CN106772712A - A kind of compound fenestrated membrane of anti-dazzle electromagnetic shielding of the protectiveness of low transmitting - Google Patents

A kind of compound fenestrated membrane of anti-dazzle electromagnetic shielding of the protectiveness of low transmitting Download PDF

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Publication number
CN106772712A
CN106772712A CN201510824949.8A CN201510824949A CN106772712A CN 106772712 A CN106772712 A CN 106772712A CN 201510824949 A CN201510824949 A CN 201510824949A CN 106772712 A CN106772712 A CN 106772712A
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China
Prior art keywords
protectiveness
dazzle
layer
electromagnetic shielding
infrared
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CN201510824949.8A
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Chinese (zh)
Inventor
颜悦
刘宏燕
望咏林
伍建华
张官理
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BEIJING INSTITUTE OF AERONAUTICAL MATERIALS CHINA AVIATION INDUSTRY GROUP Corp
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BEIJING INSTITUTE OF AERONAUTICAL MATERIALS CHINA AVIATION INDUSTRY GROUP Corp
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Priority to CN201510824949.8A priority Critical patent/CN106772712A/en
Publication of CN106772712A publication Critical patent/CN106772712A/en
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers
    • G02B1/116Multilayers including electrically conducting layers

Abstract

The present invention provides a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting, and it is included:Flexible transparent film substrate;One anti-dazzle antireflection layer of protectiveness;And at least one infrared-reflecting layers;And the flexible transparent substrate is disposed between the anti-dazzle antireflection layer of the protectiveness and infrared-reflecting layers.By at least one of which low refractive index film layer and floor height index film layer, alternately superposition is constituted the anti-dazzle antireflection layer of protectiveness, and the infrared-reflecting layers are replaced superposition and constituted by least one of which metal level and one layer of dielectric layer.The protectiveness compound fenestrated membrane of anti-dazzle electromagnetic shielding of this low transmitting is pasted onto glass surface by laminate adhesive.The protectiveness compound fenestrated membrane of anti-dazzle electromagnetic shielding of the low transmitting has infrared reflection rate higher, lower visible reflectance; with electro-magnetic screen function; and antireflection layer can completely cut off infrared-reflecting layers and air contact; metal level is oxidized in further preventing infrared-reflecting layers, plays protection, anti-dazzle double action.

Description

A kind of compound fenestrated membrane of anti-dazzle electromagnetic shielding of the protectiveness of low transmitting
Technical field
The present invention relates to field of optical films, there is the optical thin film low-launch-rate to be shifted by radiation with reducing heat energy, and the fenestrated membrane has protectiveness anti-dazzle and electromagnetic interference shield function.
Background technology
With social development and the raising of people's quality of life, requirement higher is proposed to environmental quality, for example at home and office etc. needs that translucency is good, moderate temperature, therefore, the exterior wall of building largely uses glass, under irradiation by sunlight, amount of heat is entered within doors by radiating, and causes temperature significantly to raise.Glass freezes under cold environment, easily or the icing or frosting of frosting, particularly automotive glass can influence sight line.In order to reduce influence of the heat radiation to heating indoor, and solve the problems, such as that glass freezes or frosting in cold environments, people generally eliminate these influences using the windowpane with low transmitting.
The glass of so-called low transmitting refers to that the optics for allowing specific wavelength passes through the glass, it can be common that low transmitting glass allows that visible ray (wave-length coverage is 380~780nm) passes through, while the optics beyond high reflection visible ray, such as infrared ray.Due to this low transmitting glass to infrared ray etc. with reflectivity high, therefore, can improve building, the window of vehicle it is heat-insulated, the thermal energy radiation that outside can be reduced in hot weather passes through window, interior is heated, and under arctic weather, the air that can reduce interior passes through glass to external radiation by heat radiation, so as to keep indoor temperature constant, prevent glass from freezing in cold weather or frosting.On the other hand, the low transmitting composite membrane of this patent description has heating function, and the glass of frosting or icing can be electrically heated, and frost is eliminated with this.Therefore, using the glass of low transmitting, comfortable living environment can be effectively provided, improves capacity usage ratio.
