CN106753038A - A kind of method that utilization cornstarch makes corrugation adhesive for paper - Google Patents
A kind of method that utilization cornstarch makes corrugation adhesive for paper Download PDFInfo
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- CN106753038A CN106753038A CN201710102790.8A CN201710102790A CN106753038A CN 106753038 A CN106753038 A CN 106753038A CN 201710102790 A CN201710102790 A CN 201710102790A CN 106753038 A CN106753038 A CN 106753038A
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- parts
- cornstarch
- water
- minutes
- paper
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/27—Compounds containing a nitrogen atom bound to two other nitrogen atoms, e.g. diazoamino-compounds
- C08K5/28—Azides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A kind of method that utilization cornstarch makes corrugation adhesive for paper, is related to field of packaging material, comprises the following steps, and raw material prepares, and raw material each component content is calculated as by weight：Cornstarch, hard and infertile alkali：Strong catalyst, borax, defoamer, sodium hypochlorite, water, industrial grade hydrogen peroxide, potassium permanganate；Water is added in a kettle., 60 70 DEG C are heated to, then adds cornstarch to stir 35 minutes be gelatinized；By sodium hypochlorite, hydrogen peroxide and potassium permanganate by 5 10 times of water dissolves, stirred 5 20 minutes in addition reactor；By hard and infertile alkali with 35 times of cold-water solutions, add in reactor, stir 20 40 minutes；By borax and defoamer with 6 10 times of dissolved in boiled water addition reactors, stir 35 minutes, then stand 24 minutes；Stirred during strong catalyst is added into reactor.Recipe of the invention is novel, and cost of material is low, and the production time is short, binding agent quality.
Description
Technical field：
The present invention relates to field of packaging material, and in particular to a kind of utilization cornstarch makes corrugation adhesive for paper
Method.
Background technology：
Packing board is the general name of the cardboard for Gong being packed for.Including white board, yellow plate paper, kraft liner, corrugated board etc..
It is general to require that there is tough folding strength and good bendability.It is raw material by timber, rice wheat straw etc., using distinct methods system
Slurry, manufactures paper with pulp on lap machine and forms.It is mainly used in packing carton processed, also serves as packaging material or printing material etc..Packing board
With lightweight, facilitate the characteristics of, but its low intensity, easily cracking, the poor-performing of waterproof.What but existing starch made
The method of board pasted additive is relatively simple, and the time needed for production is long, and operation is unreasonable, causes the quality of starch adesive
It is poor.
The content of the invention：
The technical problems to be solved by the invention are that a kind of offer production time is short, the measured utilization corn of binding agent matter
The method that starch makes corrugation adhesive for paper.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of method that utilization cornstarch makes corrugation adhesive for paper, it is characterised in that：Comprise the following steps,
1), raw material prepares, and raw material each component content is calculated as by weight：Cornstarch：180-220 parts, hard and infertile alkali：20-
24 parts, strong catalyst：8-10 parts, borax：4-7 parts, defoamer：3-7 parts, sodium hypochlorite 30-36 parts, water:900-1100 parts,
Industrial grade hydrogen peroxide:2-4 parts, potassium permanganate:1-3 parts；
2) water, is added in a kettle., 60-70 DEG C is heated to, then adds cornstarch to stir 3-5 minutes pasted
Change；
3) sodium hypochlorite, hydrogen peroxide and potassium permanganate, are stirred into 5-20 by 5-10 times of water dissolves in addition reactor
Minute；
4), hard and infertile alkali is added in reactor with 3-5 times of cold-water solution, is stirred 20-40 minutes；
5), borax and defoamer are stirred 3-5 minutes with 6-10 times of dissolved in boiled water addition reactor, 2-4 is then stood
Minute；
6) stirred during strong catalyst, is added into reactor.
It is preferred that described raw material each component content is calculated as by weight：Starch：200 parts, hard and infertile alkali：22 parts, strong catalysis
Agent：9 parts, borax：6 parts, defoamer：5 parts, 33 parts of sodium hypochlorite, water:1000 parts, industrial grade hydrogen peroxide:3 parts, potassium permanganate:2
Part.
