CN106753054A - A kind of bonding agent for environment-friendly stalk vegetation blanket and preparation method thereof - Google Patents
A kind of bonding agent for environment-friendly stalk vegetation blanket and preparation method thereof Download PDFInfo
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- CN106753054A CN106753054A CN201611070957.9A CN201611070957A CN106753054A CN 106753054 A CN106753054 A CN 106753054A CN 201611070957 A CN201611070957 A CN 201611070957A CN 106753054 A CN106753054 A CN 106753054A
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- environment
- bonding agent
- vegetation blanket
- acetic acid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Cultivation Of Plants (AREA)
Abstract
The invention discloses a kind of bonding agent for environment-friendly stalk vegetation blanket, it is made up of the raw material of following parts by weight：30 50 parts of polyacrylate polymers, 28 40 parts of superchlorinated polyvinyl chloride resin, 32 36 parts of ethylene-vinyl acetate copolymer, 20 30 parts of methylcellulose, 18 26 parts of 2,2 dimethylolpropionic acid, 50 60 parts of acetic acid ethylene glycol, 15 30 parts of acetic acid dibutyl ester, 40 45 parts of stearic acid.Compared with prior art, the bonding agent bonding stalk performance for environment-friendly stalk vegetation blanket of present invention synthesis is good, and adhesive strength is high, good stability, has preferable water resistance, Mechanics of Machinery and fire resistance after film forming.
Description
Technical field
The present invention relates to bonding agent preparation field, and in particular to a kind of bonding agent for environment-friendly stalk vegetation blanket.
Background technology
China is a populous nation, is again the country that an economy is developed rapidly, and 21 century will be faced with economic growth
With the dual-pressure of environmental protection.Therefore change production of energy and consumption pattern, develop the renewable moneys such as straw energy
Promote national economic development and be significant with environmental protection to setting up continuable resource system in source.
The chemical composition of stalk is mainly cellulose, hemicellulose and lignin, and waxy substance and silicon matter, boundary are contained in surface
Face activity is very poor, with traditional bonding agent effective bonding difficult to realize.It is current domestic be completed with stalk as primary raw material
Environment-friendly stalk vegetation blanket, be nearly all with PIC as bonding agent, also in the presence of many technical problems.Such as, produce
High cost causes to be lacked competitiveness compared with other similar wood-based products；This will drastically influence the industrialization of stalk vegetation blanket
Level.
The content of the invention
The present invention is intended to provide a kind of bonding agent for environment-friendly stalk vegetation blanket and preparation method thereof.
The present invention provides following technical scheme：
A kind of bonding agent for environment-friendly stalk vegetation blanket, it is made up of the raw material of following parts by weight：Polyacrylic acid
Ester polymer 30-50 parts, superchlorinated polyvinyl chloride resin 28-40 parts, ethylene-vinyl acetate copolymer 32-36 parts, methylcellulose 20-
30 parts, 18-26 parts of 2,2- dimethylolpropionic acids, 50-60 parts of acetic acid ethylene glycol, 15-30 parts of acetic acid dibutyl ester, stearic acid 40-45
Part.
A kind of preparation method of bonding agent for environment-friendly stalk vegetation blanket, comprises the following steps：
(1) by polyacrylate polymers, superchlorinated polyvinyl chloride resin, ethylene-vinyl acetate copolymer in 2,2- dihydroxymethyls
In butyric acid, 60 DEG C, agitating heating 8-12min are heated to；
(2) to methylcellulose is added in step (1) gained system, 85 DEG C are warmed up to and continue to stir 30-40min；
(3) step (2) gained system is cooled to 45 DEG C, adds acetic acid ethylene glycol to carry out termination process, after stirring 1-2h,
It is cooled to 30 DEG C；
(4) to acetic acid dibutyl ester, stearic acid is added in step (3) gained system, 85 DEG C of reactions are warming up to, add and trigger
Agent, reacts 40min, is cooled to room temperature and obtains final product the bonding agent for environment-friendly stalk vegetation blanket.
The initiator is azodiisobutyronitrile.
The polyacrylate polymers are the mixture of polyacrylate and polyethyl acrylate.