Generally, people prepare the glass of low transmitting by the direct sputter on glass or the laminated film of the low transmitting of coating, are then directly arranged on window in glass pane form.If the low compound film rupture of transmitting, or corroded under natural environment and failed, then must be changed whole window, such replacing not only high cost, and also its color appearance is uncoordinated with surrounding glass.Based on this, people employ a kind of actual and more economical method, that is, use the flexible low transmitting laminated film that may adhere on glass.This low transmitting laminated film of flexibility is easy to use and changes, and production efficiency is high.
The low transmitting laminated film of this flexibility is mainly using metal level come infrared reflecting, but this metal is in use, contact with air, steam etc. and easily corroded, and flexible substrate is easily scratched damage, the properties of infrared reflection of the reduction laminated film.A kind of effective ways for preventing the low transmitting diaphragm failure are that film plating layer is affixed with glass, flexible PET substrate and air contact, to a certain extent obstruct laminated film and air, the contact of steam.However, this installation method can cause the film with reflection very high, cause the generation of dazzle.When apply make low emission layer on glass pane, automobile wind shield glass, large-scale outdoor electrical equipment surface when, due to the generation of dazzle, the dimness of vision can be caused.How while low transmitting laminated film performance is ensured, the generation of oxidation and the reduction dazzle of metal level is prevented, obtained further extensively using the problem to be solved in fenestrated membrane field as the low transmitting laminated film of flexibility.Patent of the present invention is intended addressing above mentioned problem from film layer structure design; i.e. in the face sputter infrared external reflection composite beds of flexible PET mono-; in the another side sputter antireflection layer of PET; the antireflection layer is a kind of protectiveness antireflection layer; with double action; completely cut off infrared reflecting layer and air contact, increase the hardness of PET to prevent scratch.
In addition to control infra-red radiation and reduction dazzle, in addition it is also necessary to electromagnetic radiation is controlled, particularly in sensitive military working environment, and on electronic display unit.To the control measure of electromagnetic radiation, it is typically with copper or other conductive materials is shielded, and for glass pane, these shielding measures can have a strong impact on the transmitance of light.Laminated film described in this patent, not only with low emission characteristics, with protectiveness antireflective function, and has electromagnetic action to a certain extent.
The content of the invention
A kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting of present invention description, it is included:Flexible transparent film substrate;One anti-dazzle antireflection layer of protectiveness;And at least one infrared-reflecting layers;The laminated film is more than 90% to the reflectivity of infrared light (1000nm wave bands); visible light transmissivity is higher than 91%; visible reflectance is less than 1.3%, and wherein described flexible transparent substrate is disposed between the anti-dazzle antireflection layer of the protectiveness and infrared-reflecting layers.
The fenestrated membrane Core Feature layer, can be by infrared light reflection while visible light transmissivity, antiradar reflectivity high is ensured.The flexible fenestrated membrane is attached on glass, can prevent Infrared irradiation from entering in window the infrared light reflection outside fenestrated membrane, prevent the temperature caused by infra-red radiation from rising.On the other hand, under cold environment, heat radiation external in window is prevented from, temperature is constant in holding window to a certain extent, prevents glass frosting etc..
The infrared-reflecting layers rely primarily on the metal Ag reflecting properties good to IR.Because the oxidation resistance of Ag is weak, in use, with air contact, AgO is easily oxidized to, and AgO no longer possesses good infrared light reflection performance, so as to influence the infrared reflectivity and EMI shield effectiveness of the fenestrated membrane Core Feature layer.Ag alloys are protected or used using coating metal layer, can to a certain extent be reduced Ag and are oxidized.The present invention uses a kind of special anti-oxidation measure, i.e., in the another side sputter protectiveness antireflection layer of PET, when in use, infrared reflecting layer is affixed with glass, so as to completely cut off infrared reflecting layer and air contact, prevents Ag metal levels to be oxidized.Simultaneously as the presence of antireflection layer, enables the laminated film to have the anti-dazzle function of good anti-reflection and good antiscratching properties.
