CN106800771A - A kind of polyamide heat-conducting is material modified - Google Patents

A kind of polyamide heat-conducting is material modified Download PDF

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Publication number
CN106800771A
CN106800771A CN201510830346.9A CN201510830346A CN106800771A CN 106800771 A CN106800771 A CN 106800771A CN 201510830346 A CN201510830346 A CN 201510830346A CN 106800771 A CN106800771 A CN 106800771A
Authority
CN
China
Prior art keywords
polyamide
area
conducting
material modified
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510830346.9A
Other languages
Chinese (zh)
Inventor
黄亚楠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Gerunde New Material Co Ltd
Original Assignee
Qingdao Gerunde New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Gerunde New Material Co Ltd filed Critical Qingdao Gerunde New Material Co Ltd
Priority to CN201510830346.9A priority Critical patent/CN106800771A/en
Publication of CN106800771A publication Critical patent/CN106800771A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92514Pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • B29C2948/9259Angular velocity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Plastic industry is developed so far because it has high corrosion resistance and insulating properties, so as to instead of conventional metals in some fields, polyamide 6 (PA6) engineering plastics have excellent mechanical property and electrical property, also have the advantages that wear-resisting, oil resistant, self-lubricating, corrosion-resistant and good processing characteristics;Also more and more extensively, range of application is including automobile, plant equipment, electronic apparatus, chemical industry equipment, building, daily necessities, communications and transportation etc. for its purposes.The present invention provides a kind of mechanical property for not influenceing material, enhances the material modified preparation method of the polyamide heat-conducting of polyamide material heat conductivility.

Description

A kind of polyamide heat-conducting is material modified
Technical field
The invention belongs to polyamide PA6 material production technologies, specifically a kind of polyamide heat-conducting is material modified And preparation method thereof.
Background technology
Plastic industry is developed so far because it has high corrosion resistance and insulating properties, so as to be substituted in some fields Conventional metals, polyamide 6 (PA6) engineering plastics have excellent mechanical property and electrical property, also with it is wear-resisting, The advantages of oil resistant, self-lubricating, corrosion-resistant and good processing characteristics;Its purposes is also more and more extensive, using model Enclose including automobile, plant equipment, electronic apparatus, chemical industry equipment, building, daily necessities, communications and transportation etc..
The content of the invention
It is material modified and preparation method thereof it is an object of the invention to provide a kind of polyamide heat-conducting.
The material modified raw material of polyamide heat-conducting matches and is by mass percentage:Polyamide PA6:50th, magnesia (10-12um): 50th, antioxidant (copolymer of ethylene-octene):1.5th, colouring agent:1.0th, dispersed lubricant (TAS-2A):1.0.
The material modified preparation method of the polyamide heat-conducting is:Various raw materials are dry-mixed 15-20 minutes in super mixer, then It is placed in double screw extruder through melting extrusion, cooling, pelletizing, packed products;Wherein, the area's temperature of double screw extruder one It is 160-180 DEG C to spend, and 2nd area are 230-250 DEG C, and 3rd area are 255-275 DEG C, and 4th area are 250-270 DEG C;5th area are 230-250 DEG C, the residence time is 1-2 minutes, and pressure is 10-15Mpa.
Specific embodiment
Embodiment
(1) the material modified raw material of the polyamide heat-conducting matches and is by mass percentage:Polyamide PA6:50th, magnesia (10-12um):50th, antioxidant (copolymer of ethylene-octene):1.5th, colouring agent:1.0th, dispersed lubricant (TAS-2A): 1.0。
(2) preparation method of the material is:Various raw materials are dry-mixed 15-20 minutes in super mixer, then it is placed in twin-screw Through melting extrusion, cooling, pelletizing, packed products in extruder;Wherein, the area's temperature of double screw extruder one is 160-180 DEG C, 2nd area are 230-250 DEG C, and 3rd area are 255-275 DEG C, and 4th area are 250-270 DEG C;5th area are 230-250 DEG C, residence time It it is 1-2 minutes, pressure is 10-15Mpa.
Experimental result
Characterisitic parameter Testing standard Performance indications Test data
1 tensile strength MPa ASTM/D638 / 85.0
2 elongation at break % ASTM/D638 / 6.5
3 bending strength MPa ASTM/D790 / 98.5
4 bending modulus MPa ASTM/D790 / 3210.0
5 thermal conductivity W/MK ASTM E1461 / 2.1
6 Izod notched impact strength J/m ASTM/D256 / 75.0

Claims (2)

1. a kind of polyamide heat-conducting is material modified, it is characterised in that raw material matches and is by mass percentage:Polyamide PA6:50、 Magnesia (10-12um):50th, antioxidant (copolymer of ethylene-octene):1.5th, colouring agent:1.0th, dispersed lubricant (TAS-2A):1.0.
2. polyamide heat-conducting according to claim 1 is material modified, it is characterised in that the preparation method of the material is:Will be each Kind of raw material is dry-mixed 15-20 minutes in super mixer, then be placed in double screw extruder through melting extrusion, cooling, pelletizing, Packed products;Wherein, the area's temperature of double screw extruder one is 160-180 DEG C, and 2nd area are 230-250 DEG C, and 3rd area are 255-275 DEG C, 4th area are 250-270 DEG C;5th area are 230-250 DEG C, and the residence time is 1-2 minutes, and pressure is 10-15Mpa.
CN201510830346.9A 2015-11-25 2015-11-25 A kind of polyamide heat-conducting is material modified Pending CN106800771A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510830346.9A CN106800771A (en) 2015-11-25 2015-11-25 A kind of polyamide heat-conducting is material modified

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510830346.9A CN106800771A (en) 2015-11-25 2015-11-25 A kind of polyamide heat-conducting is material modified

Publications (1)

Publication Number Publication Date
CN106800771A true CN106800771A (en) 2017-06-06

Family

ID=58976004

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510830346.9A Pending CN106800771A (en) 2015-11-25 2015-11-25 A kind of polyamide heat-conducting is material modified

Country Status (1)

Country Link
CN (1) CN106800771A (en)

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PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170606

WD01 Invention patent application deemed withdrawn after publication