CN106769342A - A kind of integrated recombiner - Google Patents
A kind of integrated recombiner Download PDFInfo
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- CN106769342A CN106769342A CN201710140186.4A CN201710140186A CN106769342A CN 106769342 A CN106769342 A CN 106769342A CN 201710140186 A CN201710140186 A CN 201710140186A CN 106769342 A CN106769342 A CN 106769342A
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- tube
- filtering pond
- hybrid filtering
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/34—Purifying; Cleaning
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/38—Diluting, dispersing or mixing samples
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
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- General Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Biomedical Technology (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Sampling And Sample Adjustment (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
The invention discloses a kind of integrated recombiner, including proportioning device and hybrid filtering pond, proportioning device is arranged on the top in hybrid filtering pond；Proportioning device includes quantity tube and run-off, and quantity tube is provided with three, and the top of each quantity tube is connected with an overfall；The overfall other end is passed into run-off；The lower end of each quantity tube is connected with a connecting tube, and a feed tube and a valve are both provided with each connecting tube, and valve is located at the lower section of feed tube；The lower end of connecting tube is connected with a mixing feed tube by three-way connection, and the lower end for mixing feed tube is connected with the top in hybrid filtering pond；A glass core is provided with the middle part of hybrid filtering pond, bottom is provided with filtrate outlet.Integrated recombiner integrates and quantifies, mixes, filtering, the compacter stabilization of structure；Reagent and water sample mixing sample introduction, are fully contacted, and increased chemical reaction degree, improve measurement sensitivity.
Description
Technical field
The present invention relates to a kind of water quality monitoring instrument, more particularly to a kind of integrated recombiner.
Background technology
Chemical oxygen consumption (COC) (abbreviation COD) is the overall target of water quality organic contamination, is most important in water quality routine monitoring
One of project.China's national standard (GB 17378.4-2007) regulation is using potassium permanganate as oxidant oxygen in the basic conditions
Change seawater sample, chemical oxygen consumption (COC) is calculated by the consumption of oxidant potassium permanganate.
Standard conditions are complicated, time-consuming, laborious.Therefore, COD analysis methods that are easy, fast and automatically changing and instrument are explored
The effort target of device is always environmental monitoring work person.Since the eighties in last century her Vinh Long history of Japanese scholars first will flowing note
Penetrate analytical technology to be introduced into COD on-line determinations, develop automation COD analytical instrument.Subsequent other scholars have been developed different
Flow injection COD mensurations are studied, and after last century the nineties, various countries have developed various COD online analyzers in succession, its
Middle recombiner plays a key effect as the important component of COD online analyzer in COD measure.
But seawater sample is different from fresh water, because seawater contains substantial amounts of calcium, magnesium ion, hydrogen-oxygen is generated in the basic conditions
Change calcium and magnesium hydroxide white colloidal insoluble matter, and because Flow Injection Analysis process is carried out in the thin pipe of closing, it is this
White colloidal insoluble matter easily blocking pipeline, and COD determines and uses optical detection technique, this white colloidal insoluble matter,
Influence light detection.Common solution is to be dissolved calcium hydroxide and magnesium hydroxide white colloidal insoluble matter with hydrochloric acid, then is gone
Light is detected.So due to adding the hydrochloric acid of certain volume, necessarily increase total volume of reaction solution, so that diluting reaction knot
Really, larger evaluated error is caused.
The sea water COD analyzer designed before National Ocean Technology Center is exactly double current-carrying double injection flow passage structures (see figure
4)。
Main road is alkali road, quantitative using rotation sampling valve, is respectively tried water sample and potassium permanganate with two rotation sampling valves
Sodium Hydroxide Alkaline main road is injected in agent.Bypass (sour road) design be in order to dissolve alkaline sedimentation, but its negative effect can also make it is anti-
Answer solution to dilute, cause sensitivity decrease.Double injection is designed as water sample and reagent difference sample injection, and water sample and reagent are in pipeline
In lean on diffusion contact, water sample and reagent contact are few, and chemically reacting, insufficient (what the top of Fig. 4 represented is water sample and reagent in pipe
Distribution scenario in road).It is possible when this design is exceedingly fast for reaction speed or sample concentration is very high, and COD is surveyed
Surely it is the slower redox reaction of reaction speed, it is not high so as to also result in sensitivity.
