CN106800897A - A kind of table tennis bat adhesive specially and preparation method thereof - Google Patents
A kind of table tennis bat adhesive specially and preparation method thereof Download PDFInfo
- Publication number
- CN106800897A CN106800897A CN201710062464.9A CN201710062464A CN106800897A CN 106800897 A CN106800897 A CN 106800897A CN 201710062464 A CN201710062464 A CN 201710062464A CN 106800897 A CN106800897 A CN 106800897A
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- China
- Prior art keywords
- ultra
- thin titanium
- titanium sheet
- table tennis
- tennis bat
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of table tennis bat adhesive specially, primary raw material is aluminium hydroxide, carragheen, fatty alcohol-ether sodium sulfate, sodium chloride, nanoscale elastomeric additive and water；Using aqueous binder, rather than traditional solvent type adhesive, environmental protection, health；Nanoscale elastomeric additive is the ultra-thin titanium sheet that is modified, it forms cellular nano-tube array by carrying out secondary oxidation to ultra-thin titanium sheet, these nano-tube arrays have extraordinary intensity and elasticity, while there is the effect of increase skin-friction force, so as to increase the anti-rotational ability of rubber.After being protected to the rubber surface of table tennis bat using adhesive specially of the invention, than being compared using traditional adhesive, the elasticity of racket can improve 20 one 30%, and it is still not in the situation for corroding rubber after 3 years to use.
Description
Technical field
The present invention relates to technical field of sports apparatus, more particularly to a kind of table tennis bat adhesive specially and its preparation side
Method.
Background technology
Table tennis (ping-pong), Chinese national ball game is a kind of ball sports project of world pop, including attack, confrontation
And defence.Table tennis originates from Britain, and " table tennis " one is originated from 1900, sent when being hit because of it " Ping Pong "
Sound and gain the name, in China's Mainland using " table tennis " as its official name, the area such as Hong Kong and Macao is also same.Table tennis is
Spherical shape, 2.53-2.70 grams of weight, white or yellow is made, international tournament before the Sydney Olympic Games 2000 of celluloid or plastics
With a diameter of 38mm of ball, a diameter of 40mm of international tournament ball afterwards in 2000.Sportsman respectively stands billiard table side, in centre
Being separated with 274 centimetres of the length of horizontal net, wide 152 centimetres, 76 centimetres high of billiard table is carried out, batted with racket (striking have gear, take out, cut,
Rub with the hands, draw etc.), ball could fight back net after must being rebounded on platform, be effective to fall on other side's table top.A match point group, singles,
Doubles etc. are several；With 11 points for one innings, using best of 5 games, seven innings of four victory.
Table tennis bat is made up of base plate, rubber and the part of sponge three.The reasonably combined of three determines one piece of matter of racket
Amount.We frequently refer to the term of table tennis bat and sponge, such as：" speed ", " control " and " elasticity " " base plate is soft or hard " etc..In fact
, but all without the numerical value that industry is unified, simply all big enterprises when consumer buys in order to have certain experience to draw on and oneself for these indexs
What oneself divided.
Traditional table tennis bat surface rubber in use, due to the long-term use of rubber, can cause it is aging, its glue
Property degree can constantly decline, and the anti-rotational ability of rubber can constantly weaken.To ensure the performance of racket and the quality of batting, just need
Rubber is often changed, but often changes rubber not only high cost, and the sponge that may be damaged below rubber.In addition pass through
Often changing rubber may cause to transport the training and competition of work(person because the performance of rubber is inconsistent.
The content of the invention
Based on the technical problem that background technology is present, the present invention is proposed and a kind of rubber on table tennis bat surface protected
Table tennis bat adhesive specially and preparation method thereof.
Technical scheme is as follows：
A kind of table tennis bat adhesive specially, including following percentage by weight composition：
Aluminium hydroxide 2-3%
Carragheen 8-15%
Fatty alcohol-ether sodium sulfate 3-8%
Sodium chloride 0.2-0.5%
Nanoscale elastomeric additive 0.01-0.03%
Water surplus.
