CN106757279A - Steel wire drawing electrolytic phosphating liquid and production method - Google Patents
Steel wire drawing electrolytic phosphating liquid and production method Download PDFInfo
- Publication number
- CN106757279A CN106757279A CN201611087598.8A CN201611087598A CN106757279A CN 106757279 A CN106757279 A CN 106757279A CN 201611087598 A CN201611087598 A CN 201611087598A CN 106757279 A CN106757279 A CN 106757279A
- Authority
- CN
- China
- Prior art keywords
- acid
- hedp
- water
- steel wire
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/36—Phosphatising
Abstract
Steel wire drawing electrolytic phosphating liquid, by as follows into being grouped into：Phosphoric acid, HEDP, phytic acid, citric acid, zinc oxide, trbasic zinc phosphate, manganese nitrate, nickelous carbonate, sodium fluoride, m-nitrobenzene sodium sulfonate, QYL 30, water；Water is first added in stainless steel cauldron, start agitator, setting speed is 60 80 revs/min, sequentially add phosphoric acid, HEDP, phytic acid, citric acid, after stirring 30 minutes, sequentially add zinc oxide, trbasic zinc phosphate, stirring fully dissolves transparent shape after 20 minutes, sequentially add nickelous carbonate, sodium fluoride, m-nitrobenzene sodium sulfonate, stirring 30 minutes, fully dissolving are in greenish transparent liquid, add manganese nitrate, QYL 30 and water, stirring is in greenish transparent liquid in 20 minutes, obtains steel wire drawing electrolytic phosphating liquid.Technique manipulation is simple when using, parameter stability, simple production process, low cost of manufacture.
Description
Technical field
The present invention relates to a kind of Phosphating Solution and production method, particularly a kind of steel wire drawing electrolytic phosphating liquid and producer
Method.
Background technology
The processing of accurate steel wire is required for by the accurate drawing of one or many.Must be by function before steel wire drawing
Property pre-treatment drawing phosphatization, the also referred to as phosphorating treatment before steel plastic working, first spread on one layer possess functional phosphating film layer work
It is carrier, then adsorbs one layer of saponification lubrication film layer, is drawn in the particular manufacturing craft that special drawing lathe is finally entered after drying
Pull out.At present, the pre-treating technology flow of accurate steel wire automatic assembly line is that 120 steel wire automatic transports enter：Pickling degreasing is lived
Change → washing → washing → surface adjustment → phosphatization → washing → washing → saponification process → drying → drawing.36 meters of phosphatization cell body
× 3.6 meters × 0.6 meter, phosphatization temperature is 75-85 DEG C.It has the disadvantage that Steel Wire Surface phosphating coat is uneven to existing Phosphating Solution, often
Generation grinning effect, to pull off phenomenon serious for steel wire when drawing；Working solution temperature is too high, and energy resource consumption is very big.
The content of the invention
It is an object of the invention to provide a kind of low cost, phosphatization effect is good, can reduce the steel of working solution temperature, save energy
Silk drawing electrolytic phosphating liquid and production method, overcome the deficiencies in the prior art.
Steel wire drawing of the invention electrolytic phosphating liquid, by as follows into being grouped into：Phosphoric acid, HEDP, phytic acid, citric acid, oxygen
Change zinc, trbasic zinc phosphate, manganese nitrate, nickelous carbonate, sodium fluoride, m-nitrobenzene sodium sulfonate, QYL-30, water；
Mass percent shared by each composition is as follows：
Components Name mass percent
Phosphoric acid 20-35%
HEDP 1-3.5%
Phytic acid 1-3.5%
Citric acid 1-3.5%
Zinc oxide 1-6%
Trbasic zinc phosphate 1-6%
Manganese nitrate 1-12%
Nickelous carbonate 1-10%
Sodium fluoride 1-6%
M-nitrobenzene sodium sulfonate 1-5%
QYL-30 1-6%
Water surplus.