The purity of described caustic soda is more than 95%.
Described strong catalyst includes following components, benzoyl peroxide 2-3 parts, Firebrake ZB 3-5 parts, cyanogen by weight
Change 1-2 parts and calcium stearate 10-20 parts of potassium.
It is preferred that described strong catalyst by weight include following components, 2.5 parts of benzoyl peroxide, 4 parts of Firebrake ZB,
15 parts of 1.5 parts of potassium cyanide and calcium stearate.
Described defoamer includes following components, tributyl phosphate 5-6 parts, polyimides 2-4 parts, diphenyl by weight
Silicon diol 3-4 parts and petroleum sodium sulfonate 1-3 parts.
The present invention is specially gelatinized to cornstarch, is conducive to improving the viscosity of binding agent, and defoamer is together with borax
Mixing is added, and is conducive to shortening the time for producing, the production efficiency of raising, is first to have carried out the reaction of froth breaking then in the present invention
In the strong catalyst of addition, and strong catalyst froth breaking again is first added in the prior art, the effect of froth breaking can be caused poor, therefore this
Invention can improve the effect of froth breaking, it is also possible to shorten the time of froth breaking.
The beneficial effects of the invention are as follows：Recipe of the invention is novel, and cost of material is low, and the production time is short, binding agent
Quality.
Specific embodiment：
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Specific example is closed, the present invention is expanded on further.
Embodiment 1：A kind of method that utilization cornstarch makes corrugation adhesive for paper,
1), raw material prepares, and raw material each component content is calculated as by weight：Cornstarch：180 parts, hard and infertile alkali：20 parts, by force
Solid catalyst：8 parts, borax：4 parts, defoamer：3 parts, 30 parts of sodium hypochlorite, water:900 parts, industrial grade hydrogen peroxide:2 parts, Gao Meng
Sour potassium:1 part；
2) water, is added in a kettle., 60 DEG C are heated to, then adds cornstarch to stir 3 minutes be gelatinized；
3), sodium hypochlorite, hydrogen peroxide and potassium permanganate are stirred 5 minutes by 5 times of water dissolves in addition reactor；
4), hard and infertile alkali is added in reactor with 3 times of cold-water solutions, is stirred 20 minutes；
5), borax and defoamer are stirred 3 minutes with 6 times of dissolved in boiled water addition reactors, then 2 minutes is stood；
6) stirred during strong catalyst, is added into reactor.
The purity of caustic soda is more than 95%.
Strong catalyst by weight include following components, 2 parts of benzoyl peroxide, 3 parts of Firebrake ZB, 1 part of potassium cyanide and
10 parts of calcium stearate.
Defoamer includes following components, 5 parts of tributyl phosphate, 2 parts of polyimides, 3 parts of diphenyl silanediol by weight
With 1 part of petroleum sodium sulfonate.
Embodiment 2：
A kind of method that utilization cornstarch makes corrugation adhesive for paper, comprises the following steps,
1), raw material prepares, and raw material each component content is calculated as by weight：Starch：200 parts, hard and infertile alkali：It is 22 parts, strong to urge
Agent：9 parts, borax：6 parts, defoamer：5 parts, 33 parts of sodium hypochlorite, water:1000 parts, industrial grade hydrogen peroxide:3 parts, permanganic acid
Potassium:2 parts.
2) water, is added in a kettle., 65 DEG C are heated to, then adds cornstarch to stir 4 minutes be gelatinized；
3), sodium hypochlorite, hydrogen peroxide and potassium permanganate are stirred 12 minutes by 7 times of water dissolves in addition reactor；
4), hard and infertile alkali is added in reactor with 4 times of cold-water solutions, is stirred 30 minutes；
5), borax and defoamer are stirred 4 minutes with 8 times of dissolved in boiled water addition reactors, then 3 minutes is stood；
6) stirred during strong catalyst, is added into reactor.
The purity of caustic soda is more than 95%.
Strong catalyst includes following components, 2.5 parts of benzoyl peroxide, 4 parts of Firebrake ZB, potassium cyanide 1.5 by weight
15 parts of part and calcium stearate.
