CN106753565A - A kind of method that utilization ardealite prepares synthesis gas - Google Patents
A kind of method that utilization ardealite prepares synthesis gas Download PDFInfo
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- CN106753565A CN106753565A CN201710012847.5A CN201710012847A CN106753565A CN 106753565 A CN106753565 A CN 106753565A CN 201710012847 A CN201710012847 A CN 201710012847A CN 106753565 A CN106753565 A CN 106753565A
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- ardealite
- lignite
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- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 22
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000007789 gas Substances 0.000 claims abstract description 60
- 239000003077 lignite Substances 0.000 claims abstract description 37
- 238000001354 calcination Methods 0.000 claims abstract description 6
- 238000006392 deoxygenation reaction Methods 0.000 claims abstract description 6
- 239000011261 inert gas Substances 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 235000011837 pasties Nutrition 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000012266 salt solution Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 18
- 238000006243 chemical reaction Methods 0.000 abstract description 14
- 239000007787 solid Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006722 reduction reaction Methods 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 8
- 239000012265 solid product Substances 0.000 description 8
- 229910052602 gypsum Inorganic materials 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000010440 gypsum Substances 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 239000008236 heating water Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000007605 air drying Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229910052925 anhydrite Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0986—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
Abstract
The invention discloses a kind of method that utilization ardealite prepares synthesis gas, using lignite and ardealite is as raw material and adds Fe elements as auxiliary agent, after inert gas deoxygenation, carry out calcining and prepare synthesis gas.Preparation is simple for the present invention, and raw material uses industrial solid castoff ardealite and lignite inferior, using the catalytic performance reduction reaction activity of Fe so as to reduce reaction temperature, improves the resolution ratio of lignite and ardealite, reducing energy consumption.
Description
Technical field
The present invention relates to a kind of method that utilization ardealite prepares synthesis gas, belong to phosphorous chemical industry waste residue resource field.
Background technology
Ardealite is the accessory substance of Wet-process phosphoric acid (WPPA) process, and main composition is gypsum（CaSO4·2H2O）.At present, state
The inside and outside disposal to ardealite is basic using abandoned piles or to be directly discharged into by the way of sea, cause the serious wasting of resources and
Bring many potential environmental hazards.Though having in recent years, some improve but effect is still undesirable, therefore improve the synthesis of ardealite
Utilization rate has turned into phosphorous chemical industry enterprise and environmental protection department big problem urgently to be resolved hurrily.Both at home and abroad to the resource profit of ardealite
It is mainly used for the construction materials such as brickmaking, plate, production co-producing cement, cement retarder, soil conditioner etc., these moneys with mode
The added value of source Land use systems is relatively low.As patent of invention 201210128659.6 discloses guarantor prepared by a kind of utilization ardealite
Warm energy-conservation composite phase change energy-storing plasterboard and preparation method thereof；Patent of invention 201310383140.7 is disclosed using ardealite system
Standby ardealite base high-strength light building block and its production technology, the apparent close of gypsum base high-strength light building block is obtained using ardealite
Degree is not higher than 1000kg/m3, strength grade reaches more than MU10, and coefficient of softing is not less than 0.3；Patent of invention
201010179106.4 disclose motar prepared by a kind of utilization building waste and ardealite, are that one kind utilizes building waste
Powder substitutes the method that cement prepares motar；Patent application 201510470167.9 discloses one kind and utilizes solid waste
The method that thing ardealite prepares crystal whisker of gypsum, this application prepares crystal whisker of gypsum using one-step method, ardealite is washed, is centrifuged
The steps such as dehydration, lime neutralisation treatment are first pre-processed, then are blended in tube furnace according to certain ratio with glycerin solution
Inside carry out calcining obtaining semi-hydrated gypsum whisker.
Synthesis gas is a kind of unstripped gas as industrial chemicals with carbon monoxide and hydrogen as main component.Synthesis gas
Purposes is quite varied, and it is the basic material for synthesizing the products such as ammonia, natural gas, methyl alcohol, ethylene glycol.Prepare the raw material model of synthesis gas
Enclose wide, can be produced by solid fuel gasifications such as coal or coke, can also be produced by light hydrocarbons such as natural gas and naphthas, can also be by
Heavy oil partial oxidation method is produced.At present, the procedure both at home and abroad to the preparation of synthesis gas is complicated, high energy consumption.Patent application
201610430043.2 disclose ardealite prepares the method for synthesis gas with lignite chemical chain reaction, wherein individually using ardealite
It is oxygen carrier, reaction temperature is higher（875-950℃）, the resolution ratio of lignite is relatively low（About 50-86%）.
