CN106784459B - A kind of lithium ion battery box structure - Google Patents

A kind of lithium ion battery box structure Download PDF

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Publication number
CN106784459B
CN106784459B CN201611059962.XA CN201611059962A CN106784459B CN 106784459 B CN106784459 B CN 106784459B CN 201611059962 A CN201611059962 A CN 201611059962A CN 106784459 B CN106784459 B CN 106784459B
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bamboo
layer
battery case
lithium ion
wood
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CN106784459A (en
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陈福彦
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Deyang Jiuding Zhiyuan Intellectual Property Operation Co Ltd
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Deyang Jiuding Zhiyuan Intellectual Property Operation Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/233Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions
    • H01M50/24Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions adapted for protecting batteries from their environment, e.g. from corrosion
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The invention discloses a kind of lithium ion battery box structures, including Battery case, the side wall of Battery case is assembled by buffer board to be formed, the bottom plate of Battery case is made of bamboo-wood plyboard, the top of Battery case is top cover made of high molecular material, buffer board is successively made of elastic rubber layer, metal plate and amberwood inside-out, and the bottom surface of bamboo-wood plyboard is one layer of waterproof layer of bonding, and buffer board, top cover and bamboo-wood plyboard are assembled integrally composition Battery case.The lithium ion battery box structure being fabricated using bamboo-wood plyboard of the invention, while mitigating battery case self weight, meet requirement of the battery case to material property and structural behaviour, it is durable, the corrosion resistance and sealing performance for improving battery case, save a large amount of manufacturing costs, keep the manufacture and use of battery case more environmentally friendly, new application approach is opened for bamboo lumber, enriches the purposes field of bamboo lumber.

Description

A kind of lithium ion battery box structure
Technical field
The present invention relates to lithium ion battery case equipment field for electric vehicle, in particular to a kind of lithium ion battery case knot Structure.
Background technique
The existing lithium ion battery case overwhelming majority used is made of metal cabinet, so that battery case has just enough intensity And durability, since metal is vulnerable to electrochemical corrosion, Battery case gets rusty easily corrosion in the long-term use, easily leads to The defects of battery pack in battery case suffers erosion and leaks electricity, and then cause safety accident.In addition, when the battery pack in battery case Occur leakage electric leakage fortuitous event when, due to operator can not detail inner case, when watching and touching battery case, Yi Fa Raw electric shock or scald accident, safety are to be improved.
China possesses bamboo timber resource very rich, and the existing bamboo wood overwhelming majority applies to car by way of laminate In wagon-floor, Production Container and furniture construction bottom plate industry, bamboo wood is not used widely.Bamboo wood is processed at plate Afterwards, have the characteristics that intensity is big, hardness is high, lighter in weight, corrosion-resistant, good airproof performance, long service life, if by metal Battery case replaces with bamboo lumber, can not only mitigate the weight of battery case, moreover it is possible to effectively improve the corrosion-resistant of battery case Property and sealing performance, can save a large amount of manufacturing costs, keep the manufacture and use of battery case more environmentally friendly.
Summary of the invention
Goal of the invention of the invention is: in view of the above problems, provide it is a kind of using bamboo-wood plyboard manufacture and At lithium ion battery box structure, mitigate battery case self weight while, improve the corrosion resistance and sealing performance of battery case, save About a large amount of manufacturing costs, keep the manufacture and use of battery case more environmentally friendly.
The technical solution adopted by the invention is as follows: a kind of lithium ion battery box structure, including Battery case, Battery case Side wall is assembled by buffer board and is formed, and the bottom plate of Battery case is made of bamboo-wood plyboard, and the top of Battery case is macromolecule material Top cover made of expecting, buffer board are successively made of elastic rubber layer, metal plate and amberwood inside-out, and bamboo and wood is multiple The bottom surface of plywood is one layer of waterproof layer of bonding, and buffer board, top cover and bamboo-wood plyboard are assembled integrally composition Battery case.
