CN106757094B - Aluminum mobile phone battery cover whitens agent and preparation method thereof - Google Patents

Aluminum mobile phone battery cover whitens agent and preparation method thereof Download PDF

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Publication number
CN106757094B
CN106757094B CN201611117887.8A CN201611117887A CN106757094B CN 106757094 B CN106757094 B CN 106757094B CN 201611117887 A CN201611117887 A CN 201611117887A CN 106757094 B CN106757094 B CN 106757094B
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Prior art keywords
sodium
agent
mobile phone
whitens
battery cover
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CN201611117887.8A
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CN106757094A (en
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刘平
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Jiangxi Ruisibo New Material Co ltd
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JIANGXI RUISIBO CHEMICAL ENGINEERING Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/24Cleaning or pickling metallic material with solutions or molten salts with neutral solutions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides a kind of aluminum mobile phone battery cover and whitens agent and preparation method thereof, it is prepared as follows: at normal temperature, first successively by above-mentioned solid material: sodium metasilicate, sodium gluconate, Citric Acid Mono sodium, sodium benzoate, 1-hydroxy ethylidene-1,1-diphosphonic acid sodium raw materials stirring and dissolving are in deionized water, then liquid charging stock triethanolamine, still amphoteric surfactant are added and stir evenly to obtain transparency liquid.It can carry out die casting aluminium material mobile phone battery cover to clean white and have good cleaning effect, raw materials used product formula is environment-friendly type raw material, without environment controlled substance composition, properties of product performance is mild, environment-protecting and non-poisonous, and manufacture craft is simple, it is at low cost, odorlessness, effect is good, effluent no pollution to the environment.

Description

Aluminum mobile phone battery cover whitens agent and preparation method thereof
Technical field:
The invention belongs to industrial cleaning agent field in terms of fine chemistry industry, it is related to a kind of aluminum product and whitens agent and preparation method, especially It is related to a kind of aluminum mobile phone battery cover and whitens agent and preparation method thereof.
Background technique:
One kind of agent category cleaning agent is whitened, there are many product category type of cleaning agent currently on the market, daily life Cleaning agent is even more innumerable, but is applied to the cleaning agent in terms of aluminium and its alloy or cry and whitens agent and few, to be applied to It is then less that the cleaning that aluminum mobile phone battery cover whitens agent whitens agent.Such as be applied to stainless steel punching press greasy dirt, foreign white copper punching press greasy dirt, Cleaning of automobile oil pipe ROLLING OIL etc. etc. is simultaneously few.It is whitened using the metal of existing cleaning agent either aluminium alloy etc. When agent whitens precision metallic part, bright cleanliness is insufficient on aluminum metal surface after cleaning, and easily jaundice;And to high silicon die casting After the whitening of aluminium, often appear in high silicon die casting aluminium surface occur blacking, casting skin, graying phenomenon.
With the development of the fining of cleaning agent industry, how a kind of Al-alloy metal cleaning agent is provided, it can be to aluminium And its metal product such as die casting aluminium material mobile phone battery cover clean it is white, and to cleaning white effect might as well, and to aluminum It is bright clean, non-yellowing that battery of mobile phone cover piece carries out cleaning rear surface.And it whitens rear high silicon die casting aluminium surface and will not black and graying.
Summary of the invention:
The present invention provides a kind of aluminum mobile phone battery cover and whitens agent and preparation method thereof, can be to die casting aluminium material mobile phone electricity Chi Gai is carried out cleaning white and is had good cleaning effect, and raw materials used product formula is environment-friendly type raw material, no controlled environment Matter Composition, properties of product performance is mild, environment-protecting and non-poisonous, and manufacture craft is simple, at low cost, odorlessness, and effect is good, effluent pair Environmental nonpollution.
The present invention discloses a kind of aluminum mobile phone battery cover and whitens agent, including following mass ratio group is grouped as:
Sodium metasilicate 15-18%, sodium gluconate 1.5-2.5%,
1-hydroxy ethylidene-1,1-diphosphonic acid sodium 2- 4%, sodium benzoate 1.2-1.6%,
Citric Acid Mono sodium 4-6%, triethanolamine 1.0- 3.0%,
Still amphoteric surfactant 4-6%, deionized water are mended to 100%.
Whitening agent described in further is grouped as by following mass ratio group:
Sodium metasilicate 15%, sodium gluconate 2%,
1-hydroxy ethylidene-1,1-diphosphonic acid sodium 3%, sodium benzoate 1.5%,
Citric Acid Mono sodium 5%, triethanolamine 2.0%,
Still amphoteric surfactant 5%, deionized water are mended to 100%.
It is preferred that the still amphoteric surfactant is FC-39 or FC-40.
Aluminum mobile phone battery cover described in another object of the present invention whitens the preparation method of agent, is to make as follows It is standby: at normal temperature, first successively by above-mentioned solid material: sodium metasilicate, sodium gluconate, Citric Acid Mono sodium, sodium benzoate, hydroxyl Ethylene-diphosphonic acid sodium raw materials stirring and dissolving is in deionized water, then by liquid charging stock triethanolamine, still amphoteric surfactant It is added and stirs evenly to obtain transparency liquid.
Stability: observation solution delamination after composition prepared by the present invention is placed 4-6 hour, stabilize to it is not stratified, Not muddy, shakiness is set to layering or muddiness.
The present invention is had a characteristic that using said components
First is that product of the present invention is a kind of for aluminium and its alloy, including the silumin after sial die casting and sandblasting The casting skin scale removal on surface, the cleaning of remover, oil removing, whitens comprehensive treatment agent at oil removing, overcomes traditional oil removing, whitens and be divided to two Kind cleaning agent is cleaned separately the complicated technology disadvantage of processing, is before die casting aluminium mobile phone battery cover sprays pre-treatment, plating on aluminium alloy Inorganic agent, product can obtain the shiny appearance of excellent combination power after cleaning;
Second is that product of the present invention is that excellent alkalescent oil removing whitens agent, perfect traditional nitric acid, hydrofluoric acid strong acid can be substituted Property whitening technique, no acid gas generates, discharges without spent acid, do not injure to human body, to environment, to cleaning equipment, to cleaning material Risk, and reach the without phosphorus discharge of waste water, be conducive to environmental protection;
Third is that this product and aqueous solution are quite stable, and it is nontoxic, it is non-stimulated to skin, it is corrosion-free to silumin, Nigrescence phenomenon, and recyclable Reusability are not had, it is energy saving, it is low using overall cost;
Fourth is that being formulated raw materials used through this product is environment-friendly type raw material, and no environment controlled substance composition, properties of product Can be mild, it is environment-protecting and non-poisonous;
Fifth is that this product can in lower temperature conditions, 40 degree or less and it is lower use concentration, 5% cleaning agent concentration of aqueous solution, Cleaning can reach good quick deoiling and whiten effect, saved the cleaning energy, improved cleaning efficiency, reduce cleaning at This.
Product of the present invention is water-soluble product, is using deionized water as solvent, odorlessness does not burn, and overcomes tradition The flammability cleaned with solvent based product, smell weight, and the disadvantage that use cost is high;And product water-soluble is good, dissolution is fast, bubble Foam is low, antistatic, and energy effective protection die casting aluminium material mobile phone battery cover surface is not corroded while cleaning whitens.
Product of the present invention without induced by alkyl hydroxybenzene surfactant, without chromate, nitrite, phosphate etc. to human body, It is that ideal environment-friendly type whitens to the poisonous and hazardous controlled substance composition of environment, product property nontoxic to the human body, no pollution to the environment Agent.
Product of the present invention is detected through Institute of Analysis, Jiangxi Province, and all technical reaches requirement, and every technology refers to Mark such as the following table 1.
Table 1
Illustrate: 1, the corrosivity (40 DEG C ± 2 DEG C) of product of the present invention, 45 ﹟ steel discs, 0 grade of 4h,
0 grade of duralumin LY12,2h,
0 grade of brass H62,2h;
2, product of the present invention stability is good, and the holding time is long, whitens high-efficient;Product of the present invention refers to through detecting items Mark reaches requirement.
Specific embodiment: below with reference to embodiment, the present invention is described in further detail.
Embodiment: such as the following table 1
Illustrate: 1, above-mentioned each component of the invention is commercially available.
The various embodiments described above of the invention can be prepared by following methods:: it is at normal temperature, first successively that above-mentioned solid is former Material: sodium metasilicate, sodium gluconate, Citric Acid Mono sodium, sodium benzoate, 1-hydroxy ethylidene-1,1-diphosphonic acid sodium raw materials stirring and dissolving in without from In sub- water, then liquid charging stock triethanolamine, still amphoteric surfactant are added and stir evenly to obtain transparency liquid.

Claims (4)

1. a kind of aluminum mobile phone battery cover whitens agent, including following mass ratio group is grouped as:
Sodium metasilicate 15-18%, sodium gluconate 1.5-2.5%,
1-hydroxy ethylidene-1,1-diphosphonic acid sodium 2- 4%, sodium benzoate 1.2-1.6%,
Citric Acid Mono sodium 4-6%, triethanolamine 1.0- 3.0%,
Still amphoteric surfactant 4-6%, deionized water are mended to 100%.
2. aluminum mobile phone battery cover according to claim 1 whitens agent, it is characterized in that being grouped as by following mass ratio group:
Sodium metasilicate 15%, sodium gluconate 2%,
1-hydroxy ethylidene-1,1-diphosphonic acid sodium 3%, sodium benzoate 1.5%,
Citric Acid Mono sodium 5%, triethanolamine 2.0%,
Still amphoteric surfactant 5%, deionized water are mended to 100%.
3. aluminum mobile phone battery cover according to claim 1 whitens agent, it is characterized in that the still amphoteric surfactant For FC-39 or FC-40.
4. a kind of aluminum mobile phone battery cover according to claim 1 or 2 whitens the preparation method of agent, it is characterized in that by as follows Method preparation: at normal temperature, first successively by solid material: sodium metasilicate, sodium gluconate, Citric Acid Mono sodium, sodium benzoate, hydroxyl Base ethylene-diphosphonic acid sodium stirring and dissolving adds in deionized water, then by liquid charging stock triethanolamine, still amphoteric surfactant Enter and stirs evenly to obtain transparency liquid.
CN201611117887.8A 2016-12-07 2016-12-07 Aluminum mobile phone battery cover whitens agent and preparation method thereof Active CN106757094B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611117887.8A CN106757094B (en) 2016-12-07 2016-12-07 Aluminum mobile phone battery cover whitens agent and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201611117887.8A CN106757094B (en) 2016-12-07 2016-12-07 Aluminum mobile phone battery cover whitens agent and preparation method thereof

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CN106757094B true CN106757094B (en) 2019-08-09

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Publication number Priority date Publication date Assignee Title
CN107254682A (en) * 2017-06-23 2017-10-17 深圳市威通科技有限公司 Descaling agent
CN109440123A (en) * 2018-11-30 2019-03-08 佛山市海明威生态科技股份有限公司 A kind of die casting aluminium smokelessly whitens agent and its preparation
CN114875418B (en) * 2022-04-21 2024-06-25 深圳市新骏翔科技有限公司 Neutral aluminum bleaching agent and preparation method thereof

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CN102994271B (en) * 2012-11-15 2015-08-19 尹艺颖 A kind of airplane skin scavenger specially and manufacture method thereof
WO2015055234A1 (en) * 2013-10-15 2015-04-23 Ecolab Inc. Use of an active solid for cleaning and inactivating unconventional infectious agents on surfaces
CN105002542A (en) * 2015-07-20 2015-10-28 东莞市镁汝澳金属表面处理材料有限公司 Aluminum or aluminum alloy surface nanoscale treatment process
CN105369273A (en) * 2015-10-15 2016-03-02 当涂县维思共创工业产品设计有限公司 Aluminum profile surface cleaning and polishing agent
CN105483726A (en) * 2015-11-30 2016-04-13 武汉奥克特种化学有限公司 Efficient low-foam normal-temperature phosphorous-free oil removing liquid
CN105908204B (en) * 2016-06-23 2018-10-26 十堰恒融实业有限公司 A kind of aluminum fuel tank surface anticorrosive treatment technology

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Address after: 336000 No. 39, Chunfeng Road, Yichun Economic and Technological Development Zone, Jiangxi Province

Patentee after: Jiangxi Ruisibo New Material Co.,Ltd.

Address before: No. 585, Huancheng South Road, Yichun City, Jiangxi Province, 336000

Patentee before: JIANGXI RUISIBO CHEMICAL ENGINEERING Co.,Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Whitening agent for aluminum cell phone battery cover and its preparation method

Effective date of registration: 20230130

Granted publication date: 20190809

Pledgee: Yichun Branch of China Everbright Bank Co.,Ltd.

Pledgor: Jiangxi Ruisibo New Material Co.,Ltd.

Registration number: Y2023980031789

PC01 Cancellation of the registration of the contract for pledge of patent right
PC01 Cancellation of the registration of the contract for pledge of patent right

Granted publication date: 20190809

Pledgee: Yichun Branch of China Everbright Bank Co.,Ltd.

Pledgor: Jiangxi Ruisibo New Material Co.,Ltd.

Registration number: Y2023980031789