The infrared-reflecting layers can be constituted by Ag or by the Ag alloying metals layer that Cu, Au or Pd etc. are constituted.In some embodiments, the infrared-reflecting layers include at least one thin thin metal layer that can protect the infrared-reflecting layers.The thin thin metal layer is made up of the metal constituted selected from nickel, chromium, zinc, titanium, gold, palladium and its alloy.In some embodiments, the thin metallic film is made up of nickel-chromium alloy.
The infrared-reflecting layers include at least two dielectric layers, and the dielectric layer can be made up of transparency conducting layer, dielectric layer or its combination.The dielectric layer is comprising selected from by niobium pentaoxide (Nb2O5), titanium dioxide (TiO2), the material that is constituted of tin indium oxide (ITO) or indium zinc oxide (IZO).
The anti-dazzle antireflection layer of protectiveness can be made up of the dielectric film with least three layers difference low-refraction high, and the dielectric film is made up of high refractive index metal oxide and low-refraction metal oxide or fluoride.The high refractive index metal oxide includes niobium pentaoxide (Nb2O5), titanium dioxide (TiO2), the material that is constituted of tin indium oxide (ITO) or indium zinc oxide (IZO), the low-refraction metal oxide or fluoride include silica (SiO2) or magnesium fluoride (MgF2) material that is constituted.
The anti-dazzle antireflection layer of protectiveness can also include the dielectric layer of multiple low-refractions high, and the dielectric layer replaces superposition and constitutes by high index of refraction and low refractive index dielectric.
The infrared-reflecting layers can be also arranged between multiple dielectric layers comprising multiple dielectric layers and metal level, the metal level.
Also disclosed herein is a kind of anti-dazzle electromagnetic shielding transparent composite film of low transmitting, it is included:Flexible transparent substrate;One anti-dazzle antireflection layer of protectiveness;And at least one infrared-reflecting layers;The laminated film is more than 78% to the infrared reflectivity of 1000nm wave bands; visible light transmissivity is higher than 92.5%; visible reflectance is less than 2.4%, and wherein described flexible transparent substrate is disposed between the anti-dazzle antireflection layer of the protectiveness and infrared-reflecting layers.
The laminated film can also be more than 61% to the infrared reflectivity of 1000nm wave bands, it is seen that light transmission rate is higher than 94.3%, it is seen that light reflectivity is less than 2.3%.
In embodiments, the flexible transparent substrate is made up of highly cross-linked polymer poly ethylene glycol terephthalate (PET) and its UV cured polyacrylate of dual coating.
Invention additionally discloses a kind of method that anti-dazzle EMI of the protectiveness for manufacturing low transmitting shields transparent composite film.The described method comprises the following steps:Flexible transparent substrate is provided;In the UV cured polyacrylate of flexible transparent substrate dual coating;With winding film plating equipment in flexible transparent substrate side sputter infrared-reflecting layers;And, in the anti-dazzle antireflection layer of the flexible transparent substrate opposite side sputter protectiveness.
Brief description of the drawings
One profile of embodiment of the anti-dazzle electromagnetic shielding fenestrated membrane of protectiveness of the low transmittings of Fig. 1;
1 to wait to paste the glass pane of the composite membrane in figure, and 2 is laminate adhesive, and 3 is PET substrate, and 4 is infrared reflecting layer, and 5 is the anti-dazzle antireflection layer of protectiveness.
The profile of another embodiment of the anti-dazzle electromagnetic shielding fenestrated membrane of protectiveness of the low transmittings of Fig. 2
1 to wait to paste the glass pane of the composite membrane in figure, and 2 is laminate adhesive, and 3 is PET substrate, and 14 is infrared reflecting layer, and 15 is the anti-dazzle antireflection layer of protectiveness
The profile of another embodiment of the anti-dazzle electromagnetic shielding fenestrated membrane of protectiveness of the low transmittings of Fig. 3
1 to wait to paste the glass pane of the composite membrane in figure, and 2 is laminate adhesive, and 3 is PET substrate, and 24 is infrared reflecting layer, and 25 is the anti-dazzle antireflection layer of protectiveness.