The steel wire drawing of the invention production method of electrolytic phosphating liquid, first adds part water in stainless steel cauldron,
Start agitator, setting speed is 60-80 revs/min, phosphoric acid, HEDP, phytic acid, citric acid is sequentially added, as long as the consumption of water
Ensure that phosphoric acid, HEDP, phytic acid, citric acid are completely dissolved, after stirring 30 minutes, sequentially add zinc oxide, trbasic zinc phosphate, stir
Transparent shape is fully dissolved after 20 minutes, nickelous carbonate, sodium fluoride, m-nitrobenzene sodium sulfonate is sequentially added, 30 minutes are stirred, fully
Dissolving is in greenish transparent liquid, adds manganese nitrate, QYL-30 and remaining water, and stirring 20 minutes is in greenish transparent liquid
Body, obtains steel wire drawing electrolytic phosphating liquid；Mass percent shared by each composition is as follows：
Components Name mass percent
Phosphoric acid 20-35%
HEDP 1-3.5%
Phytic acid 1-3.5%
Citric acid 1-3.5%
Zinc oxide 1-6%
Trbasic zinc phosphate 1-6%
Manganese nitrate 1-12%
Nickelous carbonate 1-10%
Sodium fluoride 1-6%
M-nitrobenzene sodium sulfonate 1-5%
QYL-30 1-6%
Water surplus.
Steel wire drawing of the invention electrolytic phosphating liquid, technique manipulation is simple when being used by test, working solution items work
Skill technical parameter stabilization, the performance of electrolytic phosphating film surmounts conventional drawing phosphatization completely, and working solution temperature drops from 75-85 DEG C
Low to 45-55 DEG C, energy resource consumption is significantly reduced, fundamentally prevented the technology trouble of drawing fracture of wire, production technology letter
It is single, low cost of manufacture.
Specific embodiment
Steel wire drawing of the invention electrolytic phosphating liquid, by as follows into being grouped into：Phosphoric acid, HEDP, phytic acid, citric acid, oxygen
Change zinc, trbasic zinc phosphate, manganese nitrate, nickelous carbonate, sodium fluoride, m-nitrobenzene sodium sulfonate, QYL-30, water；
Mass percent shared by each composition is as follows：
Components Name mass percent（Account for the mass percent of total amount）
Phosphoric acid 20% or 25% or 30% or 35%
HEDP 1% or 2% or 2.5% or 3% or 3.5%
Phytic acid 1% or 2% or 2.5% or 3% or 3.5%
Citric acid 1% or 2% or 2.5% or 3% or 3.5%
Zinc oxide 1% or 2% or 3% or 4% or 5% or 6%
Trbasic zinc phosphate 1% or 2% or 3% or 4% or 5% or 6%
Manganese nitrate 1% or 3% or 6% or 8% or 10% or 12%
Nickelous carbonate 1% or 3% or 6% or 8% or 10%
Sodium fluoride 1% or 2% or 3% or 4% or 5% or 6%
M-nitrobenzene sodium sulfonate 1% or 2% or 3% or 4% or 5%
QYL-30 1% or 2% or 3% or 4% or 5% or 6%
Water surplus.
The steel wire drawing of the invention production method of electrolytic phosphating liquid, first adds part water in stainless steel cauldron,
Start agitator, setting speed is 60-80 revs/min, phosphoric acid, HEDP, phytic acid, citric acid is sequentially added, as long as the consumption of water
Ensure that phosphoric acid, HEDP, phytic acid, citric acid are completely dissolved, after stirring 30 minutes, sequentially add zinc oxide, trbasic zinc phosphate, stir
Transparent shape is fully dissolved after 20 minutes, nickelous carbonate, sodium fluoride, m-nitrobenzene sodium sulfonate is sequentially added, 30 minutes are stirred, fully
Dissolving is in greenish transparent liquid, adds manganese nitrate, QYL-30 and remaining water, and stirring 20 minutes is in greenish transparent liquid
Body, obtains steel wire drawing electrolytic phosphating liquid, sampling analysis, qualified rear blowing packaging.Mass percent shared by each composition is as follows：
Components Name mass percent（Account for the mass percent of total amount）
Phosphoric acid 20% or 25% or 30% or 35%
HEDP 1% or 2% or 2.5% or 3% or 3.5%
Phytic acid 1% or 2% or 2.5% or 3% or 3.5%
Citric acid 1% or 2% or 2.5% or 3% or 3.5%
Zinc oxide 1% or 2% or 3% or 4% or 5% or 6%
Trbasic zinc phosphate 1% or 2% or 3% or 4% or 5% or 6%
Manganese nitrate 1% or 3% or 6% or 8% or 10% or 12%
Nickelous carbonate 1% or 3% or 6% or 8% or 10%
Sodium fluoride 1% or 2% or 3% or 4% or 5% or 6%
M-nitrobenzene sodium sulfonate 1% or 2% or 3% or 4% or 5%
QYL-30 1% or 2% or 3% or 4% or 5% or 6%
Water surplus.
