CN106757490A - A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread - Google Patents
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread Download PDFInfo
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- CN106757490A CN106757490A CN201611209094.9A CN201611209094A CN106757490A CN 106757490 A CN106757490 A CN 106757490A CN 201611209094 A CN201611209094 A CN 201611209094A CN 106757490 A CN106757490 A CN 106757490A
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- spandex
- waste silk
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/94—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of other polycondensation products
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, belongs to spining technology field, comprises the following steps:1), maturation process is carried out to spandex waste silk, heat and be incubated in the environment of N2 gas;2), spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm;3), spandex waste silk superbhort fiber dried, and make spandex waste silk superbhort fiber that there is certain moisture content;4), in reactor add DMAC, spandex waste silk superbhort fiber, obtain the spinning solution of stability of characteristics;5), spinning solution by filtering, deaeration, maturation, spinning, twist, oil, winding, acquisition finished product spandex thread.The regeneration spandex thread performance indications stabilization and spinning speed produced by this method are high.This method improves the stability of spandex waste silk by curing and the control to spandex waste silk moisture content, generation situations such as so as to reduce fracture of wire, effectively improves the spinning speed and top-quality product rate of spandex thread.
Description
Technical field
The invention belongs to spining technology field, and in particular to be a kind of side of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread
Method.
Background technology
Spandex is that a kind of macromolecular compound with linear segmented structure containing polyurethanes more than 85% is made
Elastomer, because it has the advantages that other fibers are incomparable, such as light specific gravity, fracture strength are high, extension at break is high, elasticity
Reply good etc., spandex fibre is widely used in various fields.
Production spandex mainly adopts the technology that dry spinning, and dry spinning yield is about the 80% of world's spandex total output.
Main flow using dry spinning production spandex is as follows:PTMEG is with diisocyanate with 1:2 mol ratio is certain
Reaction temperature and prepolymer is formed under the conditions of the time, after prepolymer dissolves through solvent, adding diamines carries out chain propagation reaction, shape
Into block copolymer solution, then the operation such as mixing, filtering, deaeration after adding auxiliary agent, it is made the spinning original of performance uniformity
Liquid.Then with measuring pump quantitative and even ground press-in spinning head, spinning solution is extruded to form strand thread from spinneret pore,
Into spinning shaft.Filled with hot-air (or hot nitrogen) in path, the solvent in strand thread is set to volatilize rapidly, and by air
(or nitrogen) is taken away, and strand concentration is improved constantly up to solidification, while spandex is generally multifilament, will by twister before solidification
Its obvolvent, finally oils, and is wound into certain package.
General dry spinning, can all produce spandex waste silk.The treatment to spandex waste silk is usually to abandon in the prior art
Do not recycle, occasionally there is recycling spandex waste silk to be regenerated as the method for normal spandex thread, but there is energy consumption and material consumption is high, it is qualified
The low problem of rate, finished product stability can not reach requirement.
The content of the invention
It is an object of the invention to overcome defect and deficiency mentioned above, and it is efficient again to provide a kind of dry-spinning waste polyurethane filament
The method of raw spandex thread.
The present invention realizes that the technical scheme that its purpose is used is as follows.
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, comprises the following steps:
Step 1), maturation process is carried out to spandex waste silk, in N2Heated in the environment of gas and be incubated;
Step 2), spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm;
Step 3), spandex waste silk superbhort fiber dried, and make spandex waste silk superbhort fiber that there is certain moisture content;
Step 4), in reactor add DMAC, spandex waste silk superbhort fiber, obtain the spinning solution of stability of characteristics;
Step 5), spinning solution by filtering, deaeration, maturation, spinning, twist, oil, winding, acquisition finished product spandex thread.
Preferably, step 2)In, spandex waste silk crushes temperature control at 0 DEG C ~ 10 DEG C.
Preferably, step 4)In, the reaction condition of DMAC and spandex waste silk superbhort fiber in reactor is:Temperature is
50 DEG C ~ 100 DEG C, the reaction time is 5 ~ 10 hours.
Preferably, step 4)In, the DMAC is 1 ~ 3 times of spandex waste silk superbhort fiber quality.
Preferably, step 5)In, the filtering is using candle filter filtering, the screen pack of the candle filter
The metallic fiber sintered felt screen pack of 400 mesh.
Preferably, step 5)In, the deaeration is vacuum defoamation, 15 ~ 20 minutes time.