Specific embodiment
Embodiment one
As shown in figure 1, this illustrates an a kind of embodiment of the anti-dazzle electromagnetic shielding fenestrated membrane of protectiveness of low transmitting, the laminated film includes flexible and transparent polyethylene terephtalate substrate film 3, infrared-reflecting layers 4 and the anti-dazzle antireflection layer 5 of protectiveness.When as outside or inside fenestrated membrane, can be provided so that the laminated film to be adhered to the means of window in laminated film bottom in addition, as shown in figure 1, having laminate adhesive 2 in compound bottom.The laminate adhesive can be made up of any bonding laminated film to adhesive of glass or any other substrate that is suitable to.For this special laminated film, infrared reflecting layer 4 is adhered on glass or other substrates by laminate adhesive 2, with this completely cut off Ag in use with air contact, prevent from being oxidized.As described above, the bottom of laminated film will be the infrared reflecting layer 4, top is the anti-dazzle antireflection layer 5 of protectiveness, and centre is flexible PET substrate film 3.
Transparent membrane substrate 3 is constituted by flexible and transparent polyethylene terephthalate and its in the polyacrylate hardening coat of dual coating ultra-violet curing.Preferably, the thickness of flexible transparent substrate 3 is 125 microns, or 50 microns.The polyacrylate hardening coat of the ultra-violet curing, the both sides of flexible and transparent PET substrate are coated uniformly on using traditional takeup type rubbing method, to improve intensity, hardness and the durability etc. of flexible transparent substrate 3.
The infrared-reflecting layers 4 are multilayer lamination structures, the lower floor of covering flexible and transparent PET substrate 3.The stacked structure is constituted by selected from any thin layer of transparent complex metal layer 42 and the high refractive index film layer 41 and 43 to infrared ray high reflection.The complex metal layer 42 is included but is not limited to select free metal Ag or is made up of the Ag alloys that Cu, Au or Pd etc. are constituted.Preferably, core infrared reflective metallic is gold-silver alloy.The high refractive index film layer 41 and 43 includes but is not limited to be selected from niobium pentaoxide Nb2O5, titanium dioxide TiO2, the material that is constituted of tin indium oxide ITO or indium zinc oxide IZO.In preferred embodiments, high refractive index film layer 41 and 43 is all niobium pentaoxide Nb2O5.Layer 41 to 43 is formed by winding magnetic control sputtering plated film, is sputtered simultaneously by multi-chamber, once completes the deposition of multilayer film.Niobium pentaoxide 43 being deposited first, its thickness is about 32nm, metal level 42 then being covered thereon, its thickness is about 16nm, finally cover second layer niobium pentaoxide 41, its thickness is about 31nm.
The anti-dazzle antireflection layer 5 of protectiveness is multilayer lamination structure, the upper strata of covering flexible and transparent PET substrate 3.The stacked structure is made up of high refractive index film layer 52 and low refractive index film layer 51 and 53.The high refractive index film layer 52 includes but is not limited to be selected from niobium pentaoxide Nb2O5, titanium dioxide TiO2, the material that is constituted of tin indium oxide ITO or indium zinc oxide IZO.In preferred embodiments, high refractive index film layer 52 is niobium pentaoxide Nb2O5.The low refractive index film layer 51 and 53 includes but is not limited to be selected from silica SiO2Or magnesium fluoride MgF2The material for being constituted.In preferred embodiments, low refractive index film layer 51 and 53 is all silica SiO2.Layer 51 to 53 is formed by winding magnetic control sputtering plated film, is sputtered simultaneously by multi-chamber, once completes the deposition of multilayer film.Silica 51 being deposited first, its thickness is about 42nm, high refractive index film niobium pentaoxide 52 then being covered thereon, its thickness is about 22nm, finally deposit second layer silica 53, its thickness is about 110nm.