Described nanoscale elastomeric additive is the ultra-thin titanium sheet that is modified.
A kind of preparation method of table tennis bat adhesive specially, comprises the following steps：
A, at room temperature, using ultra-thin titanium sheet as anode, used as negative electrode, electrolyte is 0.2-0.5% ammonium fluoride (matter to metal platinum
Amount fraction), ethylene glycol and 1-2.5% water (volume fraction), carry out once oxidation, oxidation voltage is 60V, and the time is 10-
20min, ultra-thin titanium plate surface forms titanium dioxide array；
B, by ultra-thin titanium sheet take out after, being placed in deionized water makes the titanium dioxide of ultra-thin titanium plate surface by ultrasonic vibration
Array is removed, drying；
, used as anode, metal platinum is used as negative electrode, electrolyte in step for C, the ultra-thin titanium sheet that will be processed by step B
In carry out secondary oxidation, oxidation voltage is that 20-50V, oxidization time are 30-45min, will ultra-thin titanium sheet take out after use deionized water
Clean up；
It is D, carragheen is soluble in water, under the mixing speed of 250-300rpm, nanoscale elastomeric additive is added, continue
Stirring 15-25min；
E, addition fatty alcohol-ether sodium sulfate, aluminium hydroxide and sodium chloride adjust viscosity to 800-2000cps, you can.
In preparation process of the invention, first using secondary oxidation technique in the ultra-thin cellular nanometer of titanium sheet Surface Creation
Pipe array, is then added into being well mixed in OK a karaoke club glue solution, adhesive is had certain protective effect to ultra-thin titanium sheet,
Subsequently add other raw materials to adjust viscosity, and add aluminium hydroxide further to improve the intensity of adhesive.
The present invention is advantageous in that：Table tennis bat adhesive specially of the invention, primary raw material is aluminium hydroxide, card
Draw glue, fatty alcohol-ether sodium sulfate, sodium chloride, nanoscale elastomeric additive and water；Using aqueous binder, rather than traditional molten
Formulation adhesive, environmental protection, health；Nanoscale elastomeric additive is the ultra-thin titanium sheet that is modified, and it is secondary by carrying out to ultra-thin titanium sheet
Oxidation forms cellular nano-tube array, and these nano-tube arrays have extraordinary intensity and elasticity, while having increase
The effect of skin-friction force, so as to increase the anti-rotational ability of rubber.Using adhesive specially of the invention to table tennis bat
After rubber surface is protected, than using traditional adhesive, (rubber of Chinese invention patent CN101220235A embodiments 1 is protected
Nutrient solution) to compare, the elasticity of racket can improve 20-30%, use the situation for after 3 years being still not in corrosion rubber.
Specific embodiment
Embodiment 1：
A kind of table tennis bat adhesive specially, including following percentage by weight composition：
Aluminium hydroxide 2.5%
Carragheen 12%
Fatty alcohol-ether sodium sulfate 5.5%
Sodium chloride 0.3%
Modified ultra-thin titanium sheet 0.025%
Water surplus.
A kind of preparation method of table tennis bat adhesive specially, comprises the following steps：
A, at room temperature, using ultra-thin titanium sheet as anode, used as negative electrode, electrolyte is 0.3% ammonium fluoride (quality point to metal platinum
Number), ethylene glycol and 2% water (volume fraction), carry out once oxidation, oxidation voltage is 60V, and the time is 15min, ultra-thin titanium sheet table
Face forms titanium dioxide array；
B, by ultra-thin titanium sheet take out after, being placed in deionized water makes the titanium dioxide of ultra-thin titanium plate surface by ultrasonic vibration
Array is removed, drying；
, used as anode, metal platinum is used as negative electrode, electrolyte in step for C, the ultra-thin titanium sheet that will be processed by step B
In carry out secondary oxidation, oxidation voltage is that 35V, oxidization time are 40min, will ultra-thin titanium sheet take out after clean with deionized water and do
Only；
It is D, carragheen is soluble in water, under the mixing speed of 275rpm, nanoscale elastomeric additive is added, continue to stir
22min；
E, addition fatty alcohol-ether sodium sulfate, aluminium hydroxide and sodium chloride adjust viscosity to 1500-1800cps, you can.
