CN106755639A - A kind of leather gloss agent - Google Patents

A kind of leather gloss agent Download PDF

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Publication number
CN106755639A
CN106755639A CN201611083210.7A CN201611083210A CN106755639A CN 106755639 A CN106755639 A CN 106755639A CN 201611083210 A CN201611083210 A CN 201611083210A CN 106755639 A CN106755639 A CN 106755639A
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China
Prior art keywords
parts
leather
brightener
oil
water
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CN201611083210.7A
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Chinese (zh)
Inventor
谢林玲
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Guangxi University
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Guangxi University
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Priority to CN201611083210.7A priority Critical patent/CN106755639A/en
Publication of CN106755639A publication Critical patent/CN106755639A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/06Other polishing compositions
    • C09G1/08Other polishing compositions based on wax
    • C09G1/10Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
    • C09G1/12Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin mixtures of wax and silicon-containing polycondensates
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/06Other polishing compositions
    • C09G1/14Other polishing compositions based on non-waxy substances
    • C09G1/16Other polishing compositions based on non-waxy substances on natural or synthetic resins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

本发明公开了一种皮革光亮剂,包括油脂,脂肪族聚氨酯丙烯酸酯,水性聚氨酯,硅油,蛋白酶,月桂醇聚氧乙烯醚,十二酸,异氰酸酯,纳米活性炭,蒸馏水。形成有效保护膜,锁住油份水分,使皮革具有耐用耐磨性、抗氧化性,增加皮革柔软度、光泽度,减少异味和保持表面清洁度,增加皮革使用寿命的皮革光亮剂。The invention discloses a leather brightener, which comprises grease, aliphatic polyurethane acrylate, water-based polyurethane, silicone oil, protease, polyoxyethylene lauryl ether, dodecanoic acid, isocyanate, nano activated carbon and distilled water. It is a leather brightener that forms an effective protective film, locks oil and moisture, makes leather durable, wear-resistant, and oxidation-resistant, increases leather softness and gloss, reduces peculiar smell, maintains surface cleanliness, and prolongs the service life of leather.

Description

一种皮革光亮剂a leather brightener

技术领域technical field

本发明涉及光亮剂,具体涉及一种皮革光亮剂。The invention relates to a brightener, in particular to a leather brightener.

背景技术Background technique

皮革使用范围广泛,但打理困难,要保持皮革的耐用性和光泽度,需要光亮剂来养护。现有皮革光亮剂一般采用油脂为主要护理成分,然而无法形成有效保护膜,使得油脂挥发快,养护周期非常短,需要经常补充油脂使得护理繁复。同时皮革制品表面往往残留有加工皮革的工业制剂,这些制剂往往具有一定的刺激性气体气味,使得皮革适用性低,同时长时间放置的皮革含水量低,硬度大,容易发生碎裂,使得皮革寿命降低,适用性差。Leather has a wide range of uses, but it is difficult to take care of. To maintain the durability and gloss of the leather, brighteners are needed for maintenance. Existing leather brighteners generally use oil as the main care component, but cannot form an effective protective film, making the oil volatilize quickly, the maintenance cycle is very short, and oil needs to be replenished frequently to make the care complicated. At the same time, there are often residual industrial preparations for leather processing on the surface of leather products. These preparations often have a certain pungent gas odor, which makes the applicability of the leather low. Reduced lifespan and poor applicability.

发明内容Contents of the invention

本发明的目的在于提供一种能够使皮革制品具有良好耐用耐磨性,增加皮革柔软度、光泽度,减少异味和灰尘附着的皮革光亮剂,针对现有技术,提供一种皮革光亮剂。The object of the present invention is to provide a leather brightener that can make leather products have good durability and wear resistance, increase leather softness and gloss, reduce peculiar smell and dust adhesion, and provide a leather brightener in view of the prior art.

为实现上述目的,本发明采取以下技术方案:一种皮革光亮剂,其由质量份以下原料组成:油脂24~30份,脂肪族聚氨酯丙烯酸酯36~50份,水性聚氨酯3~6份,硅油3~8份,蛋白酶10~18份,月桂醇聚氧乙烯醚3~8份,十二酸1.5~5份,异氰酸酯0.8~7份,纳米活性炭0.8~3份,蒸馏水75~110份。In order to achieve the above object, the present invention adopts the following technical solutions: a leather brightener, which is composed of the following raw materials in parts by mass: 24 to 30 parts of oil, 36 to 50 parts of aliphatic polyurethane acrylate, 3 to 6 parts of water-based polyurethane, silicone oil 3 to 8 parts, 10 to 18 parts of protease, 3 to 8 parts of polyoxyethylene lauryl ether, 1.5 to 5 parts of dodecanoic acid, 0.8 to 7 parts of isocyanate, 0.8 to 3 parts of nano activated carbon, and 75 to 110 parts of distilled water.

