CN106760379A - A kind of Multifunctional friction electricity-generating floor leather and sensor - Google Patents

A kind of Multifunctional friction electricity-generating floor leather and sensor Download PDF

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Publication number
CN106760379A
CN106760379A CN201611110456.9A CN201611110456A CN106760379A CN 106760379 A CN106760379 A CN 106760379A CN 201611110456 A CN201611110456 A CN 201611110456A CN 106760379 A CN106760379 A CN 106760379A
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CN
China
Prior art keywords
flooring laminate
film
alloy
triboelectricity
conductive layer
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Pending
Application number
CN201611110456.9A
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Chinese (zh)
Inventor
曹霞
竭洋
王中林
朱华瑞
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University of Science and Technology Beijing USTB
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University of Science and Technology Beijing USTB
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Priority to CN201611110456.9A priority Critical patent/CN106760379A/en
Publication of CN106760379A publication Critical patent/CN106760379A/en
Pending legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02NELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N1/00Electrostatic generators or motors using a solid moving electrostatic charge carrier
    • H02N1/04Friction generators
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/02Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Floor Finish (AREA)

Abstract

The invention discloses a kind of Multifunctional friction electricity-generating floor leather and sensor, Multifunctional friction electricity-generating floor leather includes a floor body and a conductive layer elements.Described flooring laminate body is complex as a whole with conductive layer elements and is generally aligned in the same plane, and draws an electrode, is configured to single electrode integral type triboelectricity flooring laminate.Wherein described flooring laminate body serves as the first frictional layer, and the insulating materials in living serves as the second frictional layer with the surface of nonisulated object, according to triboelectrification and electrostatic induction principle, both contact with each other and separate, cause and produce electrical potential difference between electrode layer elements and the earth, described conductive layer elements being capable of outside circuit output electric signal, it is possible to used as independent sensor.The present invention based on the common flooring laminate of in the market for body is improved, simple structure, consumptive material are few, low cost, prepare easily, electric signal and without limitation the use scope of plate leather and life-span can be exported.