Generally existing drawbacks described above during present sea water COD is determined, therefore how to solve drawbacks described above, as now urgently
Technical problem to be solved.
The content of the invention
It is an object of the invention to provide a kind of integrated recombiner, to solve the problems, such as above-mentioned prior art, improve
Measurement sensitivity, reduces evaluated error.
To achieve the above object, the invention provides following scheme：The present invention provides a kind of integrated recombiner, including fixed
Amount device and hybrid filtering pond, the proportioning device are arranged on the top in the hybrid filtering pond；The proportioning device is included
Quantity tube and run-off, the run-off are arranged on the top of the quantity tube, and the quantity tube is provided with three, described in each
The top of quantity tube is all connected with an overfall；Described overfall one end is connected with the quantity tube, and the other end is passed into described
In run-off；The lower end of each quantity tube is connected with a connecting tube, and one is vertically installed with each described connecting tube
Feed tube, is additionally provided with a valve in the connecting tube, the valve is located at the lower section of the feed tube；
Three lower ends of the connecting tube are connected with a mixing feed tube, the mixing feed tube by a three-way connection
Lower end be connected with the top in the hybrid filtering pond；A glass core is provided with the middle part of the hybrid filtering pond, bottom sets
It is equipped with filtrate outlet.
Optionally, the run-off is provided with three, triangular in shape uniform；Each described quantity tube respectively with an overflow
Pond connects, and three quantity tubes are triangular in shape uniform.
Optionally, the bottom of the run-off is provided with discharge floss hole, a diameter of 6.0mm of the discharge floss hole.
Optionally, the overfall beveled, opening bore is 2.0mm, and angle of inclination is 45 °.
Optionally, a diameter of 6.0mm of the quantity tube, its top is cone with bottom.
Optionally, the top in the hybrid filtering pond is connected with gas tube and escaping pipe, and the gas tube mixes with described
One end of filtering ponds connection is goed deep into the hybrid filtering pond, and presses close to the glass core top.
Optionally, the top in the hybrid filtering pond is also associated with two inlets, is respectively used to hydrochloric acid feed liquor and pure water
Feed liquor.
Optionally, the glass core is cone, and its is opening up；The gas tube presses close to the cone of the glass core
Middle face.
Optionally, the bottom in the hybrid filtering pond is cone.
Optionally, the integrated recombiner is processed from strand by a cylindric lucite.
The present invention achieves following technique effect relative to prior art：
Integrated recombiner of the invention integrates quantitative, mixes, three kinds of functions of filtering, the compacter stabilization of structure；
Sample introduction after potassium permanganate reagent and seawater sample mixed, is fully contacted water sample and reagent, increased chemical reaction degree, improves
Measurement sensitivity；After the completion of measure, then dissolving with hydrochloric acid insoluble matter is passed through, eliminates influence of the hydrochloric acid volume to determining, carried
Measurement accuracy high.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to institute in embodiment
The accompanying drawing for needing to use is briefly described, it should be apparent that, drawings in the following description are only some implementations of the invention
Example, for those of ordinary skill in the art, on the premise of not paying creative work, can also obtain according to these accompanying drawings
Obtain other accompanying drawings.
Fig. 1 is the sectional view of integration recombiner of the invention；
The top view of the integrated recombiners of Fig. 2；
The structural representation of the integrated recombiners of Fig. 3；
Fig. 4 is the design path that prior art COD is determined；
Fig. 5 is design path of the invention；
Wherein, 1 is quantity tube, and 2 is run-off, and 3 is overfall, and 4 is hybrid filtering pond, and 5 is discharge floss hole, and 6 is company
Adapter, 7 is feed tube, and 8 is magnetic valve installing pipe, and 9 is three-way connection, and 10 is mixing feed tube, and 11 is gas tube, and 12 is filtrate
Outlet, 13 is escaping pipe, and 14 is glass core.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on
Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
It is an object of the invention to provide a kind of integrated recombiner, to solve the problems, such as prior art, survey is improve
Amount sensitivity, reduces evaluated error.
