CN106753410A - A kind of As polluted soil repairs medicament - Google Patents
A kind of As polluted soil repairs medicament Download PDFInfo
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- CN106753410A CN106753410A CN201611236326.XA CN201611236326A CN106753410A CN 106753410 A CN106753410 A CN 106753410A CN 201611236326 A CN201611236326 A CN 201611236326A CN 106753410 A CN106753410 A CN 106753410A
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- arborvitae
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- powder
- hornwort
- agar
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Medicament is repaired the invention discloses a kind of As polluted soil, the reparation medicament is made up of according to mass fraction meter following raw material：12 15 parts of hornwort, 45 parts of agar, 47 parts of manganese spar, 20 25 parts of arborvitae；Wherein, hornwort and the mass ratio of agar are 3：1；Manganese spar is first crushed into obtain manganese spar powder；Hornwort, agar and arborvitae are dried respectively, is ground into powder；Arborvitae powder is soaked, microwave treatment, be filtrated to get arborvitae liquid and arborvitae slag, arborvitae liquid is arborvitae extract solution through being concentrated under reduced pressure；The calcining of arborvitae slag is obtained calcining arborvitae；Arborvitae extract solution is well mixed with manganese spar powder, hornwort powder, parmelia saxatilis vegetable powder, mixture slurry is obtained；Calcining arborvitae is placed in immersion treatment in mixture slurry, is obtained.The present invention repairs medicament has that few consumption, low cost, effect be good, free of contamination advantage.
Description
Technical field
The present invention relates to technical field of soil remediation, specifically a kind of As polluted soil repairs medicament.
Background technology
Arsenic is widely used in many industries, and its a large amount of residual to soil are made by exploitation, processing, using, the process such as discarded
In earth.According to national Soil Pollution Investigation publication, arsenic pollution point position exceeding standard rate is up to 2.7%.With urbanization, industrialize into
The quickening of journey, increasing soil is subjected to arsenic pollution；Urban strategy layout is readjusted, and substantial amounts of arsenic pollution leaves place urgency
Need to administer.Soil arsenic pollution has disguised, hysteresis quality and chronicity, it is difficult to repair.When Arsenic in Soil is accumulated to a certain extent
Afterwards, arsenic and arsenide typically can enter human body by approach such as water, air and foods, directly endanger human health.Element arsenic
Toxicity is extremely low, and arsenide is toxic, and trivalent arsenide compound is more stronger than other arsenic compound toxicity.Arsenic pollution poisoning is (anxious
Property arsenic poisoning) or inverted nuisance disease (arsenicalism) it is of common occurrence.Meanwhile, arsenic and arsenide are plant strong accumulations
Element, the growth of crops will be suppressed.
At present, the recovery technique for arsenic pollution soil mainly includes solidification and stabilization method, physical chemistry repairing method and plant
Thing repairing method., due to low cost, easy to operate and treatment effeciency is high and receives significant attention for solidification and stabilization method.But existing arsenic
Polluted Soil solidification and stabilization treatment technology technique falls behind relatively, and solidification stable pharmaceutical is expensive and pollutes environment, result in arsenic pollution
Native solidification and stabilization remediation efficiency is low, high cost, and secondary pollution and environmental risk are protruded.
The content of the invention
It is an object of the invention to provide a kind of consumption it is few, price is low, effect good, free of contamination As polluted soil repair medicine
Agent.
To achieve the above object, the present invention provides following technical scheme：
A kind of As polluted soil repairs medicament, according to mass fraction meter, is made up of following raw material：Hornwort 12-15 parts, stone
Cauliflower 4-5 parts, manganese spar 4-7 parts, arborvitae 20-25 parts；Wherein, hornwort and the mass ratio of agar are 3：1.
As further scheme of the invention：According to mass fraction meter, it is made up of following raw material：Hornwort 13-14 parts, stone
Cauliflower 4.33-4.67 parts, manganese spar 5-6 parts, arborvitae 22-24 parts.