Preferably, step 1)In, maturation process is carried out to spandex waste silk, the end-sealed type polyethers that mass fraction is 1% is changed
The aqueous solution of property polysiloxanes is atomized and sprays to spandex waste silk, in N2Be warmed in the environment of gas 70 DEG C ~ 120 DEG C and keep 12 ~
17 hours;The end-sealed type Siloxane-Oxyalkylene Copolymers are the 2% ~ 10% of the quality of spandex waste silk.
As another preferred, step 1)In, maturation process is carried out to spandex waste silk, in N270 are heated up in the environment of gas
DEG C ~ 120 DEG C and be incubated 12 ~ 17 hours.
Preferably, step 3)In, spandex waste silk superbhort fiber is dried, moisture is controlled, make spandex waste silk ultrashort
The moisture content of fiber is 0.2% ~ 1.0%.
Preferably, step 1)In, humid control is 10% ~ 35%.
This method has the advantages that:
1. the regeneration spandex thread performance indications stabilization and spinning speed produced by this method are high.This method by curing and
Control to spandex waste silk moisture content, improves the stability of spandex waste silk, generation situations such as so as to reduce fracture of wire, effectively
Improve the spinning speed and top-quality product rate of spandex thread;
2. simple operating steps of this method, environmental pollution is few.This method uses the performance of curing process mediation spandex waste silk
State simultaneously coordinates the disintegrating process of uniqueness to peel off the auxiliary agent and foreign matter of spandex waste silk surface attachment, according to spandex waste silk and auxiliary agent and
The mass discrepancy of foreign matter disposably completes mask work.Therefore, the present invention is without using cleaning agent, it is to avoid cleaning agent is for ammonia
The adverse effect of synthetic fibre waste silk performance, saves the pollution of process costs and water for cleaning;
3. without using auxiliary agent, auxiliary agent includes this method:Reaction terminating agent, age resister, fiberizing agent etc..The present invention is avoided
Influence because of auxiliary agent side reaction to spandex thread physical and chemical performance, while save production cost and alleviate shadow of the auxiliary agent to environment
Ring;
4. this method need not add fresh normal spinning solution.In traditional method, fresh spinning solution and spandex waste silk are mixed
Close, be used to improve the stability of spandex thread.This method production regeneration spandex thread, performance indications stabilization meet professional standard and under
Trip customer requirement, without adding fresh spinning solution.Present invention process is simple, and small investment both solves problem of environmental pollution,
Economic benefit higher is obtained again.
Specific embodiment
Specific embodiment of the invention is expanded on further by the following examples, does not address part and is applicable prior art,
But the present invention should not be limited by the examples.
Embodiment one:
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, comprises the following steps:
Step 1), maturation process is carried out to spandex waste silk, in N2120 DEG C are warmed in the environment of gas and are kept for 12 hours, humidity
Control is 10%.
Step 2), at 10 DEG C or so, spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm.
Before crushing, auxiliary agent and foreign matter are attached to spandex waste silk;After crushing, spandex waste silk superbhort fiber divides with auxiliary agent, foreign matter
From.Auxiliary agent, foreign matter are less than superbhort fiber on volume and weight, therefore, it can further to be purified by negative pressure filter ultrashort
Fiber, it is of course also possible to separate both by other means.For example, when crushing, auxiliary agent and foreign matter are floated, can be by controlling wind
The mode of speed and setting screen pack separates both.Therefore, spandex waste silk completes spandex waste silk while being ground into short fine
The stripping of the auxiliary agent and debris of surface attachment.
The method that this method employs ambient ground, control temperature is at 0 DEG C ~ 10 DEG C, on the one hand, for by maturation process
Spandex waste silk, the good crushing effect in this temperature range, on the other hand, relative to low-temperature grinding, save the energy and set
Standby expenditure, reduces technological parameter requirement so that this method is easy to spread.
Step 3), spandex waste silk superbhort fiber dried, control moisture, make the moisture content of spandex waste silk superbhort fiber
0.2%.
Traditional furnace drying method, the moisture content for spandex waste silk superbhort fiber is not required.The hair of founding property of applicant
Existing, moisture content has directly influence for spandex fibre end properties, when aqueous between single spandex waste silk superbhort fiber
Rate differs greatly or moisture content is too high or too low, will all reduce the yield of finished fiber.And work as moisture control 0.2% ~
When 1.0%, the stability of spandex waste silk superbhort fiber is higher, individuation difference is small, it is to avoid generation situations such as fracture of wire, can spin
Property is high, improves the stability of finished product, and yield is high.It is small in the spandex waste silk superbhort fiber dry-hot shrinkage of this moisture content, fracture
Intensity is strong.Moisture content is absolute drift herein.
