CN106799070A - A kind of special defoamer of rubber - Google Patents

A kind of special defoamer of rubber Download PDF

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Publication number
CN106799070A
CN106799070A CN201611234690.2A CN201611234690A CN106799070A CN 106799070 A CN106799070 A CN 106799070A CN 201611234690 A CN201611234690 A CN 201611234690A CN 106799070 A CN106799070 A CN 106799070A
Authority
CN
China
Prior art keywords
defoamer
rubber
hydramine
special
aliphatic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611234690.2A
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Chinese (zh)
Inventor
王梅玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Federal Fine Chemical Co Ltd
Original Assignee
Guangdong Federal Fine Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Federal Fine Chemical Co Ltd filed Critical Guangdong Federal Fine Chemical Co Ltd
Priority to CN201611234690.2A priority Critical patent/CN106799070A/en
Publication of CN106799070A publication Critical patent/CN106799070A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/02Foam dispersion or prevention
    • B01D19/04Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/02Foam dispersion or prevention
    • B01D19/04Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • B01D19/0413Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing N-atoms

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

The present invention discloses a kind of special defoamer of rubber, by weight percentage, including:Alkymer 30 50%;Hydramine 4 30%;Aliphatic acid 3 25%;Aliphatic acid alkanolamine ester 4 20%;Dispersant 4 10%;Help defoamer 8 18%.50 70 minutes prepared special defoamers of rubber are stirred after above-mentioned substance is added.Wherein hydramine molecular weight is 100 200, and fatty acid molecule amount is 500 800, and aliphatic acid hydramine ester molecule amount is 1,000 1500;It is one or more in lower alcohol, carboxylic acid vinegar, water-insoluble soap to help defoamer, and dispersant is nonionic surface active agent.Defoamer of the invention has antifoaming speed fast, and suds ability is strong, particularly to having good foam-inhibiting effect for the conventional various anion of rubber, plastics-production system, nonionic foaming agent.In the water-based system easily dispersion, self-emulsifying is strong, froth breaking is good, suds are lasting, especially to water soluble polymer and in, low high viscosity systems have special result.Flake point and pinprick phenomenon will not be produced.

Description

A kind of special defoamer of rubber
Technical field
The present invention relates to defoamer field, more particularly to a kind of special defoamer of rubber production.
Background technology
In rubber industry, be related to rubber cement stir, topple over, flow, filter, deaerate the problems such as when because in system Kinds of surface activating agent is there is, substantial amounts of foam can be produced, because its composition is complex, one is all brought to froth breaking and suds Fixed difficulty.
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, it is an object of the invention to provide a kind of special defoamer of rubber, it is intended to solve The problem of a large amount of foams is certainly produced in rubber industry.
A kind of special defoamer of rubber, wherein:By weight percentage, including:
Alkymer 30-50%;
Hydramine 4-30%;
Aliphatic acid 3-25%;
Aliphatic acid alkanolamine ester 4-20%;
Dispersant 4-10%;
Help defoamer 8-18%.
A kind of described special defoamer of rubber, wherein:The hydramine molecular weight is 100-200, and fatty acid molecule amount is 500-800, aliphatic acid hydramine ester molecule amount is 1000-1500.
A kind of described special defoamer of rubber, wherein:It is described to help defoamer for lower alcohol, carboxylic acid vinegar, water-insoluble fat One or more in fat hydrochlorate, the dispersant is nonionic surface active agent.
Defoamer of the invention has antifoaming speed fast, and suds ability is strong, particularly to for rubber, plastics-production system The conventional various anion of system, nonionic foaming agent have good foam-inhibiting effect.In water-based system easily dispersion, from breast Change property strong, froth breaking is good, suds are lasting, especially to water soluble polymer and in, low high viscosity systems have special result.Will not produce Flake point and pinprick phenomenon.
Specific embodiment
The present invention provides a kind of special defoamer of rubber, for make the purpose of the present invention, technical scheme and effect it is clearer, Clearly, the present invention is described in more detail below.It should be appreciated that specific embodiment described herein is only used to explain this Invention, is not intended to limit the present invention.
Embodiment 1:
A kind of special defoamer of rubber, wherein:By weight percentage, including:
Alkymer 45%;
Hydramine 25%;
Aliphatic acid 10%;
Aliphatic acid alkanolamine ester 5%;
Dispersant 5%;
Help defoamer 10%.
After above-mentioned substance is added into container, 65 minutes prepared special defoamers of rubber are stirred.
Wherein hydramine molecular weight is 120, and fatty acid molecule amount is 750, and aliphatic acid hydramine ester molecule amount is 1350;Help froth breaking Agent is one or more in lower alcohol, carboxylic acid vinegar, water-insoluble soap, and dispersant is nonionic surface active agent.
The defoamer of the present embodiment 1 has antifoaming speed fast, and suds ability is strong, particularly to for rubber, plastics-production The conventional various anion of system, nonionic foaming agent have good foam-inhibiting effect.In water-based system easily dispersion, from breast Change property strong, froth breaking is good, suds are lasting, especially to water soluble polymer and in, low high viscosity systems have special result.Will not produce Flake point and pinprick phenomenon.
Embodiment 2:
A kind of special defoamer of rubber, wherein:By weight percentage, including:
Alkymer 35%;
Hydramine 22%;
Aliphatic acid 13%;
Aliphatic acid alkanolamine ester 15%;
Dispersant 5%;
Help defoamer 10%.
After above-mentioned substance is added into container, 55 minutes prepared special defoamers of rubber are stirred.
Wherein hydramine molecular weight is 150, and fatty acid molecule amount is 650, and aliphatic acid hydramine ester molecule amount is 1200;Help froth breaking Agent is one or more in lower alcohol, carboxylic acid vinegar, water-insoluble soap, and dispersant is nonionic surface active agent.
The defoamer of the present embodiment 2 has antifoaming speed fast, and suds ability is strong, particularly to for rubber, plastics-production The conventional various anion of system, nonionic foaming agent have good foam-inhibiting effect.In water-based system easily dispersion, from breast Change property strong, froth breaking is good, suds are lasting, especially to water soluble polymer and in, low high viscosity systems have special result.Will not produce Flake point and pinprick phenomenon.
It should be appreciated that application of the invention is not limited to above-mentioned citing, and for those of ordinary skills, can To be improved according to the above description or converted, all these modifications and variations should all belong to the guarantor of appended claims of the present invention Shield scope.