As further scheme of the invention：According to mass fraction meter, it is made up of following raw material：13.5 parts of hornwort, stone
4.5 parts of cauliflower, 5.5 parts of manganese spar, 23 parts of arborvitae.
Described As polluted soil repairs the preparation method of medicament, comprises the following steps：
(1) after manganese spar first being crushed into 30-50 mesh, then through ultramicro grinding to 15-18 μm, manganese spar powder is obtained；
(2) hornwort, agar and arborvitae are dried respectively, is crushed to 120-150 mesh, obtain hornwort powder, agar
Powder and arborvitae powder；
(3) arborvitae powder is added immersion treatment 3-4h in the 7-8 times of water measured of its quality, is then 320-340W with power
Microwave treatment 3-4min, be filtrated to get arborvitae liquid and arborvitae slag, arborvitae liquid is relative density 1.10-1.12's through being concentrated under reduced pressure
Arborvitae extract solution, it is standby；
(4) arborvitae slag is placed in 540-550 DEG C of temperature lower calcination 55-65min, obtains calcining arborvitae；
(5) arborvitae extract solution is well mixed with manganese spar powder, hornwort powder, parmelia saxatilis vegetable powder, obtains mixture slurry；
(6) calcining arborvitae is placed in immersion treatment 32-35min in mixture slurry, obtains described As polluted soil and repair
Multiple medicament.
Described As polluted soil repairs application of the medicament in terms of heavy-metal contaminated soil renovation agent is prepared.
Compared with prior art, the beneficial effects of the invention are as follows：The present invention is with natural mineral, algae and timber as former
Material, by specific preparation technology be made it is a kind of can significantly reduce in soil available state arsenic (including water-soluble state, ammonium carbonate exchange
State, dissolving with hydrochloric acid state and NaOH solubilised state) content soil remediation medicament, in practical application, the soil per 1kg arsenic pollutions
Earth only needs to repair the effect that medicament can be achieved with quick significant reduction available state arsenic content with 5-10g, therefore, the present invention is repaiied
Multiple medicament has that few consumption, low cost, effect be good, free of contamination advantage.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of As polluted soil repairs medicament, according to mass fraction meter, is made up of following raw material：
12 parts of hornwort, 4 parts of agar, 7 parts of manganese spar, 25 parts of arborvitae.
Described As polluted soil repairs the preparation method of medicament, comprises the following steps：
(1) after manganese spar first being crushed into 30 mesh, then through ultramicro grinding to 15 μm, manganese spar powder is obtained；
(2) respectively by hornwort, agar and arborvitae dry, be crushed to 120 mesh, obtain hornwort powder, parmelia saxatilis vegetable powder and
Arborvitae powder；
(3) arborvitae powder is added immersion treatment 3h in 7 times of water measured of its quality, is then at the microwave of 320W with power
Reason 3min, is filtrated to get arborvitae liquid and arborvitae slag, and arborvitae liquid is the arborvitae extract solution of relative density 1.10 through being concentrated under reduced pressure, standby
With；
(4) arborvitae slag is placed in 540 DEG C of temperature lower calcination 55min, obtains calcining arborvitae；
(5) arborvitae extract solution is well mixed with manganese spar powder, hornwort powder, parmelia saxatilis vegetable powder, obtains mixture slurry；
(6) calcining arborvitae is placed in immersion treatment 32min in mixture slurry, obtains described As polluted soil and repair medicine
Agent.
Embodiment 2
In the embodiment of the present invention, a kind of As polluted soil repairs medicament, according to mass fraction meter, is made up of following raw material：
15 parts of hornwort, 5 parts of agar, 4 parts of manganese spar, 20 parts of arborvitae.