It is below in conjunction with the accompanying drawings and specific real to enable the above objects, features and advantages of the present invention more obvious understandable
The present invention is further detailed explanation to apply mode.
The present invention provides integrated recombiner, as shown in Figure 1 to Figure 3, including proportioning device and hybrid filtering pond 4, it is quantitative
Device is arranged on the top in hybrid filtering pond 4；Proportioning device includes quantity tube 1 and run-off 2, and quantity tube 1 is provided with three,
The top of each quantity tube 1 is connected with an overfall 3；The one end of overfall 3 is connected with quantity tube 1, and the other end is passed into overflow
In pond 2；The lower end of each quantity tube 1 is connected with a connecting tube 6, and a feed tube 7 is vertically installed with each connecting tube 6,
Three feed tubes 7 are respectively used to be passed through potassium permanganate reagent, sodium hydroxide reagent and seawater sample, and sodium hydroxide reagent can also
Replaced being additionally provided with a valve in each connecting tube 6 with other suitable alkaline reagents, valve is magnetic valve, pacified by magnetic valve
Tubulature 8 is arranged in connecting tube 6, positioned at the lower section of feed tube 7；Magnetic valve and feed tube 7 all press close to the setting of the bottom of quantity tube 1.
Run-off 2 is provided with three, and triangular in shape uniform, each quantity tube 1 is connected with a run-off 2 respectively, and three quantity tubes 1 are in
Triangle is uniform, the compacter stabilization of structure of run-off 2 and quantity tube 1.
First, by three valve Close Alls, with micropump by potassium permanganate reagent, sodium hydroxide reagent and seawater sample
It is passed through in quantity tube 1 from three feed tubes 7 respectively, quantity tube 1 is vertical long tube, its top and bottom are cone, can
Avoid remaining bubble in quantity tube 1, influence certainty of measurement.After reagent or sample are full of quantity tube 1, unnecessary part from
Overfall 3 is spilt into run-off 2；The beveled of overfall 3, opening bore is 2.0mm, and angle of inclination is 45 °, be ensure that
Unnecessary liquid all overflows, and error improves quantitative accuracy less than a drop.The bottom of run-off 2 sets discharge discharge
Mouth 5, a diameter of 6.0mm of discharge floss hole 5, the surplus liquid in run-off 2 is discharged from discharge floss hole 5.
Three lower ends of connecting tube 6 are connected with a mixing feed tube 10 by a three-way connection 9, mixing feed tube 10
Lower end is connected with the top in hybrid filtering pond 4, for three kinds of liquid to be passed into hybrid filtering pond 4, is mixed.Mixed
The middle part in filter tank 4 is provided with a glass core 14, and bottom is provided with filtrate outlet 12, and glass core 14 is cone, is used
Corrosion-resistant glass is made, and its is opening up, and inside is alveolate texture, and potassium permanganate reagent, sodium hydroxide reagent and seawater are tried
Three kinds of liquid of sample are mixed on the top of glass core 14；Because there is substantial amounts of calcium, magnesium ion in seawater sample, reaction is again
Carried out under the conditions of Sodium Hydroxide Alkaline, now mixed solution reacts and produces white colloidal insoluble matter, and reaction equation is such as
Under：
Ca2++2OH-=Ca (OH)2↓
Mg2++2OH-=Mg (OH)2↓
In order that above-mentioned three kinds of liquid is well mixed, the top in hybrid filtering pond 4 uses flat head design, connects thereon
Gas tube 11 is connected to, one end that gas tube 11 is connected with hybrid filtering pond 4 is goed deep into hybrid filtering pond 4, and presses close to glass core
14 conical surface middle part top, air is passed through with air pump through gas tube 11 to the top of hybrid filtering pond 4, is inflated stirring, makes to mix
Close the more uniform of liquid mixing.The top in hybrid filtering pond 4 is also associated with escaping pipe 13, so as to by hybrid filtering pond 4
Gas is discharged.
After Aerated stirring is uniform, unlatching is connected to the suction filter pump at filtrate outlet 12, causes the bottom of hybrid filtering pond 4 to bear
Pressure, under suction function, the mixed liquor positioned at the top of hybrid filtering pond 4 is just flowed down through glass core 14, and white colloidal is not
Molten thing is trapped within the surface of glass core 14, and limpid filtered fluid just can inject photodetector measure.The bottom in hybrid filtering pond 4
It is cone, conical surface top is connected with filtrate outlet 12, facilitates filtrate outflow, reduce residual, improves certainty of measurement.
