulsibility, filming function and thickening power.Present KGM has turned into important food additives and health food.Natural polymer Sub- KGM hydrosols film forming under proper condition, can as edibility and the membrane material of Natural Degradation, be widely used in food, medicine, The field such as agricultural and chemical industry.The film forming of KGM has been obtained for being widely applied in food, especially in fruit freshness preserving side Face.KGM is dissolved in water and forms gelatinous solution, and viscosity is high, stability and good film-forming property, is suitable as the matrix of coating-film fresh-keeping, together When SKGM also there is the ability of Restrain browning and growth of microorganism.
At present, conventional vegetable washing method has clear water to soak, chemical reagent soaks etc..Clear water dip operation is simple, no Fruits and vegetables can be polluted, but cleaning performance is general, and some nutritional ingredients can be lost;Chemical reagent immersion effect is excellent In clear water immersion, but have reagent residual, it is impossible to ensure the security of food.Ultrasonic cleaning technology is using ultrasonic wave Cavitation effect is theoretical, in the attachment of vegetable surface is incorporated water rapidly, so as to reach the purpose of clean vegetables.
With continuing to develop for science and technology, in order to meet modern to the food security of food, steady quality, do not attach Plus the requirement of agent, in the world some new non-thermal sterilization technologies arise at the historic moment.Ozone sterilization technology is exactly to develop in recent years Come a kind of sterilization technology, with sterilizing ability it is strong, speed is fast, scope is wide, security is good, simple to operate, production cost is low Prominent the characteristics of, have become a key technology of food security technology.
In April, 1997 U.S.'s food and Drug Administration(FDA)A straight grip ozone is have modified to be limited as " food additives " The regulation that system is used, it is allowed to processed using ozone in food processing, storage by need not applying;FDA is arranged again within 2001 Enter the additive range that directly can be contacted with food, this is the milestone of ozone sterilization, for foods processing technique progress and The raising of food quality plays the role of great.
The content of the invention
The invention provides a kind of alliin of protection in process of production, allinnase(Allinase)The method of active component. The garlic pieces or garlic powder that the method is produced are with garlic as raw material, through undue valve, decortication, ultrasonic wave cleaning, ozonization, section (0.1 ~ 5% citric acid and konjaku glucomannan protection liquid), dehydration, drying, gained garlic pieces or garlic powder are not less than containing alliin 2.2%, allinase specific activity 80 ~ 900.
The present invention uses ultrasonic cleaning technology, effectively remove soil, pathogenic microorganism that garlic surface carries and Worm's ovum etc., realizes quick, water saving, pollution-free washing.
The present invention uses ozone sterilization technology, and the micro organism quantity for adhering to garlic has 105~107Individual/g, is reduced to 1/100 ~ 1/1000, instead of traditional chemical disinfectant(Such as sodium hypochlorite), improve the security of food.
The technological process of the method is:After garlic-splitting-and, decortication, carry out stirring cleaning into first paragraph rinse bath, pass through Lifting is delivered in second segment rinse bath, opens ultrasonic wave cleaning, and frequency is 20 ~ 80KHz, and power is 0.3 ~ 200W, during cleaning Between 10 minutes ~ 30. minutes, 20 ~ 30 DEG C of temperature, then lifted and be delivered in the 3rd section of rinse bath is passed through ozone sterilization, net garlic rice warp After microtome, into there being protective agent(0.1 ~ 5% citric acid and konjaku glucomannan)In rinse bath, conveyed by being lifted Into centrifuge, surface water is sloughed, into air drier or low-temperature microwave drying machine, dried.The temperature of heated-air drying is 50 ~ 60 DEG C, the time is 120 minutes.2200 ~ the 3200MHz of frequency of microwave drying, the time is 20 ~ 180 minutes, and temperature is 50 ~ 60 DEG C, 0.08 ~ 0.09MPa of vacuum.
Specific embodiment of the invention is elaborated below in conjunction with actual conditions.
Embodiment 1
100 kilograms of fresh garlic is taken, after point valve, decortication, in conveying hoisting to first paragraph rinse bath, cleaning is stirred, surface is removed Soil after, boosted to deliver into second segment rinse bath, unlatching ultrasonic frequency is 20kHz, power is 0.3W, temperature 20 DEG C, after cleaning 10 minutes, lifting again is delivered in the 3rd section of rinse bath, opens ozone generator, carries out sterilization, 10 minutes Afterwards, the sliced machine section of garlic rice for cleaning up, into the cleaning equipped with 0.2% citric acid and 0.1% konjak portuguese gansu polyose sugar liquors In groove, it is delivered in centrifuge by lifting, air drier drying is carried out after dehydration, temperature is 50 DEG C, and the time is 120 points Clock.Obtain 14.2 kilograms of product, alliin content 2.3%, garlic activity ratio 100 ~ 200.
Embodiment 2
100 kilograms of fresh garlic is taken, after point valve, decortication, in conveying hoisting to first paragraph rinse bath, cleaning is stirred, surface is removed Soil after, boosted to deliver into second segment rinse bath, unlatching ultrasonic frequency is 40kHz, power is 50W, and temperature is 25 DEG C, after cleaning 8 minutes, lifting again is delivered in the 3rd section of rinse bath, opens ozone generator, carries out sterilization, 10 minutes Afterwards, the sliced machine section of garlic rice for cleaning up, into the cleaning equipped with 0.5% citric acid and 0.2% konjak portuguese gansu polyose sugar liquors In groove, it is delivered in centrifuge by lifting, air drier drying is carried out after dehydration, temperature is 55 DEG C, and the time is 120 points Clock.Obtain 14.5 kilograms of product, alliin content 2.4%, garlic activity ratio 150 ~ 220.
Embodiment 3
100 kilograms of fresh garlic is taken, after point valve, decortication, in conveying hoisting to first paragraph rinse bath, cleaning is stirred, surface is removed Soil after, boosted to deliver into second segment rinse bath, unlatching ultrasonic frequency is 50kHz, power is 180W, and temperature is 30 DEG C, after cleaning 5 minutes, lifting again is delivered in the 3rd section of rinse bath, opens ozone generator, carries out sterilization, 10 minutes Afterwards, the sliced machine section of garlic rice for cleaning up, into the cleaning equipped with 0.8% citric acid and 0.1% konjak portuguese gansu polyose sugar liquors In groove, it is delivered in centrifuge by lifting, low-temperature microwave drying machine drying, 2200 ~ 3200MHz of frequency, temperature is carried out after dehydration It is 50 DEG C to spend, and the time is 150 minutes.Obtain 14.8 kilograms of product, alliin content 2.7%, garlic activity ratio 130 ~ 250.