其中,所述的油脂为巴西棕榈蜡、虫蜡、乳木果油的一种或几种。Wherein, the oil is one or more of carnauba wax, insect wax and shea butter.

本发明中的硅油增加光亮剂的抗氧化、绝缘能力,同时保持皮革一定的含水量,增加皮革的平滑柔软度,同时具有良好黏温性能,能保持光亮剂成膜稳定性。The silicone oil in the invention increases the oxidation resistance and insulating ability of the brightener, maintains a certain water content of the leather, increases the smoothness and softness of the leather, has good viscosity-temperature performance, and can maintain the film-forming stability of the brightener.

本发明中,纳米活性炭具有良好的吸附性,能有效去除光亮剂残留气味和皮革上工业成分气味、降低灰尘附着,增加皮革的适用性。In the present invention, the nano-activated carbon has good adsorption, can effectively remove the residual odor of the brightener and the industrial component odor on the leather, reduce the adhesion of dust, and increase the applicability of the leather.

本发明中,脂肪族聚氨酯丙烯酸酯、十二酸通过异氰酸酯与空气发生交联成膜,使皮革具有一定的抗氧化、耐磨损能力,同时加入油脂、硅油,使皮革保持一定水分油分,保持皮革的光亮度和使用寿命。In the present invention, aliphatic urethane acrylate and dodecanoic acid are cross-linked with air to form a film through isocyanate, so that the leather has certain oxidation resistance and wear resistance. The brightness and longevity of the leather.

本发明中,油脂经由月桂醇聚氧乙烯醚乳化,能改善光亮剂分散、渗透性能,使油脂能够深层的润化皮革,从而增加皮革的耐用性;同时对皮肤刺激性低,增加皮革适用性。In the present invention, the oil is emulsified by lauryl alcohol polyoxyethylene ether, which can improve the dispersion and penetration performance of the brightener, so that the oil can deeply lubricate the leather, thereby increasing the durability of the leather; at the same time, it is less irritating to the skin and increases the applicability of the leather. .

本发明的有益效果是:The beneficial effects of the present invention are:

1、本发明加入纳米活性炭,有效吸附和去除皮革表面残留刺激性气味,同时减少灰尘附着,保持皮革表面清洁度。1. The present invention adds nano-activated carbon to effectively absorb and remove residual irritating odors on the leather surface, while reducing dust adhesion and maintaining the cleanliness of the leather surface.

2、本发明加入硅油,提高抗氧化性、黏温性能、稳定性,同时增加皮革含水量、含油量,增加皮革的使用寿命和光亮度。2. Silicone oil is added in the present invention to improve oxidation resistance, viscosity-temperature performance, and stability, and at the same time increase the water content and oil content of the leather, and increase the service life and brightness of the leather.

3、本发明的脂肪族聚氨酯丙烯酸酯、十二酸通过异氰酸酯与空气发生交联成膜,保持皮革表面的光亮性、耐磨性、稳定性,使皮革具有良好的耐用性能。3. The aliphatic urethane acrylate and dodecanoic acid of the present invention form a film through cross-linking of isocyanate and air to maintain the brightness, wear resistance and stability of the leather surface, so that the leather has good durability.

4、本发明加入月桂醇聚氧乙烯醚,能够乳化油脂,降低油脂的分子大小易于渗透皮革深层,保持皮革整体的柔韧性、耐用性。4. The present invention adds polyoxyethylene lauryl ether, which can emulsify oil, reduce the molecular size of oil and easily penetrate into the deep layer of leather, and maintain the overall flexibility and durability of leather.

5、本发明加入蛋白酶,能够增加皮革柔软度。5. The present invention adds protease, which can increase the softness of leather.

具体实施方式detailed description

下面结合具体实施例,对本发明进一步的说明。The present invention will be further described below in conjunction with specific embodiments.

实施例1Example 1

一种皮革光亮剂,其由质量份以下原料组成:虫脂28份,脂肪族聚氨酯丙烯酸酯44份,水性聚氨酯5份,硅油5份,蛋白酶16份,月桂醇聚氧乙烯醚6份,十二酸3份,异氰酸酯5份,纳米活性炭2份,蒸馏水90份。A leather brightener, which is composed of the following raw materials in parts by mass: 28 parts of insect fat, 44 parts of aliphatic polyurethane acrylate, 5 parts of water-based polyurethane, 5 parts of silicone oil, 16 parts of protease, 6 parts of polyoxyethylene lauryl ether, ten parts 3 parts of diacid, 5 parts of isocyanate, 2 parts of nano activated carbon, 90 parts of distilled water.

