CN106811771A - A kind of aluminum electrolyzing cell used insulation of fire door formula compound covering method and device - Google Patents

A kind of aluminum electrolyzing cell used insulation of fire door formula compound covering method and device Download PDF

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Publication number
CN106811771A
CN106811771A CN201710060344.5A CN201710060344A CN106811771A CN 106811771 A CN106811771 A CN 106811771A CN 201710060344 A CN201710060344 A CN 201710060344A CN 106811771 A CN106811771 A CN 106811771A
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China
Prior art keywords
insulation
cladding system
compound
anode
cell
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CN201710060344.5A
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CN106811771B (en
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杨涛
肖红俊
黄�俊
陈才荣
李猛
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Guiyang Aluminum Magnesium Design and Research Institute Co Ltd
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Guiyang Aluminum Magnesium Design and Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08Cell construction, e.g. bottoms, walls, cathodes
    • C25C3/12Anodes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

The invention discloses a kind of aluminum electrolyzing cell used insulation of fire door formula compound covering method and device, the method is the inner side along the whole ring recess shell of aluminium cell between the outside of anode unit, it is more than electrolyte levels and sideways furnace wall, and below cell cover plate, more than two pieces of the compound cladding system of integrally formed insulation is set, the compound cladding system of monolithic insulation is independently opened and closed, form the fire door formula insulation covering complexes being completely covered along the whole circle of pot shell, substitute the sidepiece coverage mode that tradition electrolyte aluminum oxide mixed powder receives side, the insulation of integrated existing powdery mulch simultaneously, gas collection and anti-oxidation function.The present invention can substitute the setting insulation cladding system of traditional bulk electrolyte aluminum oxide mixed powder, with good insulation and sealing property.Meanwhile, insulation cladding system of the invention also has good shaping performance and anti-wear performance.