Claims (4)

1. it is a kind of to protect alliin, allinnase(Allinase)The method of active component, it is characterised in that by garlic-splitting-and, decortication Afterwards, by after ultrasonic wave-ozone linkage cleaning and sterilization, being cut into slices in the protection liquid of 0.1 ~ 5% citric acid and konjaku glucomannan, Dehydration, then heated-air drying or low-temperature microwave drying are carried out, can obtain alliin content and be not less than 2.2%, garlic activity ratio 80 ~ 900 Different size and purposes garlic pieces or garlic powder.
2. the ultrasonic wave as described in claim 1-ozone linkage cleaning and sterilization, it is characterised in that:Ultrasonic wave cleaning frequency be 20 ~ 80KHz, power is 0.3 ~ 200W, scavenging period 10 minutes ~ 30. minutes, 20 ~ 30 DEG C of temperature, the linkage of ultrasonic wave-ozone Cleaning and sterilization, thoroughly instead of traditional chemical disinfectant(Such as sodium hypochlorite)Residual in food.
3. the garlic as described in claim 1 is cut into slices under the protection of 0.1 ~ 5% citric acid and konjaku glucomannan, and it is special Levy and be:Garlic active ingredient is alliin and allinase, and they are respectively present in the cytoplasm and cell liquid of garlic, work as garlic After breaking-wall cell, the two contacts with each other, and reacts rapidly, produces allicin, and further reaction is that garlic is newly plain, i.e. allicin, With 0.1 ~ 5% citric acid and konjaku glucomannan as protective agent, konjaku glucomannan can form one layer of protection in garlic pieces Film, used as the blocking agent for reflecting, both citric acid act synergistically, and has been effectively blocked alliin and allinase after Garlic cell broken wall Reaction.
4. the heated-air drying or low-temperature microwave as described in claim 1 are caught up with, it is characterised in that the frequency of microwave drying be 2200 ~ 3200MHz, the time is 20 ~ 180 minutes, and temperature is 50 ~ 60 DEG C, 0.08 ~ 0.09Mpa of vacuum;The temperature of heated-air drying be 50 ~ 60 DEG C, the time is 120 minutes.
CN201611120040.5A 2016-12-08 2016-12-08 One kind protection alliin, allinnase(Allinase)The method of active component Pending CN106819963A (en)

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CN201611120040.5A CN106819963A (en) 2016-12-08 2016-12-08 One kind protection alliin, allinnase(Allinase)The method of active component

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108523050A (en) * 2018-04-25 2018-09-14 成都菊乐科技发展有限公司 A kind of production technology of high-quality garlic powder
CN111773159A (en) * 2019-04-04 2020-10-16 陈伟宏 Garlic extract and its preparation method
CN112516156A (en) * 2020-11-02 2021-03-19 江苏泰德医药有限公司 Product for inhibiting virus, preparation method and application

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN102382020A (en) * 2010-08-31 2012-03-21 成都菊乐制药有限公司 Method for simultaneously extracting alliin and garlic enzyme from garlic
CN102630888A (en) * 2012-03-30 2012-08-15 宁波立华植物提取技术有限公司 Preparation method of high-content alliin garlic slice
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* Cited by examiner, † Cited by third party
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CN101849810A (en) * 2010-05-27 2010-10-06 农业部南京农业机械化研究所 Ultrasonic ozone combined cleaning equipment used for kitchens and cleaning method thereof
CN102382020A (en) * 2010-08-31 2012-03-21 成都菊乐制药有限公司 Method for simultaneously extracting alliin and garlic enzyme from garlic
CN102630888A (en) * 2012-03-30 2012-08-15 宁波立华植物提取技术有限公司 Preparation method of high-content alliin garlic slice
CN104026214A (en) * 2014-05-13 2014-09-10 福建立兴食品有限公司 Preparing method of vacuum freeze-dried strawberry products

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108523050A (en) * 2018-04-25 2018-09-14 成都菊乐科技发展有限公司 A kind of production technology of high-quality garlic powder
CN111773159A (en) * 2019-04-04 2020-10-16 陈伟宏 Garlic extract and its preparation method
CN112516156A (en) * 2020-11-02 2021-03-19 江苏泰德医药有限公司 Product for inhibiting virus, preparation method and application

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Application publication date: 20170613