实施例2Example 2

一种皮革光亮剂,其由质量份以下原料组成:巴西棕榈油16份,乳木果油10份,脂肪族聚氨酯丙烯酸酯48份,水性聚氨酯4份,硅油6份,蛋白酶12份,月桂醇聚氧乙烯醚4份,十二酸4份,异氰酸酯3份,纳米活性炭2.5份,蒸馏水100份。A leather brightener, which is composed of the following raw materials in parts by mass: 16 parts of carnauba oil, 10 parts of shea butter, 48 parts of aliphatic polyurethane acrylate, 4 parts of water-based polyurethane, 6 parts of silicone oil, 12 parts of protease, lauryl alcohol 4 parts of polyoxyethylene ether, 4 parts of dodecanoic acid, 3 parts of isocyanate, 2.5 parts of nano activated carbon, 100 parts of distilled water.

实施例3Example 3

一种皮革光亮剂,其由质量份以下原料组成:巴西棕榈油28份,脂肪族聚氨酯丙烯酸酯40份,水性聚氨酯6份,硅油8份,蛋白酶17份,月桂醇聚氧乙烯醚8份,十二酸2份,异氰酸酯6份,纳米活性炭2份,蒸馏水100份。A leather brightener, which consists of the following raw materials in parts by mass: 28 parts of carnauba oil, 40 parts of aliphatic polyurethane acrylate, 6 parts of water-based polyurethane, 8 parts of silicone oil, 17 parts of protease, 8 parts of polyoxyethylene lauryl ether, 2 parts of dodecanoic acid, 6 parts of isocyanate, 2 parts of nano activated carbon, 100 parts of distilled water.

Claims (2)

1.一种皮革光亮剂,其特征在于,其由质量份以下原料组成:油脂24~30份,脂肪族聚氨酯丙烯酸酯36~50份,水性聚氨酯3~6份,硅油3~8份,蛋白酶10~18份,月桂醇聚氧乙烯醚3~8份,十二酸1.5~5份,异氰酸酯0.8~7份,纳米活性炭0.8~3份,蒸馏水75~110份。1. A leather brightener, characterized in that it consists of the following raw materials in parts by mass: 24 to 30 parts of oil, 36 to 50 parts of aliphatic polyurethane acrylate, 3 to 6 parts of water-based polyurethane, 3 to 8 parts of silicone oil, protease 10-18 parts, 3-8 parts of polyoxyethylene lauryl ether, 1.5-5 parts of dodecanoic acid, 0.8-7 parts of isocyanate, 0.8-3 parts of nano activated carbon, 75-110 parts of distilled water. 2.根据权利要求1所述的一种皮革光亮剂,其特征在于,所述的油脂为巴西棕榈蜡、虫蜡、乳木果油的一种或几种。2. a kind of leather brightening agent according to claim 1, is characterized in that, described grease is one or more of carnauba wax, insect wax, shea butter.
CN201611083210.7A 2016-11-30 2016-11-30 A kind of leather gloss agent Pending CN106755639A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752973A (en) * 2016-11-30 2017-05-31 广西大学 A kind of turtle shell brightener
CN108624727A (en) * 2018-04-24 2018-10-09 安徽乐踏鞋业有限公司 Leather nano method of modifying after a kind of covering with paint
CN114717367A (en) * 2022-04-12 2022-07-08 吉安市三菱超细纤维有限公司 Fiber leather treatment composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851691A (en) * 2009-03-30 2010-10-06 上海皇宇科技发展有限公司 Leather repairing agent
CN102660197A (en) * 2012-04-20 2012-09-12 上海皇宇科技发展有限公司 Leather brightening agent and leather brightening wet wiper
CN102676313A (en) * 2011-03-12 2012-09-19 郑彦 Detergent for environmental protection toilet
US20130036557A1 (en) * 2010-10-21 2013-02-14 Sam Won Chang Functional leather and the method of preparing thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851691A (en) * 2009-03-30 2010-10-06 上海皇宇科技发展有限公司 Leather repairing agent
US20130036557A1 (en) * 2010-10-21 2013-02-14 Sam Won Chang Functional leather and the method of preparing thereof
CN102676313A (en) * 2011-03-12 2012-09-19 郑彦 Detergent for environmental protection toilet
CN102660197A (en) * 2012-04-20 2012-09-12 上海皇宇科技发展有限公司 Leather brightening agent and leather brightening wet wiper

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752973A (en) * 2016-11-30 2017-05-31 广西大学 A kind of turtle shell brightener
CN108624727A (en) * 2018-04-24 2018-10-09 安徽乐踏鞋业有限公司 Leather nano method of modifying after a kind of covering with paint
CN114717367A (en) * 2022-04-12 2022-07-08 吉安市三菱超细纤维有限公司 Fiber leather treatment composition

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