Due to the setting of above structure, the setting of elastic rubber layer is prevented to protect the intracorporal battery pack of battery case Battery pack collision is impaired, and the setting of amberwood can guarantee that buffer board has enough intensity and anti-pressure ability, makes The Battery case of bamboo and wood can meet requirement, meanwhile, the excellent corrosion resistance and electricity that amberwood has Insulating properties can resist the erosion of external most corrosive substances, make Battery case not and will receive the corrosion of electrochemistry, i.e., Make in the case where electric leakage, electric shock accidents, the security performance enhancing of Battery case, the setting of metal plate will not occur for operator Act not only as the support plate of buffer board, moreover it is possible to improve buffer board leakproofness, when external amberwood or When person's elastic rubber slab breakage generates gap, fine and close metal plate can prevent the further erosion of corrosive liquids, Jin Erti The high leakproofness and corrosion resistance of buffer board.The buffer board that elastic rubber layer, metal plate and amberwood are constituted, no Only intensity with higher, the structure of multilayer also have the function of heat-insulated, shock-absorbing, when buffer board is impacted, phenolic aldehyde tree The fibre structure that rouge glued board has can disperse to absorb most energy, and dependent variable is smaller, has little influence on buffer board The stability of structure.On the one hand the bamboo-wood plyboard of setting to battery pack damping, protects battery pack from damaged in collision, another party When the bottom of Battery case is by the time of tide, bamboo-wood plyboard can play the role of waterproof LP blades, be better than existing made of metal in face Battery case.
Further, in order to preferably play leakproofness, energy absorption performance and the durability of amberwood, phenolic aldehyde tree Rouge glued board is successively made of phenolic resin impregnated paper, bamboo curtain splint layer and nonwoven layer from top to bottom, wherein phenolic resin dipping Paper, bamboo curtain splint layer and nonwoven layer are integrally formed by heat pressing process, and the nonwoven layer of amberwood is viscous by bonding agent It connects in metal plate, and the periphery of amberwood is fixedly connected on a metal plate by fastening screw.
In order to further increase the damping performance and sealing performance of bamboo-wood plyboard, bamboo-wood plyboard successively glues from top to bottom Close layer of polyurethane and bamboo and wood composite layer, wherein the outer surface of bamboo and wood composite layer coats one layer of wood shavings plank, in bamboo and wood composite layer Between formed by the thin bamboo strips used for weaving piece hot pressing that several layers are impregnated with phenolic resin glue.
In order to improve the durability and leakproofness of bamboo curtain splint, bamboo curtain splint layer is passed through by the thin bamboo strips used for weaving piece that several layers are impregnated with phenolic resin glue Perforation weaved hot-pressing form, wherein thin bamboo strips used for weaving piece with a thickness of 0.5-1.5mm.
Preferably, the thin bamboo strips used for weaving piece perforated weaved hot-pressing that bamboo curtain splint layer is impregnated with phenolic resin glue by two layers forms, wherein Thin bamboo strips used for weaving piece with a thickness of 0.8mm.
Preferably, the thin bamboo strips used for weaving piece hot pressing that the centre of bamboo and wood composite layer is impregnated with phenolic resin glue by four layers is formed, wherein Thin bamboo strips used for weaving piece with a thickness of 0.6mm.
Further, the parameter of bamboo curtain splint heat pressing process of the invention needs especially selection, so that phenolic resin obtained is glued The performances such as intensity, wearability, the elasticity of plate meet design requirement, and heat pressing process generally comprises a hot pressing and secondary hot pressing, and one The pressure of secondary hot pressing is 1.4-1.55MPa, preferably 1.48MPa, hot pressing time 30-45s, and the pressure of secondary hot pressing is 2.2- 2.37MPa, temperature are 120-130 DEG C, preferably pressure 2.27MPa, 124 DEG C of temperature.
Preferably, waterproof layer is phenolic resin impregnated paper, and it is bonded on bamboo and wood composite layer by heat pressing process.
Preferably, layer of polyurethane is made of hard polyurethane foam, with a thickness of 2-8mm.
Preferably, the Q235 steel plate that metal plate is 0.8-1.2mm thickness forms.