Phosphating Solution of the invention, add water preparation working solution when using, and Phosphating Solution accounts for the 10% of working solution total amount, total acidity：
45-55 pt, acid ratio：6-9, temperature：45-55 DEG C, cathode-current density：1.5-3.0A/dm2, anode material：Stainless steel plate, electricity
Pressure：6-12V, time：2 more than min, thickness：More than 10 μm.
Claims (2)
1. a kind of steel wire drawing electrolytic phosphating liquid, it is characterised in that：By as follows into being grouped into：Phosphoric acid, HEDP, phytic acid, lemon
Acid, zinc oxide, trbasic zinc phosphate, manganese nitrate, nickelous carbonate, sodium fluoride, m-nitrobenzene sodium sulfonate, QYL-30, water；
Mass percent shared by each composition is as follows：
Components Name mass percent
Phosphoric acid 20-35%
HEDP 1-3.5%
Phytic acid 1-3.5%
Citric acid 1-3.5%
Zinc oxide 1-6%
Trbasic zinc phosphate 1-6%
Manganese nitrate 1-12%
Nickelous carbonate 1-10%
Sodium fluoride 1-6%
M-nitrobenzene sodium sulfonate 1-5%
QYL-30 1-6%
Water surplus.
2. a kind of steel wire drawing as claimed in claim 1 production method of electrolytic phosphating liquid, it is characterised in that：First stainless
Water is added in steel reactor, starts agitator, setting speed is 60-80 revs/min, sequentially adds phosphoric acid, HEDP, phytic acid, lemon
Lemon acid, as long as the consumption of water ensures that phosphoric acid, HEDP, phytic acid, citric acid are completely dissolved, after stirring 30 minutes, sequentially adds
Zinc oxide, trbasic zinc phosphate, stirring fully dissolve transparent shape after 20 minutes, sequentially add nickelous carbonate, sodium fluoride, m-nitrobenzene sulfonic acid
Sodium, stirs 30 minutes, and fully dissolving is in greenish transparent liquid, adds manganese nitrate, QYL-30 and remaining water, stirs 20 points
Clock is in greenish transparent liquid, obtains steel wire drawing electrolytic phosphating liquid；Mass percent shared by each composition is as follows：
Components Name mass percent
Phosphoric acid 20-35%
HEDP 1-3.5%
Phytic acid 1-3.5%
Citric acid 1-3.5%
Zinc oxide 1-6%
Trbasic zinc phosphate 1-6%
Manganese nitrate 1-12%
Nickelous carbonate 1-10%
Sodium fluoride 1-6%
M-nitrobenzene sodium sulfonate 1-5%
QYL-30 1-6%
Water surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611087598.8A CN106757279A (en) | 2016-12-01 | 2016-12-01 | Steel wire drawing electrolytic phosphating liquid and production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611087598.8A CN106757279A (en) | 2016-12-01 | 2016-12-01 | Steel wire drawing electrolytic phosphating liquid and production method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106757279A true CN106757279A (en) | 2017-05-31 |
Family
ID=58914029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611087598.8A Pending CN106757279A (en) | 2016-12-01 | 2016-12-01 | Steel wire drawing electrolytic phosphating liquid and production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106757279A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107419317A (en) * | 2017-07-04 | 2017-12-01 | 马鞍山起劲磁塑科技有限公司 | A kind of method for lifting magnechuck bottom plate wearability |
| CN107723779A (en) * | 2017-10-31 | 2018-02-23 | 浙江亦宸五金有限公司 | A kind of normal temperature electrolytic phosphating drawing integrated production method |
| CN108165969A (en) * | 2017-12-26 | 2018-06-15 | 贵州钢绳股份有限公司 | A kind of preparation method of steel wire room temperature electrolytic phosphating liquid |
| CN108505099A (en) * | 2018-04-20 | 2018-09-07 | 安徽省康宇水电机械成套设备有限公司 | A kind of vehicle bridge lower thrust rod bearing anticorrosion treatment technology |
| CN108672706A (en) * | 2018-05-11 | 2018-10-19 | 娄底市格林新材料科技有限公司 | A kind of preparation process of stainless steel fibre micro mist |