Embodiment two
As shown in Figure 2; this illustrates another embodiment that a kind of anti-dazzle EMI of protectiveness of low transmitting shields fenestrated membrane; its overall structure is essentially identical with Fig. 1, except that the number of plies of infrared reflecting layer 14 and the anti-dazzle antireflection layer 15 of protectiveness is than infrared reflecting layer 4 and the anti-dazzle antireflection layer more than 5 of protectiveness.The infrared reflecting layer 14 is made up of multiple dielectric layers 141,143 and 145 and infrared external reflection complex metal layer 142 and 144.
The infrared-reflecting layers 14 are multilayer lamination structures, the lower floor of covering flexible and transparent PET substrate 3.The stacked structure is constituted by selected from any thin layer of transparent complex metal layer 142 and 144 and the high refractive index film layer 141,143 and 145 to infrared ray high reflection.The complex metal layer 142 and 144 is included but is not limited to select free metal Ag or is made up of the Ag alloys that Cu, Au or Pd etc. are constituted.Preferably, core infrared reflective metallic is gold-silver alloy.The high refractive index film layer 141,143 and 145 includes but is not limited to be selected from niobium pentaoxide Nb2O5, titanium dioxide TiO2, the material that is constituted of tin indium oxide ITO or indium zinc oxide IZO.In preferred embodiments, high refractive index film layer 141,143 and 145 is all niobium pentaoxide.
In preferred embodiments, infrared-reflecting layers 14 are made up of the 3rd dielectric layer 141 for being deposited on about 66 nanometers of the first thin layer composite metal level 144, thickness and about 14 nanometers of the second dielectric layer 143, thickness and about 29 nanometers of the second complex metal layer 142 and thickness covering second dielectric layer 143 that cover the first thin layer composite metal level 144 that substrate 3 and thickness are about 30 nanometers of first medium layer 145, about 12 nanometers of thickness and cover first medium layer 145.Layer 141 to 145 is formed by winding magnetic control sputtering plated film, is sputtered simultaneously by multi-chamber, once completes the deposition of multilayer film.
The anti-dazzle antireflection layer 15 of protectiveness is multilayer lamination structure, the upper strata of covering flexible and transparent PET substrate 3.The stacked structure is made up of high refractive index film layer 151 and 153 and low refractive index film layer 152 and 154.The high refractive index film layer 151 and 153 includes but is not limited to be selected from niobium pentaoxide Nb2O5, titanium dioxide TiO2, the material that is constituted of tin indium oxide ITO or indium zinc oxide IZO.In preferred embodiments, high refractive index film layer 151 and 153 is all niobium pentaoxide Nb2O5.The low refractive index film layer 152 and 154 includes but is not limited to be selected from silica SiO2Or magnesium fluoride MgF2The material for being constituted.In preferred embodiments, low refractive index film layer 152 and 154 is all silica SiO2
In preferred embodiments, the anti-dazzle antireflection layer 15 of protectiveness is made up of the first low refractive index film layer 154 for being deposited on the first low refractive index film layer 152, about 23 nanometers of thickness and about 105 nanometers of the second high refractive index film layer 153 and thickness and the second high refractive index film of covering layer 153 that cover the first low refractive index film layer 152 that substrate 3 and thickness are about 17 nanometers of the first high refractive index film layer 151, about 43 nanometers of thickness and cover the first high refractive index film layer 151.Layer 151 to 154 is formed by winding magnetic control sputtering plated film, is sputtered simultaneously by multi-chamber, once completes the deposition of multilayer film.
Embodiment three
As shown in Figure 3; this illustrates another embodiment that a kind of anti-dazzle EMI of protectiveness of low transmitting shields fenestrated membrane; its overall structure is essentially identical with Fig. 1, except that the number of plies of infrared reflecting layer 24 and the anti-dazzle antireflection layer 25 of protectiveness is than infrared reflecting layer 4 and the anti-dazzle antireflection layer more than 5 of protectiveness.The infrared reflecting layer 24 is made up of multiple dielectric layers 241,243,245 and 247 and infrared external reflection complex metal layer 242,244 and 246.The anti-dazzle antireflection layer 25 of protectiveness is made up of multiple low refractive index films layer 251,253,255 and 257 and high refractive index film layer 252,254 and 256.