Description

A kind of Multifunctional friction electricity-generating floor leather and sensor
Technical field
The invention belongs to friction generator technical field, and in particular to a kind of Multifunctional friction electricity-generating floor leather and sensing Device.
Background technology
Mechanical energy is ubiquitous in life at present, but is ignored by people extensively.The present invention utilizes triboelectrification and electrostatic Mechanical energy is converted into electric energy this basic thought by principle of induction, there is provided a kind of Multifunctional friction electricity-generating floor leather.This is rubbed Indoors, it is external that the mechanical energy of the process generation such as walk using people, trampled, stroked changes into electric energy to the laying of electricity-generating floor leather Circuit provides electric signal, forms a kind of generation mode of environmental protection.The Multifunctional friction electricity-generating floor possesses multiple functions, when When triggering generating multifunctional floor leather with different attitudes, produce the size or shape of electric signal different, can be as biography Sensor, the activity of monitoring people or animal;When conductive layer is array architecture, during triggering diverse location, corresponding region produces electricity Signal, can be used for position monitoring;Also, transmission electric signal out is combined by the design of external circuit with intelligence system, can As warning system.
There is the carpet with generating function in the prior art, but most of is piezoelectric or pressure electricity-generating, Complex structure, consumptive material is more, expensive, unitary function.Chinese patent 201520857542.0 discloses a kind of pressure electricity-generating ground Plate is, it is necessary to, there is complex structure in the part such as spring, gear, generator, and preparation process is cumbersome.Chinese patent 201510385439.5 disclose the carpet that a kind of utilization piezoelectric generates electricity, and need to add fixing end and elasticity in preparation process Bar, equally exists baroque problem.
The Multifunctional friction electricity-generating floor leather mentioned in the present invention, the particular problem of solution is as follows:
In order to solve the labyrinth of existing generating carpet, consumptive material is more, the problem of high cost, the triboelectricity ground that the present invention is provided Plate leather is to be designed into integral type triboelectricity flooring laminate using the existing flooring laminate of in the market, is normally made carpet is not influenceed On the premise of, the more functions in floor are assigned, can not only generate electricity as power supply but also can be applied right as sensor The occasions such as the monitoring of old man and children.
1st, Multifunctional friction electricity-generating floor leather of the invention uses integral structure, by conductive layer elements and flooring laminate body Concentrate in the same plane, without complicated elastic strip and fixing end, simple structure, consumptive material are few.
2nd, in the form of triboelectricity, flooring laminate is the first frictional layer to Multifunctional friction electricity-generating floor leather of the invention, The triboelectricity flooring laminate need not deliberately design the second frictional layer, sole, socks, human body and itself and flooring laminate material in life Distinguishing other materials of matter may act as the second rubbing surface.
3rd, the Multifunctional friction electricity-generating floor leather that the present invention is provided, is commercially to add one on the basis of existing flooring laminate Individual conductive layer elements, are not affected to flooring laminate use in itself, and low cost.
4th, the Multifunctional friction electricity-generating floor leather that the present invention is provided, acts not only as the power supply of energy-conserving and environment-protective, Er Qietong The relation crossed between the feature and trigger condition that produce electric signal, the flooring laminate can be as independently-powered sensor.
The content of the invention
In order to solve the above problems, the present invention provides a kind of Multifunctional friction electricity-generating floor leather, the triboelectricity floor Leather includes conductive layer elements and flooring laminate body, and described conductive layer elements are complex as a whole with flooring laminate body, and positioned at same One plane;
Further, the flooring laminate body is composite construction, homogeneous penetrating structure or half homogeneous penetrating structure;
Further, described conductive layer elements are conductor, semi-conducting material or conductive material;
Further, the flooring laminate body is rubber floor covering, flax floor, plastic floor or timber floor;
Further, the conductive layer elements are located at the interlayer of flooring laminate body or the bottommost of flooring laminate;
Further, the conductive layer elements include electrically conductive simple metal or alloy, the simple metal include gold, silver, copper, Iron, platinum, palladium, aluminium, nickel, titanium, vanadium, chromium, manganese, selenium, molybdenum and tungsten;The alloy include aluminium alloy, copper alloy, titanium alloy, magnesium alloy, Beryllium alloy, kirsite, manganese alloy, nickel alloy, metal, tin alloy, cadmium alloy, bismuth alloy, indium alloy, gallium alloy, tungsten alloy, Molybdenum alloy, niobium alloy and tantalum alloy;The conductive material includes indium tin oxide, Graphene and its derivative, ion doping Semiconductor and conductive film material;
Further, described flooring laminate body is high molecular polymer, and the high molecular polymer includes polydimethylsiloxanes Alkane, polyethylene, polypropylene, Kynoar, vinylidene chloride-acrylonitrile copolymerization film, polytetrafluoroethylene (PTFE), polyvinyl chloride, fluorination second Allyl alkene copolymer, polytrifluorochloroethylene, polychlorobutadiene, Kapton, aniline-formaldehyde resin film, polyformaldehyde are thin Film, ethyl cellulose film, polyamide film, melamino-formaldehyde film, makrolon, polyethylene glycol succinate film, Phenolic resin, neoprene, cellophane, natural rubber, ethyl cellulose, cellulose acetate film, polyadipate second Terephthalate films, polydiallyl phthalate film, staple fibre, PVOH butyral, styrene-acrylonitrile copolymer copolymer are thin Film, styrene-butadiene-copolymer film, the third diphenol of polyethylene carbonate, staple fibre film, polystyrene, polymethyl Acid esters film, polyvinyl alcohol film, polyvinyl alcohol film, polyester film, polyisobutene film, polyurethane flexible sponge films, Poly bis phenol carbonate, CPPG, polyethylene terephthalate and wood;
Further, the triboelectricity flooring laminate also includes a triboelectricity system, and the triboelectricity system includes first Frictional layer, the second frictional layer and external circuit, first frictional layer are flooring laminate body, and second frictional layer is energy in life The material of enough and flooring laminate surfacing generation triboelectrification, the first frictional layer, the second frictional layer and external circuit, described first rubs Layer and the second frictional layer are wiped under external force, by the outside circuit output electric signal of the process being contacting and separating;
Further, second frictional layer is insulating materials or non-insulating material;
Further, a kind of sensor, so sensor is triboelectricity flooring laminate, the conductive layer elements are one continuous Big unit or multiple independent discontinuous units.
Beneficial effects of the present invention are as follows:
1st, based on triboelectrification and the integrated structure of electrostatic induction principle design multifunctional generating flooring laminate and independent sensing Device, conductive layer elements are complex as a whole by the modes such as electro-deposition, sputtering, bonding and flooring laminate, without add elastic strip and Fixing end;
