CN106757506A - Fire protection flame retarding composite material - Google Patents
Fire protection flame retarding composite material Download PDFInfo
- Publication number
- CN106757506A CN106757506A CN201610984560.4A CN201610984560A CN106757506A CN 106757506 A CN106757506 A CN 106757506A CN 201610984560 A CN201610984560 A CN 201610984560A CN 106757506 A CN106757506 A CN 106757506A
- Authority
- CN
- China
- Prior art keywords
- composite material
- flame retarding
- fire
- protection flame
- fire protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04C—BRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
- D04C1/00—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
- D04C1/02—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof made from particular materials
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/06—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyethers
- D10B2331/061—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyethers polyetherketones, polyetheretherketones, e.g. PEEK
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/14—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/30—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polycondensation products not covered by indexing codes D10B2331/02 - D10B2331/14
- D10B2331/301—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polycondensation products not covered by indexing codes D10B2331/02 - D10B2331/14 polyarylene sulfides, e.g. polyphenylenesulfide
Abstract
The present invention relates to a kind of fire protection flame retarding composite material, include according to the raw material of percentage by weight：Colloid 35 ~ 55%, azo crosslinking agent 10 ~ 20%, polyhedral silsesquioxane 1 ~ 2%, polyphenylene sulfide 5 ~ 8%, polyether-ether-ketone 6 ~ 10%, polyamidoimide 5 ~ 8%, phenolic fibre 3 ~ 8%, polyimides 3 ~ 6%, carbon fiber 6 ~ 8%.Polyphenylene sulfide（PPS), polyether-ether-ketone（PEEK）, polyamidoimide（Kermal）, phenolic fibre（Kynol）, the fabric that obtains of polyimides (P84), the combination matching of carbon fiber there is excellent fire resistance；Polyhedral silsesquioxane (POSS) is the distinctive organic silicon fibre retardant of a class, and excellent fire-retardant, mechanics and thermal property can be shown under extremely low addition.Soft, ventilative according to the fire protection flame retarding composite material that above-mentioned material proportioning is obtained, environmental protection is washable, wear-resisting, with good mechanics and thermal property, and can reach the fire retardant poles of B1.
Description
Technical field
The present invention relates to fire proofing field, and in particular to a kind of fire protection flame retarding composite material.
Background technology
Industry work(on the thousand is built, the same day is burnt poor.Fire is one of frequency of occurrences highest disaster in natural calamity, is also a kind of
Do not limited by space-time, destructive huge disaster.With continuing to develop for society, while the wealth of society is increasing, lead
Causing the incidence that fire occurs also is increasing, and the harmfulness of fire is also increasing.The improvement of people's living standards and with artificial
The enhancing of this security protection consciousness, the fire resistance of textile is increasingly paid close attention to by people.Present chemical fibre class clothes kind increases
It is many, and people are met to wearing the diversified demand of dress ornament, but its essence is inflammable, is thus brought not to clothes storage
Just, fire hazardous, cause heavy losses.The fire-retardant of existing textile industry fabric filament stage use coating or spray-coating surface more
The fabric that the method for material, this coating or spraying are obtained is not washable, adheres to insecure, and fabric is stiffening, and feel is very poor, impermeable
Gas, wears or uses and uncomfortable.
The content of the invention
Soft, ventilative it is an object of the present invention to provide a kind of fire protection flame retarding composite material, environmental protection is washable, wear-resisting, tool
There is good mechanics and thermal property, and the fire retardant poles of B1 can be reached.
In order to realize the above object the technical solution adopted by the present invention is：A kind of fire protection flame retarding composite material, according to weight
The raw material of percentage includes：Colloid 35 ~ 55%, azo crosslinking agent 10 ~ 20%, polyhedral silsesquioxane 1 ~ 2%, polyphenylene sulfide 5 ~
8%th, polyether-ether-ketone 6 ~ 10%, polyamide-imides 5 ~ 8%, phenolic fibre 3 ~ 8%, polyimides 3 ~ 6%, carbon fiber 6 ~ 8%.