Compared with prior art, the beneficial effects of the invention are as follows：The gluing for environment-friendly stalk vegetation blanket of present invention synthesis
Connect that agent bonding stalk performance is good, adhesive strength is high, good stability, has preferable water resistance, Mechanics of Machinery and fire-retardant after film forming
Performance.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
A kind of bonding agent for environment-friendly stalk vegetation blanket of embodiment 1, it is made up of the raw material of following parts by weight：It is poly-
30 parts of acrylate polymer, 28 parts of superchlorinated polyvinyl chloride resin, 32 parts of ethylene-vinyl acetate copolymer, 20 parts of methylcellulose, 2,
18 parts of 2- dimethylolpropionic acids, 50 parts of acetic acid ethylene glycol, 15 parts of acetic acid dibutyl ester, 40 parts of stearic acid.
A kind of preparation method of bonding agent for environment-friendly stalk vegetation blanket, comprises the following steps：
(1) by polyacrylate polymers, superchlorinated polyvinyl chloride resin, ethylene-vinyl acetate copolymer in 2,2- dihydroxymethyls
In butyric acid, 60 DEG C, agitating heating 8-12min are heated to；
(2) to methylcellulose is added in step (1) gained system, 85 DEG C are warmed up to and continue to stir 30-40min；
(3) step (2) gained system is cooled to 45 DEG C, adds acetic acid ethylene glycol to carry out termination process, after stirring 1-2h,
It is cooled to 30 DEG C；
(4) to acetic acid dibutyl ester, stearic acid is added in step (3) gained system, 85 DEG C of reactions are warming up to, add and trigger
Agent, reacts 40min, is cooled to room temperature and obtains final product the bonding agent for environment-friendly stalk vegetation blanket.
The initiator is azodiisobutyronitrile.
The polyacrylate polymers are the mixture of polyacrylate and polyethyl acrylate.
A kind of bonding agent for environment-friendly stalk vegetation blanket of embodiment 2, it is made up of the raw material of following parts by weight：It is poly-
50 parts of acrylate polymer, 40 parts of superchlorinated polyvinyl chloride resin, 36 parts of ethylene-vinyl acetate copolymer, 30 parts of methylcellulose, 2,
26 parts of 2- dimethylolpropionic acids, 60 parts of acetic acid ethylene glycol, 30 parts of acetic acid dibutyl ester, 45 parts of stearic acid.
A kind of preparation method of bonding agent for environment-friendly stalk vegetation blanket, comprises the following steps：
(1) by polyacrylate polymers, superchlorinated polyvinyl chloride resin, ethylene-vinyl acetate copolymer in 2,2- dihydroxymethyls
In butyric acid, 60 DEG C, agitating heating 8-12min are heated to；
(2) to methylcellulose is added in step (1) gained system, 85 DEG C are warmed up to and continue to stir 30-40min；
(3) step (2) gained system is cooled to 45 DEG C, adds acetic acid ethylene glycol to carry out termination process, after stirring 1-2h,
It is cooled to 30 DEG C；
(4) to acetic acid dibutyl ester, stearic acid is added in step (3) gained system, 85 DEG C of reactions are warming up to, add and trigger
Agent, reacts 40min, is cooled to room temperature and obtains final product the bonding agent for environment-friendly stalk vegetation blanket.
The initiator is azodiisobutyronitrile.
The polyacrylate polymers are the mixture of polyacrylate and polyethyl acrylate.
A kind of bonding agent for environment-friendly stalk vegetation blanket of embodiment 3, it is made up of the raw material of following parts by weight：It is poly-
40 parts of acrylate polymer, 35 parts of superchlorinated polyvinyl chloride resin, 34 parts of ethylene-vinyl acetate copolymer, 25 parts of methylcellulose, 2,
24 parts of 2- dimethylolpropionic acids, 55 parts of acetic acid ethylene glycol, 22 parts of acetic acid dibutyl ester, 42 parts of stearic acid.