The content of the invention
It is brown with colm under anaerobic it is an object of the present invention to provide a kind of method that utilization ardealite prepares synthesis gas
Coal makes full use of the main component CaSO in ardealite as carbon source and hydrogen source4As oxygen carrier, coordinate making for Fe series catalysts
With, reaction activity is reduced, the reaction temperature of ardealite and lignite is reduced, the resolution ratio of lignite and ardealite is improved, improve system
Standby synthesis gas efficiency, reducing energy consumption.
A kind of method that utilization ardealite prepares synthesis gas, comprises the following steps that：
（1）By ardealite and lignite it is air-dried, broken, grinding, screening, respectively obtain granularity be 60-120 mesh ardealite powder and
Lignite powder；
（2）By step（1）The ardealite powder for obtaining is immersed in the ferric salt solution that concentration is 0.1-1mol/L, and uses ammonia
The pH of water regulation solution reaches 8-10, and heating water bath is to 80-90 DEG C and stirs, to ardealite powder for pasty state is to stop adding
Heat, filtering, filter residue is washed with deionized water to neutrality, and 2-3h is dried at 100-120 DEG C, removes Free water, obtains the phosphorus rich in Fe
Gypsum pretreatment sample；
（3）By step（2）Obtained ardealite pretreatment sample and step rich in Fe（1）The lignite powder for obtaining is according to quality
Than being well mixed for 0.01-2, calcined after being passed through inert gas deoxygenation（Calcining is from room temperature to 700-850 DEG C）, it is incubated 1.5-
2.5h, collects synthesis gas in calcination process.
Beneficial effects of the present invention：
（1）With phosphorous chemical industry waste ardealite, inferior matter lignite as raw material, raw material is easy to get the present invention, cheap, economizes in raw materials into
This；
（2）The present invention takes full advantage of each element in ardealite and lignite, reduces waste and produces；
（3）The present invention reduces reaction temperature due to the use of Fe series catalysts, improves the resolution ratio of lignite, also can at low temperature
The requirement of synthesis gas is reached, is that the future energy is maximally utilized there is provided new way.
Brief description of the drawings
Fig. 1 is the gained solid product XRD spectrum of embodiment 1；
Fig. 2 is the gained solid product XRD spectrum of embodiment 2；
Fig. 3 is the gained solid product XRD spectrum of embodiment 3；
Fig. 4 is the gained solid product XRD spectrum of embodiment 4.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail, and these embodiments are only used in more detail specifically
The bright present invention, and the scope that should not be construed as above-mentioned theme of the invention is only limitted to the limitation of following embodiments.
Embodiment 1
（1）By ardealite natural air drying, broken, grinding, 120 mesh sieves are crossed, 10g ardealite powder is immersed in 50mL 0.1mol/
Fe (the NO of L3)3In solution, it is 10 to adjust pH with ammoniacal liquor, and heating water bath is to 85 DEG C and stirs, when ardealite powder for pasty state is to stop
Only heat, it is 7 to filter and be washed with deionized to pH, filter residue is placed in 110 DEG C of baking oven after drying 3h removal Free waters, is obtained
To the ardealite of pretreatment；
（2）Lignite dries 2h at 105 DEG C and removes Free water, then is ground and crosses 80 mesh sieves, 0.01g is weighed respectively and is located in advance
The ardealite powder and 1g lignite powders of reason are well mixed, and are put into tube furnace, and the logical nitrogen of tube furnace will be managed as protective gas
Formula stove calcines 2.5h from room temperature to 850 DEG C, and ardealite and lignite fully react, and course of reaction produces gas, gas cooling
Afterwards, it is passed through again by silica dehydrator in gas chromatograph and detects the concentration of various gases, from gas chromatograph as can be seen that producing
Gas in the amount of carbon monoxide and hydrogen slowly increase, then being gradually decreased completely with reaction, until without gas
Body is produced, and tube furnace finally is cooled into room temperature.
The solid product obtained after being cooled down to the present embodiment carries out XRD detections, as shown in figure 1, solid is produced as we know from the figure
Contain CaS and a small amount of silica in thing, while using the S in iodometric determination residue2-Content.Calculated according to stechiometry
CaSO in residue4With the amount of CaS, it is calculated analytically and obtains, does not have CaSO in residue4, during above analysis can draw ardealite
CaSO4It is completely converted into CaS.
The resolution ratio of lignite is calculated according to following equation：
Because except CaSO in raw material ardealite4Other compositions content it is relatively low, raw material ardealite impurity is defaulted as herein is
0, analysis is computed, lignite resolution ratio is 59.19%, and the H:Cmoleratio of the present embodiment gained gas is 1.21, meets synthesis gas
The requirement of the coarse raw materials gas H:Cmoleratio 1.0-5.0 ratios of downstream product.