The infrared-reflecting layers 24 are multilayer lamination structures, the lower floor of covering flexible and transparent PET substrate 3.The stacked structure is constituted by selected from any thin layer of transparent complex metal layer 242,244 and 246 and the high refractive index film layer 241,243,245 and 247 to infrared ray high reflection.The complex metal layer 242,244 and 246 is included but is not limited to select free metal Ag or is made up of the Ag alloys that Cu, Au or Pd etc. are constituted.Preferably, core infrared reflective metallic is gold-silver alloy.The high refractive index film layer 241,243,245 and 247 includes but is not limited to be selected from niobium pentaoxide Nb2O5, titanium dioxide TiO2, the material that is constituted of tin indium oxide ITO or indium zinc oxide IZO.In preferred embodiments, high refractive index film 241,243,245 and 247 is all niobium pentaoxide.
In preferred embodiments, infrared-reflecting layers 24 are by being deposited on substrate 3 and thickness is about 30 nanometers of first medium layer 247, first thin layer composite metal level 246 of about 12 nanometers of thickness and covering first medium layer 247, the second dielectric layer 245 of about 62 nanometers of thickness and the first thin layer composite metal level 246 of covering, second complex metal layer 244 of about 12 nanometers of thickness and covering second dielectric layer 245, 3rd dielectric layer 243 of about 62 nanometers of thickness and the second thin layer composite metal level 244 of covering, 4th dielectric layer 241 of about 30 nanometers of the triplex metal level 242 and thickness of about 15 nanometers of thickness and the 3rd dielectric layer 243 of covering is constituted.Layer 241 to 245 is formed by winding magnetic control sputtering plated film, is sputtered simultaneously by multi-chamber, once completes the deposition of multilayer film.
The anti-dazzle antireflection layer 25 of protectiveness is multilayer lamination structure, the upper strata of covering flexible and transparent PET substrate 3.The stacked structure is made up of low refractive index film layer 251,253,255 and 257 and high refractive index film layer 252,254 and 256.The low refractive index film layer 251,253,255 and 257 includes but is not limited to be selected from silica SiO2Or magnesium fluoride MgF2The material for being constituted.In preferred embodiments, low refractive index film layer 251,253,255 and 257 is all silica.The high refractive index film layer 252,254 and 256 includes but is not limited to be selected from niobium pentaoxide Nb2O5, titanium dioxide TiO2, the material that is constituted of tin indium oxide ITO or indium zinc oxide IZO.In preferred embodiments, high refractive index film layer 252,254 and 256 is all niobium pentaoxide.
In preferred embodiments,The anti-dazzle antireflection layer 25 of protectiveness is by being deposited on substrate 3 and thickness is about 206 nanometers of the first low refractive index film 251,First high refractive index film 152 of about 13 nanometers of thickness and the first low refractive index film 251 of covering,Second low refractive index film 253 of about 34 nanometers of thickness and the first high refractive index film 252 of covering,Second high refractive index film 254 of about 111 nanometers of thickness and the second low refractive index film 253 of covering,3rd low refractive index film 255 of about 20 nanometers of thickness and the second high refractive index film 254 of covering,4th low refractive index film 257 of about 13 nanometers of thickness and about 66 nanometers of the 3rd high refractive index film 256 and thickness and the 3rd high refractive index film 256 of covering that cover the 3rd low refractive index film 255 is constituted.Layer 251 to 257 is formed by winding magnetic control sputtering plated film, is sputtered simultaneously by multi-chamber, once completes the deposition of multilayer film.
Embodiment one to embodiment three parameter as shown in table 1 to table 3.
Table 1
Table 2
Table 3
Preferred embodiment of the present invention, its detailed description is intended to illustrative, should not be understood as the limitation to disclosure scope.Any independent material disclosed in this invention, numerical value or characteristic all can with any other material of the disclosure, numerical value or characteristic used interchangeably, as the specific embodiment given by the present invention.Anyone can draw other various forms of products under enlightenment of the invention, however, make any change in its material, shape or structure, it is every with technical scheme same as the present application or similar, it is within the scope of the present invention.