Described As polluted soil repairs the preparation method of medicament, comprises the following steps：
(1) after manganese spar first being crushed into 50 mesh, then through ultramicro grinding to 18 μm, manganese spar powder is obtained；
(2) respectively by hornwort, agar and arborvitae dry, be crushed to 150 mesh, obtain hornwort powder, parmelia saxatilis vegetable powder and
Arborvitae powder；
(3) arborvitae powder is added immersion treatment 4h in 8 times of water measured of its quality, is then at the microwave of 340W with power
Reason 4min, is filtrated to get arborvitae liquid and arborvitae slag, and arborvitae liquid is the arborvitae extract solution of relative density 1.12 through being concentrated under reduced pressure, standby
With；
(4) arborvitae slag is placed in 550 DEG C of temperature lower calcination 65min, obtains calcining arborvitae；
(5) arborvitae extract solution is well mixed with manganese spar powder, hornwort powder, parmelia saxatilis vegetable powder, obtains mixture slurry；
(6) calcining arborvitae is placed in immersion treatment 35min in mixture slurry, obtains described As polluted soil and repair medicine
Agent.
Embodiment 3
In the embodiment of the present invention, a kind of As polluted soil repairs medicament, according to mass fraction meter, is made up of following raw material：
13 parts of hornwort, 4.33 parts of agar, 6 parts of manganese spar, 24 parts of arborvitae.
Described As polluted soil repairs the preparation method of medicament, comprises the following steps：
(1) after manganese spar first being crushed into 30 mesh, then through ultramicro grinding to 18 μm, manganese spar powder is obtained；
(2) respectively by hornwort, agar and arborvitae dry, be crushed to 120 mesh, obtain hornwort powder, parmelia saxatilis vegetable powder and
Arborvitae powder；
(3) arborvitae powder is added immersion treatment 3h in 8 times of water measured of its quality, is then at the microwave of 340W with power
Reason 3min, is filtrated to get arborvitae liquid and arborvitae slag, and arborvitae liquid is the arborvitae extract solution of relative density 1.12 through being concentrated under reduced pressure, standby
With；
(4) arborvitae slag is placed in 540 DEG C of temperature lower calcination 65min, obtains calcining arborvitae；
(5) arborvitae extract solution is well mixed with manganese spar powder, hornwort powder, parmelia saxatilis vegetable powder, obtains mixture slurry；
(6) calcining arborvitae is placed in immersion treatment 32min in mixture slurry, obtains described As polluted soil and repair medicine
Agent.
Embodiment 4
In the embodiment of the present invention, a kind of As polluted soil repairs medicament, according to mass fraction meter, is made up of following raw material：
14 parts of hornwort, 4.67 parts of agar, 5 parts of manganese spar, 22 parts of arborvitae.
Described As polluted soil repairs the preparation method of medicament, comprises the following steps：
(1) after manganese spar first being crushed into 50 mesh, then through ultramicro grinding to 15 μm, manganese spar powder is obtained；
(2) respectively by hornwort, agar and arborvitae dry, be crushed to 150 mesh, obtain hornwort powder, parmelia saxatilis vegetable powder and
Arborvitae powder；
(3) arborvitae powder is added immersion treatment 4h in 7 times of water measured of its quality, is then at the microwave of 320W with power
Reason 4min, is filtrated to get arborvitae liquid and arborvitae slag, and arborvitae liquid is the arborvitae extract solution of relative density 1.10 through being concentrated under reduced pressure, standby
With；
(4) arborvitae slag is placed in 550 DEG C of temperature lower calcination 55min, obtains calcining arborvitae；
(5) arborvitae extract solution is well mixed with manganese spar powder, hornwort powder, parmelia saxatilis vegetable powder, obtains mixture slurry；
(6) calcining arborvitae is placed in immersion treatment 35min in mixture slurry, obtains described As polluted soil and repair medicine
Agent.
Embodiment 5
In the embodiment of the present invention, a kind of As polluted soil repairs medicament, according to mass fraction meter, is made up of following raw material：
13.5 parts of hornwort, 4.5 parts of agar, 5.5 parts of manganese spar, 23 parts of arborvitae.