Embodiment 2：
A kind of table tennis bat adhesive specially, including following percentage by weight composition：
Aluminium hydroxide 2%
Carragheen 15%
Fatty alcohol-ether sodium sulfate 3%
Sodium chloride 0.2%
Modified ultra-thin titanium sheet 0.01%
Water surplus.
A kind of preparation method of table tennis bat adhesive specially, comprises the following steps：
A, at room temperature, using ultra-thin titanium sheet as anode, used as negative electrode, electrolyte is 0.2% ammonium fluoride (quality point to metal platinum
Number), ethylene glycol and 2.5% water (volume fraction), carry out once oxidation, oxidation voltage is 60V, and the time is 10min, ultra-thin titanium sheet
Surface forms titanium dioxide array；
B, by ultra-thin titanium sheet take out after, being placed in deionized water makes the titanium dioxide of ultra-thin titanium plate surface by ultrasonic vibration
Array is removed, drying；
, used as anode, metal platinum is used as negative electrode, electrolyte in step for C, the ultra-thin titanium sheet that will be processed by step B
In carry out secondary oxidation, oxidation voltage is that 50V, oxidization time are 30min, will ultra-thin titanium sheet take out after clean with deionized water and do
Only；
It is D, carragheen is soluble in water, under the mixing speed of 300rpm, nanoscale elastomeric additive is added, continue to stir
15min；
E, addition fatty alcohol-ether sodium sulfate, aluminium hydroxide and sodium chloride adjust viscosity to 1800-2000cps, you can.
Embodiment 3：
A kind of table tennis bat adhesive specially, including following percentage by weight composition：
Aluminium hydroxide 3%
Carragheen 8%
Fatty alcohol-ether sodium sulfate 8%
Sodium chloride 0.5%
Modified ultra-thin titanium sheet 0.03%
Water surplus.
A kind of preparation method of table tennis bat adhesive specially, comprises the following steps：
A, at room temperature, using ultra-thin titanium sheet as anode, used as negative electrode, electrolyte is 0.5% ammonium fluoride (quality point to metal platinum
Number), ethylene glycol and 1% water (volume fraction), carry out once oxidation, oxidation voltage is 60V, and the time is 20min, ultra-thin titanium sheet table
Face forms titanium dioxide array；
B, by ultra-thin titanium sheet take out after, being placed in deionized water makes the titanium dioxide of ultra-thin titanium plate surface by ultrasonic vibration
Array is removed, drying；
, used as anode, metal platinum is used as negative electrode, electrolyte in step for C, the ultra-thin titanium sheet that will be processed by step B
In carry out secondary oxidation, oxidation voltage is that 20V, oxidization time are 45min, will ultra-thin titanium sheet take out after clean with deionized water and do
Only；
It is D, carragheen is soluble in water, under the mixing speed of 250rpm, nanoscale elastomeric additive is added, continue to stir
25min；
E, addition fatty alcohol-ether sodium sulfate, aluminium hydroxide and sodium chloride adjust viscosity to 800-1200cps, you can.
Comparative example 1
By the modified ultra-thin titanium sheet removal in embodiment 1, remaining preparation condition is constant.
Using comparative example 1 adhesive specially make table tennis bat compared with adhesive is not used, the bullet of racket
Property and anti-rotational ability are without being obviously improved.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (4)
1. a kind of table tennis bat adhesive specially, it is characterised in that the composition including following percentage by weight：
Aluminium hydroxide 2-3%
Carragheen 8-15%
Fatty alcohol-ether sodium sulfate 3-8%
Sodium chloride 0.2-0.5%
Nanoscale elastomeric additive 0.01-0.03%
Water surplus.