Preferably, colloid 45%, azo crosslinking agent 15%, polyhedral silsesquioxane 2%, polyphenylene sulfide 7%, polyether-ether-ketone
8%th, polyamide-imides 6%, phenolic fibre 5%, polyimides 5%, carbon fiber 7%.
Further, described colloid is acryl glue or PU glue.
Further, described azo crosslinking agent is BDB or azodiisobutyronitrile.
The technical effects of the invention are that：Polyphenylene sulfide（PPS), polyether-ether-ketone（PEEK）, polyamide-imides
（Kermal）, phenolic fibre（Kynol）, the fabric that obtains of polyimides (P84), the combination matching of carbon fiber there is excellent resistance
Combustion performance；Polyhedral silsesquioxane (POSS) is the distinctive organic silicon fibre retardant of a class, can table under extremely low addition
Reveal excellent fire-retardant, mechanics and thermal property.According to the fire protection flame retarding composite material that above-mentioned material proportioning is obtained, feel is soft
Soft, ventilative, environmental protection is washable, wear-resisting, with good mechanics and thermal property, and can reach the fire retardant poles of B1.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1：A kind of fire protection flame retarding composite material, includes according to the raw material of percentage by weight：Colloid 45%, azo is handed over
Connection agent 15%, polyhedral silsesquioxane 2%, polyphenylene sulfide 7%, polyether-ether-ketone 8%, polyamide-imides 6%, phenolic fibre 5%,
Polyimides 5%, carbon fiber 7%.
Further, described colloid is acryl glue or PU glue.
Further, described azo crosslinking agent is BDB or azodiisobutyronitrile.
Polyphenylene sulfide（PPS), polyether-ether-ketone（PEEK）, polyamide-imides（Kermal）, phenolic fibre（Kynol）, it is poly-
The fabric that acid imide (P84), the combination matching of carbon fiber are obtained has excellent fire resistance；Polyhedral silsesquioxane
(POSS) it is the distinctive organic silicon fibre retardant of a class, excellent fire-retardant, mechanics and heat can be shown under extremely low addition
Learn performance.Soft, ventilative according to the fire protection flame retarding composite material that above-mentioned material proportioning is obtained, environmental protection is washable, wear-resisting, tool
There is good mechanics and thermal property, and the fire retardant poles of B1 can be reached.
Embodiment 2：A kind of fire protection flame retarding composite material, includes according to the raw material of percentage by weight：Colloid 42%, azo is handed over
Connection agent 13%, polyhedral silsesquioxane 2%, polyphenylene sulfide 7%, polyether-ether-ketone 7%, polyamide-imides 7%, phenolic fibre 8%,
Polyimides 6%, carbon fiber 8%.
Further, described colloid is acryl glue or PU glue.
Further, described azo crosslinking agent is BDB or azodiisobutyronitrile.
Soft, ventilative according to the fire protection flame retarding composite material that above-mentioned material proportioning is obtained, environmental protection is washable, wear-resisting,
With good mechanics and thermal property, and the fire retardant poles of B1 can be reached.
Embodiment 3：A kind of fire protection flame retarding composite material, includes according to the raw material of percentage by weight：Colloid 55%, azo is handed over
Connection agent 12%, polyhedral silsesquioxane 1%, polyphenylene sulfide 7%, polyether-ether-ketone 6%, polyamide-imides 5%, phenolic fibre 3%,
Polyimides 3%, carbon fiber 8%.
Further, described colloid is acryl glue or PU glue.
Further, described azo crosslinking agent is BDB or azodiisobutyronitrile.
Soft, ventilative according to the fire protection flame retarding composite material that above-mentioned material proportioning is obtained, environmental protection is washable, wear-resisting,
With good mechanics and thermal property, and the fire retardant poles of B1 can be reached.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.
Claims (4)
1. a kind of fire protection flame retarding composite material, it is characterised in that the raw material according to percentage by weight includes：Colloid 35 ~ 55%, it is even
Nitrogen crosslinking agent 10 ~ 20%, polyhedral silsesquioxane 1 ~ 2%, polyphenylene sulfide 5 ~ 8%, polyether-ether-ketone 6 ~ 10%, polyamide-imides 5
~ 8%, phenolic fibre 3 ~ 8%, polyimides 3 ~ 6%, carbon fiber 6 ~ 8%.