Defoamer includes following components, 5.5 parts of tributyl phosphate, 3 parts of polyimides, diphenyl silanediol by weight
3.5 parts and 2 parts of petroleum sodium sulfonate.
Embodiment 3：
A kind of method that utilization cornstarch makes corrugation adhesive for paper, comprises the following steps,
1), raw material prepares, and raw material each component content is calculated as by weight：Cornstarch：220 parts, hard and infertile alkali：24 parts, by force
Solid catalyst：10 parts, borax：7 parts, defoamer：7 parts, 36 parts of sodium hypochlorite, water:1100 parts, industrial grade hydrogen peroxide:It is 4 parts, high
Potassium manganate:3 parts；
2) water, is added in a kettle., 70 DEG C are heated to, then adds cornstarch to stir 5 minutes be gelatinized；
3) sodium hypochlorite, hydrogen peroxide and potassium permanganate, are added into 20 points of stirring in reactor by 10 times of water dissolves
Clock；
4), hard and infertile alkali is added in reactor with 5 times of cold-water solutions, is stirred 40 minutes；
5), borax and defoamer are stirred 5 minutes with 10 times of dissolved in boiled water addition reactors, then 4 minutes is stood；
6) stirred during strong catalyst, is added into reactor.
The purity of caustic soda is more than 95%.
Strong catalyst by weight include following components, 3 parts of benzoyl peroxide, 5 parts of Firebrake ZB, 2 parts of potassium cyanide and
20 parts of calcium stearate.
Defoamer includes following components, 6 parts of tributyl phosphate, 4 parts of polyimides, 4 parts of diphenyl silanediol by weight
With 3 parts of petroleum sodium sulfonate.
General principle of the invention and principal character and advantages of the present invention has been shown and described above.The technology of the industry
Personnel it should be appreciated that the present invention is not limited to the above embodiments, simply explanation described in above-described embodiment and specification this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appending claims and its
Equivalent thereof.
Claims (6)
1. a kind of method that utilization cornstarch makes corrugation adhesive for paper, it is characterised in that：Comprise the following steps,
1), raw material prepares, and raw material each component content is calculated as by weight：Cornstarch：180-220 parts, hard and infertile alkali：20-24 parts,
Strong catalyst：8-10 parts, borax：4-7 parts, defoamer：3-7 parts, sodium hypochlorite 30-36 parts, water:900-1100 parts, industry
Grade hydrogen peroxide:2-4 parts, potassium permanganate:1-3 parts；
2) water, is added in a kettle., 60-70 DEG C is heated to, then adds cornstarch to stir 3-5 minutes be gelatinized；
3) sodium hypochlorite, hydrogen peroxide and potassium permanganate, are added into 5-20 points of stirring in reactor by 5-10 times of water dissolves
Clock；
4), hard and infertile alkali is added in reactor with 3-5 times of cold-water solution, is stirred 20-40 minutes；
5), borax and defoamer are stirred 3-5 minutes with 6-10 times of dissolved in boiled water addition reactor, 2-4 points is then stood
Clock；
6) stirred during strong catalyst, is added into reactor.
2. the method that a kind of utilization cornstarch according to claim 1 makes corrugation adhesive for paper, it is characterised in that：Institute
The raw material each component content stated is calculated as by weight：Starch：200 parts, hard and infertile alkali：22 parts, strong catalyst：9 parts, borax：6
Part, defoamer：5 parts, 33 parts of sodium hypochlorite, water:1000 parts, industrial grade hydrogen peroxide:3 parts, potassium permanganate:2 parts.
3. the method that a kind of utilization cornstarch according to claim 1 makes corrugation adhesive for paper, it is characterised in that：Institute
The purity of the caustic soda stated is more than 95%.
4. the method that a kind of utilization cornstarch according to claim 1 makes corrugation adhesive for paper, it is characterised in that：Institute
The strong catalyst stated includes following components, benzoyl peroxide 2-3 parts, Firebrake ZB 3-5 parts, potassium cyanide 1-2 parts by weight
With calcium stearate 10-20 parts.