| CN109853023A (en) * | 2019-03-26 | 2019-06-07 | 华南理工大学 | A kind of zinc system anti-corrosion electrolytic phosphating liquid and preparation method thereof |
| CN109898123A (en) * | 2019-03-11 | 2019-06-18 | 山东凤阳佰乐舒家居有限公司 | A kind of steel wire drawing electrolytic phosphating liquid and preparation method thereof |
| CN110125209A (en) * | 2018-02-08 | 2019-08-16 | 惠州市秋叶原铜业发展有限公司 | A kind of production method making copper wire |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967666A (en) * | 2010-11-19 | 2011-02-09 | 江苏巨力钢绳有限公司 | Electrolytic phosphorization pool for electrolytic phosphorization of steel wire |
| CN102061503A (en) * | 2010-11-19 | 2011-05-18 | 江苏巨力钢绳有限公司 | Electrolytic phosphating method for steel wires |
| CN102560464A (en) * | 2011-12-30 | 2012-07-11 | 大连三达奥克化学股份有限公司 | Normal-temperature phosphatizing agent used before pulling of steel pipe and production method thereof |
| CN102586838A (en) * | 2012-03-26 | 2012-07-18 | 南通高罕金属设备科技有限公司 | On-line low temperature electrolysis phosphating method for steel wires |
| CN103103514A (en) * | 2013-01-30 | 2013-05-15 | 合肥佳和表面科技有限公司 | Spraying type iron phosphating comprehensive treatment agent prior to coating of spheroidal graphite casting and preparation method of treatment agent |
| CN104711563A (en) * | 2013-12-14 | 2015-06-17 | 三达奥克化学股份有限公司 | Composite phosphatizing agent with degreasing rust-removing phosphatization functions, and production method thereof |
| CN104962893A (en) * | 2015-06-30 | 2015-10-07 | 大连碧城环保科技股份有限公司 | Environmental phosphating solution |
| CN104962898A (en) * | 2015-06-30 | 2015-10-07 | 大连碧城环保科技股份有限公司 | Manganese-bearing phosphating solution additive and using method thereof |
-
2016
- 2016-12-01 CN CN201611087598.8A patent/CN106757279A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967666A (en) * | 2010-11-19 | 2011-02-09 | 江苏巨力钢绳有限公司 | Electrolytic phosphorization pool for electrolytic phosphorization of steel wire |
| CN102061503A (en) * | 2010-11-19 | 2011-05-18 | 江苏巨力钢绳有限公司 | Electrolytic phosphating method for steel wires |
| CN102560464A (en) * | 2011-12-30 | 2012-07-11 | 大连三达奥克化学股份有限公司 | Normal-temperature phosphatizing agent used before pulling of steel pipe and production method thereof |
| CN102586838A (en) * | 2012-03-26 | 2012-07-18 | 南通高罕金属设备科技有限公司 | On-line low temperature electrolysis phosphating method for steel wires |
| CN103103514A (en) * | 2013-01-30 | 2013-05-15 | 合肥佳和表面科技有限公司 | Spraying type iron phosphating comprehensive treatment agent prior to coating of spheroidal graphite casting and preparation method of treatment agent |
| CN104711563A (en) * | 2013-12-14 | 2015-06-17 | 三达奥克化学股份有限公司 | Composite phosphatizing agent with degreasing rust-removing phosphatization functions, and production method thereof |
| CN104962893A (en) * | 2015-06-30 | 2015-10-07 | 大连碧城环保科技股份有限公司 | Environmental phosphating solution |
| CN104962898A (en) * | 2015-06-30 | 2015-10-07 | 大连碧城环保科技股份有限公司 | Manganese-bearing phosphating solution additive and using method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107419317A (en) * | 2017-07-04 | 2017-12-01 | 马鞍山起劲磁塑科技有限公司 | A kind of method for lifting magnechuck bottom plate wearability |
| CN107723779A (en) * | 2017-10-31 | 2018-02-23 | 浙江亦宸五金有限公司 | A kind of normal temperature electrolytic phosphating drawing integrated production method |
| CN108165969A (en) * | 2017-12-26 | 2018-06-15 | 贵州钢绳股份有限公司 | A kind of preparation method of steel wire room temperature electrolytic phosphating liquid |
| CN110125209A (en) * | 2018-02-08 | 2019-08-16 | 惠州市秋叶原铜业发展有限公司 | A kind of production method making copper wire |
| CN108505099A (en) * | 2018-04-20 | 2018-09-07 | 安徽省康宇水电机械成套设备有限公司 | A kind of vehicle bridge lower thrust rod bearing anticorrosion treatment technology |