Step 4), in reactor add DMAC, spandex waste silk superbhort fiber, at 50 DEG C reaction obtain characteristic within 5 hours
The spinning solution of stabilization;The mass ratio of the DMAC and spandex waste silk superbhort fiber is 3:1.
DMAC, scientific name dimethylacetylamide, uses as solvent.
Step 5), by filtering, deaeration, maturation, spinning, twist, oil, wind, obtain finished product spandex thread.
Using candle filter filtering, the screen pack of the candle filter uses the metallic fiber of 400 mesh for the filtering
Sintering felt screen pack.Gel and particle in candle filter energy filter raw liquid.Screen pack is set to 400 mesh, except mistake
Outside the function of filter, moreover it is possible to play a part of to control Air Bubble Size.Air pocket can be divided into minute bubbles by the screen pack of 400 mesh, i.e.,
Minute bubbles are made also to be unlikely to fracture of wire into there is gas explosion behind path.The filtration resistance of metallic fiber sintered felt screen pack only has tradition
/ 3rd of screen pack, are conducive to shortening throughput time.
The deaeration is vacuum defoamation 15 ~ 20 minutes.Before deaeration, there is gas in spinning solution, if do not excluded,
Gas explosion can be formed in the die orifice exit of filament spinning component causes silk thread to be broken.Therefore, this method before spinning, is employed true
Empty deaeration mode, excludes the gas in spinning solution.
The spinning is that stoste is delivered into spinning appts, and in high temperature path, solvent volatilization, stoste solidification obtains ammonia
Synthetic fibre.
Embodiment two:
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, comprises the following steps:
Step 1), maturation process is carried out to spandex waste silk, in N270 DEG C are warmed in the environment of gas and are kept for 17 hours, humidity control
System is 35%.
Step 2), at 0 DEG C or so, spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm.
Step 3), spandex waste silk superbhort fiber dried, control moisture, make the moisture content of spandex waste silk superbhort fiber
1.0%.
Step 4), in reactor add DMAC, spandex waste silk superbhort fiber, at 100 DEG C reaction obtain spy within 10 hours
Property stabilization spinning solution;The mass ratio of the DMAC and spandex waste silk superbhort fiber is 1:1.
Step 5), by filtering, deaeration, maturation, spinning, twist, oil, wind, obtain finished product spandex thread.
Remaining is identical with embodiment one, repeats no more.
Embodiment three:
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, comprises the following steps:
Step 1), maturation process is carried out to spandex waste silk, by the water of end-sealed type Siloxane-Oxyalkylene Copolymers that mass fraction is 1%
Solution atomization simultaneously sprays to spandex waste silk, in N2110 DEG C are warmed in the environment of gas and are kept for 12 hours, humid control is 10%.Institute
State the 2% of the quality that end-sealed type Siloxane-Oxyalkylene Copolymers are spandex waste silk.
Under maturation, end-sealed type Siloxane-Oxyalkylene Copolymers are adsorbed in spandex waste silk surface, and progressively useless to spandex
Silk diffusion inside.The end-sealed type Siloxane-Oxyalkylene Copolymers on spandex waste silk surface are used to adsorb greasy dirt, and are removed in shredding stage.
End-sealed type Siloxane-Oxyalkylene Copolymers inside spandex waste silk participate in changing the proterties of spandex fibre, reduce surface tension,
Bubble is eliminated, fracture of wire is reduced, the stability of spandex fibre is improved.
Step 2), at 10 DEG C or so, spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm.
Step 3), spandex waste silk superbhort fiber dried, control moisture, make the moisture content of spandex waste silk superbhort fiber
0.2%.
Step 4), in reactor add DMAC, spandex waste silk superbhort fiber, at 50 DEG C reaction obtain characteristic within 5 hours
The spinning solution of stabilization;The mass ratio of the DMAC and spandex waste silk superbhort fiber is 3:1.
Step 5), by filtering, deaeration, maturation, spinning, twist, oil, wind, obtain finished product spandex thread.
Remaining is identical with embodiment one, repeats no more.
Example IV:
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, comprises the following steps:
Step 1), maturation process is carried out to spandex waste silk, by the water of end-sealed type Siloxane-Oxyalkylene Copolymers that mass fraction is 1%
Solution atomization simultaneously sprays to spandex waste silk, in N270 DEG C are warmed in the environment of gas and are kept for 17 hours.The end-sealed type polyethers changes
Property polysiloxanes for spandex waste silk quality 10%, control humidity 35%.