2nd, it is not required to deliberately provide the second frictional layer, and insulated with material and nonisulated, it is sole, socks in life, conductive What human body and other materials distinguishing with flooring laminate Facing material can be itself acted as the second frictional layer and flooring laminate First frictional layer is acted on;
3rd, Multifunctional friction electricity-generating floor leather is applied to multiple kinds of energy drive form, such as pats, tramples, strokes, rubs, slides Electric current output is all shown Deng, the triboelectricity flooring laminate, for the interior for laying the flooring laminate provides a kind of green ring newly Protect forms of electricity generation;
4th, the integral multifunctional triboelectricity flooring laminate and standalone sensor that the present invention is provided, simple structure, it is easy to prepare, no Influence flooring laminate use and outward appearance, triggering material and energy drive form variation, can as sensor, and to choosing With the structure of flooring laminate material, material, hardness no requirement (NR), these advantages are the triboelectricity flooring laminate band provided in the present invention Carry out bigger application market.
Brief description of the drawings
Fig. 1 is a kind of typical structure generalized section of Multifunctional friction electricity-generating floor leather of the present invention;
Fig. 2 is the electricity generating principle schematic diagram of Multifunctional friction electricity-generating floor leather of the present invention;
Fig. 3 is another structural representation of Multifunctional friction electricity-generating floor leather of the present invention;
Fig. 4 is another structural representation of Multifunctional friction electricity-generating floor leather of the present invention;
Fig. 5 is another new structure pictorial diagram of Multifunctional friction electricity-generating floor leather of the present invention;
Fig. 6 is a kind of electric current output figure of Multifunctional friction electricity-generating floor leather in the embodiment of the present invention 2;
Fig. 7 is a kind of voltage output figure of Multifunctional friction electricity-generating floor leather in the embodiment of the present invention 2;
A kind of Multifunctional friction electricity-generating floor leather is applied and known in physical activity as sensor in Fig. 8 embodiment of the present invention 3 Not.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples The present invention is explained in further detail.It should be appreciated that specific embodiment described herein is used only for explaining the present invention, and It is not used in the restriction present invention.Conversely, the present invention cover it is any be defined by the claims done in spirit and scope of the invention Replacement, modification, equivalent method and scheme.Further, in order that the public has a better understanding to the present invention, below to this It is detailed to describe some specific detail sections in the detailed description of invention.It is thin without these for a person skilled in the art The description for saving part can also completely understand the present invention.
The present invention is provided and a kind of human body walking, the mechanical energy trampled, the naturally occurring such as stroke can be converted into electric energy Multifunction triboelectricity flooring laminate.Electricity-generating floor leather is the compound one layer of conductive layer of lower surface or interlayer in flooring laminate Element, constitutes the integral type triboelectricity system of simple structure, and can be as standalone sensor, below in conjunction with the accompanying drawings and tool The invention will be further described for body embodiment, but not as a limitation of the invention.It is specific as follows:
Embodiment 1
1st, the construction of Multifunctional friction electricity-generating floor leather and standalone sensor
Fig. 1 is that Multifunctional friction electricity-generating floor of the present invention removes from office a kind of generalized section of typical structure.Including:Flooring laminate body 10 With conductive layer elements 20.By modes such as laminating, sputtering or plating, conductive layer is combined into the lower surface of flooring laminate and is located at Conplane integral structure.The sole of people, clothes, tire etc. can produce triboelectrification with flooring laminate surface in life Material can serve as the second rubbing surface 11, such as pats in external force, tramples, stroking, under the form that rubs effect, by flooring laminate Body 10 and the outside circuit transmission electric signal of conductive layer elements 20.Conductive layer elements may be located at the lower surface of flooring laminate body 10 Or the interlayer of compound flooring laminate, by taking Multi-layer composite flooring laminate 10 as an example, the schematic diagram of different structure as shown in Fig. 2 its Middle Multi-layer composite flooring laminate 10 includes, wearing layer 12, printed layer 13, flexible foaming layer 14, basic unit 15.
2nd, the operation principle of triboelectricity flooring laminate
It is and of the invention when the friction different various objects of electrode sequence that the external world exists and removed from office from the Multifunctional friction electricity-generating floor When there is triboelectrification and electrostatic induction between triboelectricity flooring laminate, the triboelectricity flooring laminate system can turn mechanical energy Electric energy is changed to, external circuit is done work.
Embodiment 2:
A kind of Multifunctional friction electricity-generating floor leather is provided in the present embodiment, pictorial diagram is referring to accompanying drawing 4.Flooring laminate in the present embodiment Body 10 is selected from compound coiled material PVC floor leather, and thickness is 2mm.Conductive layer elements 20 are chosen for the stronger Copper Foil of electric conductivity, thick Spend is 80 μm.Conductive layer elements 20 and flooring laminate body 10 in the present embodiment are prepared by way of simple bonding, the friction The size of electricity-generating floor leather is 4cm*9cm.It is the second frictional layer with butyronitrile gloves in the present embodiment, the mode of beating carries out energy Amount is driven, and Multifunctional friction electricity-generating floor leather produces electric current to outside, and the current data through the test display of electrometer 6514 is joined See accompanying drawing 6, voltage data figure is as shown in Figure 7.
Embodiment 3:
A kind of Multifunctional friction electricity-generating floor leather is provided in the present embodiment, as sensor, the flooring laminate body in the present embodiment 10 selected from coiled material plastic floor leather, and thickness is 5mm.Conductive layer elements 20 are chosen for the stronger Copper Foil of electric conductivity, and thickness is 80 μm. Conductive layer elements 20 and flooring laminate body 10 in the present embodiment are prepared by way of simple bonding.In the present embodiment, with footwear The frictional layer of bottom second, multi-motion mode carries out energy driving, and Multifunctional friction electricity-generating floor leather produces voltage letter to outside Number, the rules and difference of waveform voltage signals are produced according to different actions, the multifunctional floor is removed from office as standalone sensor, can be with Physical activity identification is carried out, through the voltage of the test display of electrometer 6514 referring to accompanying drawing 6.
Embodiment described above, simply one kind of the present invention more preferably specific embodiment, those skilled in the art The usual variations and alternatives that member is carried out in the range of technical solution of the present invention all should be comprising within the scope of the present invention.