5. the method that a kind of utilization cornstarch according to claim 4 makes corrugation adhesive for paper, it is characterised in that：Institute
The strong catalyst stated by weight include following components, 2.5 parts of benzoyl peroxide, 4 parts of Firebrake ZB, 1.5 parts of potassium cyanide and
15 parts of calcium stearate.
6. the method that a kind of utilization cornstarch according to claim 1 makes corrugation adhesive for paper, it is characterised in that：Institute
The defoamer stated includes following components, tributyl phosphate 5-6 parts, polyimides 2-4 parts, diphenyl silanediol 3-4 by weight
Part and petroleum sodium sulfonate 1-3 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710102790.8A CN106753038A (en) | 2017-02-24 | 2017-02-24 | A kind of method that utilization cornstarch makes corrugation adhesive for paper |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710102790.8A CN106753038A (en) | 2017-02-24 | 2017-02-24 | A kind of method that utilization cornstarch makes corrugation adhesive for paper |
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| CN106753038A true CN106753038A (en) | 2017-05-31 |
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| CN201710102790.8A Pending CN106753038A (en) | 2017-02-24 | 2017-02-24 | A kind of method that utilization cornstarch makes corrugation adhesive for paper |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502225A (en) * | 2017-09-18 | 2017-12-22 | 广西师范学院 | Preparation method for the adhesive of corrugated paper |
| CN107523232A (en) * | 2017-08-22 | 2017-12-29 | 安徽杰可森木业科技有限公司 | A kind of poplar makes binding agent of pencil and preparation method thereof |
| CN108049235A (en) * | 2017-11-25 | 2018-05-18 | 蚌埠申徽彩色印刷包装有限公司 | A kind of high-strength corrugated board |
| CN115537147A (en) * | 2022-09-27 | 2022-12-30 | 台州金卡达科技股份有限公司 | Preparation method of corrugated paper adhesive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0590161A1 (en) * | 1991-08-29 | 1994-04-06 | National Starch and Chemical Investment Holding Corporation | Alkaline corrugating adhesive composition |
| CN1528849A (en) * | 2003-10-15 | 2004-09-15 | 西安交通大学 | Method for preparing rapid-dry corn starch adhesive |
| CN101892022A (en) * | 2010-07-09 | 2010-11-24 | 贵州外贸神彩包装有限责任公司 | Starch adhesive for producing corrugated board and preparation method thereof |
-
2017
- 2017-02-24 CN CN201710102790.8A patent/CN106753038A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0590161A1 (en) * | 1991-08-29 | 1994-04-06 | National Starch and Chemical Investment Holding Corporation | Alkaline corrugating adhesive composition |
| CN1528849A (en) * | 2003-10-15 | 2004-09-15 | 西安交通大学 | Method for preparing rapid-dry corn starch adhesive |
| CN101892022A (en) * | 2010-07-09 | 2010-11-24 | 贵州外贸神彩包装有限责任公司 | Starch adhesive for producing corrugated board and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 陈永常: "《瓦楞纸箱的印刷与成型》", 31 January 2005, 化学工业出版社 * |
| 陈港等: "《现代纸容器》", 31 October 2002, 化学工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107523232A (en) * | 2017-08-22 | 2017-12-29 | 安徽杰可森木业科技有限公司 | A kind of poplar makes binding agent of pencil and preparation method thereof |
| CN107502225A (en) * | 2017-09-18 | 2017-12-22 | 广西师范学院 | Preparation method for the adhesive of corrugated paper |
| CN107502225B (en) * | 2017-09-18 | 2019-04-02 | 广西师范学院 | The preparation method of adhesive for corrugated paper |
| CN108049235A (en) * | 2017-11-25 | 2018-05-18 | 蚌埠申徽彩色印刷包装有限公司 | A kind of high-strength corrugated board |
| CN115537147A (en) * | 2022-09-27 | 2022-12-30 | 台州金卡达科技股份有限公司 | Preparation method of corrugated paper adhesive |
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Application publication date: 20170531 |