Step 2), at 0 DEG C or so, spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm.
Step 3), spandex waste silk superbhort fiber dried, control moisture, make the moisture content of spandex waste silk superbhort fiber
1.0%.
Step 4), in reactor add DMAC, spandex waste silk superbhort fiber, at 100 DEG C reaction obtain spy within 10 hours
Property stabilization spinning solution;The mass ratio of the DMAC and spandex waste silk superbhort fiber is 1:1.
Step 5), by filtering, deaeration, maturation, spinning, twist, oil, wind, obtain finished product spandex thread.
Remaining is identical with embodiment one, repeats no more.
Control group 1, this control group is corresponding with embodiment 1:
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, comprises the following steps:
Step 1), using less than -30 DEG C freeze grinding technologies, spandex waste silk is ground into the spandex waste silk of fibre length≤30mm
Superbhort fiber.
Step 2), with water and detergent clean spandex waste silk superbhort fiber;
Step 3), drying spandex waste silk superbhort fiber surface point water;
Step 4), DMAC, spandex waste silk superbhort fiber and auxiliary agent are added in reactor, reaction obtains spy in 8 hours at 50 DEG C
Property stabilization spinning solution;
The mass ratio of the DMAC and spandex waste silk superbhort fiber is 5:1.
The auxiliary agent includes reaction terminating agent, antiager and fiberizing agent;The reaction terminating agent, antiager and fiber
The mass percent that forming agent accounts for spinning solution is respectively 0.03%, 0.03% and 0.03%.
Step 5)By filtering, deaeration, maturation, spinning, twist, oil, wind, obtain finished product spandex thread.
Control group 2, this control group is corresponding with embodiment 1:
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, comprises the following steps:
Step 1), maturation process is carried out to spandex waste silk, in N2120 DEG C are warmed in the environment of gas and are kept for 12 hours, humidity
Control is 10%.
Step 2), at 10 DEG C or so, spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm.
Step 3), spandex waste silk superbhort fiber dried, moisture content is not controlled.
Step 4), in reactor add DMAC, spandex waste silk superbhort fiber, at 50 DEG C reaction obtain characteristic within 5 hours
The spinning solution of stabilization;The mass ratio of the DMAC and spandex waste silk superbhort fiber is 3:1.
Step 5), by filtering, deaeration, maturation, spinning, twist, oil, wind, obtain finished product spandex thread.
Control group 3, this control group is corresponding with embodiment 1:
A kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, comprises the following steps:
Step 1), at 10 DEG C or so, spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm.
Step 2), spandex waste silk superbhort fiber dried, control moisture, make the moisture content of spandex waste silk superbhort fiber
0.2%.
Step 3), in reactor add DMAC, spandex waste silk superbhort fiber, at 50 DEG C reaction obtain characteristic within 5 hours
The spinning solution of stabilization;The mass ratio of the DMAC and spandex waste silk superbhort fiber is 5:1.
DMAC, scientific name dimethylacetylamide, uses as solvent.
Step 4), by filtering, deaeration, maturation, spinning, twist, oil, wind, obtain finished product spandex thread.
Relative to control group 1, embodiment 1 is keeping line density deviation ratio less simultaneously, and Grade A is greatly improved
Qualification rate, therefore, more preferably, yields is high for the product stability of embodiment 1.Relative to control group 2 and control group 3, control group 1
Line density change rate is smaller, and Grade A qualification rate is larger, illustrates both curing and the control to spandex waste silk moisture content simultaneously
Use, better than effect is used alone, both have synergy.It is whole from embodiment 1, embodiment 2, embodiment 3 and embodiment 4
Body can be seen that the stability that this method improves spandex waste silk, generation situations such as so as to reduce fracture of wire, effectively increase
The spinning speed and top-quality product rate of spandex thread.
The present invention is illustrated according to embodiment, on the premise of present principles are not departed from, if the present apparatus can also make
Dry deformation and improvement.It should be pointed out that the technical scheme that the mode such as all use equivalents or equivalent transformation is obtained, all falls within this
In the protection domain of invention.