Description

A kind of aluminum electrolyzing cell used insulation of fire door formula compound covering method and device
Technical field
The invention belongs to technical field of aluminum electrolysis, and in particular to one kind reduces aluminum electrolysis energy consumption, substitutes existing electrolysis Matter and aluminum oxide mixed powder receive the method and complexes on side.
Background technology
Aluminium electroloysis equipment technology level is improved in production run, is the pass for realizing energy saving of electrolytic production of aluminium, consumption reduction, emission reduction Key.In production run, the composition of anode-covered material is electrolyte granular and the oxidation of different grain size size to existing aluminium cell The mixed material of alumina particles, mulch mainly plays a part of to be incubated and prevents anode surface from aoxidizing, mulch mainly by overhead traveling crane and Manually it is added.
In electrolysis production link now, change poles almost turn into every electrolytic cell daily necessary to operational sequence, and from Change poles prepares to start, and to the addition for completing mulch, takes about 30min.During change poles, there are such some steps, such as: Preparation change it is old it is extremely preceding the loosenings mulch of anode surface is shoveled out, overhead traveling crane loosens hardened coating, taking-up anode, extremely gone up newly Addition mulch etc., produces substantial amounts of dust in these steps, deteriorate operating environment.
Meanwhile, electrolytic cell production run requires fine-grained management further, in the addition step of anode-covered material, each factory rules and regulations The model component proportion of mulch, Particle size requirements, cladding thickness etc..However, more artificial participations make practical implementation difficult To accomplish the monitoring of quantification of targets and implement, each workshop section, the presentation attributes of each area's electrolytic cell are difficult to standardize.
In addition, the continuous consumption of operation and the anode with production, the heat condition of various location also with changing, And existing anode coverage mode is more difficult accomplishes to adjust the heat condition leave of absence.
Due to the severe corrosive of electrolyte, the compound cladding system of insulation can be affected by and be difficult to ensure that the life-span more long Cycle.
The content of the invention
It is an object of the invention to provide a kind of aluminum electrolyzing cell used insulation of fire door formula compound covering method and device, it is used to substitute The bulk electrolyte granular of parts of traditional and the mixing mulch of alumina particle, are ensureing not oxidizing anode, electrolytic cell insulation Performance and do not influence electrolytic cell inner anode change on the basis of overcome foregoing the deficiencies in the prior art.
The technical scheme is that such:
Present invention firstly provides the aluminum electrolyzing cell used anode covering method of such a, the method is along the whole ring recess of aluminium cell The inner side of shell more than electrolyte levels and sideways furnace wall, and below cell cover plate, sets more than two pieces between the outside of anode unit The compound cladding system of integrally formed insulation, monolithic insulation compound cladding system independently opens and closes, and formation is whole along pot shell The fire door formula insulation covering complexes that circle is completely covered, the sidepiece for substituting tradition electrolyte aluminum oxide mixed powder receipts side covers Lid mode, while the insulation of integrated existing powdery mulch, gas collection and anti-oxidation function.
The present invention proposes a kind of aluminum electrolyzing cell used anode cladding system according to the above method, and it is including more than two pieces along aluminium The inner side of the whole ring recess shell of electrolytic cell is between the outside of anode unit, more than the liquid level of electrolyte solution and sideways furnace wall and cell cover plate The compound cladding system of insulation arranged below, the compound cladding system of the insulation includes being located at outside electrolysis flute length side slots shell and anode The compound covering dress of the compound cladding system of sidepiece long between side and the end between electrolytic cell end pot shell and anode outside Put;The compound cladding system of monolithic insulation is independently opened and closed, and is formed the fire door formula being completely covered along the whole circle of pot shell and is incubated covering Complexes.
Further, the compound cladding system of monolithic insulation uses groove type structure, and including working lining, working lining is using resistance to Fiery material global formation;It is heat-insulation layer to be provided with the working lining of groove type, and working lining and heat-insulation layer are collectively forming covering aluminium electroloysis The compound cladding system of the insulation on groove groove periphery;Heat-resisting bar-mat reinforcement is provided with working lining or working lining and heat-insulation layer to reinforce.
Further, between the adjacent compound cladding system of insulation and insulation is compound between cladding system and anode unit Flexibly thermal insulation material layer is provided with, flexibly thermal insulation material layer is using ceramic fibre rope, ceramic fiber blanket, ceramic fiber blanket or asbestos cord In one or more composition.
Further, monolithic insulation composite coating outer upper is provided with frame-type opening and closing structure, frame-type opening and closing Structure is fixedly connected with the compound cladding system of insulation, and is actively coupled with the loose-leaf seat on pot shell.
Principle of the invention:
The coating of aluminium cell has insulation and seals anti-oxidation effect, and traditional coating uses bulk electricity Solution matter and aluminum oxide mixed powder, with impurity is brought into during mixing, in high-temperature region, the mixed powder easily forms hardness Larger block, and area in electrolyte is molten to, pollute electrolyte.The use of bulk compound easily cause production operation it is complicated, It is difficult to control to, also deteriorates operating environment.
Coating heat-insulating property be weigh electrolytic cell energy consumption level an important indicator, seal it is bad will cause aluminium liquid, The oxidation of anode etc., it is therefore desirable to the setting insulation cladding system for substituting traditional bulk electrolyte aluminum oxide mixed powder will Ask good insulation and sealing property.Simultaneously as insulation cladding system has the function of upset concurrently, insulation cladding system is also required Good shaping performance and anti-wear performance.