Seawater sample of the present invention is identical with potassium permanganate reagent sampling volume, and now potassium permanganate reagent excess, works as reaction
After the completion of, by the reduction of remaining potassium permanganate reagent, to measure.
The top in hybrid filtering pond 4 is also associated with two inlets, is respectively used to hydrochloric acid feed liquor and pure water feed liquor；Work as measure
After the completion of, the top in hydrochloric acid inlet injection hybrid filtering pond 4 therefrom retains on the surface of dissolving glass core 14
White colloidal insoluble matter, reaction equation is as follows：
Ca(OH)2+ 2HCl=CaCl2+2H2O
Mg(OH)2+ 2HCl=MgCl2+2H2O
Discharged from filtrate outlet 12 after dissolving, thrown aside.
By pure water from the top of another inlet injection hybrid filtering pond 4, cleaning glass core 14.
Waste liquid after cleaning is also discharged from filtrate outlet 12, is thrown aside.
Then can start to determine next time.
The present invention use flow path designs as shown in figure 5, water sample and reagent mixing after sample introduction, water sample and reagent is fully connect
Touch, increased chemical reaction degree, improve measurement sensitivity.(top of Fig. 5 represent be water sample and reagent mixing after pipe
Distribution scenario in road).
Integrated recombiner of the invention integrates quantitative, mixes, three kinds of functions of filtering, by a cylindric lucite
Process, integrated recombiner is located in cylindric lucite, the compacter stabilization of structure；Potassium permanganate reagent and seawater
Sample introduction after sample mixed, is fully contacted water sample and reagent, increased chemical reaction degree, improves measurement sensitivity；Work as survey
After the completion of fixed, then dissolving with hydrochloric acid insoluble matter is passed through, eliminates influence of the hydrochloric acid volume to determining, improve measurement accuracy.
Specific case is applied in the present invention to be set forth principle of the invention and implementation method, above example
Illustrate that being only intended to help understands the method for the present invention and its core concept；Simultaneously for those of ordinary skill in the art, according to
According to thought of the invention, will change in specific embodiments and applications.In sum, this specification content
Should not be construed as limiting the invention.
Claims (10)
1. a kind of integrated recombiner, it is characterised in that：Including proportioning device and hybrid filtering pond, the proportioning device is arranged on
The top in the hybrid filtering pond；The proportioning device includes quantity tube and run-off, and the run-off is arranged on described fixed
The top of buret, the quantity tube is provided with three, and the top of each quantity tube is connected with an overfall；The overflow
Mouth one end is connected with the quantity tube, and the other end is passed into the run-off；The lower end of each quantity tube is connected with
One connecting tube, is vertically installed with a feed tube in each described connecting tube, a valve is additionally provided with the connecting tube, described
Valve is located at the lower section of the feed tube；
Three lower ends of the connecting tube are connected with a mixing feed tube by a three-way connection, under the mixing feed tube
End is connected with the top in the hybrid filtering pond；A glass core is provided with the middle part of the hybrid filtering pond, bottom is provided with
Filtrate outlet.
2. integrated recombiner according to claim 1, it is characterised in that：The run-off is provided with three, in triangle
Shape is uniform；Each described quantity tube is connected with a run-off respectively, and three quantity tubes are triangular in shape uniform.
3. integrated recombiner according to claim 1, it is characterised in that：The bottom of the run-off is provided with discharge row
Put mouth, a diameter of 6.0mm of the discharge floss hole.
4. integrated recombiner according to claim 1, it is characterised in that：The overfall beveled, be open bore
It is 2.0mm, angle of inclination is 45 °.
5. integrated recombiner according to claim 1, it is characterised in that：A diameter of 6.0mm of the quantity tube, its top
End is cone with bottom.
6. integrated recombiner according to claim 1, it is characterised in that：The top in the hybrid filtering pond is connected with to be filled
Tracheae and escaping pipe, the gas tube go deep into the hybrid filtering pond with one end that the hybrid filtering pond is connected, and press close to
The glass core top.