Claims (13)

1. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting, it is characterized in that, it is included:Flexible transparent substrate;One anti-dazzle antireflection layer of protectiveness;And at least one infrared-reflecting layers;And wherein described flexible transparent substrate is disposed between the anti-dazzle antireflection layer of the protectiveness and infrared-reflecting layers.
2. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 1, it is characterized in that, wherein flexible transparent substrate is included:Polyethylene terephthalate (PET) and two-sided stiffened clear coat, the two-sided stiffened clear coat are the polyacrylate coatings of ultra-violet curing.
3. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 1, it is characterized in that, the wherein anti-dazzle antireflection layer of protectiveness is included:Low refractive index film layer and high refractive index film layer, the low refractive index film layer and high refractive index film layer are alternately stacked.
4. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 3, it is characterized in that, wherein the low refractive index film layer choosing freely includes silica (SiO2) or magnesium fluoride (MgF2) material that is constituted, the high refractive index film layer choosing freely includes niobium pentaoxide (Nb2O5), titanium dioxide (TiO2), the material that is constituted of tin indium oxide (ITO) or indium zinc oxide (IZO).
5. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 1, it is characterized in that, wherein infrared-reflecting layers are included:Multiple dielectric layers and complex metal layer, the complex metal layer are arranged between multiple high refractive index medium layers.
6. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 5, it is characterized in that, wherein the complex metal layer is selected from the Ag alloying metals layer constituted by Ag or by Cu, Au or Pd.
7. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 6, it is characterized in that, the complex metal layer, it is further included:Protectiveness thin metal layer, the protectiveness thin metal layer is the metal constituted selected from nickel, chromium, zinc, titanium, gold, palladium and its alloy.
8. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 5, it is characterized in that, the dielectric layer is made up of transparency conducting layer, dielectric layer or its combination.
9. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 8, it is characterized in that, the dielectric layer is comprising being selected from by niobium pentaoxide (Nb2O5), titanium dioxide (TiO2), the material that is constituted of tin indium oxide (ITO) or indium zinc oxide (IZO).
10. a kind of anti-dazzle electromagnetic shielding transparent composite film of the protectiveness of low transmitting as claimed in claim 1; it is characterized in that; the laminated film is more than 78% to the reflectivity of the infrared light of 800nm-1100nm wave bands, it is seen that light transmission rate is higher than 92.5%, and reflectivity is less than 2.4%.
A kind of 11. anti-dazzle electromagnetic shielding transparent composite films of the protectiveness of low transmitting as claimed in claim 1; it is characterized in that; the laminated film is more than 90% to the reflectivity of the infrared light of 800nm-1100nm wave bands, it is seen that light transmission rate is higher than 91%, it is seen that light reflectivity is less than 1.3%.
A kind of 12. anti-dazzle electromagnetic shielding transparent composite films of the protectiveness of low transmitting as claimed in claim 1; it is characterized in that; the laminated film is more than 61% to the reflectivity of the infrared light of 800nm-1100nm wave bands, it is seen that light transmission rate is higher than 94.3%, and reflectivity is less than 2.3%.
A kind of 13. methods for manufacturing the anti-dazzle electromagnetic shielding laminated film of low reflection, it is characterized in that, methods described includes:Flexible transparent substrate is provided;In PET dual coating stiffened coatings;In the face sputter protectiveness antireflective composite bed of flexible transparent substrate one;And in flexible transparent substrate another side sputter infrared reflection composite bed.