Described As polluted soil repairs the preparation method of medicament, comprises the following steps：
(1) after manganese spar first being crushed into 40 mesh, then through ultramicro grinding to 18 μm, manganese spar powder is obtained；
(2) respectively by hornwort, agar and arborvitae dry, be crushed to 150 mesh, obtain hornwort powder, parmelia saxatilis vegetable powder and
Arborvitae powder；
(3) arborvitae powder is added immersion treatment 3h in 8 times of water measured of its quality, is then at the microwave of 330W with power
Reason 4min, is filtrated to get arborvitae liquid and arborvitae slag, and arborvitae liquid is the arborvitae extract solution of relative density 1.12 through being concentrated under reduced pressure, standby
With；
(4) arborvitae slag is placed in 545 DEG C of temperature lower calcination 60min, obtains calcining arborvitae；
(5) arborvitae extract solution is well mixed with manganese spar powder, hornwort powder, parmelia saxatilis vegetable powder, obtains mixture slurry；
(6) calcining arborvitae is placed in immersion treatment 34min in mixture slurry, obtains described As polluted soil and repair medicine
Agent.
Comparative example 1
On the basis of embodiment 5, agar is replaced with hornwort, remaining is identical with embodiment 5.
Comparative example 2
On the basis of embodiment 5, hornwort is replaced with agar, remaining is identical with embodiment 5.
Comparative example 3
On the basis of embodiment 5, manganese spar this component is deleted, remaining is identical with embodiment 5.
Comparative example 4
Only containing this component of arborvitae, remaining is identical with embodiment 5.
The pedotheque by arsenic pollution is taken, it is (including water-soluble to determine soil available arsenic using continuous chemical extraction
State, ammonium carbonate exchange state, dissolving with hydrochloric acid state and NaOH solubilised state) content.Repaired with 10g according to every 1kg pedotheques
The ratio of medicament, will repair during medicament adds corresponding pedotheque, fully obtained in embodiment 1-5 and comparative example 1-4 respectively
It is well mixed, stand 3 days, that is, complete to repair, recycle continuous chemical extraction to determine soil available arsenic (bag after reparation
Include water-soluble state, ammonium carbonate exchange state, dissolving with hydrochloric acid state and NaOH solubilised state) content.Variousization in soil before and after repairing
The arsenic content for learning form is as shown in table 1.
Before and after the reparation medicament of each example of table 1 is repaired, the available state arsenic content of As polluted soil
| Project | Before reparation (mg/kg) | After reparation (mg/kg) |
| Embodiment 1 | 3300 | 1.1 |
| Embodiment 2 | 3200 | 1.1 |
| Embodiment 3 | 3500 | 0.9 |
| Embodiment 4 | 3500 | 0.9 |
| Embodiment 5 | 3400 | 0.5 |
| Comparative example 1 | 3200 | 42.3 |
| Comparative example 2 | 3400 | 56.8 |
| Comparative example 3 | 3400 | 438.6 |
| Comparative example 4 | 3500 | 1524.9 |
As can be seen from Table 1：The present invention repairs available state arsenic (including water-soluble state, the carbon that medicament can be significantly reduced in soil
Sour ammonium exchange state, dissolving with hydrochloric acid state and NaOH solubilised state) content；Comparative example 5 and comparative example 1-4, it can be seen that
Hornwort in modifying agent of the present invention, agar, manganese spar, that the compounding mode of four kinds of components of arborvitae can significantly reduce soil is effective
The content of state arsenic (including water-soluble state, ammonium carbonate exchange state, dissolving with hydrochloric acid state and NaOH solubilised state), single arborvitae or
Hornwort/agar, manganese spar, the combination of arborvitae or hornwort, agar, the combination of arborvitae are then substantially without this effect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires to be limited rather than described above, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (5)
1. a kind of As polluted soil repairs medicament, it is characterised in that according to mass fraction meter, be made up of following raw material：Hornwort
12-15 parts, agar 4-5 parts, manganese spar 4-7 parts, arborvitae 20-25 parts；Wherein, hornwort and the mass ratio of agar are 3：1.