The present invention is incubated compound cladding system and covers the inner side of the whole ring recess shell of aluminium cell to outside anode unit using polylith Between side, more than electrolyte levels and sideways furnace wall, the sidepiece covering that tradition electrolyte aluminum oxide mixed powder receives side is substituted Mode, between the gap of the adjacent compound cladding system of insulation, filling flexible insulation material using ceramic fibre rope (felt, blanket), The refractory fibrous materials such as asbestos cord, realize sealing and heat insulation effect.
The compound cladding system of insulation of the invention is mainly opened by refractory material, insulation material, heat-resisting bar-mat reinforcement and frame-type Close structure composition.Refractory material constitutes the working lining of the compound cladding system of insulation, good with corrosion-resistant, wear-resisting and elevated temperature strength Feature, the refractory material for using for example Al-Si Refractory Materials, phosphate refractory, carbonitride of silicium, carborundum, carbon material, Electrolyte of generation etc. is electrolysed, working lining is groove type monolithic molding.Filled thermal insulation materials have within the groove of working lining Good heat-insulating property, such as silicic acid cover plate, aluminosilicate fiber cotton, ceramic fibre, perlite.Heat-resisting bar-mat reinforcement is located at working lining Internal or working lining and the inside of heat-insulation layer, strengthen the globality and non-deformability of the compound cladding system of insulation.Frame-type is opened The top that structure is located at the compound cladding system of insulation is closed, respectively with insulation cladding system and installed in groove along fixed fastener phase Even, it is ensured that the compound cladding system of insulation can be overturn around fastener.
Brief description of the drawings
Fig. 1 is aluminum electrolyzing cell used compound cladding system schematic diagram (top view) of fire door formula insulation;
Fig. 2 is aluminum electrolyzing cell used compound cladding system schematic diagram (side view) of fire door formula insulation;
Fig. 3 is the compound cladding system of insulation and loose-leaf seat schematic diagram.
Description of reference numerals:1- sidepieces long are combined cladding system, and 2- ends are combined cladding system, 3- electrolysis flute length side slots Shell, 4- anodes, 5- electrolytic cells end pot shell, 6- electrolyte solutions, 7- sideways furnace walls, 8- working linings, 9- heat-insulation layers, 10- heat resisting steel Muscle net, 11- flexibly thermal insulation materials layer, 12- frame-type opening and closing structures, 13- loose-leaves seat.
Specific embodiment
The present invention is described in further detail with reference to the accompanying drawings and examples.
As shown in Figure 1-Figure 3, covering method of the invention is the inner side along the whole ring recess shell of aluminium cell to the outer of anode unit Between side, more than the liquid level and sideways furnace wall of electrolyte solution 6, and below cell cover plate, the integrally formed insulation of configuration polylith is compound Cladding system, the compound cladding system of monolithic can be opened and closed independently, formed the fire door formula being completely covered along the whole circle of pot shell and be incubated Covering complexes, substitute the sidepiece coverage mode that tradition electrolyte aluminum oxide mixed powder receives side, while integrated existing powder The insulation of shape mulch, gas collection and anti-oxidation function.As shown in figure 1, the compound cladding system 1 of sidepiece long is located at electrolysis flute length sidepiece Between pot shell 3 and the outside of anode 4, the compound cladding system 2 in end is located between electrolytic cell end pot shell 5 and the outside of anode 4;As schemed Shown in 2, the compound coating device layer of sidepiece long and end is all located at the liquid level and sideways furnace wall more than 7 of electrolyte solution 6.
As shown in figure 3, monolithic is incubated composite coating using groove type design, nearly anode and pot shell and fused electrolyte High-temperature region working lining 8, using the good refractory material monolithic molding of corrosion-resistant, wear-resisting and elevated temperature strength, such as aluminium silicon systems fire resisting Electrolyte that material, phosphate refractory, carbonitride of silicium, carborundum, carbon material, electrolysis are produced etc., groove type working lining It is inside heat-insulation layer 9, fills the insulation material of good heat preservation performance, such as silicic acid cover plate, aluminosilicate fiber cotton, ceramic fibre, perlite, Working lining 8 and heat-insulation layer 9 are collectively forming the compound cladding system of insulation on covering aluminium electrolysis cell periphery.In working lining 8 or work Make to be reinforced using heat-resisting bar-mat reinforcement 10 in layer 8 and heat-insulation layer 9, the bulk strength and performance of the compound cladding system of enhancing insulation.
As shown in Figure 1, Figure 2, between the adjacent compound cladding system of insulation and insulation is compound between cladding system and anode unit Configuration flexibly thermal insulation material layer 11, to make the seam between insulation composite coating up, plays insulation and closed, flexible heat-insulating Material is using refractory fibrous materials such as ceramic fibre rope (felt, blanket), asbestos cords.Such as Fig. 3, on monolithic insulation composite coating outside Portion, configuration block posture opening and closing structure 12.Frame-type opening and closing structure is fixedly connected with the compound cladding system of insulation, and with installed in groove 13 (such as Fig. 3) of loose-leaf seat on shell are actively coupled, it is ensured that overturn the compound cladding system of insulation using pry bar special for new type.
Implementation steps of the invention are as follows:
1) directly transformed in aluminium cell in existing operation, loose-leaf seat 13 is arranged on electrolysis flute length side on request The groove of portion's pot shell 3 and end pot shell 5 is along upper;
2) the compound cladding system 1 of sidepiece insulation long and end guarantor are respectively mounted along the whole circle of pot shell in electrolytic bath of aluminium side 7 The compound cladding system 2 of temperature;
3) the frame-type opening and closing structure 12 at the top of compound cladding system and step 1 will be incubated) in loose-leaf seat 13 couple, reality Now it is incubated the turn over function of compound cladding system.
4) by step 1), 2), 3) after the compound cladding system of installation insulation, in the gap of the compound lid arrangement of adjacent insulation Place and insulation are compound resistance to using ceramic fibre rope 11 (felt, blanket), asbestos cord etc. with flexibly thermal insulation material between lid arrangement and anode 4 Fiery fibrous material is filled, and realizes sealing and heat insulation effect.
Certainly, it is more than concrete application example of the invention, the present invention also has other implementation methods, all using equivalent The technical scheme that replacement or equivalent transformation are formed, all falls within protection domain of the presently claimed invention.