In conclusion by adopting the above-described technical solution, the beneficial effects of the present invention are: use bamboo and wood of the invention is multiple The lithium ion battery box structure that plywood is fabricated meets battery case to material property while mitigating battery case self weight It is durable with the requirement of structural behaviour, the corrosion resistance and sealing performance of battery case are improved, a large amount of manufacturing costs are saved, Keep the manufacture and use of battery case more environmentally friendly, opens new application approach for bamboo lumber, enrich the purposes of bamboo lumber Field.
Detailed description of the invention
Fig. 1 is a kind of lithium ion battery box structure schematic diagram of the invention;
Fig. 2 is lithium ion battery case main view partial structure diagram of the invention;
Fig. 3 is amberwood structural schematic diagram of the invention;
Fig. 4 is bamboo-wood plyboard structural schematic diagram of the invention.
Marked in the figure: 1 is Battery case, 2 be battery pack, and 3 be buffer board, and 4 be elastic rubber layer, and 5 be metal plate, and 6 are Amberwood, 601 be phenolic resin impregnated paper, and 602 be bamboo curtain splint layer, and 603 be nonwoven layer, and 7 be bamboo-wood plyboard, 701 be layer of polyurethane, and 702 be bamboo and wood composite layer, and 8 be waterproof layer, and 9 be thin bamboo strips used for weaving piece, and 10 be wood shavings plank.
Specific embodiment
With reference to the accompanying drawing, the present invention is described in detail.
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
As shown in Figures 1 to 4, a kind of lithium ion battery box structure, including Battery case 1, the side wall of Battery case 1 is by delaying The assembling of punching 3 is formed, and the bottom plate of Battery case 1 is made of bamboo-wood plyboard 7, and the top of Battery case 1 is high molecular material system At top cover (being not drawn into figure), buffer board 3 is inside-out successively by elastic rubber layer 4, metal plate 5 and amberwood 6 are constituted, and the bottom surface of bamboo-wood plyboard 7 is one layer of waterproof layer 8 of bonding, and buffer board 3, top cover and bamboo-wood plyboard 7 are assembled integrally Constitute Battery case 1.
As depicted in figs. 1 and 2, in the present embodiment, the setting of elastic rubber layer 4 is to protect in Battery case 1 Battery pack 2 prevents the collision of battery pack 2 impaired, and it is enough strong that the setting of amberwood 6 can guarantee that buffer board 3 has Degree and anti-pressure ability, enable the Battery case 1 of bamboo and wood to meet requirement, meanwhile, amberwood 6 has excellent Different corrosion resistance and electrical insulating property can resist the erosion of external most corrosive substances, make Battery case 1 will not be by To the corrosion of electrochemistry, even if electric shock accidents, the safety of Battery case 1 will not occur for operator in the case where electric leakage It can enhance, the setting of metal plate 5 acts not only as the support plate of buffer board 3, moreover it is possible to the leakproofness for improving buffer board 3, when outer When the amberwood 6 in portion or 4 breakage of elastic rubber layer generate gap, fine and close metal plate 5 can prevent corrosivity The further erosion of liquid, and then improve the leakproofness and corrosion resistance of buffer board 3.Elastic rubber layer 4, metal plate 5 and phenol The buffer board 3 that urea formaldehyde glued board 6 is constituted, not only intensity with higher, the structure of multilayer also have heat-insulated, shock-absorbing work With, when buffer board 3 is impacted, the fibre structure that amberwood 6 has can disperse to absorb most energy, Its dependent variable is smaller, has little influence on the stability of 3 structure of buffer board.7 one side of bamboo-wood plyboard of setting subtracts battery pack 2 Shake protects battery pack 2 from damaged in collision, and on the other hand when the bottom of Battery case 1 is by the time of tide, bamboo-wood plyboard 7 can be risen To the effect of waterproof LP blades, it is better than existing made of metal Battery case.
As an implementation, in order to preferably play the leakproofness of amberwood 6, energy absorption performance and resistance to With property, amberwood 6 is from top to bottom successively by 603 structure of phenolic resin impregnated paper 601, bamboo curtain splint layer 602 and nonwoven layer At, as shown in figure 3, phenolic resin impregnated paper 601, bamboo curtain splint layer 602 and nonwoven layer 603 are integrally formed by heat pressing process, phenol The nonwoven layer 603 of urea formaldehyde glued board 6 is bonded in metal plate 5 by bonding agent, and the periphery of amberwood 6 passes through Fastening screw is fixedly connected on metal plate 5.