2. fire protection flame retarding composite material according to claim 1, it is characterised in that：Colloid 45%, azo crosslinking agent 15% is more
Face body silsesquioxane 2%, polyphenylene sulfide 7%, polyether-ether-ketone 8%, polyamide-imides 6%, phenolic fibre 5%, polyimides 5%,
Carbon fiber 7%.
3. fire protection flame retarding composite material according to claim 1 and 2, it is characterised in that：Described colloid is acryl glue
Or PU glue.
4. fire protection flame retarding composite material according to claim 1 and 2, it is characterised in that：Described azo crosslinking agent is double
Azo benzidine or azodiisobutyronitrile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610984560.4A CN106757506A (en) | 2016-11-09 | 2016-11-09 | Fire protection flame retarding composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610984560.4A CN106757506A (en) | 2016-11-09 | 2016-11-09 | Fire protection flame retarding composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106757506A true CN106757506A (en) | 2017-05-31 |
Family
ID=58972367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610984560.4A Pending CN106757506A (en) | 2016-11-09 | 2016-11-09 | Fire protection flame retarding composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106757506A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107794647A (en) * | 2017-08-23 | 2018-03-13 | 江苏格玛斯特种织物有限公司 | Fire-resistant waterproof fabrics and fibers and its manufacture method |
| CN117462763A (en) * | 2023-12-27 | 2024-01-30 | 中国科学院空间应用工程与技术中心 | Silicon nitride fiber reinforced polyether-ether-ketone composite material, preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702115A (en) * | 2005-06-27 | 2005-11-30 | 北京中卫邦华技术开发有限责任公司 | Non-backing flameproof materials and fireproof composite lining and method for making same |
| US20080054230A1 (en) * | 2006-01-24 | 2008-03-06 | No-Burn Investments, Llc | Intumescent fire retardant paint with insecticide |
| CN102094339A (en) * | 2010-11-30 | 2011-06-15 | 吴江市凌志纺织有限公司 | Fireproof and waterproof composite face fabric |
| CN102352098A (en) * | 2011-08-30 | 2012-02-15 | 丹宸科技（大连）有限公司 | Flame retardation material |
| CN105647158A (en) * | 2014-11-14 | 2016-06-08 | 南通市跃达针织服饰有限公司 | Flame-retardant fireproof composite fabric |
-
2016
- 2016-11-09 CN CN201610984560.4A patent/CN106757506A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1702115A (en) * | 2005-06-27 | 2005-11-30 | 北京中卫邦华技术开发有限责任公司 | Non-backing flameproof materials and fireproof composite lining and method for making same |
| US20080054230A1 (en) * | 2006-01-24 | 2008-03-06 | No-Burn Investments, Llc | Intumescent fire retardant paint with insecticide |
| CN102094339A (en) * | 2010-11-30 | 2011-06-15 | 吴江市凌志纺织有限公司 | Fireproof and waterproof composite face fabric |
| CN102352098A (en) * | 2011-08-30 | 2012-02-15 | 丹宸科技（大连）有限公司 | Flame retardation material |
| CN105647158A (en) * | 2014-11-14 | 2016-06-08 | 南通市跃达针织服饰有限公司 | Flame-retardant fireproof composite fabric |
Non-Patent Citations (1)
| Title |
|---|
| 刘威: "POSS/PET复合材料的制备及性能研究", 《中国优秀硕士学位论文全文数据库 工程科技1辑》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107794647A (en) * | 2017-08-23 | 2018-03-13 | 江苏格玛斯特种织物有限公司 | Fire-resistant waterproof fabrics and fibers and its manufacture method |
| CN117462763A (en) * | 2023-12-27 | 2024-01-30 | 中国科学院空间应用工程与技术中心 | Silicon nitride fiber reinforced polyether-ether-ketone composite material, preparation method and application |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
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| RJ01 | Rejection of invention patent application after publication |