Claims (10)
1. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, it is characterised in that comprise the following steps:
Step 1), maturation process is carried out to spandex waste silk, in N2Heated in the environment of gas and be incubated;
Step 2), spandex waste silk is ground into the spandex waste silk superbhort fiber of fibre length≤30mm;
Step 3), spandex waste silk superbhort fiber dried, and make spandex waste silk superbhort fiber that there is certain moisture content;
Step 4), in reactor add DMAC, spandex waste silk superbhort fiber, obtain the spinning solution of stability of characteristics;
Step 5), spinning solution by filtering, deaeration, maturation, spinning, twist, oil, winding, acquisition finished product spandex thread.
2. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread as claimed in claim 1, it is characterised in that step 2)
In, spandex waste silk crushes temperature control at 0 DEG C ~ 10 DEG C.
3. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread as claimed in claim 1, it is characterised in that step 4)
In, the reaction condition of DMAC and spandex waste silk superbhort fiber in reactor is:Temperature be 50 DEG C ~ 100 DEG C, the reaction time be 5 ~
10 hours.
4. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread as claimed in claim 3, it is characterised in that step 4)
In, the DMAC is 1 ~ 3 times of spandex waste silk superbhort fiber quality.
5. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread as claimed in claim 1, it is characterised in that step 5)
In, using candle filter filtering, the screen pack of the candle filter is the metallic fiber sintered felt mistake of 400 mesh for the filtering
Filter screen.
6. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread as claimed in claim 1, it is characterised in that step 5)
In, the deaeration is vacuum defoamation, 15 ~ 20 minutes time.
7. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread as claimed in claim 1, it is characterised in that step 1)
In, maturation process is carried out to spandex waste silk, the aqueous solution of the end-sealed type Siloxane-Oxyalkylene Copolymers that mass fraction is 1% is atomized
And spandex waste silk is sprayed to, in N270 DEG C ~ 120 DEG C are warmed in the environment of gas and are kept for 12 ~ 17 hours;The end-sealed type polyethers changes
Property polysiloxanes for spandex waste silk quality 2% ~ 10%.
8. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread as claimed in claim 1, it is characterised in that step 1)
In, maturation process is carried out to spandex waste silk, in N270 DEG C ~ 120 DEG C are heated up in the environment of gas and 12 ~ 17 hours are incubated.
9. a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread as claimed in claim 1, it is characterised in that step 3)
In, spandex waste silk superbhort fiber is dried, moisture is controlled, make the moisture content of spandex waste silk superbhort fiber 0.2% ~ 1.0%.
10. as claimed in claim 7 or 8 a kind of method of dry-spinning waste polyurethane filament highly efficient regeneration spandex thread, it is characterised in that step
Rapid 1)In, humid control is 10% ~ 35%.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107419358A (en) * | 2017-06-13 | 2017-12-01 | 武汉纺织大学 | Selfreparing regeneration spandex based on microcapsules and preparation method thereof |
CN110016730A (en) * | 2019-05-05 | 2019-07-16 | 浙江华峰氨纶股份有限公司 | A kind of method of the aqueous useless stoste processing of spandex and spinning |
WO2021060292A1 (en) | 2019-09-24 | 2021-04-01 | 旭化成株式会社 | Recycled polyurethane elastic fiber, method of producing same, fiber structure containing said recycled polyurethane elastic fiber, gather member, and sanitary material |
-
2016
- 2016-12-23 CN CN201611209094.9A patent/CN106757490A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107419358A (en) * | 2017-06-13 | 2017-12-01 | 武汉纺织大学 | Selfreparing regeneration spandex based on microcapsules and preparation method thereof |
CN107419358B (en) * | 2017-06-13 | 2020-04-24 | 武汉纺织大学 | Self-repairing regenerated spandex based on microcapsule and preparation method thereof |
CN110016730A (en) * | 2019-05-05 | 2019-07-16 | 浙江华峰氨纶股份有限公司 | A kind of method of the aqueous useless stoste processing of spandex and spinning |
CN110016730B (en) * | 2019-05-05 | 2021-09-03 | 华峰化学股份有限公司 | Method for processing and spinning spandex aqueous waste stock solution |
WO2021060292A1 (en) | 2019-09-24 | 2021-04-01 | 旭化成株式会社 | Recycled polyurethane elastic fiber, method of producing same, fiber structure containing said recycled polyurethane elastic fiber, gather member, and sanitary material |
KR20220037510A (en) | 2019-09-24 | 2022-03-24 | 아사히 가세이 가부시키가이샤 | Recycled polyurethane elastic fiber, manufacturing method thereof, fiber structure comprising said recycled polyurethane elastic fiber, gather member, and sanitary material |
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