2. table tennis bat adhesive specially as claimed in claim 1, it is characterised in that described nanoscale elastomeric additive is
Be modified ultra-thin titanium sheet.
3. table tennis bat adhesive specially as claimed in claim 2, it is characterised in that including following percentage by weight into
Point：
Aluminium hydroxide 2.5%
Carragheen 12%
Fatty alcohol-ether sodium sulfate 5.5%
Sodium chloride 0.3%
Modified ultra-thin titanium sheet 0.025%
Water surplus.
4. a kind of preparation method of table tennis bat adhesive specially, it is characterised in that comprise the following steps：
A, at room temperature, using ultra-thin titanium sheet as anode, used as negative electrode, electrolyte is 0.2-0.5% ammonium fluorides (quality point to metal platinum
Number), ethylene glycol and 1-2.5% water (volume fraction), carry out once oxidation, oxidation voltage is 60V, and the time is 10-20min, is surpassed
Thin titanium plate surface forms titanium dioxide array；
B, by ultra-thin titanium sheet take out after, being placed in deionized water makes the titanium dioxide array of ultra-thin titanium plate surface by ultrasonic vibration
It is removed, drying；
, used as anode, metal platinum is entered as negative electrode in electrolyte in step for C, the ultra-thin titanium sheet that will be processed by step B
Row secondary oxidation, oxidation voltage is 20-50V, oxidization time is 30-45min, will be cleaned with deionized water after the taking-up of ultra-thin titanium sheet
Totally；
It is D, carragheen is soluble in water, under the mixing speed of 250-300rpm, the ultra-thin titanium sheet of modified Nano is added, continue to stir
15-25min；
E, addition fatty alcohol-ether sodium sulfate, aluminium hydroxide and sodium chloride adjust viscosity to 800-2000cps, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710062464.9A CN106800897A (en) | 2017-01-19 | 2017-01-19 | A kind of table tennis bat adhesive specially and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710062464.9A CN106800897A (en) | 2017-01-19 | 2017-01-19 | A kind of table tennis bat adhesive specially and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106800897A true CN106800897A (en) | 2017-06-06 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710062464.9A Pending CN106800897A (en) | 2017-01-19 | 2017-01-19 | A kind of table tennis bat adhesive specially and preparation method thereof |
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| Country | Link |
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| CN (1) | CN106800897A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982591A (en) * | 2019-11-29 | 2020-04-10 | 西京学院 | Durable high-wear-resistance automobile diesel engine lubricating oil |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220235A (en) * | 2007-12-12 | 2008-07-16 | 沈阳工业大学 | Liquid for improving viscidity of bat for table tennis rubber and maintaining the same, and method for producing the same |
| CN105950061A (en) * | 2016-05-16 | 2016-09-21 | 天津纽威特橡胶制品股份有限公司 | Adhering glue for table tennis racket surface rubber |
-
2017
- 2017-01-19 CN CN201710062464.9A patent/CN106800897A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220235A (en) * | 2007-12-12 | 2008-07-16 | 沈阳工业大学 | Liquid for improving viscidity of bat for table tennis rubber and maintaining the same, and method for producing the same |
| CN105950061A (en) * | 2016-05-16 | 2016-09-21 | 天津纽威特橡胶制品股份有限公司 | Adhering glue for table tennis racket surface rubber |
Non-Patent Citations (2)
| Title |
|---|
| 吴红军等: "蜂窝状二氧化钛纳米管阵列的制备及光催化性能", 《东北石油大学学报》 * |
| 李广宇等: "《胶粘与密封新技术》", 31 January 2006, 国防工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982591A (en) * | 2019-11-29 | 2020-04-10 | 西京学院 | Durable high-wear-resistance automobile diesel engine lubricating oil |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170606 |