A kind of preparation method of bonding agent for environment-friendly stalk vegetation blanket, comprises the following steps：
(1) by polyacrylate polymers, superchlorinated polyvinyl chloride resin, ethylene-vinyl acetate copolymer in 2,2- dihydroxymethyls
In butyric acid, 60 DEG C, agitating heating 8-12min are heated to；
(2) to methylcellulose is added in step (1) gained system, 85 DEG C are warmed up to and continue to stir 30-40min；
(3) step (2) gained system is cooled to 45 DEG C, adds acetic acid ethylene glycol to carry out termination process, after stirring 1-2h,
It is cooled to 30 DEG C；
(4) to acetic acid dibutyl ester, stearic acid is added in step (3) gained system, 85 DEG C of reactions are warming up to, add and trigger
Agent, reacts 40min, is cooled to room temperature and obtains final product the bonding agent for environment-friendly stalk vegetation blanket.
The initiator is azodiisobutyronitrile.
The polyacrylate polymers are the mixture of polyacrylate and polyethyl acrylate.
It is obvious to a person skilled in the art that the invention is not restricted to the details of the one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires to be limited rather than the explanation, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each
Implementation method only includes an independent technical scheme, and this narrating mode of specification is only this area for clarity
Specification an as entirety, the technical scheme in each embodiment should can also be formed this by technical staff through appropriately combined
Art personnel may be appreciated other embodiment.
Claims (4)
1. a kind of bonding agent for environment-friendly stalk vegetation blanket, it is characterised in that it is made up of the raw material of following parts by weight：
Polyacrylate polymers 30-50 parts, superchlorinated polyvinyl chloride resin 28-40 parts, ethylene-vinyl acetate copolymer 32-36 parts, methyl fibre
20-30 parts of element of dimension, 18-26 parts of 2,2- dimethylolpropionic acids, 50-60 parts of acetic acid ethylene glycol, 15-30 parts of acetic acid dibutyl ester, tristearin
It is sour 40-45 parts.
2. a kind of preparation method of the as claimed in claim 1 bonding agent for being used for environment-friendly stalk vegetation blanket, it is characterised in that bag
Include following steps：
(1) by polyacrylate polymers, superchlorinated polyvinyl chloride resin, ethylene-vinyl acetate copolymer in 2,2- dimethylolpropionic acids
In, it is heated to 60 DEG C, agitating heating 8-12min；
(2) to methylcellulose is added in step (1) gained system, 85 DEG C are warmed up to and continue to stir 30-40min；
(3) step (2) gained system is cooled to 45 DEG C, adds acetic acid ethylene glycol to carry out termination process, after stirring 1-2h, cooling
To 30 DEG C；
(4) to acetic acid dibutyl ester, stearic acid is added in step (3) gained system, 85 DEG C of reactions are warming up to, add initiator, instead
40min is answered, room temperature is cooled to and is obtained final product the bonding agent for environment-friendly stalk vegetation blanket.
3. a kind of preparation method of bonding agent for environment-friendly stalk vegetation blanket according to claim 1 and 2, its feature exists
In：The initiator is azodiisobutyronitrile.
4. a kind of preparation method of bonding agent for environment-friendly stalk vegetation blanket according to claim 1 and 2, its feature exists
In：The polyacrylate polymers are the mixture of polyacrylate and polyethyl acrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611070957.9A CN106753054A (en) | 2016-11-29 | 2016-11-29 | A kind of bonding agent for environment-friendly stalk vegetation blanket and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611070957.9A CN106753054A (en) | 2016-11-29 | 2016-11-29 | A kind of bonding agent for environment-friendly stalk vegetation blanket and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106753054A true CN106753054A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611070957.9A Pending CN106753054A (en) | 2016-11-29 | 2016-11-29 | A kind of bonding agent for environment-friendly stalk vegetation blanket and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110028906A (en) * | 2019-04-10 | 2019-07-19 | 广东粤辉科技股份有限公司 | A kind of high tensile, polyester film glue resistant to high temperature and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880512A (en) * | 2010-07-14 | 2010-11-10 | 浙江德尚化工科技有限公司 | Aqueous binding agent and preparation method thereof |
-
2016
- 2016-11-29 CN CN201611070957.9A patent/CN106753054A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880512A (en) * | 2010-07-14 | 2010-11-10 | 浙江德尚化工科技有限公司 | Aqueous binding agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 俞铁铭 等 编著: "《精细有机单元反应与工艺》", 31 January 2005, 杭州：浙江大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110028906A (en) * | 2019-04-10 | 2019-07-19 | 广东粤辉科技股份有限公司 | A kind of high tensile, polyester film glue resistant to high temperature and preparation method thereof |
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