Embodiment 2
（1）By ardealite natural air drying, broken, grinding, 60 mesh sieves are crossed, 10g ardealite powder is immersed in 50mL 1mol/L
FeCl3In solution, it is 9 to adjust pH with ammoniacal liquor, and heating water bath is to 90 DEG C and stirs, when ardealite powder for pasty state is to stop adding
Heat, it is 7 to filter and be washed with deionized to pH, and filter residue is placed in 120 DEG C of baking oven after drying 2h removal Free waters, obtains pre-
The ardealite for the treatment of；
（2）Lignite dries 2.5h at 115 DEG C and removes Free water, then is ground and crosses 100 mesh sieves, 2g is weighed respectively and is located in advance
The ardealite powder and 1g lignite powders of reason are well mixed, and are put into tube furnace, after the logical argon gas deoxygenation of tube furnace, by tube furnace from
Room temperature calcines 1.5h to 750 DEG C, and ardealite and lignite fully react, and course of reaction produces gas, after gas cooling, leads to
Cross silica dehydrator and be passed through in gas chromatograph the concentration for detecting various gases again, from gas chromatograph as can be seen that the gas for producing
The amount of carbon monoxide and hydrogen slowly increases in body, then being gradually decreased completely with reaction, until being produced without gas
It is raw, tube furnace is finally cooled to room temperature.
The solid product obtained after being cooled down to the present embodiment carries out XRD detections, as shown in Fig. 2 solid is produced as we know from the figure
Contain CaS and a small amount of silica in thing, while using the S in iodometric determination residue2-Content, calculates according to stechiometry
Go out CaSO in residue4With the amount of CaS, it is calculated analytically and obtains, does not have CaSO in residue4, the above analysis can draw ardealite
In CaSO4It is completely converted into CaS.
The resolution ratio of lignite is calculated according to following equation：
Because except CaSO in raw material ardealite4Other compositions content it is relatively low, raw material ardealite impurity is defaulted as herein is
0, analysis is computed, lignite resolution ratio is 91.25%, and the H:Cmoleratio of the present embodiment gained gas is 1.45, meets synthesis gas
The requirement of the coarse raw materials gas H:Cmoleratio 1.0-5.0 ratios of downstream product.
Embodiment 3
（1）By ardealite natural air drying, broken, grinding, 80 mesh sieves are crossed, 10g ardealite powder is immersed in 50mL 0.5mol/L
Fe2(SO4)3In solution, it is 9 to adjust pH with ammoniacal liquor, and heating water bath is to 80 DEG C and stirs, when ardealite powder for pasty state is to stop
Only heat, it is 7 to filter and be washed with deionized to pH, filter residue is placed in 100 DEG C of baking oven after drying 3h removal Free waters, is obtained
To the ardealite of pretreatment；
（2）Lignite dries 2h at 120 DEG C and removes Free water, then is ground and crosses 100 mesh sieves, and 1g pretreatments are weighed respectively
Ardealite powder and 1g lignite powders it is well mixed, be put into tube furnace, after tube furnace helium injection gas deoxygenation, by tube furnace from room
Temperature is warmed up to 800 DEG C, calcines 2h, and ardealite and lignite fully react, and course of reaction produces gas, after gas cooling, by silicon
Glue dries the concentration for being passed through again in gas chromatograph and detecting various gases, from gas chromatograph as can be seen that in the gas for producing
The amount of carbon monoxide and hydrogen slowly increases, then being gradually decreased completely with reaction, until produced without gas, most
Tube furnace is cooled to room temperature afterwards.
The solid product obtained after being cooled down to the present embodiment carries out XRD detections, as shown in figure 3, solid is produced as we know from the figure
Contain CaS and a small amount of silica in thing, while using the S in iodometric determination residue2-Content, calculates according to stechiometry
The CaSO gone out in residue4With the amount of CaS, it is calculated analytically and obtains, does not have CaSO in residue4, the above analysis can draw phosphorus stone
CaSO in cream4It is completely converted into CaS.
The resolution ratio of lignite is calculated according to following equation：
Because except CaSO in raw material ardealite4Other compositions content it is relatively low, raw material ardealite impurity is defaulted as herein is
0, analysis is computed, lignite resolution ratio is 90.29%, and the H:Cmoleratio of the present embodiment gained gas is 1.5, meets synthesis gas
The requirement of the coarse raw materials gas H:Cmoleratio 1.0-5.0 ratios of downstream product.