Among the above, top cover preferably uses ABS material or PC material to be made, elastic rubber layer 4 can for high elastic rubber, Thermoplastic elastomer etc., for save the cost, elastic rubber layer 4 is made of waste tire rubber, and waste tire rubber has good Elastic, electrical insulating property and stability well are highly suitable as the buffer layer of battery pack;Metal plate 5 can for steel plate, aluminium sheet or Person's magnalium plate etc. uses the Q235 stainless steel plate of 0.8-1.2mm, preferably to reduce manufacturing cost.
In order to improve the durability and leakproofness of bamboo curtain splint, bamboo curtain splint layer 602 is impregnated with the thin bamboo strips used for weaving of phenolic resin glue by several layers 9 perforated weaved hot-pressing of piece forms, wherein thin bamboo strips used for weaving piece 9 with a thickness of 0.5-1.5mm, preferably 1.2mm.
Furthermore, the heat pressing process of bamboo curtain splint layer 602 uses prior art, i.e., soaks the woven thin bamboo strips used for weaving piece of drying After stain phenolic resin glue is dried again, after assembly, precompressed, hot pressing, cut out to obtain the final product, wherein in precompressed, the pressure of precompressed (hot pressing) is 1.4-1.55MPa, preferably 1.48MPa, hot pressing time 30-45s, and the pressure of secondary hot pressing is 2.2- 2.37MPa, temperature are 120-130 DEG C, preferably pressure 2.27MPa, 124 DEG C of temperature.The bamboo curtain splint as made from the technological parameter The density of layer is greater than 1.1G/cm3, moisture content is less than 10%, and for water absorption rate less than 10%, static bending strength is greater than 30N/mm2, quiet song bullet Property be not less than 500N/mm2, there is excellent comprehensive performance, can satisfy Battery case to the intensity of amberwood, resistance to The requirement of the performances such as mill property, elasticity, overcomes existing amberwood lower defect of intensity due to thickness is thin, improves The adaptability of amberwood.
It is preferably carried out mode as one kind, bamboo curtain splint layer 602 is impregnated with 9 perforated of thin bamboo strips used for weaving piece of phenolic resin glue by two layers Weaved hot-pressing forms, wherein thin bamboo strips used for weaving piece 9 with a thickness of 0.8mm, as shown in Figure 3.
As an implementation, in order to further increase the damping performance and sealing performance of bamboo-wood plyboard 7, bamboo and wood is multiple Plywood 7 successively bonds layer of polyurethane 701 and bamboo and wood composite layer 702 from top to bottom, as shown in figure 4, the appearance of bamboo and wood composite layer 702 Bread covers one layer of wood shavings plank 10, and the centre of bamboo and wood composite layer 702 is impregnated with 9 hot pressing of thin bamboo strips used for weaving piece of phenolic resin glue by several layers It is formed, correspondingly, the centre of bamboo and wood composite layer 702 is also to be made by above-mentioned heat pressing process, to guarantee that bamboo and wood composite layer 702 has There is comprehensive performance well.
It is preferably carried out mode as one kind, the centre of bamboo and wood composite layer 702 is impregnated with the bamboo of phenolic resin glue by four layers 9 hot pressing of thin bamboo strip is formed, wherein thin bamboo strips used for weaving piece 9 with a thickness of 0.6mm.
It is preferably carried out mode as one kind, waterproof layer 8 is phenolic resin impregnated paper, and is bonded in bamboo by heat pressing process On the wooden composite layer 702.
It is preferably carried out mode as one kind, layer of polyurethane 701 is made of hard polyurethane foam, and thickness can be 2-8mm, most It is well 6.5mm.