Claims (10)

1. a kind of Multifunctional friction electricity-generating floor leather, it is characterised in that the triboelectricity flooring laminate include conductive layer elements and Flooring laminate body, described conductive layer elements are complex as a whole with flooring laminate body, and are generally aligned in the same plane.
2. triboelectricity flooring laminate according to claim 1, it is characterised in that the flooring laminate body be composite construction, Homogeneous penetrating structure or half homogeneous penetrating structure.
3. triboelectricity flooring laminate according to claim 1, it is characterised in that described conductive layer elements are conductor, half Conductor material or conductive material.
4. triboelectricity flooring laminate according to claim 2, it is characterised in that the flooring laminate body be rubber floor covering, Flax floor, plastic floor or timber floor.
5. triboelectricity flooring laminate according to claim 3, it is characterised in that the conductive layer elements are located at flooring laminate sheet The interlayer of body or the bottommost of flooring laminate.
6. triboelectricity flooring laminate according to claim 3, it is characterised in that the conductive layer elements include electrically conductive Simple metal or alloy, the simple metal include gold, silver, copper, iron, platinum, palladium, aluminium, nickel, titanium, vanadium, chromium, manganese, selenium, molybdenum and tungsten;Institute Alloy is stated to be closed including aluminium alloy, copper alloy, titanium alloy, magnesium alloy, beryllium alloy, kirsite, manganese alloy, nickel alloy, metal, tin Gold, cadmium alloy, bismuth alloy, indium alloy, gallium alloy, tungsten alloy, molybdenum alloy, niobium alloy and tantalum alloy;The conductive material includes The semiconductor and conductive film material of indium tin oxide, Graphene and its derivative, ion doping.
7. triboelectricity flooring laminate according to claim 1, it is characterised in that described flooring laminate body is polyphosphazene polymer Compound, the high molecular polymer includes dimethyl silicone polymer, polyethylene, polypropylene, Kynoar, vinylidene chloride propylene It is nitrile copolymerization film, polytetrafluoroethylene (PTFE), polyvinyl chloride, fluorinated ethylene propylene copolymer, polytrifluorochloroethylene, polychlorobutadiene, poly- Imide membrane, aniline-formaldehyde resin film, polyformaldehyde film, ethyl cellulose film, polyamide film, melamino-formaldehyde Film, makrolon, polyethylene glycol succinate film, phenolic resin, neoprene, cellophane, natural rubber, ethyl Cellulose, cellulose acetate film, polyethylene glycol adipate film, polydiallyl phthalate film, artificial fibre Dimension, PVOH butyral, styrene-acrylonitrile copolymer copolymer film, styrene-butadiene-copolymer film, polyethylene the third diphenol carbonic acid Salt, staple fibre film, polystyrene, polymethacrylates film, polyvinyl alcohol film, polyvinyl alcohol film, polyester Film, polyisobutene film, polyurethane flexible sponge films, poly bis phenol carbonate, CPPG, polyethylene terephthalate And wood.
8. according to the triboelectricity flooring laminate that one of the claims 1-7 is described, it is characterised in that the triboelectricity floor Leather also includes a triboelectricity system, and the triboelectricity system includes the first frictional layer, the second frictional layer and external circuit, described First frictional layer is flooring laminate body, and second frictional layer is that can produce triboelectrification with flooring laminate surfacing in living Material, the first frictional layer, the second frictional layer and external circuit, first frictional layer and the second frictional layer under external force, By the outside circuit output electric signal of the process being contacting and separating.
9. triboelectricity flooring laminate system according to claim 8, it is characterised in that second frictional layer is insulating materials Or non-insulating material.
10. a kind of sensor, based on the described triboelectricity flooring laminates of one of the claims 1-9, it is characterised in that so Sensor is triboelectricity flooring laminate, and the conductive layer elements are a continuous big unit or multiple independent discontinuous lists Unit.
CN201611110456.9A 2016-12-06 2016-12-06 A kind of Multifunctional friction electricity-generating floor leather and sensor Pending CN106760379A (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN106760391A (en) * 2017-01-18 2017-05-31 王珏 A kind of Multifunctional friction electricity-generating floor leather and a kind of standalone sensor
CN108531011A (en) * 2018-04-11 2018-09-14 南京工业大学 A kind of electric energy generation and sampler based on leather
CN108988677A (en) * 2018-07-20 2018-12-11 东华大学 A kind of single-electrode nano structural friction power generation sponge and its preparation and application
CN110242006A (en) * 2019-06-21 2019-09-17 南方科技大学 A kind of magnetohydrodynamic generator floor and preparation method thereof
CN111021665A (en) * 2019-10-15 2020-04-17 国网浙江省电力有限公司嘉兴供电公司 Anti-static movable floor capable of alarming
CN112031325A (en) * 2020-09-30 2020-12-04 忻州师范学院 Friction power generation floor, and preparation method and application thereof