Claims (3)

1. the special defoamer of a kind of rubber, it is characterised in that:By weight percentage, including:
Alkymer 30-50%;
Hydramine 4-30%;
Aliphatic acid 3-25%;
Aliphatic acid alkanolamine ester 4-20%;
Dispersant 4-10%;
Help defoamer 8-18%.
2. the special defoamer of a kind of rubber according to claim 1, it is characterised in that:The hydramine molecular weight is 100- 200, fatty acid molecule amount is 500-800, and aliphatic acid hydramine ester molecule amount is 1000-1500.
3. the special defoamer of a kind of rubber according to claim 1, it is characterised in that:It is described help defoamer for lower alcohol, One or more in carboxylic acid vinegar, water-insoluble soap, the dispersant is nonionic surface active agent.
CN201611234690.2A 2016-12-28 2016-12-28 A kind of special defoamer of rubber Pending CN106799070A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611234690.2A CN106799070A (en) 2016-12-28 2016-12-28 A kind of special defoamer of rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611234690.2A CN106799070A (en) 2016-12-28 2016-12-28 A kind of special defoamer of rubber

Publications (1)

Publication Number Publication Date
CN106799070A true CN106799070A (en) 2017-06-06

Family

ID=58984256

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611234690.2A Pending CN106799070A (en) 2016-12-28 2016-12-28 A kind of special defoamer of rubber

Country Status (1)

Country Link
CN (1) CN106799070A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1115261A (en) * 1994-07-16 1996-01-24 朱吉锦 High effective defrother
JPH09215903A (en) * 1995-11-14 1997-08-19 Kabelmetal Electro Gmbh Deforming agent dispersion substance for aqueous surfactant system
CN1426827A (en) * 2001-12-17 2003-07-02 中国石油天然气集团公司 Defoaming agent
CN102300612A (en) * 2009-02-02 2011-12-28 圣诺普科有限公司 Defoaming agent
CN103641195A (en) * 2013-12-13 2014-03-19 深圳市安品有机硅材料有限公司 Organic silicon defoamer and preparation method thereof
CN104689607A (en) * 2013-12-04 2015-06-10 青岛浩泰水务有限公司 Emulsion-type antifoaming agent used for rubber and plastic

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1115261A (en) * 1994-07-16 1996-01-24 朱吉锦 High effective defrother
JPH09215903A (en) * 1995-11-14 1997-08-19 Kabelmetal Electro Gmbh Deforming agent dispersion substance for aqueous surfactant system
CN1426827A (en) * 2001-12-17 2003-07-02 中国石油天然气集团公司 Defoaming agent
CN102300612A (en) * 2009-02-02 2011-12-28 圣诺普科有限公司 Defoaming agent
CN104689607A (en) * 2013-12-04 2015-06-10 青岛浩泰水务有限公司 Emulsion-type antifoaming agent used for rubber and plastic
CN103641195A (en) * 2013-12-13 2014-03-19 深圳市安品有机硅材料有限公司 Organic silicon defoamer and preparation method thereof

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Application publication date: 20170606

RJ01 Rejection of invention patent application after publication