Embodiment 4
（1）By ardealite natural air drying, broken, grinding, 100 mesh sieves are crossed, 10g ardealite powder is immersed in 50mL
Fe (the NO of 0.75mol/L3)3In solution, it is 8 to adjust pH with ammoniacal liquor, and heating water bath is to 80 DEG C and stirs, when ardealite powder is
Pasty state is to stop heating, and it is 7 to filter and be washed with deionized to pH, and filter residue is placed in 100 DEG C of baking oven and dries 3h removals certainly
After by water, the ardealite for being pre-processed；
（2）Lignite dries 2h at 120 DEG C and removes Free water, then is ground and crosses 100 mesh sieves, and 2g pretreatments are weighed respectively
Ardealite powder and 1g lignite powders it is well mixed, be put into tube furnace, after the logical nitrogen deoxygenation of tube furnace, by tube furnace from room
Temperature is warmed up to 850 DEG C, calcines 2h, and ardealite and lignite fully react, and course of reaction produces gas, after gas cooling, by silicon
Glue dries the concentration for being passed through again in gas chromatograph and detecting various gases, from gas chromatograph as can be seen that in the gas for producing
The amount of carbon monoxide and hydrogen slowly increases, then being gradually decreased completely with reaction, until produced without gas, most
Tube furnace is cooled to room temperature afterwards.
The solid product obtained after being cooled down to the present embodiment carries out XRD detections, as shown in figure 4, solid is produced as we know from the figure
Contain CaS and a small amount of silica in thing, while using the S in iodometric determination residue2-Content, calculates according to stechiometry
The CaSO gone out in residue4With the amount of CaS, it is calculated analytically and obtains, does not have CaSO in residue4, the above analysis can draw phosphorus stone
CaSO in cream4It is completely converted into CaS.
The resolution ratio of lignite is calculated according to following equation：
Because except CaSO in raw material ardealite4Other compositions content it is relatively low, raw material ardealite impurity is defaulted as herein is
0, analysis is computed, lignite resolution ratio is 93.26%, and the H:Cmoleratio of the present embodiment gained gas is 1.61, meets synthesis gas
The requirement of the coarse raw materials gas H:Cmoleratio 1.0-5.0 ratios of downstream product.
Claims (4)
1. a kind of method that utilization ardealite prepares synthesis gas, comprises the following steps：
（1）By ardealite and brown coal drying, crushing；
（2）By step（1）The ardealite powder for obtaining is immersed in ferric salt solution, and adjusts pH to 8-10, water with ammoniacal liquor
Bath is heated to 80-90 DEG C and stirs, and to ardealite powder for pasty state is to stop heating, filtering, filter residue is washed with deionized water into
Property, 2-3h is dried at 100-120 DEG C, obtain the ardealite pretreatment sample rich in Fe；
（3）By step（2）The ardealite pretreatment sample and step rich in Fe for obtaining（1）The lignite powder mixing for obtaining is equal
It is even, after being passed through inert gas deoxygenation, 700-850 DEG C of calcining 1.5-2.5h is warming up to, synthesis gas is collected in calcination process.
2. method according to claim 1, it is characterised in that step（1）Middle ardealite and lignite are crushed to 60-120 mesh.
3. method according to claim 1, it is characterised in that step（2）Middle ferric salt solution concentration is 0.1-1mol/
L。
4. method according to claim 1, it is characterised in that step（3）In rich in Fe ardealite pretreatment sample with
Lignite powder is according to mass ratio for the ratio of 0.01-2 mixes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710012847.5A CN106753565A (en) | 2017-01-09 | 2017-01-09 | A kind of method that utilization ardealite prepares synthesis gas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710012847.5A CN106753565A (en) | 2017-01-09 | 2017-01-09 | A kind of method that utilization ardealite prepares synthesis gas |
Publications (1)
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107285357A (en) * | 2017-06-14 | 2017-10-24 | 昆明理工大学 | A kind of method that utilization carbide slag traps carbon dioxide |
| CN107674727A (en) * | 2017-09-27 | 2018-02-09 | 昆明理工大学 | A kind of preparation method of calcium oxygen carrier |
| CN107674728A (en) * | 2017-09-27 | 2018-02-09 | 昆明理工大学 | A kind of preparation method of composite calcium-base oxygen carrier |
| CN113996265A (en) * | 2021-11-02 | 2022-02-01 | 南京理工大学 | Preparation method and application of iron-modified phosphogypsum |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107285357A (en) * | 2017-06-14 | 2017-10-24 | 昆明理工大学 | A kind of method that utilization carbide slag traps carbon dioxide |
| CN107285357B (en) * | 2017-06-14 | 2019-09-27 | 昆明理工大学 | A method of carbon dioxide is trapped using carbide slag |
| CN107674727A (en) * | 2017-09-27 | 2018-02-09 | 昆明理工大学 | A kind of preparation method of calcium oxygen carrier |
| CN107674728A (en) * | 2017-09-27 | 2018-02-09 | 昆明理工大学 | A kind of preparation method of composite calcium-base oxygen carrier |
| CN113996265A (en) * | 2021-11-02 | 2022-02-01 | 南京理工大学 | Preparation method and application of iron-modified phosphogypsum |
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