After tested, for the Battery case 1 made of buffer board 3 when by enormous impact force, what is be firstly broken is buffering Coupling part between plate 3, and significant change does not occur for buffer board 3 itself, furthermore, by enormous impact force And the coupling part between buffer board 3, when not being destroyed, amberwood 6 and metal plate 5 absorb big energy and with vibration Dynamic form releases energy, and after 4 snubber of elastic rubber layer, the impact that battery pack 2 is subject to is greatly reduced for the vibration of generation, Battery pack 2 receives good protection, and compared with metal protection board, anticollision coefficient almost maintains an equal level, in terms of thermal insulation, phenol Urea formaldehyde glued board 6 can scorch that 30min is non-ignitable in 300 DEG C or so of temperature, the temperature of elastic rubber layer 4 rise it is unobvious, The local temperature that amberwood 6 is not scorched rises 5-50 DEG C, and metal protection board is processed in 300 DEG C or so of temperature Roasting 30min is non-ignitable, and the inside and outside wall temperature difference of protection board is little, reaches 350 DEG C or more, and for battery pack, battery core reaches 200 DEG C or more, then will appear rupture, exothermic phenomenon of largely discharging, or even explode, therefore, buffer board 3 of the invention every Hot property is prominent.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (8)

1. a kind of lithium ion battery box structure, including Battery case, which is characterized in that the side wall of Battery case is assembled by buffer board It is formed, the bottom plate of Battery case is made of bamboo-wood plyboard, and the top of Battery case is top cover made of high molecular material, buffering Plate is successively made of elastic rubber layer, metal plate and amberwood inside-out, and the bottom surface of bamboo-wood plyboard is bonding One layer of waterproof layer, buffer board, top cover and bamboo-wood plyboard are assembled integrally composition Battery case, amberwood on to Under be successively made of phenolic resin impregnated paper, bamboo curtain splint layer and nonwoven layer, wherein phenolic resin impregnated paper, bamboo curtain splint layer and nonwoven Layer of cloth is integrally formed by heat pressing process, and the nonwoven layer of amberwood is bonded in metal plate, and phenol by bonding agent The periphery of urea formaldehyde glued board is fixedly connected on a metal plate by fastening screw, and successively bonding is poly- from top to bottom for bamboo-wood plyboard Urethane layer and bamboo and wood composite layer, wherein the outer surface of bamboo and wood composite layer coats one layer of wood shavings plank, the centre of bamboo and wood composite layer by The thin bamboo strips used for weaving piece hot pressing that several layers are impregnated with phenolic resin glue is formed.
2. lithium ion battery box structure as described in claim 1, which is characterized in that bamboo curtain splint layer is impregnated with phenolic aldehyde tree by several layers The thin bamboo strips used for weaving piece perforated weaved hot-pressing of rouge glue forms, wherein thin bamboo strips used for weaving piece with a thickness of 0.5-1.5mm.
3. lithium ion battery box structure as claimed in claim 2, which is characterized in that bamboo curtain splint layer is impregnated with phenolic resin by two layers The thin bamboo strips used for weaving piece perforated weaved hot-pressing of glue forms, wherein thin bamboo strips used for weaving piece with a thickness of 0.8mm.
4. lithium ion battery box structure as described in claim 1, which is characterized in that the centre of bamboo and wood composite layer is impregnated by four layers There is the thin bamboo strips used for weaving piece hot pressing of phenolic resin glue to be formed, wherein thin bamboo strips used for weaving piece with a thickness of 0.6mm.
5. lithium ion battery box structure as described in claim 1, which is characterized in that heat pressing process includes a hot pressing and secondary Hot pressing, the pressure of a hot pressing are 1.4-1.55MPa, and hot pressing time 30-45s, the pressure of secondary hot pressing is 2.2- 2.37MPa, temperature are 120-130 DEG C.
6. lithium ion battery box structure as described in claim 1, which is characterized in that waterproof layer is phenolic resin impregnated paper, and It is bonded on bamboo and wood composite layer by heat pressing process.
7. lithium ion battery box structure as described in claim 1, which is characterized in that layer of polyurethane is made of hard polyurethane foam, With a thickness of 2-8mm.
8. lithium ion battery box structure as described in claim 1, which is characterized in that metal plate is the Q235 of 0.8-1.2mm thickness Steel plate composition.
CN201611059962.XA 2016-11-28 2016-11-28 A kind of lithium ion battery box structure Active CN106784459B (en)

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CN110473648B (en) * 2018-07-04 2021-03-02 中国工程物理研究院核物理与化学研究所 Modularized radiation similar-potential syngen battery
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