| CN108672706A (en) * | 2018-05-11 | 2018-10-19 | 娄底市格林新材料科技有限公司 | A kind of preparation process of stainless steel fibre micro mist |
| CN108672706B (en) * | 2018-05-11 | 2021-11-26 | 娄底市格林新材料科技有限公司 | Preparation process of stainless steel fiber micro powder |
| CN109898123A (en) * | 2019-03-11 | 2019-06-18 | 山东凤阳佰乐舒家居有限公司 | A kind of steel wire drawing electrolytic phosphating liquid and preparation method thereof |
| CN109853023A (en) * | 2019-03-26 | 2019-06-07 | 华南理工大学 | A kind of zinc system anti-corrosion electrolytic phosphating liquid and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106757279A (en) | Steel wire drawing electrolytic phosphating liquid and production method | |
| CN103184446B (en) | Forming solution for environment-friendly non-phosphate ceramic film and preparation method and application thereof | |
| CN105543826B (en) | A kind of normal-temperature phosphorizing liquid, preparation method and phosphating process for forming high anti-corrosion phosphating coat | |
| CN101935863B (en) | Aluminum alloy electrolytic polishing solution, preparation method and aluminum alloy electrolytic polishing method | |
| CN102443825B (en) | High-concentration chromium sulfate-ammonium fluoride trivalent chromium electroplating solution and preparation method thereof | |
| CN101792917A (en) | Preparation method and electroplating method of normal-temperature environment-friendly sulfate trivalent chromium electroplating liquid | |
| CN103484847B (en) | A kind of Phosphating Solution and method for bonderizing | |
| CN103469267B (en) | A kind of processing method of surface-treated electro-deposited copper foil and the Copper Foil of process thereof | |
| CN103668030A (en) | Improved hot galvanizing method of iron handicraft or furniture | |
| CN103276386A (en) | Chromium-free environment-friendly passivator for brass cartridge case of cartridge and preparation method | |
| CN104485459A (en) | Method for preparing copper foil for lithium ion battery through low eutectic type ionic liquid electro-deposition | |
| CN103695881B (en) | Room temperature is without slag fast bonderizing liquor and preparation method thereof | |
| CN109778166A (en) | The phosphorization treatment process of phosphating solution, the preparation method of phosphating solution and metal wire rod | |
| CN104073796A (en) | Metal plating passivation solution and preparation method thereof | |
| CN102817059B (en) | Novel hole sealing tank liquid for aluminum alloy oxidation section and sealing method by using the same | |
| CN105483681B (en) | A kind of preparation method of zinc system metal treatment fluid | |
| CN103305855B (en) | Energy-saving and environment-friendly aluminum alloy anode oxide film stripping process | |
| CN106479504A (en) | A kind of low-viscosity etching solution for ITO Ag ITO conductive film and preparation method thereof | |
| CN102808168A (en) | Method for carrying out room-temperature chemical nickel plating on modified magnesium-based surface with micro-arc oxidation porous membrane | |
| CN104962898B (en) | A kind of manganese-series phosphorized solution additive and its application method | |
| CN104313562B (en) | A kind of normal-temperature phosphorizing liquid and preparation method thereof | |
| CN103866372A (en) | Electrochemical coloring solution for stainless steel and coloring method | |
| CN104342683A (en) | Magnesium alloy work-piece surface anti-corrosion conversion film treatment process | |
| CN103469189A (en) | Metal phosphatization liquid and preparation method thereof | |
| CN103526218B (en) | A kind of titanium alloy anodic oxidation activation moves back the ageing method of the two-in-one solution of film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |