CN106756240B - A kind of tungstenic 3D printing titanium-based alloy material and preparation method thereof - Google Patents
A kind of tungstenic 3D printing titanium-based alloy material and preparation method thereof Download PDFInfo
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- CN106756240B CN106756240B CN201710068175.XA CN201710068175A CN106756240B CN 106756240 B CN106756240 B CN 106756240B CN 201710068175 A CN201710068175 A CN 201710068175A CN 106756240 B CN106756240 B CN 106756240B
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- 239000000956 alloy Substances 0.000 title claims abstract description 49
- 238000010146 3D printing Methods 0.000 title claims abstract description 40
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000010936 titanium Substances 0.000 title claims abstract description 36
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 56
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 26
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 17
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 17
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims abstract description 17
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010949 copper Substances 0.000 claims abstract description 13
- 229910052802 copper Inorganic materials 0.000 claims abstract description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 13
- 239000011733 molybdenum Substances 0.000 claims abstract description 13
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 13
- 239000010955 niobium Substances 0.000 claims abstract description 13
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 13
- 238000005551 mechanical alloying Methods 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 238000005245 sintering Methods 0.000 claims abstract 2
- 239000002245 particle Substances 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 4
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 claims description 2
- 239000003984 copper intrauterine device Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- RTAQQCXQSZGOHL-AKLPVKDBSA-N titanium-51 Chemical compound [51Ti] RTAQQCXQSZGOHL-AKLPVKDBSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims 1
- 239000011812 mixed powder Substances 0.000 abstract description 9
- 238000000265 homogenisation Methods 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 5
- 238000013461 design Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 6
- 229910001069 Ti alloy Inorganic materials 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 238000005275 alloying Methods 0.000 description 4
- 238000001311 chemical methods and process Methods 0.000 description 4
- 238000000713 high-energy ball milling Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- B22F1/0003—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
- C22C32/0052—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
- B22F2009/041—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by mechanical alloying, e.g. blending, milling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
Abstract
The invention discloses a kind of tungstenic 3D printing titanium-based alloy materials, contain tungsten carbide, nickel, niobium, vanadium, copper, molybdenum and titanium.Preparation method is：Metal powder is sufficiently mixed after carrying out composition design, alloy powder is obtained by mixed-powder sintering and alloy homogenization and then by mechanical alloying.The material of gained has the advantages that lightweight, high temperature hardness big, High-temperature-resandant andant wear-resistant function admirable and erosion-resisting through the finished product that 3D printing goes out.
Description
Technical field
The present invention relates to field of preparing metal powder, particularly a kind of tungstenic 3D printing titanium-based alloy material and its preparation
Method.
Background technology
The core of 3D printing technique is equipment and material.With the development of 3D printing technique, 3D printing equipment is ripe, but mesh
The preceding material category available for 3D printing is few, performance is unstable, becomes the bottleneck problem for restricting 3D printing technique development and application.
The metal powder material of prior powder metallurgy can't adapt to 3D printing technique completely, current existing metal powder type
Less, price is high, productionization extent is low.
Titanium alloy has small density, specific strength, specific stiffness height, corrosion resistance, mechanical behavior under high temperature, antifatigue and creep
The excellent comprehensive performances such as performance is good, are a kind of structural materials that is novel, having very much development potentiality and application prospect, are navigated in aviation
My god, the fields such as chemical industry, nuclear industry, sports equipment and medical instrument are widely used.But due to titanium or titanium alloy
Strain hardening exponent is low (being approximately 0.15), anti-plasticity shear deformation ability and wears no resistance, thus limits its product in height
Use under the conditions of mild corrosive wear.
Because in consideration of it, special propose the invention.
Invention content
The object of the present invention is to provide a kind of wear-resistant, high temperature resistants, erosion-resisting titanium alloy and preparation method thereof.
To achieve these goals, in a first aspect, a kind of tungstenic 3D printing titanium-based alloy material provided by the invention,
It is characterized in that：The titanium-based alloy material is contained with mass percent note：
Tungsten carbide：15~30%
Nickel：2~5%
Niobium：3~8%
Vanadium：1~3%
Copper：5~8%
Molybdenum：5~10%, surplus is titanium and inevitable impurity.
Preferably, the mass percent of each component is in the titanium-based alloy material：Tungsten carbide 15%, nickel 5%, niobium 8%,
Vanadium 3%, copper 8%, molybdenum 10%, titanium 51%.
Preferably, the mass percent of each component is in the titanium-based alloy material：Tungsten carbide 20%, nickel 4%, niobium 6%,
Vanadium 2%, copper 7%, molybdenum 8%, titanium 53%.
Preferably, the mass percent of each component is in the titanium-based alloy material：Tungsten carbide 25%, nickel 3%, niobium 4%,
Vanadium 2%, copper 6%, molybdenum 6%, titanium 54%.
Preferably, the mass percent of each component is in the titanium-based alloy material：Tungsten carbide 30%, nickel 2%, niobium 3%,
Vanadium 1%, copper 5%, molybdenum 5%, titanium 54%.
Preferably, the titanium-based alloy material is alloy powder particle.
Preferably, the alloy powder particle is spherical morphology, and grain size is 30~150 μm, oxygen content for 0.07~
0.12%.
Second aspect, the present invention provide a kind of preparation method of tungstenic 3D printing titanium-based alloy material, successively according to
Lower step carries out：
(1) metal powder is sufficiently mixed；The metal powder contains by mass percentage：
Tungsten carbide：15~30%
Nickel：2~5%
Niobium：3~8%
Vanadium：1~3%
Copper：5~8%
Molybdenum：5~10%, surplus is titanium and inevitable impurity；
(2) the powder sintered and alloy obtained after mixing is homogenized；And
(3) alloy powder is obtained by mechanical alloying.
The third aspect, the present invention provide a kind of 3D printing part, which is by the titanium-base alloy described in first aspect
Material is made through 3D printing.
It is provided by the invention, it has the advantages that：Using tungstenic 3D printing titanium-base alloy provided by the present invention
Dusty material, the design feature of the existing titanium alloy of obtained parts " lightweight ", and with high temperature hardness is big, high temperature resistance
The advantages of polishing machine is excellent, breaching titanium alloy can only be as the limitation that structural material uses.
Description of the drawings
Fig. 1 is a kind of flow chart of the preparation method of tungstenic 3D printing titanium-based alloy material provided by the present invention.
Specific embodiment
In order to which those skilled in the art is made to more fully understand the present invention program, with reference to the accompanying drawings and detailed description
The present invention is described in further detail.
What all embodiments used in the present invention program is all 280 metals of SLM of German SLM Solution companies production
3D printing equipment.
Embodiment one
It please refers to Fig.1, takes 1.5 kilograms of tungsten-carbide powder, 0.5 kilogram of nickel by powder, 0.8 kilogram of niobium powder, vanadium powder 0.3 thousand
Gram, 0.8 kilogram of copper powders, 1.0 kilograms of molybdenum powder, 5.1 kilograms of titanium powder, it is spherical morphology to take powder particle, and grain size is
30~150 μm, oxygen content is 0.07~0.12%.Taken powder is placed in mixed powder machine and mix 10 minutes to uniformly mixed.
Mixed-powder is sintered and carries out alloy Homogenization Treatments.
Product obtains powder product by mechanical alloying.Mechanical alloying is one passes through powder by high-energy ball milling
By deformation, cold welding, broken repeatedly, so as to reach the complicated physical and chemical process of atomic level alloying between element.
Alloy powder particle is spherical morphology, and grain size is 30~150 μm, and oxygen content is 0.07~0.12%.
3D printing is carried out with the finished powder obtained, print parameters are：Build rate：40cm3/ h, laser scanning speed
Degree：10m/s, lift height：30μm.
Density, hardness and the wearability of 3D printing parts are shown in Table 1.
Embodiment two
Take 2.0 kilograms of tungsten-carbide powder, 0.4 kilogram of nickel by powder, 0.6 kilogram of niobium powder, 0.2 kilogram of vanadium powder, copper powders
0.7 kilogram, 0.8 kilogram of molybdenum powder, 5.3 kilograms of titanium powder, it is spherical morphology to take powder particle, and grain size is 30~150 μm,
Oxygen content is 0.07~0.12%.Taken powder is placed in mixed powder machine and mix 10 minutes to uniformly mixed.
Mixed-powder is sintered and carries out alloy Homogenization Treatments.
Product obtains powder product by mechanical alloying.Mechanical alloying is one passes through powder by high-energy ball milling
By deformation, cold welding, broken repeatedly, so as to reach the complicated physical and chemical process of atomic level alloying between element.
Alloy powder particle is spherical morphology, and grain size is 30~150 μm, and oxygen content is 0.07~0.12%.
3D printing is carried out with the finished powder obtained, print parameters are：Build rate：40cm3/ h, laser scanning speed
Degree：10m/s, lift height：30μm.
Density, hardness and the wearability of 3D printing parts are shown in Table 1.
Embodiment three
Take 2.5 kilograms of tungsten-carbide powder, 0.3 kilogram of nickel by powder, 0.4 kilogram of niobium powder, 0.2 kilogram of vanadium powder, copper powders
0.6 kilogram, 0.6 kilogram of molybdenum powder, 5.4 kilograms of titanium powder, it is spherical morphology to take powder particle, and grain size is 30~150 μm,
Oxygen content is 0.07~0.12%.Taken powder is placed in mixed powder machine and mix 10 minutes to uniformly mixed.
Mixed-powder is sintered and carries out alloy Homogenization Treatments.
Product obtains powder product by mechanical alloying.Mechanical alloying is one passes through powder by high-energy ball milling
By deformation, cold welding, broken repeatedly, so as to reach the complicated physical and chemical process of atomic level alloying between element.
Alloy powder particle is spherical morphology, and grain size is 30~150 μm, and oxygen content is 0.07~0.12%.
3D printing is carried out with the finished powder obtained, print parameters are：Build rate：40cm3/ h, laser scanning speed
Degree：10m/s, lift height：30μm.
Density, hardness and the wearability of 3D printing parts are shown in Table 1.
Example IV
Take 3.0 kilograms of tungsten-carbide powder, 0.2 kilogram of nickel by powder, 0.3 kilogram of niobium powder, 0.1 kilogram of vanadium powder, copper powders
0.5 kilogram, 0.5 kilogram of molybdenum powder, 5.4 kilograms of titanium powder, it is spherical morphology to take powder particle, and grain size is 30~150 μm,
Oxygen content is 0.07~0.12%.Taken powder is placed in mixed powder machine and mix 10 minutes to uniformly mixed.
Mixed-powder is sintered and carries out alloy Homogenization Treatments.
Product obtains powder product by mechanical alloying.Mechanical alloying is one passes through powder by high-energy ball milling
By deformation, cold welding, broken repeatedly, so as to reach the complicated physical and chemical process of atomic level alloying between element.
Alloy powder particle is spherical morphology, and grain size is 30~150 μm, and oxygen content is 0.07~0.12%.
3D printing is carried out with the finished powder obtained, print parameters are：Build rate：40cm3/ h, laser scanning speed
Degree：10m/s, lift height：30μm.
Density, hardness and the wearability of 3D printing parts are shown in Table 1, and the number " 1~4 " in table is corresponding in turn to above-mentioned implementation
The 3D printing parts obtained in example one to example IV.
The density of material hardness relative wear resistance table of comparisons in 1 four kinds of embodiments of table
Its Midst density is measured using drainage, first measures mass M with balance；Volume V is measured with graduated cylinder；With formula P=M/V
Calculate density.
For beaten hardness using HR -150A Rockwell hardness machines, load 150kg takes 3D printing parts beat firmly at 5 points
Degree finally obtains the average Rockwell hardness number of the parts.
Wear test carries out wear test using MLS-225 type wet type rubber wheels grain-abrasion testing machine.
Take six 57 × 25 × 5mm abrasion styles in 3D printing parts, during wear test, experiment parameter is as follows：Rubber
Rubber tire rotating speed：240 revs/min, rubber wheel diameter：178mm, rubber wheel hardness：60 (Shao Er hardness), load：10Kg, during abrasion
Between：250s, rubber wheel revolution：About 1000 turns, abrasive material：The quartz sand of 40~70 mesh.The weightlessness of the wear-resisting property abrasion of material
It measures to weigh.It is forward and backward testing, test specimen is put into the beaker for filling acetone soln, 3~5 are cleaned in ultrasonic washing instrument
Minute, during experiment with Q235 steel as a comparison, the ratio between contrast piece weight loss and measuring piece weight loss are as the relatively resistance to of the formula
Mill property.Relative wear resistance
As it can be seen from table 1 the parts HRC printed>48, possess good hardness；Relative wear resistance is Q235 steel
14 times or more, in addition, inventor is also surprising that in example IV, the relative wear resistance of 3D printing parts is up to
31 times.Although the density of material is slightly larger than pure titanium (4.5g/cm simultaneously3), but much smaller than steel (7.85g/cm3)；Therefore, this hair
Bright provided tungstenic 3D printing titanium-based alloy material has reached wear-resisting either the parts lightweight printed
Damage, the requirement of erosion-resisting functionalization.
A kind of tungstenic 3D printing provided by the present invention has been carried out in detail with titanium-based alloy material and preparation method thereof above
It is thin to introduce.Specific case used herein is expounded the principle of the present invention and embodiment, and above example is said
It is bright to be merely used to help understand the core idea of the present invention.It should be pointed out that for those skilled in the art,
Without departing from the principle of the present invention, can also to the present invention some improvement and modification can also be carried out, these improvement and modification
It falls into the protection domain of the claims in the present invention.
Claims (7)
1. a kind of tungstenic 3D printing titanium-based alloy material, it is characterised in that：The titanium-based alloy material is alloy powder particle,
And the alloy powder particle is spherical morphology, grain size is 30~150 μm, and oxygen content is 0.07~0.12%, and with quality hundred
Divide and contain than meter：
Tungsten carbide：15~30%
Nickel：2~5%
Niobium：3~8%
Vanadium：1~3%
Copper：5~8%
Molybdenum：5~10%, surplus is titanium and inevitable impurity；
And the alloy powder particle is by being homogenized raw material powder mixed sintering, alloy and carrying out mechanical alloying powder
It obtains.
2. a kind of tungstenic 3D printing titanium-based alloy material according to claim 1, it is characterised in that：The titanium-base alloy
The mass percent of each component is in material：Tungsten carbide 15%, nickel 5%, niobium 8%, vanadium 3%, copper 8%, molybdenum 10%, titanium 51%.
3. a kind of tungstenic 3D printing titanium-based alloy material according to claim 1, it is characterised in that：The titanium-base alloy
The mass percent of each component is in material：Tungsten carbide 20%, nickel 4%, niobium 6%, vanadium 2%, copper 7%, molybdenum 8%, titanium 53%.
4. a kind of tungstenic 3D printing titanium-based alloy material according to claim 1, it is characterised in that：The titanium-base alloy
The mass percent of each component is in material：Tungsten carbide 25%, nickel 3%, niobium 4%, vanadium 2%, copper 6%, molybdenum 6%, titanium 54%.
5. a kind of tungstenic 3D printing titanium-based alloy material according to claim 1, it is characterised in that：The titanium-base alloy
The mass percent of each component is in material：Tungsten carbide 30%, nickel 2%, niobium 3%, vanadium 1%, copper 5%, molybdenum 5%, titanium 54%.
6. a kind of preparation method of tungstenic 3D printing titanium-based alloy material, which is characterized in that follow the steps below successively：
(1) metal powder is sufficiently mixed；The metal powder contains by mass percentage：
Tungsten carbide：15~30%
Nickel：2~5%
Niobium：3~8%
Vanadium：1~3%
Copper：5~8%
Molybdenum：5~10%, surplus is titanium and inevitable impurity；
(2) the powder sintered and alloy obtained after mixing is homogenized；And
(3) alloy powder is obtained by mechanical alloying.
7. a kind of 3D printing part, which is characterized in that using any titanium-based alloy materials of claim 1-5 through 3D printing
It is made.
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| CN109722582B (en) | 2017-10-31 | 2023-01-10 | 史密斯国际有限公司 | Metal matrix composite materials for additive manufacturing of downhole tools |
| CN108159488B (en) * | 2018-01-12 | 2020-08-07 | 杭州电子科技大学 | Porous titanium-magnesium alloy artificial bone capable of promoting bone growth and preparation method thereof |
| EP3758866A4 (en) * | 2018-06-08 | 2021-09-08 | Hewlett-Packard Development Company, L.P. | Powder bed materials |
| CN111235564A (en) * | 2018-11-29 | 2020-06-05 | 中国科学院金属研究所 | Method for designing components of high-temperature alloy special for additive manufacturing |
| CN110480008B (en) * | 2019-09-03 | 2021-10-15 | 北京工业大学 | Three-dimensional communicated tungsten-based composite material prepared by laser 3D printing and preparation method thereof |
| CN111155014B (en) * | 2020-02-08 | 2021-09-07 | 苏州轻金三维科技有限公司 | High-strength alloy for three-dimensional printing and preparation method thereof |
| CN111155015B (en) * | 2020-02-08 | 2021-06-25 | 苏州轻金三维科技有限公司 | High-plasticity light alloy for three-dimensional printing and preparation method thereof |
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| JPH02258948A (en) * | 1989-03-30 | 1990-10-19 | Tokyo Yogyo Co Ltd | Ceramic grain reinforced titanium composite material |
| US20040261912A1 (en) * | 2003-06-27 | 2004-12-30 | Wu Ming H. | Method for manufacturing superelastic beta titanium articles and the articles derived therefrom |
| CN105458256A (en) * | 2015-12-07 | 2016-04-06 | 株洲西迪硬质合金科技股份有限公司 | Metal-based composite material and material additive manufacturing method thereof |
| CN105483439B (en) * | 2015-12-23 | 2017-03-29 | 成都新柯力化工科技有限公司 | A kind of high temperature resistant titanium alloy material for 3D printing and preparation method thereof |
| CN105583401B (en) * | 2015-12-25 | 2018-11-02 | 华中科技大学 | A kind of method preparing the composite powder for 3D printing, product and application |
| CN105506378A (en) * | 2016-02-23 | 2016-04-20 | 桐乡市搏腾贸易有限公司 | Tungsten carbide reinforced titanium-based composite material for mechanical use and preparation method of tungsten carbide reinforced titanium-based composite material for mechanical use |
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