2. As polluted soil according to claim 1 repairs medicament, it is characterised in that according to mass fraction meter, by following
Raw material is constituted：Hornwort 13-14 parts, agar 4.33-4.67 parts, manganese spar 5-6 parts, arborvitae 22-24 parts.
3. As polluted soil according to claim 2 repairs medicament, it is characterised in that according to mass fraction meter, by following
Raw material is constituted：13.5 parts of hornwort, 4.5 parts of agar, 5.5 parts of manganese spar, 23 parts of arborvitae.
4. the preparation method of medicament is repaired according to any described As polluted soils of claim 1-3, it is characterised in that including with
Lower step：
(1) after manganese spar first being crushed into 30-50 mesh, then through ultramicro grinding to 15-18 μm, manganese spar powder is obtained；
(2) respectively by hornwort, agar and arborvitae dry, be crushed to 120-150 mesh, obtain hornwort powder, parmelia saxatilis vegetable powder and
Arborvitae powder；
(3) arborvitae powder is added immersion treatment 3-4h in the 7-8 times of water measured of its quality, is then the micro- of 320-340W with power
Ripple processes 3-4min, is filtrated to get arborvitae liquid and arborvitae slag, and arborvitae liquid is the arborvitae of relative density 1.10-1.12 through being concentrated under reduced pressure
Extract solution, it is standby；
(4) arborvitae slag is placed in 540-550 DEG C of temperature lower calcination 55-65min, obtains calcining arborvitae；
(5) arborvitae extract solution is well mixed with manganese spar powder, hornwort powder, parmelia saxatilis vegetable powder, obtains mixture slurry；
(6) calcining arborvitae is placed in immersion treatment 32-35min in mixture slurry, obtains described As polluted soil and repair medicine
Agent.
5. medicament is repaired according to any described As polluted soils of claim 1-3 and preparing heavy-metal contaminated soil renovation agent side
The application in face.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611236326.XA CN106753410A (en) | 2016-12-28 | 2016-12-28 | A kind of As polluted soil repairs medicament |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611236326.XA CN106753410A (en) | 2016-12-28 | 2016-12-28 | A kind of As polluted soil repairs medicament |
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| Publication Number | Publication Date |
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| CN106753410A true CN106753410A (en) | 2017-05-31 |
Family
ID=58925166
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611236326.XA Pending CN106753410A (en) | 2016-12-28 | 2016-12-28 | A kind of As polluted soil repairs medicament |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233865A (en) * | 2018-11-22 | 2019-01-18 | 四川大学 | A kind of As polluted soil long-acting repair materials in situ |
| CN109354318A (en) * | 2018-11-22 | 2019-02-19 | 四川大学 | A kind of pair of tailing arsenic pollution rainfall runoff collects the device and method repaired |
| CN113245360A (en) * | 2021-06-29 | 2021-08-13 | 什邡市优禾工业产品设计工作室 | Ecological soil remediation method |
-
2016
- 2016-12-28 CN CN201611236326.XA patent/CN106753410A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233865A (en) * | 2018-11-22 | 2019-01-18 | 四川大学 | A kind of As polluted soil long-acting repair materials in situ |
| CN109354318A (en) * | 2018-11-22 | 2019-02-19 | 四川大学 | A kind of pair of tailing arsenic pollution rainfall runoff collects the device and method repaired |
| CN109233865B (en) * | 2018-11-22 | 2021-02-26 | 四川大学 | In-situ long-acting repair material for arsenic-polluted soil |
| CN109354318B (en) * | 2018-11-22 | 2021-09-03 | 四川大学 | Device and method for collecting and restoring rainwater runoff polluted by arsenic in tailings |
| CN113245360A (en) * | 2021-06-29 | 2021-08-13 | 什邡市优禾工业产品设计工作室 | Ecological soil remediation method |
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