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CN103368453A (en) * 2013-03-12 2013-10-23 国家纳米科学中心 Nanometer electric generator utilizing sliding friction and electricity generating method
CN103780122A (en) * 2013-02-01 2014-05-07 国家纳米科学中心 Sliding type friction nanometer generating set
CN104578892A (en) * 2013-10-12 2015-04-29 纳米新能源(唐山)有限责任公司 Integrated frictional generator and vibration sensor
CN204840350U (en) * 2015-06-29 2015-12-09 纳智源科技(唐山)有限责任公司 Film disinfects based on triboelectricity
CN105811800A (en) * 2016-05-19 2016-07-27 北京科技大学 Single-electrode integrated friction power generator

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CN103780122A (en) * 2013-02-01 2014-05-07 国家纳米科学中心 Sliding type friction nanometer generating set
CN103368453A (en) * 2013-03-12 2013-10-23 国家纳米科学中心 Nanometer electric generator utilizing sliding friction and electricity generating method
CN104578892A (en) * 2013-10-12 2015-04-29 纳米新能源(唐山)有限责任公司 Integrated frictional generator and vibration sensor
CN204840350U (en) * 2015-06-29 2015-12-09 纳智源科技(唐山)有限责任公司 Film disinfects based on triboelectricity
CN105811800A (en) * 2016-05-19 2016-07-27 北京科技大学 Single-electrode integrated friction power generator

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106760391A (en) * 2017-01-18 2017-05-31 王珏 A kind of Multifunctional friction electricity-generating floor leather and a kind of standalone sensor
CN108531011A (en) * 2018-04-11 2018-09-14 南京工业大学 A kind of electric energy generation and sampler based on leather
CN108988677A (en) * 2018-07-20 2018-12-11 东华大学 A kind of single-electrode nano structural friction power generation sponge and its preparation and application
CN110242006A (en) * 2019-06-21 2019-09-17 南方科技大学 A kind of magnetohydrodynamic generator floor and preparation method thereof
CN110242006B (en) * 2019-06-21 2024-01-09 南方科技大学 Magnetohydrodynamic power generation floor and preparation method thereof
CN111021665A (en) * 2019-10-15 2020-04-17 国网浙江省电力有限公司嘉兴供电公司 Anti-static movable floor capable of alarming
CN112031325A (en) * 2020-09-30 2020-12-04 忻州师范学院 Friction power generation floor, and preparation method and application thereof

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Application publication date: 20170531