7. integrated recombiner according to claim 6, it is characterised in that：The top of the mixer filter is also associated with
Two inlets, are respectively used to hydrochloric acid feed liquor and pure water feed liquor.
8. integrated recombiner according to claim 6, it is characterised in that：The glass core is cone, its opening
Upward；The gas tube presses close to the conical surface middle part of the glass core.
9. integrated recombiner according to claim 1, it is characterised in that：The bottom in the hybrid filtering pond is circular cone
Shape.
10. integrated recombiner according to claim 1, it is characterised in that：The integrated recombiner is cylindric by one
Lucite processes from strand.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710140186.4A CN106769342B (en) | 2017-03-10 | 2017-03-10 | A kind of integration recombiner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710140186.4A CN106769342B (en) | 2017-03-10 | 2017-03-10 | A kind of integration recombiner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106769342A true CN106769342A (en) | 2017-05-31 |
| CN106769342B CN106769342B (en) | 2018-05-08 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710140186.4A Expired - Fee Related CN106769342B (en) | 2017-03-10 | 2017-03-10 | A kind of integration recombiner |
Country Status (1)
| Country | Link |
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| CN (1) | CN106769342B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107144676A (en) * | 2017-06-12 | 2017-09-08 | 山东龙发环保科技有限公司 | Detection device and gauge line, metering device and its metering method |
| CN111413149A (en) * | 2020-04-26 | 2020-07-14 | 广州海研生物科技有限公司 | Sampling device for detecting biological technology medicament products |
| CN111458211A (en) * | 2020-05-14 | 2020-07-28 | 青海省药品检验检测院 | Prevent that medicine that deposits from detecting and leaving a kind device with sample |
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| CN1971264A (en) * | 2005-11-24 | 2007-05-30 | 江苏江分电分析仪器有限公司 | Control device for automatically removing oxygen, adding liquid and mixing of titration solvent |
| US20080277347A1 (en) * | 2007-05-08 | 2008-11-13 | Robert Lee Grenz | Sample preparation device and method utilizing polyamide tube |
| CN104297419A (en) * | 2013-07-17 | 2015-01-21 | 国家电网公司 | Device for evaluating liquid foaming performance and foam generating method |
| CN105521650A (en) * | 2014-09-30 | 2016-04-27 | 宝钢不锈钢有限公司 | Quantitative gas-liquid mixing device and method |
| CN206740469U (en) * | 2017-03-10 | 2017-12-12 | 国家海洋技术中心 | A kind of integrated recombiner |
-
2017
- 2017-03-10 CN CN201710140186.4A patent/CN106769342B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1971264A (en) * | 2005-11-24 | 2007-05-30 | 江苏江分电分析仪器有限公司 | Control device for automatically removing oxygen, adding liquid and mixing of titration solvent |
| US20080277347A1 (en) * | 2007-05-08 | 2008-11-13 | Robert Lee Grenz | Sample preparation device and method utilizing polyamide tube |
| CN104297419A (en) * | 2013-07-17 | 2015-01-21 | 国家电网公司 | Device for evaluating liquid foaming performance and foam generating method |
| CN105521650A (en) * | 2014-09-30 | 2016-04-27 | 宝钢不锈钢有限公司 | Quantitative gas-liquid mixing device and method |
| CN206740469U (en) * | 2017-03-10 | 2017-12-12 | 国家海洋技术中心 | A kind of integrated recombiner |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107144676A (en) * | 2017-06-12 | 2017-09-08 | 山东龙发环保科技有限公司 | Detection device and gauge line, metering device and its metering method |
| CN111413149A (en) * | 2020-04-26 | 2020-07-14 | 广州海研生物科技有限公司 | Sampling device for detecting biological technology medicament products |
| CN111413149B (en) * | 2020-04-26 | 2020-10-13 | 广州海研生物科技有限公司 | Sampling device for detecting biological technology medicament products |
| CN111458211A (en) * | 2020-05-14 | 2020-07-28 | 青海省药品检验检测院 | Prevent that medicine that deposits from detecting and leaving a kind device with sample |
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| Publication number | Publication date |
|---|---|
| CN106769342B (en) | 2018-05-08 |
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