CN201510824949.8A 2015-11-24 2015-11-24 A kind of compound fenestrated membrane of anti-dazzle electromagnetic shielding of the protectiveness of low transmitting Pending CN106772712A (en)

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CN109720026A (en) * 2019-02-25 2019-05-07 深圳德宝天成科技有限公司 A kind of high transmission high reflection thermal isolation film
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CN110542940A (en) * 2019-09-30 2019-12-06 东莞市光志光电有限公司 High-brightness optical reflector plate
CN111638610A (en) * 2020-07-20 2020-09-08 宁波材料所杭州湾研究院 Flexible intelligent light adjusting film with high visible light transmittance and heat insulation and preparation method thereof
CN111764471A (en) * 2020-07-01 2020-10-13 安徽皖南电机股份有限公司 Mirror surface high-level water tank
CN111970915A (en) * 2020-08-28 2020-11-20 山东大学 Electromagnetic radiation prevention ultrathin film, electromagnetic radiation prevention ultrathin film device, preparation method and application
CN112423574A (en) * 2020-11-18 2021-02-26 中国科学院宁波材料技术与工程研究所 Ultrathin flexible transparent electromagnetic shielding film and preparation method thereof
CN112902751A (en) * 2021-01-14 2021-06-04 中国电子科技集团公司第三十三研究所 High-shielding-effect high-light-transmission temperature-resistant pressure-resistant shielding aiming glass with transparent ceramic substrate
CN113703206A (en) * 2021-08-25 2021-11-26 京东方科技集团股份有限公司 Light-adjusting glass and light-adjusting module
CN113719221A (en) * 2021-08-17 2021-11-30 福建恒春织造股份有限公司 Magic tape window membrane convenient to installation is dismantled and is accomodate
CN117465081A (en) * 2023-10-12 2024-01-30 广东工业大学 High-absorbance composite membrane and application thereof in laser-induced transfer

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CN107144898A (en) * 2017-06-29 2017-09-08 中国建筑材料科学研究总院 Optics regulation and control electromagnetic shielding glass and preparation method thereof
CN110066118A (en) * 2018-01-21 2019-07-30 苏州奥科飞光电科技有限公司 A kind of new A G glass and its production technology
CN108515743A (en) * 2018-05-09 2018-09-11 同济大学 A kind of medium/metal ultra wide band absorbing membrane and preparation method thereof
CN109720026B (en) * 2019-02-25 2024-03-12 深圳德宝天成科技有限公司 High-permeability high-reflection heat insulation film
CN109720026A (en) * 2019-02-25 2019-05-07 深圳德宝天成科技有限公司 A kind of high transmission high reflection thermal isolation film
CN110542940A (en) * 2019-09-30 2019-12-06 东莞市光志光电有限公司 High-brightness optical reflector plate
CN111764471A (en) * 2020-07-01 2020-10-13 安徽皖南电机股份有限公司 Mirror surface high-level water tank
CN111638610A (en) * 2020-07-20 2020-09-08 宁波材料所杭州湾研究院 Flexible intelligent light adjusting film with high visible light transmittance and heat insulation and preparation method thereof
CN111970915A (en) * 2020-08-28 2020-11-20 山东大学 Electromagnetic radiation prevention ultrathin film, electromagnetic radiation prevention ultrathin film device, preparation method and application
CN112423574A (en) * 2020-11-18 2021-02-26 中国科学院宁波材料技术与工程研究所 Ultrathin flexible transparent electromagnetic shielding film and preparation method thereof
CN112423574B (en) * 2020-11-18 2023-03-10 中国科学院宁波材料技术与工程研究所 Ultrathin flexible transparent electromagnetic shielding film and preparation method thereof
CN112902751A (en) * 2021-01-14 2021-06-04 中国电子科技集团公司第三十三研究所 High-shielding-effect high-light-transmission temperature-resistant pressure-resistant shielding aiming glass with transparent ceramic substrate
CN113719221A (en) * 2021-08-17 2021-11-30 福建恒春织造股份有限公司 Magic tape window membrane convenient to installation is dismantled and is accomodate
CN113703206A (en) * 2021-08-25 2021-11-26 京东方科技集团股份有限公司 Light-adjusting glass and light-adjusting module
CN113703206B (en) * 2021-08-25 2023-10-17 京东方科技集团股份有限公司 Dimming glass and dimming module
CN117465081A (en) * 2023-10-12 2024-01-30 广东工业大学 High-absorbance composite membrane and application thereof in laser-induced transfer

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Application publication date: 20170531