CN106752895A - A kind of self-lubricating renovation agent and preparation method thereof - Google Patents
A kind of self-lubricating renovation agent and preparation method thereof Download PDFInfo
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- CN106752895A CN106752895A CN201710033164.8A CN201710033164A CN106752895A CN 106752895 A CN106752895 A CN 106752895A CN 201710033164 A CN201710033164 A CN 201710033164A CN 106752895 A CN106752895 A CN 106752895A
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- Prior art keywords
- lubricating
- self
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- polyimides
- powder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C09D179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/16—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of self-lubricating renovation agent, including following main component:Vinyl polysilazane resin, aluminium powder, zinc powder, Graphene, polyimides, curing agent and solvent;Add Graphene; and by itself and vinyl polysilazane resin, the common powder ball milling of polyimides; vinyl polysilazane resin, polyimides are dispersed in graphenic surface; crosslinking is so controlled in film forming procedure is sprayed; film forming physical and mechanical properties is more excellent; glossiness, guarantor's light unfading are good, can quickly repair the protective coating that object surface is damaged, and product is small to environmental danger.
Description
Technical field
The present invention relates to protective coating recovery technique field, more particularly to a kind of self-lubricating healant.
Background technology
Object exposure is susceptible to oxidation in atmosphere, often increases by one layer of protective coating using in object surface.Zinc and
Aluminium aoxidizes generation one layer of diaphragm of densification --- zinc oxide and aluminum oxide in atmosphere, so often selecting zinc in the prior art
With aluminium as the protective coating of object surface to prevent object from being oxidized, blue white zine is often further selected during plating
Used as protective coating, the local damage of object surface often results in protective coating failure, causes object metal in itself local rotten
Erosion or plastics local ageing etc., object are difficult to keep attractive in appearance, therefore the protective coating to object surface safeguards particularly significant in time.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of self-lubricating renovation agent and preparation method thereof.
Technical scheme is as follows:
A kind of self-lubricating renovation agent, including following percentage by weight main component:
Vinyl polysilazane resin 12-20%;
Aluminium powder 8-15%
Zinc powder 10-20%
Graphene 0.03-0.05%
Polyimides 15-25%
Curing agent 3-5%
Balance of solvent.
Preferably, described curing agent is diethylenetriamine.
Preferably, the particle diameter of described aluminium powder and zinc powder is 250 mesh.
Preferably, described solvent is the mixture of ethyl acetate and DMF.
A kind of self-lubricating renovation agent and preparation method thereof, comprises the following steps:
A, vinyl polysilazane resin, polyimides and Graphene are carried out powder ball milling, cross 250 mesh sieves;
B, above-mentioned raw materials are dissolved in solvent and aluminium powder is added and zinc powder, be uniformly dispersed;
C, when using, curing agent is added in above-mentioned raw materials, after being well mixed.
The present invention is advantageous in that:Add Graphene in the present invention, and by it with vinyl polysilazane resin, it is poly-
The common powder ball milling of acid imide, graphenic surface is dispersed in by vinyl polysilazane resin, polyimides, so in spray
Control crosslinking in film forming procedure is applied, film forming physical and mechanical properties is more excellent, and glossiness, guarantor's light unfading are good, can quickly repair
The protective coating that object surface is damaged, product is small to environmental danger.
Specific embodiment
Embodiment 1:
A kind of self-lubricating renovation agent, including following percentage by weight main component:
Vinyl polysilazane resin 18%;
Aluminium powder 12%
Zinc powder 15%
Graphene 0.05%
Polyimides 22%
Curing agent 3.5%
Balance of solvent.
Described curing agent is diethylenetriamine.
Described aluminium powder and the particle diameter of zinc powder are 250 mesh.
Described solvent is the mixture of ethyl acetate and DMF, ethyl acetate and N, N- dimethyl methyl
The mass ratio of acid amides is 2:1.
A kind of self-lubricating renovation agent and preparation method thereof, comprises the following steps:
A, vinyl polysilazane resin, polyimides and Graphene are carried out powder ball milling, cross 250 mesh sieves;
B, above-mentioned raw materials are dissolved in solvent and aluminium powder is added and zinc powder, be uniformly dispersed;
C, when using, curing agent is added in above-mentioned raw materials, after being well mixed.
Embodiment 2:
A kind of self-lubricating renovation agent, including following percentage by weight main component:
Vinyl polysilazane resin 20%;
Aluminium powder 8%
Zinc powder 20%
Graphene 0.03%
Polyimides 15%
Curing agent 5%
Balance of solvent.
Described curing agent is diethylenetriamine.
Described aluminium powder and the particle diameter of zinc powder are 250 mesh.
Described solvent is the mixture of ethyl acetate and DMF, ethyl acetate and N, N- dimethyl methyl
The mass ratio of acid amides is 3:1.
A kind of self-lubricating renovation agent and preparation method thereof, comprises the following steps:
A, vinyl polysilazane resin, polyimides and Graphene are carried out powder ball milling, cross 250 mesh sieves;
B, above-mentioned raw materials are dissolved in solvent and aluminium powder is added and zinc powder, be uniformly dispersed;
C, when using, curing agent is added in above-mentioned raw materials, after being well mixed.
Embodiment 3:
A kind of self-lubricating renovation agent, including following percentage by weight main component:
Vinyl polysilazane resin 12%;
Aluminium powder 15%
Zinc powder 10%
Graphene 0.05%
Polyimides 25%
Curing agent 3%
Balance of solvent.
Described curing agent is diethylenetriamine.
Described aluminium powder and the particle diameter of zinc powder are 250 mesh.