Claims (5)

1. a kind of aluminum electrolyzing cell used anode covering method, it is characterised in that:Along the inner side of the whole ring recess shell of aluminium cell to anode unit Outside between, more than electrolyte levels and sideways furnace wall, and below cell cover plate, more than two pieces of integrally formed insulation is set Compound cladding system, the compound cladding system of monolithic insulation is independently opened and closed, and forms the fire door being completely covered along the whole circle of pot shell Formula insulation covering complexes, substitute the sidepiece coverage mode that tradition electrolyte aluminum oxide mixed powder receives side, while integrated The insulation of existing powdery mulch, gas collection and anti-oxidation function.
2. a kind of aluminum electrolyzing cell used anode cladding system, it is characterised in that:It is including more than two pieces along the whole ring recess of aluminium cell To between the outside of anode unit, more than the liquid level and sideways furnace wall of electrolyte solution (6), and cell cover plate is arranged below for the inner side of shell The compound cladding system of insulation, the compound cladding system of the insulation includes being located at electrolysis flute length side slots shell (3) and anode (4) outside Between the compound cladding system (1) of sidepiece long and the end between electrolytic cell end pot shell (5) and anode (4) outside be combined and cover Lid arrangement (2).
3. aluminum electrolyzing cell used anode cladding system according to claim 2, it is characterised in that:The compound covering dress of monolithic insulation Put using groove type structure, and including working lining (8), working lining (8) uses refractory material global formation;The working lining of groove type (8) it is heat-insulation layer (9) to be provided with, and the insulation that working lining (8) and heat-insulation layer (9) are collectively forming covering aluminium electrolysis cell periphery is combined Cladding system;Reinforced in working lining (8) or working lining (8) the heat-resisting bar-mat reinforcement (10) that is provided with interior with heat-insulation layer (9).
4. aluminum electrolyzing cell used anode cladding system according to claim 2, it is characterised in that:In the compound covering of adjacent insulation Between device and insulation is compound that flexibly thermal insulation material layer (11), flexibly thermal insulation material layer are provided between cladding system and anode unit (11) using one or more composition in ceramic fibre rope, ceramic fiber blanket, ceramic fiber blanket or asbestos cord.
5. aluminum electrolyzing cell used anode cladding system according to claim 2, it is characterised in that:Monolithic is incubated composite coating Outer upper is provided with frame-type opening and closing structure (12), and the frame-type opening and closing structure (12) is fixed with the compound cladding system of insulation and connected Connect, and be actively coupled with loose-leaf seat (13) on pot shell.
CN201710060344.5A 2017-01-24 2017-01-24 Furnace door type heat preservation composite covering method and device for aluminum electrolytic cell Active CN106811771B (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108056831A (en) * 2017-12-27 2018-05-22 海盐纵诚物资有限公司 Ultrasonic scaling device
CN110106527A (en) * 2019-04-02 2019-08-09 贵州省六盘水双元铝业有限责任公司 A kind of electrolytic cell stereoscopic heat-insulating device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102061487A (en) * 2009-11-17 2011-05-18 贵阳铝镁设计研究院 External thermal insulation structure of electrolytic cell
CN102747382A (en) * 2011-04-21 2012-10-24 贵阳铝镁设计研究院有限公司 Heat preserving and oxidation resisting method in aluminum electrolysis cell production and heat preserving covering device
CN104514011A (en) * 2013-09-13 2015-04-15 高伟 Aluminum electrolysis tank provided with heat insulation and material stopping device
CN105274571A (en) * 2014-06-04 2016-01-27 贵阳铝镁设计研究院有限公司 Method for covering aluminum electrolysis bath prebaked anode
CN206467299U (en) * 2017-01-24 2017-09-05 贵阳铝镁设计研究院有限公司 A kind of aluminum electrolyzing cell used compound cladding system of fire door formula insulation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102061487A (en) * 2009-11-17 2011-05-18 贵阳铝镁设计研究院 External thermal insulation structure of electrolytic cell
CN102747382A (en) * 2011-04-21 2012-10-24 贵阳铝镁设计研究院有限公司 Heat preserving and oxidation resisting method in aluminum electrolysis cell production and heat preserving covering device
CN104514011A (en) * 2013-09-13 2015-04-15 高伟 Aluminum electrolysis tank provided with heat insulation and material stopping device
CN105274571A (en) * 2014-06-04 2016-01-27 贵阳铝镁设计研究院有限公司 Method for covering aluminum electrolysis bath prebaked anode
CN206467299U (en) * 2017-01-24 2017-09-05 贵阳铝镁设计研究院有限公司 A kind of aluminum electrolyzing cell used compound cladding system of fire door formula insulation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108056831A (en) * 2017-12-27 2018-05-22 海盐纵诚物资有限公司 Ultrasonic scaling device
CN108056831B (en) * 2017-12-27 2021-09-10 海盐纵诚物资有限公司 Ultrasonic tooth cleaning device
CN110106527A (en) * 2019-04-02 2019-08-09 贵州省六盘水双元铝业有限责任公司 A kind of electrolytic cell stereoscopic heat-insulating device

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