Described solvent is the mixture of ethyl acetate and DMF, ethyl acetate and N, N- dimethyl methyl
The mass ratio of acid amides is 3:2.
A kind of self-lubricating renovation agent and preparation method thereof, comprises the following steps:
A, vinyl polysilazane resin, polyimides and Graphene are carried out powder ball milling, cross 250 mesh sieves;
B, above-mentioned raw materials are dissolved in solvent and aluminium powder is added and zinc powder, be uniformly dispersed;
C, when using, curing agent is added in above-mentioned raw materials, after being well mixed.
Self-lubricating healant described in embodiment 1-3 is carried out into performance test, test result is as follows:
Test event | Testing standard | Embodiment 1-3 test result average values | Examination criteria |
Resistance to neutral salt spray(480h) | There is not damage phenomenon except scoring position in formula plate | It is qualified | GB/T 1771-2007 |
Coating film gloss | ≥90% | 96.9% | GB9754-88 |
Heat endurance | Divide oil reservoir≤25 | Divide oil reservoir=17 | API RP5A3 |
Salt spray test | A grades | A grades | SH/T 0081-91 |
Damp heat test | A grades | A grades | GB/T 2361-92 |
PH value | 8-10 | 9.1 | / |
Wherein coating film gloss degree is 60 ° of testing results, and heat stability test condition is 24h, 138 DEG C;Degree of corrosion testing conditions are
100 DEG C, 24h;Salt spray test testing conditions are 5%NaCl, 35 DEG C ± 1 DEG C, 45 steel prints, 7 days;Damp heat test testing conditions are
49 DEG C, 45 steel prints, 45 days.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (5)
1. a kind of self-lubricating renovation agent and preparation method thereof, it is characterised in that the main component including following percentage by weight:
Vinyl polysilazane resin 12-20%;
Aluminium powder 8-15%
Zinc powder 10-20%
Graphene 0.03-0.05%
Polyimides 15-25%
Curing agent 3-5%
Balance of solvent.
2. self-lubricating renovation agent as claimed in claim 1 and preparation method thereof, it is characterised in that described curing agent is diethyl
Alkene triamine.
3. self-lubricating renovation agent as claimed in claim 1 and preparation method thereof, it is characterised in that described aluminium powder and zinc powder
Particle diameter is 250 mesh.
4. self-lubricating renovation agent as claimed in claim 1 and preparation method thereof, it is characterised in that described solvent is acetic acid second
The mixture of ester and N,N-dimethylformamide.
5. a kind of self-lubricating renovation agent and preparation method thereof, it is characterised in that comprise the following steps:
A, vinyl polysilazane resin, polyimides and Graphene are carried out powder ball milling, cross 250 mesh sieves;
B, above-mentioned raw materials are dissolved in solvent and aluminium powder is added and zinc powder, be uniformly dispersed;
C, when using, curing agent is added in above-mentioned raw materials, after being well mixed.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106997845A (en) * | 2016-01-19 | 2017-08-01 | 财团法人工业技术研究院 | Flexible substrate repairing structure, manufacturing method and detection repairing method |
CN110982428A (en) * | 2019-10-12 | 2020-04-10 | 韶关市中广测协同创新技术有限公司 | Zinc-aluminum anticorrosive paint based on polysilazane |
IT201900008193A1 (en) * | 2019-06-06 | 2020-12-06 | Antonio Andreino Remo Barbieri | METHOD FOR THE PRODUCTION OF AN ANTIFOULING PAINT AND ANTIFOULING PAINT SO OBTAINED |
Citations (4)
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CN102728989A (en) * | 2012-06-02 | 2012-10-17 | 安徽国通高新管业股份有限公司 | Repairing process of pits on forming mold |
CN104387078A (en) * | 2014-10-22 | 2015-03-04 | 华文蔚 | SiBCN composite material and preparation method thereof |
CN104530966A (en) * | 2014-12-26 | 2015-04-22 | 上海大学 | Graphene-doped high-temperature-resistant organic anticorrosive paint and preparation method thereof |
CN105462414A (en) * | 2014-08-27 | 2016-04-06 | 天长市高新技术创业服务中心 | Metal mending agent |
-
2017
- 2017-01-18 CN CN201710033164.8A patent/CN106752895A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102728989A (en) * | 2012-06-02 | 2012-10-17 | 安徽国通高新管业股份有限公司 | Repairing process of pits on forming mold |
CN105462414A (en) * | 2014-08-27 | 2016-04-06 | 天长市高新技术创业服务中心 | Metal mending agent |
CN104387078A (en) * | 2014-10-22 | 2015-03-04 | 华文蔚 | SiBCN composite material and preparation method thereof |
CN104530966A (en) * | 2014-12-26 | 2015-04-22 | 上海大学 | Graphene-doped high-temperature-resistant organic anticorrosive paint and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106997845A (en) * | 2016-01-19 | 2017-08-01 | 财团法人工业技术研究院 | Flexible substrate repairing structure, manufacturing method and detection repairing method |
IT201900008193A1 (en) * | 2019-06-06 | 2020-12-06 | Antonio Andreino Remo Barbieri | METHOD FOR THE PRODUCTION OF AN ANTIFOULING PAINT AND ANTIFOULING PAINT SO OBTAINED |
CN110982428A (en) * | 2019-10-12 | 2020-04-10 | 韶关市中广测协同创新技术有限公司 | Zinc-aluminum anticorrosive paint based on polysilazane |
CN110982428B (en) * | 2019-10-12 | 2021-12-07 | 韶关市中广测协同创新技术有限公司 | Zinc-aluminum anticorrosive paint based on polysilazane |
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Application publication date: 20170531 |